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Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 01.02.2010 Revision: 01.02.2010
1 Identification of the substance/preparation and of the company/undertaking
?Product details
?Trade name: Polyesterharz Reparatur-Set
?Article number: REZ99
?Application of the substance / the preparation Knife filler/ Surfacer
?Manufacturer/Supplier:
Peter Kwasny GmbH
Heilbronner Str. 96
D-74831 Gundelsheim Tel.: 0049-(0)6269-95-20
E-mail: labor@kwasny.de
?Further information obtainable from: Product safety department
?Information in case of emergency: Tel.: +49 6269 95 20
2 Hazards identification
?Hazard description:
Xn Harmful
?Information concerning particular hazards for human and environment:
The product has to be labelled due to the calculation procedure of the "General Classification guideline for
preparations of the EU" in the latest valid version.
R 10 Flammable.
R 20 Harmful by inhalation.
R 36/38 Irritating to eyes and skin.
?Classification system:
The classification is according to the latest editions of the EU-lists, and extended by company and literature
data.
?GHS label elements
Warning
H226 - Flammable liquid and vapour.
Warning
H315 - Causes skin irritation.
H319 - Causes serious eye irritation.
?Prevention:
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P241 Use explosion-proof electrical/ventilating/lighting/equipment.
?Response:
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse
skin with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
P321 Specific treatment (see on this label).
?Disposal:
P501 Dispose of contents/container in accordance with local/regional/national/international regulations.
GB
(Contd. on page 2)
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Page 2/6
Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 01.02.2010 Revision: 01.02.2010
Trade name: Polyesterharz Reparatur-Set
(Contd. of page 1)
3 Composition/information on ingredients
?Chemical characterization
?Description: Mixture of substances listed below with nonhazardous additions.
?Dangerous components:
CAS: 100-42-5 styrene Xn, Xi; R 10-20-36/38 25-50%
EINECS: 202-851-5 Warning: 2.6/3; 3.1.I/4, 3.2/2, 3.3/2
?Additional information: For the wording of the listed risk phrases refer to section 16.
4 First-aid measures
?General information:
Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48
hours after the accident.
?After inhalation:
Supply fresh air. If required, provide artificial respiration. Keep patient warm. Consult doctor if symptoms
persist.
In case of unconsciousness place patient stably in side position for transportation.
?After skin contact: Immediately wash with water and soap and rinse thoroughly.
?After eye contact:
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
?After swallowing: If symptoms persist consult doctor.
5 Fire-fighting measures
?Suitable extinguishing agents:
CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
?For safety reasons unsuitable extinguishing agents: Water with full jet
?Protective equipment: Mouth respiratory protective device.
6 Accidental release measures
?Person-related safety precautions: Wear protective equipment. Keep unprotected persons away.
?Measures for environmental protection: Do not allow to enter sewers/ surface or ground water.
?Measures for cleaning/collecting:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
Do not flush with water or aqueous cleansing agents
7 Handling and storage
?Handling:
?Information for safe handling:
Take note of emission threshold.
Ensure good interior ventilation, especially at floor level. (Fumes are heavier than air).
?Information about fire - and explosion protection:
Keep ignition sources away - Do not smoke.
Protect against electrostatic charges.
?Storage:
?Requirements to be met by storerooms and receptacles: No special requirements.
?Information about storage in one common storage facility: Not required.
(Contd. on page 3)
GB
R
Page 3/6
Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 01.02.2010 Revision: 01.02.2010
Trade name: Polyesterharz Reparatur-Set
(Contd. of page 2)
?Further information about storage conditions: Keep container tightly sealed.
* 8 Exposure controls/personal protection
?Additional information about design of technical facilities: No further data; see item 7.
?Ingredients with limit values that require monitoring at the workplace:
100-42-5 styrene
WEL Short-term value: 1080 mg/m? 250 ppm
Long-term value: 430 mg/m? 100 ppm
?Additional information: The lists valid during the making were used as basis.
?Personal protective equipment:
?General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing
Wash hands before breaks and at the end of work.
Do not inhale gases / fumes / aerosols.
Avoid contact with the eyes and skin.
?Respiratory protection:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer
exposure use self-contained respiratory protective device.
?Protection of hands:
Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the
degradation
?Material of gloves Nitrile rubber, NBR
?Penetration time of glove material
Gloves must be changed after every contamination.
The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be
observed.
?Eye protection:
Tightly sealed goggles
9 Physical and chemical properties
?General Information
Form: Pasty
Colour: According to product specification
Odour: Characteristic
?Change in condition
Melting point/Melting range: Undetermined.
Boiling point/Boiling range: 145癈
?Flash point: 31癈
?Ignition temperature: 480癈
(Contd. on page 4)
GB
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Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 01.02.2010 Revision: 01.02.2010
Trade name: Polyesterharz Reparatur-Set
(Contd. of page 3)
?Self-igniting: Product is not selfigniting.
?Danger of explosion: Product is not explosive. However, formation of explosive air/vapour
mixtures are possible.
?Explosion limits:
Lower: 1.2 Vol %
Upper: 8.9 Vol %
?Vapour pressure at 20癈: 6 hPa
?Density at 20癈: 1.12 g/cm?br>
?Solubility in / Miscibility with
water: Not miscible or difficult to mix.
?Solvent content:
Organic solvents: 37.5 %
Solids content: 62.5 %
10 Stability and reactivity
?Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.
?Materials to be avoided:
?Dangerous reactions Reacts with acids, alkalis and oxidizing agents.
?Dangerous decomposition products: Possible in traces.
11 Toxicological information
?Acute toxicity:
?LD/LC50 values relevant for classification:
100-42-5 styrene
Oral LD50 5000 mg/kg (rat)
Inhalative LC50/4 h 24 mg/l (rat)
?Primary irritant effect:
?on the skin: Irritant to skin and mucous membranes.
?on the eye: Irritating effect.
?Sensitization: No sensitizing effects known.
?Additional toxicological information:
The product shows the following dangers according to the calculation method of the General EU
Classification Guidelines for Preparations as issued in the latest version:
Harmful
Irritant
12 Ecological information
?Additional ecological information:
?General notes:
Water hazard class 2 (German Regulation) (Self-assessment): hazardous for water
Do not allow product to reach ground water, water course or sewage system.
Danger to drinking water if even small quantities leak into the ground.
GB
(Contd. on page 5)
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Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 01.02.2010 Revision: 01.02.2010
Trade name: Polyesterharz Reparatur-Set
(Contd. of page 4)
13 Disposal considerations
?Product:
?Recommendation
Must not be disposed together with household garbage. Do not allow product to reach sewage system.
Empty aerosols can be disposed with the ordinary waste.
?Uncleaned packaging:
?Recommendation: Disposal must be made according to official regulations.
14 Transport information
?Land transport ADR/RID (cross-border)
?ADR/RID class: 3 (F1) Flammable liquids.
?Danger code (Kemler): -
?UN-Number: 3269
?Packaging group: III
?Hazard label 3
?Description of goods: 3269 POLYESTER RESIN KIT
?Limited quantities (LQ) LQ7
?Transport category 3
?Tunnel restriction code E
?Maritime transport IMDG:
?IMDG Class: 3
?UN Number: 3269
?Label 3
?Packaging group: III
?EMS Number: F-E,S-D
?Marine pollutant: No
?Proper shipping name: POLYESTER RESIN KIT
?Air transport ICAO-TI and IATA-DGR:
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Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 01.02.2010 Revision: 01.02.2010
Trade name: Polyesterharz Reparatur-Set
(Contd. of page 5)
15 Regulatory information
?Labelling according to EU guidelines:
The product has been classified and marked in accordance with EU Directives / Ordinance on Hazardous
Materials.
?Code letter and hazard designation of product:
Xn Harmful
?Hazard-determining components of labelling:
styrene
?Risk phrases:
10 Flammable.
20 Harmful by inhalation.
36/38 Irritating to eyes and skin.
?Safety phrases:
2 Keep out of the reach of children.
9 Keep container in a well-ventilated place.
23 Do not breathe vapour.
46 If swallowed, seek medical advice immediately and show this container or label.
51 Use only in well-ventilated areas.
56 Dispose of this material and its container to hazardous or special waste collection point.
?National regulations:
?Technical instructions (air):
Class Share in %
NK 25-50
?Waterhazard class: Water hazard class 2 (Self-assessment): hazardous for water.
16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
?Relevant R-phrases
10 Flammable.
20 Harmful by inhalation.
36/38 Irritating to eyes and skin.
?Department issuing MSDS: Product safety department
?Contact: Hr. Hamberger
?Abbreviations and acronyms:
ADR: Accord europ閑n sur le transport des marchandises dangereuses par Route (European Agreement concerning the
International Carriage of Dangerous Goods by Road)
RID: R鑗lement international concernant le transport des marchandises dangereuses par chemin de fer (Regulations Concerning
the International Transport of Dangerous Goods by Rail)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
IATA-DGR: Dangerous Goods Regulations by the "International Air Transport Association" (IATA)
ICAO: International Civil Aviation Organization
ICAO-TI: Technical Instructions by the "International Civil Aviation Organization" (ICAO)
GHS: Globally Harmonized System of Classification and Labelling of Chemicals
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
?* Data compared to the previous version altered.
GB