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9051-49-4 139-90-2 102-60-3 77-58-7

File Name: 9051-49-4_139-90-2_102-60-3_77-58.asp

SAFETY DATA SHEET
according to applicable EC directive


Ident-No: RENPIM-VG 5287 POLYOL
Version 1 Print Date 07.07.2007
Revision Date 04.07.2007

1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND THE
COMPANY/UNDERTAKING

Product information
Trade name : RENPIM-VG 5287 POLYOL

Use : Polyol component for tooling systems

Company : Huntsman Advanced Materials (Europe)BVBA
Everslaan 45
3078 Everberg / Belgium
Telephone : +41619661599
Telefax : +41619661589
Emergency telephone : +41 61 966 40 00 (in France ORFILA : +33(0)145425959)
number

2. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical nature
Formulated polyol
preparation

Hazardous components
Chemical Name CAS-No. Symbol(s): R-phrase(s) Concentration [%]
pentaerythritol,-propoxylated- 9051-49-4 Xi R36/38 48.00 - 60.00
1,1'-(2-(N-2-hydroxyethyl-2- 139-90-2 Xi R36 20.00 - 28.00
hydroxypropylamino)ethylimin
o)dipropan-2-ol
EC-No.: 205-382-4
1,1',1'',1'''- 102-60-3 Xi R36/37/38 20.00 - 28.00
ethylenedinitrilotetrapropan-2-
ol-
EC-No.: 203-041-4
dibutyltin dilaurate 77-58-7 Xn, N R36/38 R48/22 R50/53 < 7.00
EC-No.: 201-039-8

3. HAZARDS IDENTIFICATION

Irritating to eyes, respiratory system and skin.
Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.


4. FIRST AID MEASURES

Inhalation : Move to fresh air.
Call a physician immediately.

Eye contact : Rinse immediately with plenty of water for at least 15 minutes.
If eye irritation persists, consult a specialist.

Skin contact : Wash off immediately with soap and plenty of water.
If skin irritation persists, call a physician.



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SAFETY DATA SHEET
according to applicable EC directive


Ident-No: RENPIM-VG 5287 POLYOL
Version 1 Print Date 07.07.2007
Revision Date 04.07.2007


Ingestion : Immediately give plenty of water (if possible charcoal slurry).
Do not induce vomiting.
Obtain medical attention.



5. FIRE-FIGHTING MEASURES

Suitable extinguishing : Water spray.
media Carbon dioxide (CO2).
Foam.
Dry powder.

Extinguishing media which : High volume water jet.
must not be used for safety
reasons
Special protective : Wear self-contained breathing apparatus and protective suit.
equipment for fire-fighters
Further information : Burning produces obnoxious and toxic fumes.
Carbon oxides.
Nitrogen oxides.



6. ACCIDENTAL RELEASE MEASURES

Personal precautions : Keep away from sources of ignition - No smoking.
Do not breathe vapours/dust.
Avoid contact with skin, eyes and clothing.

Environmental precautions : Prevent product from entering drains.
Avoid subsoil penetration.
Do not contaminate surface water.

Methods for cleaning up : Soak up with inert absorbent material and dispose of as
hazardous waste.


7. HANDLING AND STORAGE
Handling
Advice on safe handling : Provide sufficient air exchange and/or exhaust in work rooms.
Handle and open container with care.


Storage
Further information on : Keep away from food, drink and animal feeding stuffs.
storage conditions Keep container tightly closed.
Keep at temperatures between 2 and 40癈.

Storage hazard class : Storage class 12, Liquids, not dangerous
Huntsman Advanced
Materials


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SAFETY DATA SHEET
according to applicable EC directive


Ident-No: RENPIM-VG 5287 POLYOL
Version 1 Print Date 07.07.2007
Revision Date 04.07.2007


8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Components with workplace control parameters
Components CAS-No. Control Update Basis
parameters

Engineering measures
Ensure adequate ventilation, especially in confined areas.

Personal protective equipment
Respiratory protection : In case of insufficient ventilation wear suitable respiratory
equipment.
Filter type AX-P2 (organic vapours, particles)

Eye protection : Tightly fitting safety goggles.

Hand protection : Material of gloves for long term application (BTT>480 min):
Butyl rubber
Ethyl Vinyl Alcohol Laminate (EVAL)
Material of gloves for short term/splash application (10
min Nitrile rubber
Use gloves approved to relevant standards e.g. EN 374
(Europe), F739 (US).
Suitability and durability of a glove is dependent on usage, e.g.
frequency and duration of contact, chemical resistance of glove
material and dexterity. Always seek advice from glove
suppliers.
Additonal information can be found for instance at
www.gisbau.de

Skin and body protection : long sleeved clothing

Hygiene measures : Keep away from food, drink and animal feeding stuffs.
Wash hands before breaks and immediately after handling the
product.

Protective measures : Keep away from sources of ignition - No smoking.
Avoid contact with skin, eyes and clothing.
Do not breathe vapours/dust.


9. PHYSICAL AND CHEMICAL PROPERTIES

Form : liquid

Colour : light blue
clear

Odour : slight

Thermal decomposition : > 150 癈



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SAFETY DATA SHEET
according to applicable EC directive


Ident-No: RENPIM-VG 5287 POLYOL
Version 1 Print Date 07.07.2007
Revision Date 04.07.2007

Method: estimated

Flash point : > 180 癈
Method: Data based on tests on similar product.

Density : 1.09 g/cm3
at 25 癈

Water solubility : at 20 癈
Note: partly soluble

Miscibility with water : immiscible
at 20 癈

Viscosity, dynamic : 3,500 - 4,500 mPa.s
at 25 癈
Method: ISO 2555


10. STABILITY AND REACTIVITY

Conditions to avoid : Note: Take necessary action to avoid static electricity
discharge.

Materials to avoid : Strong acids and strong bases.
Strong oxidizing agents.

Hazardous decomposition : Burning produces obnoxious and toxic fumes.
products Carbon oxides.
nitrogen oxides (NOx)


11. TOXICOLOGICAL INFORMATION

Acute oral toxicity : LD50 rat
Dose: > 2,000 mg/kg

Eye irritation : Irritating to eyes.
rabbit

Skin irritation : Irritating to skin.
rabbit
dermal

Sensitization : No skin sensitization.
guinea pig
dermal


12. ECOLOGICAL INFORMATION

Ecotoxicity effects




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SAFETY DATA SHEET
according to applicable EC directive


Ident-No: RENPIM-VG 5287 POLYOL
Version 1 Print Date 07.07.2007
Revision Date 04.07.2007

Further information on ecology
Additional ecological : Avoid subsoil penetration.
information Prevent product from entering drains.
Do not contaminate surface water.


13. DISPOSAL CONSIDERATIONS

Product : Waste Key Number: 070208
Must be incinerated, when in compliance with local regulations.

Container : Empty containers can be landfilled after cleaning, when in
compliance with the Environmental Protection (Duty of Care)
Regulations 1991.


14. TRANSPORT INFORMATION
Land transport

ADR:
Regulation: Not dangerous goods

RID:
Regulation: Not dangerous goods

Sea transport

IMDG:
Regulation: Not dangerous goods


Air transport

IATA-DGR:
Regulation: Not dangerous goods

15. REGULATORY INFORMATION
Labelling according to EEC Directive
Labelling required

Symbol(s): : Xi Irritant


R-phrase(s) : R36/37/38 Irritating to eyes, respiratory system and
skin.
R52/53 Harmful to aquatic organisms, may cause
long-term adverse effects in the aquatic
environment.


5/7
SAFETY DATA SHEET
according to applicable EC directive


Ident-No: RENPIM-VG 5287 POLYOL
Version 1 Print Date 07.07.2007
Revision Date 04.07.2007



S-phrase(s) : S24/25 Avoid contact with skin and eyes.
S26 In case of contact with eyes, rinse
immediately with plenty of water and seek
medical advice.
S37/39 Wear suitable gloves and eye/face
protection.
S61 Avoid release to the environment. Refer to
special instructions/safety data sheets.


Hazardous components : dibutyltin dilaurate
which must be listed on the EC-No.: 201-039-8
label
1,1',1'',1'''-ethylenedinitrilotetrapropan-2-ol-
EC-No.: 203-041-4


National legislation



Notification status

: EINECS yes
The formulation contains ELINCS substances.


: TSCA yes


: DSL yes


: AICS yes



16. OTHER INFORMATION
List of R-phrases (Section 2)

R36 Irritating to eyes.
R36/37/38 Irritating to eyes, respiratory system and skin.
R36/38 Irritating to eyes and skin.
R48/22 Harmful: danger of serious damage to health by prolonged exposure if
swallowed.
R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in
the aquatic environment.




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SAFETY DATA SHEET
according to applicable EC directive


Ident-No: RENPIM-VG 5287 POLYOL
Version 1 Print Date 07.07.2007
Revision Date 04.07.2007

The provision of Safety Data Sheets comes under Regulation 6 of CHIP (CHIP is the recognised
abbreviation for the Chemicals Hazard Information and Packaging Regulations). This is an addition
to the Health and Safety at Work Act 1974.Users of products supplied by Huntsman Advanced
Materials should take appropriate measures to ensure working practices are in accordance with the
Control of Substances Hazardous to Health Regulations (COSHH).
All information is based on results gained from experience and tests and is believed to be accurate
but is given without acceptance of liability for loss or damage attributable to reliance thereon as
conditions of use lie outside our control. Users should always carry out sufficient tests to establish
the suitability of any products for their intended applications. No statements shall be incorporated in
any contract unless expressly agreed in writing nor construed as recommending the use of any
product in conflict of any patent. All goods are supplied subject to Huntsman Advanced Materials
General Conditions of Sale.




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