SAFETY DATA SHEET
Based on Directive 2001/58/EC of the Commission of the European Communities
Art. No. 130102000 NOVABLACK MAGIC
1. Identification of the substance/preparation and the company
1.1 Identification of the substance or preparation:
Synonyms: None
CAS No. : N.A.
EC index No. : N.A. NFPA code : N.D.
EINECS No. : N.A. Molecular weight : N.A.
RTECS No. : N.A. Formula : N.A.
1.2 Use of the substance or the preparation:
Sealing compound
1.3 Company/undertaking identification:
NOVATIO EUROPE N.V.
Industrielaan 5D
B-2250 Olen
Tel. : +32 14 25 76 40
Fax : +32 14 22 02 66
www.novatio.com
1.4 Telephone number for emergency:
+32 14 58 45 45
Brandweerinformatiecentrum voor gevaarlijke stoffen (B.I.G.)
Technische Schoolstraat 43 A, B-2440 Geel
2. Composition/information on ingredients
Hazardous ingredients CAS No. Conc. in Hazard Risks
% symbol
EINECS/ELINCS No. (R-phrases)
styrene 100-42-5 10-30 Xn 10-20-36/38 (1)
202-851-5
(1) For R-phrases in full: see heading 16
3. Hazards identification
- Flammable
- Harmful by inhalation
- Irritating to eyes and skin
4. First aid measures
4.1 Eye contact:
- If irritation persists: consult a doctor/medical service
- Rinse immediately with plenty of water
- Do not apply neutralizing agents
4.2 Skin contact:
- If irritation persists: consult a doctor/medical service
- Rinse immediately with plenty of water
- Soap may be used
4.3 After inhalation:
- If breathing problems develop: consult a doctor/medical service
- Remove the victim into fresh air
- Unconscious: maintain adequate airway and respiration
Printing date : 10-2005 1/8
Compiled by : Brandweerinformatiecentrum voor Gevaarlijke Stoffen vzw (BIG)
Technische Schoolstraat 43 A, B-2440 Geel
+32 14 58 45 47 http://www.big.be E-mail: info@big.be
MSDS established : 26-05-2000 Revision date : 28-09-2005
Reference number : BIG\32508GB Revision number : 005
Reason for revision : 14
Art. No. 130102000 NOVABLACK MAGIC
4.4 After ingestion:
- If you feel unwell: consult a doctor/medical service
- Immediately after ingestion: give lots of water to drink
- Never give water to an unconscious person
- Do not induce vomiting
5. Fire-fighting measures
5.1 Suitable extinguishing media:
- Polyvalent foam
- Alcohol-resistant foam
- BC powder
- Carbon dioxide
5.2 Unsuitable extinguishing media:
- Solid water jet ineffective as extinguishing medium
5.3 Special exposure hazards:
- Gas/vapour spreads at floor level: ignition hazard
- Gas/vapour flammable with air within explosion limits
- Upon combustion CO and CO2 are formed
5.4 Instructions:
- Cool closed containers with water if they are exposed to the fire
- Take account of environmentally hazardous firefighting water
- Use firefighting water moderately and contain it
5.5 Special protective equipment for firefighters:
- Heat/fire exposure: compressed air/oxygen apparatus
- Protective clothing for exposure to chemicals
6. Accidental release measures
6.1 Personal protection/precautions:
See headings 8.2/8.3/13
6.2 Environmental precautions:
- Prevent soil and water pollution
- Prevent spreading in sewers
- Contain leaking substance
- Dam up the liquid spill
6.3 Methods of cleaning up:
- Shovel solid spill into closing drums
- Carefully collect the spill/leftovers
- Clean contaminated surfaces with an excess of water
- Wash clothing and equipment after handling
7. Handling and storage
7.1 Handling:
- In case of insufficient ventilation:
- Observe normal hygiene standards
- Use spark-/explosionproof appliances and lighting system
- Take precautionary measures against static discharges
- Do not discharge the waste into the drain
7.2 Storage:
- Keep container tightly closed
- Keep out of direct sunlight
- Store in a cool area
- Ventilation at floor level
- Keep away from: heat sources, ignition sources, oxidizing agents
Storage temperature : N.D. 癈
Quantity limits : N.D. kg
Storage life : N.D. days
Materials for packaging :
- to avoid : No data available
7.3 Specific uses:
- See information supplied by the manufacturer
Printing date : 10-2005 2/8
Art. No. 130102000 NOVABLACK MAGIC
8. Exposure controls/Personal protection
8.1 Exposure limit values:
styrene
mg/m3
TLV-TWA : 20 ppm
mg/m3
TLV-STEL : 40 ppm
mg/m3
TLV-Ceiling : ppm
mg/m3
MEL-LTEL : 430 100 ppm
mg/m3
MEL-STEL : 1080 250 ppm
mg/m3
MAK : 86 20 ppm
mg/m3
TRK : ppm
mg/m3
MAC-TGG 8 h : 107
mg/m3
MAC-TGG 15 min. :
mg/m3
MAC-Ceiling :
mg/m3
VME-8 h : 215 50 ppm
mg/m3
VLE-15 min. :- - ppm
mg/m3
GWBB-8 h : 216 50 ppm
mg/m3
GWK-15 min. : 432 100 ppm
mg/m3
Momentary value : ppm
mg/m3
EC : ppm
mg/m3
EC-STEL : ppm
Sampling methods:
- Styrene (Phenylethylene) OSHA 89
- Styrene NON 37
- Styrene (Phenylethylene) OSHA 9
- Styrene (Phenylethylene) (Hydrocarbons, aromatic) NIOSH 1501
8.2 Exposure controls:
8.2.1 Occupational exposure controls:
- Measure the concentration in the air regularly
8.2.2 Environmental exposure controls: see heading 13
8.3 Personal protection:
8.3.1 respiratory protection:
- Dust/aerosol mask with filter type P2
8.3.2 hand protection:
- Gloves
suitable materials: Nitrile rubber
Printing date : 10-2005 3/8
Art. No. 130102000 NOVABLACK MAGIC
9. Physical and chemical properties
9.1 General information:
Appearance (at 20癈) : Paste
Odour : Aromatic
Colour : Black
9.2 Important health, safety and environmental information:
pH value : N.D.
Boiling point/boiling range : N.D. 癈
Flashpoint : 32 癈
Explosion limits : 1.1-6.1 Vol% ( 癈)
Vapour pressure (at 20癈) : N.D. hPa
Vapour pressure (at 50癈) : N.D. hPa
Relative density (at 20癈) : 1.5
Water solubility : Insoluble
Soluble in : Organic solvents
Relative vapour density : >2
Viscosity (at 20癈) : N.D. Pa.s
Partition coefficient n-octanol/water : N.D.
Evaporation rate
ratio to butyl acetate : N.D.
ratio to ether : N.D.
9.3 Other information:
Melting point/melting range : N.D. 癈
Auto-ignition point : 490 癈
g/m3
Saturation concentration : N.D.
10. Stability and reactivity
10.1 Conditions to avoid/reactivity:
- Stable under normal conditions
10.2 Materials to avoid:
- Keep away from: heat sources, ignition sources, oxidizing agents
10.3 Hazardous decomposition products:
- Upon combustion CO and CO2 are formed
11. Toxicological information
11.1 Acute toxicity:
styrene
LD50 oral rat : 5000 mg/kg
LD50 dermal rabbit : 2820 mg/kg
LD50 dermal rabbit : 5010 mg/kg
LC50 inhalation rat : 24 mg/l/4 h
LC50 inhalation rat : 5640 ppm/4 h
11.2 Chronic toxicity:
EC carc. cat. : not listed
EC muta. cat. : not listed
EC repr. cat. : not listed
Carcinogenicity (TLV) : A4 (styrene)
Carcinogenicity (MAC) : not listed
Carcinogenicity (VME) : not listed
Carcinogenicity (GWBB) : not listed
Carcinogenicity (MAK) : Category 5 (styrene)
Mutagenicity (MAK) : not listed
Teratogenicity (MAK) : Group C (styrene)
IARC classification : 2B (styrene)
Printing date : 10-2005 4/8
Art. No. 130102000 NOVABLACK MAGIC
11.3 Routes of exposure: ingestion, inhalation, eye and skin
11.4 Acute effects/symptoms:
AFTER INHALATION
ON CONTINUOUS EXPOSURE/CONTACT:
- CNS depression
- Feeling of weakness
- Nausea
- Headache
- Dizziness
- Impaired concentration
- Disturbances of consciousness
AFTER INGESTION
AFTER ABSORPTION OF HIGH QUANTITIES:
- CNS depression
- Symptoms similar to those listed under inhalation
AFTER SKIN CONTACT
- Tingling/irritation of the skin
AFTER EYE CONTACT
- Irritation of the eye tissue
11.5 Chronic effects:
- Contains a substance which (possibly) impairs fertility (styrene)
- Contains substance with uncertain carcinogenic properties (styrene)
- Contains substance of group C (MAK-Schwangerschaftsgruppe (styrene)
ON CONTINUOUS EXPOSURE/CONTACT:
- Feeling of weakness
- Dry skin
- Itching
- Skin rash/inflammation
- Change in the haemogramme/blood composition
- Loss of appetite
- Enlargement/affection of the liver
12. Ecological information
12.1 Ecotoxicity:
- No data available
12.2 Mobility:
- Volatile organic compounds (VOC): > 10%
- Insoluble in water
substance sinks in water
For other physicochemical properties see section 9
12.3 Persistence and degradability:
- Biodegradation BOD5 : N.D. % ThOD
- Water : Non biodegradable in water
- Soil : T? N.D. days
12.4 Bioaccumulative potential:
- log Pow : N.D.
- BCF : N.D.
12.5 Other adverse effects:
- WGK :2 (classification based on the components in compliance
with Verwaltungsvorschrift wassergef鋒rdender Stoffe
(VwVwS) of 17 May 1999)
- Effect on the ozone layer : Not dangerous for the ozone
layer (1999/45/EC)
- Greenhouse effect : No data available
- Effect on waste water purification : No data available
Printing date : 10-2005 5/8
Art. No. 130102000 NOVABLACK MAGIC
13. Disposal considerations
13.1 Provisions relating to waste:
- Hazardous waste (91/689/EEC)
13.2 Disposal methods:
- Allow waste to solidify
- Remove to an authorized dump (Class I)
- Contains a component for which a prohibition exists against discharge into
surface water (styrene)
13.3 Packaging:
- Waste material code packaging (91/689/EEC, Council Decision 2001/118/EC,
O.J. L47 of 16/2/2001): 15 01 10* (packaging containing residues of or
contaminated by dangerous substances)
14. Transport information
14.1 Classification of the substance in compliance with UN Recommendations
UN number : 3269
CLASS : 3
SUB RISKS : -
PACKING : III
PROPER SHIPPING NAME :
UN 3269, Polyester resin kit
14.2 ADR (transport by road)
CLASS : 3
PACKING : III
CLASSIFICATION CODE : F1
DANGER LABEL TANKS : -
DANGER LABEL PACKAGES : 3
14.3 RID (transport by rail)
CLASS : 3
PACKING : III
CLASSIFICATION CODE : F1
DANGER LABEL TANKS : -
DANGER LABEL PACKAGES : 3
14.4 ADNR (transport by inland waterways)
CLASS : 3
PACKING : III
CLASSIFICATION CODE : F1
DANGER LABEL TANKS : -
DANGER LABEL PACKAGES : 3
14.5 IMDG (maritime transport)
CLASS : 3
SUB RISKS : -
PACKING : III
MFAG : -
EMS : F-E, S-D
MARINE POLLUTANT : -
14.6 ICAO (air transport)
CLASS : 3
SUB RISKS : -
PACKING : III
PACKING INSTRUCTIONS PASSENGER AIRCRAFT : 312/Y312
PACKING INSTRUCTIONS CARGO AIRCRAFT : 312
Printing date : 10-2005 6/8
Art. No. 130102000 NOVABLACK MAGIC
14.7 Special precautions in connection with : None
transport
14.8 Limited quantities (LQ) :
When substances and their packaging meet the conditions established by
ADR/RID/ADNR in chapter 3.4, only the following prescriptions shall be complied
with:
each package shall display a diamond-shaped figure with the following
inscription:
- 'UN 3269'
or, in the case of different goods with different identification numbers within
a single package:
- the letters 'LQ'
15. Regulatory information
Labelling in accordance with directives 67/548/EEC and 1999/45/EC
Harmful
Contains : styrene
R10 : Flammable
R20 : Harmful by inhalation
R36/38 : Irritating to eyes and skin
S(02) : (Keep out of reach of children)
S03 : Store in a cool area
S(46) : (If swallowed, seek medical advice immediately and show
this container or label)
S51 : Use only in well ventilated area
Printing date : 10-2005 7/8
Art. No. 130102000 NOVABLACK MAGIC
16. Other information
The information provided on this MSDS is correct to the best of our knowledge, information and belief
at the date of its publication. The information given is designed only as a guidance for safe
handling, use, processing, storage, transportation, disposal and release and is not to be considered
as a warranty or quality specification. The information relates only to the specific material
designated and may not be valid for such material used in combination with any other material or in
any process, unless specified in the text.
N.A. = NOT APPLICABLE
N.D. = NOT DETERMINED
(*) = INTERNAL CLASSIFICATION (NFPA)
Exposure limits:
TLV : Threshold Limit Value - ACGIH US 2004
OES : Occupational Exposure Standards - United Kingdom 2003
MEL : Maximum Exposure Limits - United Kingdom 2003
MAK : Maximale Arbeitsplatzkonzentrationen - Germany 2002
TRK : Technische Richtkonzentrationen - Germany 2002
MAC : Maximale aanvaarde concentratie - the Netherlands 2004
VME : Valeurs limites de Moyenne d'Exposition - France 1999
VLE : Valeurs limites d'Exposition ?court terme - France 1999
GWBB : Grenswaarde beroepsmatige blootstelling - Belgium 2002
GWK : Grenswaarde kortstondige blootstelling - Belgium 2002
EC : Indicative occupational exposure limit values - directive 2000/39/EC
I : Inhalable fraction = T : Total dust = E : Einatembarer Aerosolanteil
R : Respirable fraction = A : Alveoleng鋘giger Aerosolanteil/Alveolar dust
C : Ceiling limit