Page 1/5
Material Safety Data Sheet
According to 91/155 EEC
Printing date 03.11.2005 Reviewed on 03.11.2005
* 1 Identification of the substance/preparation and of the company/undertaking
?Product details
?Trade name: METAFLUX Metaplast 70-60
?Article number: 70-60
?Application of the substance / the preparation Knife filler/ Surfacer
?Manufacturer/Supplier:
TECHNO-SERVICE GmbH
Detmolder Str. 515
D-33605 Bielefeld
?Further information obtainable from: Abteilung Produktsicherheit
?Information in case of emergency:
Tel.:+49 521 924440
Fax +49 521 207432
* 2 Composition/information on ingredients
?Chemical characterization
?Description: Mixture of substances listed below with nonhazardous additions.
?Dangerous components:
CAS: 100-42-5 styrene 10-25%
EINECS: 202-851-5 Xn; R 10-20-36/38
0.5%
CAS: 64742-95-6 Solvent naphtha (petroleum), light arom.
EINECS: 265-199-0 Carc. Cat. 2; Xn, N; R 10-51/53-65-66-67
?Additional information: For the wording of the listed risk phrases refer to section 16.
* 3 Hazards identification
?Hazard description: Not applicable.
?Information concerning particular hazards for human and environment:
The product has to be labelled due to the calculation procedure of the "General Classification guideline for
preparations of the EU" in the latest valid version.
R 10 Flammable.
?Classification system:
The classification is according to the latest editions of the EU-lists, and extended by company and literature
data.
4 First-aid measures
?After inhalation: Supply fresh air; consult doctor in case of complaints.
?After skin contact: Generally the product does not irritate the skin.
?After eye contact: Rinse opened eye for several minutes under running water.
?After swallowing: Drink plenty of water and provide fresh air. Call for a doctor immediately.
5 Fire-fighting measures
?Suitable extinguishing agents: CO2, sand, extinguishing powder. Do not use water.
?For safety reasons unsuitable extinguishing agents:
Water
(Contd. on page 2)
GB
Page 2/5
Material Safety Data Sheet
According to 91/155 EEC
Printing date 03.11.2005 Reviewed on 03.11.2005
Trade name: METAFLUX Metaplast 70-60
(Contd. of page 1)
Water with full jet
?Protective equipment: No special measures required.
6 Accidental release measures
?Person-related safety precautions: Wear protective equipment. Keep unprotected persons away.
?Measures for environmental protection: Do not allow to enter sewers/ surface or ground water.
?Measures for cleaning/collecting:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Ensure adequate ventilation.
Do not flush with water or aqueous cleansing agents
7 Handling and storage
?Handling:
?Information for safe handling:
Ensure good ventilation/exhaustion at the workplace.
Prevent formation of aerosols.
?Information about fire - and explosion protection:
Keep ignition sources away - Do not smoke.
Protect against electrostatic charges.
?Storage:
?Requirements to be met by storerooms and receptacles: No special requirements.
?Information about storage in one common storage facility: Not required.
?Further information about storage conditions: Keep container tightly sealed.
8 Exposure controls/personal protection
*
?Additional information about design of technical facilities: No further data; see item 7.
?Ingredients with limit values that require monitoring at the workplace:
100-42-5 styrene
WEL Short-term value: 1080 mg/m? 250 ppm
Long-term value: 430 mg/m? 100 ppm
?Additional information: The lists valid during the making were used as basis.
?Personal protective equipment:
?General protective and hygienic measures: Wash hands before breaks and at the end of work.
?Respiratory protection:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure
use self-contained respiratory protective device.
?Protection of hands:
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/
the chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the
degradation
?Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality
and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the
resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the
application.
?Penetration time of glove material
The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be
observed.
(Contd. on page 3)
GB
Page 3/5
Material Safety Data Sheet
According to 91/155 EEC
Printing date 03.11.2005 Reviewed on 03.11.2005
Trade name:METAFLUX Metaplast 70-60
(Contd. of page 2)
?Eye protection:
Tightly sealed goggles
* 9 Physical and chemical properties
?General Information
Fluid
Form:
According to product specification
Colour:
Characteristic
Odour:
?Change in condition
Melting point/Melting range: Undetermined.
Boiling point/Boiling range: 145癈
?Flash point: 31癈
Product is not selfigniting.
?Self-igniting:
Product is not explosive. However, formation of explosive air/vapour
?Danger of explosion:
mixtures are possible.
?Explosion limits:
1.2 Vol %
Lower:
8.9 Vol %
Upper:
6.0 hPa
?Vapour pressure at 20癈:
1.92 g/cm?br>
?Density at 20癈:
?Solubility in / Miscibility with
Not miscible or difficult to mix.
water:
?Solvent content:
12.6 %
Organic solvents:
241.0 g/l / 2.01 lb/gl
VOC-USA
80.5 %
?Solids content:
10 Stability and reactivity
?Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.
?Dangerous reactions No dangerous reactions known.
?Dangerous decomposition products: No dangerous decomposition products known.
11 Toxicological information
?Acute toxicity:
?LD/LC50 values relevant for classification:
100-42-5 styrene
Oral LD50 5000 mg/kg (rat)
Inhalative LC50/4 h 24 mg/l (rat)
?Primary irritant effect:
?on the skin: No irritant effect.
?on the eye: No irritating effect.
(Contd. on page 4)
GB
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Material Safety Data Sheet
According to 91/155 EEC
Printing date 03.11.2005 Reviewed on 03.11.2005
Trade name:METAFLUX Metaplast 70-60
(Contd. of page 3)
?Sensitization: No sensitizing effects known.
* 12 Ecological information
?General notes:
Water hazard class 2 (German Regulation) (Self-assessment): hazardous for water
Do not allow product to reach ground water, water course or sewage system.
Danger to drinking water if even small quantities leak into the ground.
13 Disposal considerations
*
?Product:
?Recommendation
Must not be disposed together with household garbage. Do not allow product to reach sewage system.
?European waste catalogue
08 04 09 waste adhesives and sealants containing organic solvents or other dangerous substances
15 01 04 metallic packaging
?Uncleaned packaging:
?Recommendation: Disposal must be made according to official regulations.
14 Transport information
*
?Land transport ADR/RID (cross-border)
?ADR/RID class: 3 (F1) Flammable liquids.
?Danger code (Kemler): 30
?UN-Number: 3269
III
?Packaging group:
3
?Hazard label
?Description of goods: 3269 POLYESTER RESIN KIT
?Maritime transport IMDG:
?IMDG Class: 3
3269
?UN Number:
3
?Label
III
?Packaging group:
F-E,S-D
?EMS Number:
No
?Marine pollutant:
?Proper shipping name: POLYESTER RESIN KIT
?Air transport ICAO-TI and IATA-DGR:
?ICAO/IATA Class: 3
3269
?UN/ID Number:
(Contd. on page 5)
GB
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Material Safety Data Sheet
According to 91/155 EEC
Printing date 03.11.2005 Reviewed on 03.11.2005
* 15 Regulatory information
?Labelling according to EU guidelines:
The product has been classified and marked in accordance with EU Directives / Ordinance on Hazardous
Materials.
?Risk phrases:
10 Flammable.
?Safety phrases:
2 Keep out of the reach of children.
23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer).
43 In case of fire, use sand, carbon dioxide or powdered extinguishing agent. Never use water.
46 If swallowed, seek medical advice immediately and show this container or label.
56 Dispose of this material and its container to hazardous or special waste collection point.
60 This material and its container must be disposed of as hazardous waste.
?National regulations:
?Technical instructions (air):
Class Share in %
NK 12.6
?Waterhazard class: Water hazard class 2 (Self-assessment): hazardous for water.
16 Other information
*
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
?Relevant R-phrases
10 Flammable.
20 Harmful by inhalation.
36/38 Irritating to eyes and skin.
51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
65 Harmfull: may cause lung damage if swallowed
66 Repeated exposure may cause skin dryness or cracking.
67 Vapours may cause drowsiness and dizziness.
?Department issuing MSDS: Abteilung Labor/QS
?Contact: Anwendungstechnik
?* Data compared to the previous version altered.
GB