Spal-Pro 2000 "A" Page 1 of 6
MATERIAL SAFETY DATA SHEET
SPAL-PRO 2000 "A"
1. PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: Spal-Pro 2000 "A"
PRODUCT DESCRIPTION: Polyol part of a two-component poured polyurethane elastomer
MANUFACTURED BY 24 HOUR EMERGENCY TELEPHONE NUMBER
Metzger McGuire Co., Inc. Chemtrec: 800-424-9300
557 Route 3-A
Bow, NH 03304
800-223-6680 www. metzgermcguire.com
2. COMPOSITION / INFORMATION ON INGREDIENTS
Chemical Name Wt.% CAS
6-Methyl-2,4-Bis(Methylthio)Phenylene-1,3-Diamine 10-15 106264-79-3
N,N,N',N'-Tetrakis(2-Hydroxylpropyl)Ethylenediamine <= 10 102-60-3
Polyether Polyol 75-85 9082-00-2
3. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
PHYSICAL APPEARANCE: Various colors, including but not limited to: Gray, Black, Brown,
Cream.
IMMEDIATE CONCERNS: Irritating to eyes, skin, gastrointestinal tract, and respiratory system.
POTENTIAL HEALTH EFFECTS
EYES: May cause moderate irritation.
SKIN: May cause mild to moderate irritation.
INGESTION: Ingestion may cause irritation of the gastrointestinal tract and gastrointestinal
discomfort with any or all of the following symptoms: nausea, vomiting, lethargy, or diarrhea.
INHALATION: Inhalation of vapors or mist at concentrations above the TLV can cause
respiratory tract irritation. (nose, throat, lungs)
SIGNS AND SYMPTOMS OF OVEREXPOSURE
EYES: Contact may cause moderate irritation consisting of transient redness, swelling, and
mucous membrane discharge to the conjunctiva.
SKIN: Contact may cause mild irritation consisting of transient redness and/or swelling.
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INGESTION: Ingestion may cause gastrointestinal discomfort.
INHALATION: High concentrations may be irritating to in nose, throat, and lungs.
ROUTES OF ENTRY: Inhalation, skin contact, eye contact, ingestion.
4. FIRST AID MEASURES
EYES: Immediately flush eyes with plenty of water for at least 15 minutes, lifting upper and lower
eyelids occasionally. Get immediate medical attention.
SKIN: Remove contaminated clothing. Wash affected areas thoroughly with soap and water. Wash
clothing thoroughly before reuse. Discard shoes. Get medical attention if swelling or redness
occurs, or if irritation persists after being washed.
INGESTION: Do not induce vomiting. Never give anything by mouth to a drowsy or unconscious
person. If the individual is conscious, rinse mouth with water. Give 1 to 2 cups of water to drink.
Seek immediate medical attention.
INHALATION: Remove individual from exposure, keep warm and at rest. If respiratory irritation
develops, get medical attention.
5. FIRE FIGHTING MEASURES
FLASHPOINT AND METHOD: > 300 oF (Closed Cup)
EXTINGUISHING MEDIA: Dry Chemical, Carbon Dioxide, Alcohol Foam, Water Fog or Spray.
Water or foam may cause frothing if liquid is burning, but it still may be a useful extinguishing
agent if carefully applied to the fire.
HAZARDOUS COMBUSTION PRODUCTS: Carbon Monoxide, Carbon Dioxide
FIRE FIGHTING PROCEDURES: Isolate fuel supply from fire. Use water spray to cool fire-
exposed surfaces and containers. Avoid spreading burning liquid with water used for cooling
purposes. Fire fighters should wear self-contained breathing apparatus in addition to emergency
fire fighting protective clothing.
6. ACCIDENTAL RELEASE MEASURES
SMALL SPILL: Clean up spills wearing proper personal protective equipment. (See section 8)
Absorb with dry chemical absorbent, earth, sand, or any other inert material. Place in a chemical
waste container.
LARGE SPILL: Create a dike or trench to contain materials. Prevent entry into waterways, sewers,
basements or confined areas. Clean-up personnel should wear appropriate personal protection
equipment. (see section 8) May be a slipping hazard. Absorb with dry chemical absorbent, earth,
sand, or any other inert material. Place in a chemical waste container. Wash residues from area
with soap and water and rinse. Contaminated water should be retained and not allowed to flow
into ground or surface water.
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ENVIRONMENTAL PRECAUTIONS: This product is a marine pollutant.
SPECIAL PROTECTIVE EQUIPMENT: See Section 8. Clean-up crews should always wear
Personal Protective Equipment.
COMMENT: Dispose of by any standard method of disposal in accordance with good industrial
practice and in compliance with federal, state, and local environmental protection regulations.
7. HANDLING AND STORAGE
HANDLING: Wear proper personal protective equipment. Use in a well ventilated area. Avoid
smoking, bare lights, or ignition sources. Avoid physical damage to containers. Practice good
hygiene procedures.
STORAGE: Protect from atmospheric moisture. Keep containers sealed in order to avoid
contamination. Do not reseal if contaminated. Store indoors in a cool, well-ventilated area.
STORAGE TEMPERATURE: 60 oF ?120 oF
SHELF LIFE: 6 months
SPECIAL SENSITIVITY: Material is hygroscopic and may absorb small amounts of atmospheric
moisture.
COMMENT: See Section 10 for more information on precautions concerning storage and handling of
this material.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE GUIDELINES:
OSHA HAZARDOUS COMPONENTS (29 CFR 1910.1200)
EXPOSURE LIMITS
CHEMICAL NAME OSHA PEL ACGIH TLV SUPPLIER OEL
3 3
ppm mg/m3
ppm mg/m ppm mg/m
6-Methyl-2,4-Bis(Methylthio)Phenylene- TWA NE NE NE NE
1,3-Diamine
N,N,N',N'-Tetrakis(2-Hydroxylpropyl) TWA NL NL NL NL
Ethylenediamine
KEY:
NE = Not Established
NL ?Not Listed
ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering
controls to control airborne levels.
PERSONAL PROTECTIVE EQUIPMENT
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EYES AND FACE: Wear safety glasses with side shields.
SKIN: Wear impervious gloves and clothing to cover exposed skin.
RESPIRATORY: If adequate engineering controls are not feasible, an approved respirator must be
worn.
WORK HYGIENIC PRACTICES: Follow good normal hygiene practices. Avoid contact with skin.
Avoid eating, drinking, or smoking while using this product. Wash hands thoroughly after use.
OTHER PROTECTIVE EQUIPMENT: Safety showers and eye wash stations are recommended.
9. PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL STATE: Liquid
ODOR: Slightly musty
COLOR: Various colors, including but not limited to: Gray, Black, Brown, Cream
BOILING POINT: > 300 oF
FREEZING POINT: < 32 oF
SOLUBILITY IN WATER: Partially soluble
SPECIFIC GRAVITY: 1.040 ?1.080 (water = 1) at 74 oF
VISCOSITY: 1350 ?1550 Centipoise at 74 oF
10. STABILITY AND REACTIVITY
CONDITIONS TO AVOID: Temperature extremes. Container contamination. Moisture.
STABILITY: Stable under recommended storage conditions.
POLYMERIZATION: Will not occur.
HAZARDOUS DECOMPOSITION PRODUCTS: By fire: Carbon Monoxide, Carbon Dioxide,
Oxides or Nitrogen, Oxides of Sulfur.
INCOMPATIBLE MATERIALS: Moisture, strong oxidizing agents, temperature extremes.
11. TOXICOLOGICAL INFORMATION
ORAL DERMAL INHALATION
LD50 (rat) LD50 (rabbit) LC50 (rat)
__________________________________________________________________________________________________________________________________________________________________________________________________________________________
6-Methyl-2,4-Bis(Methylthio)Phenylene-1,3-Diamine > 1515 mg/kg > 2000 mg/kg
N,N,N',N'-Tetrakis(2-Hydroxylpropyl)Ethylenediamine 3280 mg/kg > 2000 mg/kg
EYE EFFECTS: Moderate irritant
SKIN EFFECTS: Mild to moderate irritant
CARCINOGENICITY
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IARC: Not classified as a carcinogen.
NTP: Not classified as a carcinogen.
OSHA: Not classified as a carcinogen.
ACGIH: Not classified as a carcinogen.
12. ECOLOGICAL INFORMATION
ENVIRONMENTAL DATE: This product is a marine pollutant.
COMMENTS: No testing for product as a whole.
13. DISPOSAL CONSIDERATIONS
DISPOSAL METHOD: Disposal should be in accordance with local, state, provincial or national
regulations.
EMPTY CONTAINER: Empty containers should be decontaminated and either passed to an
approved drum recycler or destroyed.
RCRA HAZARD CLASS: This material is not a hazardous waste under RCRA 40 CFR 261.
COMMENTS: The generation of waste should be avoided or minimized whenever possible.
Chemical waste, even small quantities, should never be poured down drains, sewers or waterways.
Refer to Section 6 for additional information.
14. TRANSPORT INFORMATION
TECHNICAL NAME: Compound Resin
DOT (DEPARTMENT OF TRANSPORTATION)
Bulk containers (>119 gallon capacity) are regulated as: UN3082, Environmentally Hazardous
Substances, Liquid, N.O.S. (Aromatic amines), 9, III. Non-bulk containers are not regulated unless
any part of shipment will be by vessel.
VESSEL (IMO/IMDG)
All containers are regulated as: UN3082, Environmentally Hazardous Substances, Liquid, N.O.S.
(Aromatic amines), 9, III. When shipping non-bulk packages and a hazardous material meets the
definition of a marine pollutant, it must be identified as a marine pollutant if any portion of
transportation is by vessel.
15. REGULATORY INFORMATION
UNITED STATES
SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT)
311/312 HAZARD CATEGORIES: Immediate, Delayed
313 REPORTABLE INGREDIENTS: This product does not contain any chemical components
with known CAS numbers that exceed their de minimis reporting levels.
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CERCLA (COMPREHENSIVE RESPONSE, COMPENSATION, AND LIABILITY ACT)
No chemicals in this material with known CAS numbers are subject to the reporting
requirements of CERCLA.
TSCA (TOXIC SUBSTANCE CONTROL ACT)
TSCA REGULATORY: All ingredients are on TSCA inventory.
RCRA STATUS: Not hazardous if discarded in its purchased form. However, under RCRA, it is the
responsibility of the product user to determine at the time of disposal whether a material
containing the product or derived from the product should be classified as a hazardous waste (40
CFR 261.20-24).
OSHA HAZARD COMM. RULE: This material is classified as a hazardous material under the
criteria outlined in the OSHA Hazard Communication Standard (HCS) at 29 CFR 1910.1200.
16. OTHER INFORMATION
HMIS RATING: Health ?2*, Flammability - 1, Physical Hazard - 0
HMIS RATING NOTES: If present, the asterisk signifies a chronic health hazard.
Rating system: 0 = low hazard to 4 = high hazard
MANUFACTURER, SUPPLIER, OR DISTRIBUTOR DISCLAIMER: The information in this
MSDS was obtained from sources that we believe are reliable. The information is provided
without warranty, implied or expressed, concerning accuracy. The manufacturer or supplier
assumes no legal responsibility for use or reliance on this information. This MSDS is provided
solely for the purpose of conveying health, safety, and environmental information. This MSDS
is not a specification data sheet. Some of the information and conclusions may be derived from
sources other than test data on the material itself.
KEY LEGEND INFORMATION:
ACGIH - American Conference of Governmental Industrial Hygienists
EPA - Environmental Protection Agency
IARC - International Agency for Research on Cancer
NTP - National Toxicology Program
OEL - Occupational Exposure Limit
OSHA - Occupational Safety and Health Administration
PEL - Permissible Exposure Limit
STEL - Short Term Exposure Limit
TLV - Threshold Limit Value
TWA - Time Weighted Average
PREPARED BY: L. Priest
DATE ISSUED: 2/11/2005
MSDS #: SPAL-PRO 2000 A
REVISION # and DATE: Rev #6, 9/30/2008
CHANGES FROM LAST VERSION: Section 14 [Transportation Information]
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