P.O. Box 856
Del Mar, CA 92014
Telephone Number: (858) 755-4959
Facsimile Number: (858) 755-0733
www.cbsscientific.com
MATERIAL SAFETY DATA SHEET
1. PRODUCT IDENTIFICATION
Trade Name: ClearPAGETM TGS Cassette Gel, all percentages and well
?br>
configurations
Catalog numbers: FK00812, FK00827, FK01001, FK01012,
?br>
FK01027, FK01201, FK01212, FK01227,
FK01612, FK01627, FK40812, FK40827,
FK41212, FK41227, FK42001, FK42002,
FK42012, FK42027, FK82001, FK82002,
FK82012, FK82027, FK02001, FK02012
Manufacturer/Supplier: C.B.S. Scientific Company
P.O. Box 856
Del Mar, CA 92014
Information department: Technical Services, customer support.
?br>
Telephone number: +1 (858) 755-4959
?br>
2. COMPOSITION / INFORMATION OF COMPONENTS
Mixture of the substances listed below with non-hazardous additions.
Chemical Name % CAS # EINECS #
Polyacrylamide 3 to 20% 9003-05-8 Not available
Tris-hydroxymethyl- 4 to 5% 77-86-1 201-064-4
amino-methane ("Tris")
Sodium Dodecyl Sulfate 0.01 to 0.2% 151-21-3 205-788-1
Acrylamide <0.02% 79-06-1 201-173-7
N,N'-methylene bis- <0.002% 110-26-9 203-750-9
acrylamide
C.B.S. Scientific Company, ClearPAGE Gels, MSDS, Revision A, January 2, 2007 Page 1 of 12
3. HAZARDS IDENTIFICATION
Potential Health Effects:
WARNING!
IRRITANT - IRRITATING TO THE SKIN, EYES, AND UPPER RESPIRATORY TRACT
HARMFUL IF SWALLOWED. CONTAINS COMPOUND THAT MAY CAUSE
ALLERGIC REACTION IN CERTAIN INDIVIDUALS.
CONTAINS COMPOUND THAT IS A KNOWN NEUROTOXIN.
CONTAINS COMPOUNDS THAT ARE SUSPECTED CARCINOGENS.
CONTAINS COMPOUNDS THAT ARE SUSPECTED MUTAGENS.
Eye:
Can cause minor irritation, tearing and reddening.
Skin:
This material may cause skin irritation. Reddening, itching and inflammation may result. Not
likely to cause acute or permanent damage.
Inhalation:
May cause irritation to the respiratory tract. This material may cause injury or illness if
inhaled.
Ingestion:
If ingested, this material may be irritating to mouth, throat and gastrointestinal tract. May be
harmful if swallowed.
Special Toxic Effects:
Contains a substance that is a possible cancer hazard based on high dose animal studies
and/or human study. Contains a substance(s) that is a possible reproductive system hazard
based on high dose tests with laboratory animals. (See Section 11).
Repeated exposure to low levels of ACRYLAMIDE dust has resulted in neurotoxicity in
humans. The primary route of occupational exposure is skin absorption, but inhalation and
ingestion can contribute significantly to the overall exposure. The appearance of symptoms
may be delayed up to 2 months, with low-level exposures. Symptoms may include: tiredness,
weakness in hands and feet, tremor, dizziness, muscular incoordination (ataxia), sleepiness,
poor memory, confusion, slurred speech, abnormal behavior, vision changes, urinary system
changes, and weight loss. Recovery from these toxic effects is usually good, but may take
months to years, depending on the severity and duration of exposure.
CAUTION! THE TOXICOLOGICAL PROPERTIES OF THIS MATERIAL HAVE NOT
BEEN FULLY INVESTIGATED.
C.B.S. Scientific Company, ClearPAGE Gels, MSDS, Revision A, January 2, 2007 Page 2 of 12
4. FIRST AID MEASURES
Eye:
Flush eyes with plenty of water for at least 20 minutes retracting eyelids often. Tilt the head
to prevent chemical from transferring to the uncontaminated eye. Get immediate medical
attention.
Skin:
Wash with soap and water under a drench shower. Remove contaminated clothing, launder
immediately and discard contaminated leather goods. Get medical attention immediately.
Inhalation:
Remove to fresh air. If breathing is difficult, have a trained individual administer oxygen. If
not breathing, give artificial respiration and have a trained individual administer oxygen. Get
medical attention immediately.
Ingestion:
If swallowed, wash out mouth with water provided person is conscious.
Never give anything by mouth to an unconscious person. Get medical attention.
Note to Physician:
Treat symptomatically.
5. FIRE FIGHTING MEASURES
Flashpoint ND
Lower Flammable Limit % ND
Upper Flammable Limit % ND
Autoignition Temperature ND
Extinguishing Media:
Use extinguisher media appropriate for surrounding fire.
Firefighting Techniques / Equipment:
As in any fire, wear self-contained breathing apparatus pressure-demand (MHSA/NIOSH
approved or equivalent) and full protective gear. Evacuate the area and fight fire from a safe
distance.
Hazardous Combustion Products:
MAY EMIT TOXIC FUMES UNDER FIRE CONDITIONS.
C.B.S. Scientific Company, ClearPAGE Gels, MSDS, Revision A, January 2, 2007 Page 3 of 12
6. ACCIDENTAL RELEASE MEASURES
Accidental releases may be subject to special reporting requirements and other regulatory
mandates. Refer to section 8 for personal protection equipment recommendations.
Spill Cleanup:
Exposure to the spilled material may be irritating. Follow personal protective equipment
recommendations found in Section 8 of this MSDS.
7. HANDLING AND STORAGE
Storage pressure: Ambient.
Handling Procedures:
DO NOT GET IN EYES, ON SKIN OR CLOTHING. Wash hands thoroughly before eating,
drinking or smoking.
Storage Procedures
Store in a cool location. Isolate from incompatible materials and conditions. Keep
container(s) closed. The material is suitable for most general chemical storage areas,
including refrigerators, but not to be stored with food.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Exposure Limits:
Component OSHA PEL AGCIH TWA
(ppm) (ppm)
0.03 MG/ M 0.03 MG/ M3 Skin
3
Acrylamide
Engineering Controls:
No special exhaust ventilation, process enclosures, or other engineering controls are
necessary when handling or using this product to avoid overexposure.
Personal Protective Equipment:
Eye:
An eye wash station must be available where this product is used. Wear chemically resistant
safety glasses with side shields when handling this product. Wear additional eye protection
such as chemical splash goggles and/or face shield when the possibility exists for eye contact
with splashing or spraying liquid, or airborne material. Do not wear contact lenses. Have an
eye wash station available.
C.B.S. Scientific Company, ClearPAGE Gels, MSDS, Revision A, January 2, 2007 Page 4 of 12
Skin:
Wear protective gloves. Inspect gloves for chemical break-through and replace at regular
intervals. Clean protective equipment regularly. Wash hands and other exposed areas with
mild soap and water before eating, drinking, smoking and when leaving work. Have a safety
shower available.
Respiratory:
No special equipment is required.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance/physical state: Liquid solution / gel
Odor: No odor.
Boiling point (oC): ND
Melting Point (oC): ND
Solubility in water: ND
pH: 8.3 to 8.8
Vapor Pressure: ND
Vapor Density: ND
Specific Gravity/Density: ND
Octanol/water Partition Coeff: ND
Volatiles: ND
Evaporation Rate: ND
Viscosity: ND
10. STABILITY AND REACTIVITY
Stability/Incompatibility:
Stable under normal conditions of use. Incompatible with strong oxidizing agents.
Hazardous Decomposition Products:
Combustion may produce Nitrogen oxides, Carbon dioxide. Carbon monoxide.
Hazardous Polymerization:
Will not occur.
C.B.S. Scientific Company, ClearPAGE Gels, MSDS, Revision A, January 2, 2007 Page 5 of 12
11. TOXICOLOGICAL INFORMATION
FOR PURE TRIS-HYDROXYMETHYL-AMINO-METHANE:
LD50
REGISTRY OF THE TOXIC EFFECTS OF CHEMICAL SUBSTANCES (RTECS)
RTECS # TY2900000 (listed as: 1,3-propanediol, 2-amino-2-(hydroxymethyl)- )
The oral LD50 in rats is = 5,900 mg/kg.
Intravenous LD50 - rat = 1800 mg/kg. Intravenous LD50 - mouse = 1210 mg/kg.
Only selected data is presented here. See actual entry in RTECS for complete information.
Carcinogenicity
NOT LISTED BY IARC, NTP OR OSHA AS A CARCINOGEN.
Routes of Exposure
Inhalation, ingestion, skin and eye contact. Skin contact is the primary route of occupational
exposure.
FOR PURE ACRYLAMIDE:
Irritation Data:
Standard Draize Test - Administration onto the Skin, Rabbit = 50 mg/3D, Mild.
Standard Draize Test - Administration onto the Skin, Rabbit = 500 mg/24H, Mild.
Rinsed with Water - Administration into the Eye, Rabbit = 10 mg/30S, Mild.
Standard Draize Test - Administration into the Eye, Rabbit = 100 mg/24H, Moderate.
Tumorigenic Data:
Oral TDLo - rat = 1456 mg/kg/2Y-C (Toxic Effects: Tumorigenic - carcinogenic by RTECS
criteria; Reproductive - tumorigenic Effects - testicular tumors).
Intraperitoneal TDLo - mouse = 24 mg/kg/8W-I (Toxic Effects: Tumorigenic - neoplastic by
RTECS criteria; Lungs/Thorax/Respiration - tumors).
Oral TDLo - mouse = 300 mg/kg/2W-I (Toxic Effects: Tumorigenic - carcinogenic by
RTECS criteria; Lungs/Thorax/Respiration - tumors; Skin and Appendages - tumors).
Reproductive Data:
Oral TDLo - rat = 200 mg/kg, female 7-16 days after conception (Toxic Effects:
Reproductive - Effects on Newborn - biochemical and metabolic)
Oral TDLo - rat = 560 mg/kg, female 6-21 days after conception, lactating female 10 days
post-birth (Toxic Effects: Reproductive - Maternal Effects - parturition; Effects on
Newborn - stillbirth, viability index).
Oral TDLo - rat = 75 mg/kg, male 5 days pre-mating (Toxic Effects: Reproductive - Fertility
- male fertility index).
C.B.S. Scientific Company, ClearPAGE Gels, MSDS, Revision A, January 2, 2007 Page 6 of 12
Mutation Data:
Unscheduled DNA Synthesis - Human Mammary gland = 1 mmol/L.
Micronucleus test - Intraperitoneal, rat = 100 mg/kg. Micronucleus Test - mouse fibroblast =
100 mg/L.
Micronucleus test - Intraperitoneal, mouse = 30 mg/kg.
Only selected toxicological data is presented here. See actual entry in RTECS for complete
information.
Carcinogenicity
ACGIH TLV - CONFIRMED ANIMAL CARCINOGEN - DTLVS* TLV/BEI, 1999
IARC CANCER REVIEW: ANIMAL SUFFICIENT EVIDENCE - IMEMDT 39,41,1986
IARC CANCER REVIEW: ANIMAL SUFFICIENT EVIDENCE - IMEMDT 60, 389, 1994
IARC CANCER REVIEW: HUMAN NO ADEQUATE EVIDENCE - IMEMDT 39, 41,
1986
IARC CANCER REVIEW: HUMAN INADEQUATE EVIDENCE - IMEMDT 60, 389,
1994
IARC CANCER REVIEW: GROUP 2A - IMEMDT 60, 389, 1994
NTP 10th REPORT ON CARCINOGENS, 2000: REASONABLY ANTICIPATED TO BE
HUMAN CARCINOGEN.
LD50
REGISTRY OF THE TOXIC EFFECTS OF CHEMICAL SUBSTANCES (RTECS)
RTECS # AS3325000
The oral LD50 in rats is = 124 mg/kg.
Oral LD50 - mouse = 107 mg/kg. Oral LD50 - rabbit = 150 mg/kg. Oral LD50 - guinea pig =
150 mg/kg.
Administration onto the skin LD50 - rat = 400 mg/kg (Toxic Effects: Blood - other changes;
Biochemical ?Enzyme inhibition, induction or change in blood or tissue levels -
transaminases, peptidases).
Administration onto the skin LD50 - rabbit = 1680 uL/kg (Toxic Effects: Behavioral -
hallucinations, distorted perceptions).
Routes of Exposure
Inhalation, ingestion, skin and eye contact. Skin contact is the primary route of occupational
exposure.
Only selected data is presented here. See actual entry in RTECS for complete information.
FOR PURE SODIUM DODECYL SULFATE:
Irritation Data:
Standard Draize Test - Administration onto the skin - Human = 250 mg/24H, Mild.
Standard Draize Test - Administration onto the skin - Rabbit = 50 mg/24H, Severe.
Standard Draize Test - Administration into the Eye, Rabbit = 100 mg/24H, Moderate.
Only selected toxicological data is presented here. See actual entry in RTECS for complete
information.
Carcinogenicity
NOT LISTED BY IARC, NTP OR OSHA AS A CARCINOGEN
C.B.S. Scientific Company, ClearPAGE Gels, MSDS, Revision A, January 2, 2007 Page 7 of 12
LD50
REGISTRY OF THE TOXIC EFFECTS OF CHEMICAL SUBSTANCES(RTECS)
RTECS # WT1050000 (listed as: Sulfuric acid, monododecyl ester, sodium salt)
The oral LD50 in rats is = 1288 mg/kg. Inhalation LC50 - rat = >3900 mg/m3/1H.
Intraperitoneal LD50 - rat = 210 mg/kg. Intravenous LD50 - rat = 118 mg/kg.
Routes of Exposure
Inhalation, ingestion, skin and eye contact
Only selected data is presented here. See actual entry in RTECS for complete information.
OTHER TOXICOLOGICAL INFORMATION:
CAUTION! THE TOXICOLOGICAL PROPERTIES OF THIS MATERIAL HAVE NOT
BEEN FULLY INVESTIGATED. FOLLOW GOOD LABORATORY PRACTICES WHEN
HANDLING
12. ECOLOGICAL INFORMATION
Ecotoxicological Information: Acrylamide is readily leachable in soils. The hazard of
leachability to ground water appears greater in sandy soils than in clay soils. In soils, the
half-life ranges from 14 hours to 45 hours and is about 94.5 hours in water at 22C.
Environmental Fate (Degradation, Transformation, and Persistence) for Acrylamide:
Biological Oxygen Demand BOD5 = 0.97 mg/L std. dil/acclimated.
13. DISPOSAL CONSIDERATIONS
Waste Disposal
Under RCRA, it is the responsibility of the user of the product to determine, at the time of
disposal, whether the product meets RCRA criteria for hazardous waste.
If the material is determined to be a hazardous waste, the transportation, storage, treatment
and disposal of this waste material must be conducted in compliance with 40 CFR 262, 263,
264, 268 and 270. Disposal can occur only in properly permitted facilities.
Contact your local disposal service provider(s) for appropriate method(s) of disposal.
14. TRANSPORT INFORMATION
Proper Shipping Name: NOT REGULATED
Hazard Class: NA
UN/NA Code: NA
Packaging Group: NA
Reportable Quantity: None
Labels Required: NA
Marine Pollutant (49 CFR 172.101 Appendix B): No
C.B.S. Scientific Company, ClearPAGE Gels, MSDS, Revision A, January 2, 2007 Page 8 of 12
15. REGULATORY INFORMATION
FEDERAL REGULATIONS
All ingredients are listed on Inventory of Existing Chemical Substances under the Toxic
Substances Control Act (TSCA).
Information For Pure Tris-hydroxymethyl-amino-methane
This product is listed on the Inventory of Existing Chemical Substances under the Toxic
Substances Control Act (TSCA). TSCA Section 8(b)
NOHS 1974: HZD 81165; TNF 850 (est.); NIS 4; NOS 6; TNE 7274 (est.)
NOES 1983: HZD 81165; TNF 2296 (est).; NIS 9; NOS 22; TNE 40897 (est.); TFE
30773 (est.)
Information For Pure Acrylamide
EPA TSCA Test Submission (TSCATS) Data Base, January 2001.
NOHS 1974: HZD 03540; TNF 442 (est); NIS 10; NOS 24; TNE 7047 (est).
NOES 1983: HZD 03540; TNF 453 (est); NIS 19; NOS 22; TNE 10651 (est); TFE 721
(est)
This compound is listed on the Inventory of Existing Chemical Substances under the
Toxic Substances Control Act (TSCA). TSCA Sections: 8(b) - inventory; 8(a) -
preliminary assessment information, final rule; 8(d) - unpublished health/safety
studies.
CLEAN AIR ACT: SOCMI chemical, HAP code: XOV.
RCRA code: U007. CERCLA RQ: 5,000 pounds.
SARA EHS RQ: 5,000; SARA EHS TPQ: 1,000/10,000 pounds;
SARA TR Concentration: 0.1%; SARA TR Threshold: Standard.
NIOSH Standard: 77-112; 91-115. NIOSH/OSHA Guidelines: 92-110. OSHA Analytical
Method # 21
EPA Genetox Program 1988, Positive: Cytogenetics-male germ cell
EPA Genetox Program 1988, Negative: In vivo cytogenetics-nonhuman bone marrow.
EPA Genetox Program 1988, Inconclusive: In vivo SCE-nonhuman
On EPA IRIS database.
Information For Pure Sodium Dodecyl Sulfate
This compound is listed on the Inventory of Existing Chemical Substances under the
Toxic Substances Control Act (TSCA). TSCA Sections 8(b) - inventory; 8(d) -
unpublished health/safety studies; and 8(e) = Risk Notification, 8EHQ-0892-8800.
EPA TSCA Test Submission (TSCATS) Data Base, January 2001.
EPA FIFRA 1988 Pesticide subject to registration or re-registration. FIFRA Disclaimer:
This compound is not to be used for any pesticidal purpose, including plant growth
regulation, outside of a research and development laboratory. Any pesticidal use,
including plant growth regulation, outside of a research and development laboratory,
may be a violation of the Federal Insecticide, Fungicide and Rodenticide Act
(FIFRA), 40CFR parts 150 - 189.
EPA FIFRA 1998 Status of Pesticides: RED Completed (Rainbow Report: -,323,1998)
NOHS 1974: HZD 81990; TNF 32028 (est); NIS 167; NOS 113; TNE 388848 (est)
C.B.S. Scientific Company, ClearPAGE Gels, MSDS, Revision A, January 2, 2007 Page 9 of 12
NOES 1983: HZD 81990; TNF 46312 (est); NIS 232; NOS 170; TNE 886968 (est); TFE
415360 (est)
STATE REGULATIONS
Based on available information, this material does not contain any components currently
known to the State of California to cause cancer, birth defects or reproductive harm at levels,
which would be subject to Proposition 65.
Information For Pure Acrylamide
CALIFORNIA Proposition 65 code: C
DELAWARE Air Quality Management List: DRQ: 5000; Must be reported to the DRQ.
FLORIDA Toxic Substance: Listed as a toxic substance by the state of Florida.
MASSACHUSETTS Haz. Substance codes: 1,2,3,4,5,6*E*C*F8 F9
MINNESOTA Haz. Substance: Codes: ANOR; Hazards: Skin; Carcinogen? Yes.
NEW JERSEY RTK Hazardous Substance: DOT: 2074; Sub. No.: 0022; TPQ: -; EHS: -
NEW YORK List of Hazardous Substances: RQ--Air: 5000; RQ--Land: 100;
Note: No Note Associated with this chemical.
PENNSYLVANIA Haz. Substance code: E
WASHINGTON Air Contaminant: TWA (mg): 0.03; Skin: Protective measures should
be taken to prevent or reduce skin absorption.
INTERNATIONAL REGULATIONS
Information For Pure Tris-hydroxymethyl-amino-methane
CANADA: Domestic Substances List / Non-Confidential.
OEL=MAK
Information For Pure Acrylamide
CANADA: Domestic Substances List / Non-Confidential.
Listed on chemical list(s) in the following countries: AUSTRALIA; CHINA; JAPAN;
KOREA; PHILLIPINES
EUROPEAN Priority Lists: Rapporteur: United Kingdom; Priority List # 1; ECB # 011.
OEL-AUSTRALIA: TWA 0.3 mg/m3, Skin, Carcinogen, JAN1993.
OEL-AUSTRIA: Skin, Carcinogen, JAN1999.
OEL-BELGIUM: TWA 0.3 mg/m3, Skin, Carcinogen, JAN1993.
OEL-DENMARK: TWA 0.03 mg/m3, Skin, JAN1999.
OEL-FINDLAND: TWA 0.3 mg/m3, STEL 0.9 mg/m3, JAN1993.
OEL-FRANCE: VME 0.1 ppm (0.3 mg/m3), Skin, C2 Carcinogen, JAN1999.
OEL-GERMANY: Skin, Carcinogen, JAN1999.
OEL-HUNGARY: STEL 0.3 mg/m3, Skin, Carcinogen, JAN1993.
OEL-JAPAN: OEL 0.3 mg/m3, Skin, 2A Carcinogen, JAN1999.
OEL-THE NETHERLANDS: MAC-TGG 0.3 mg/m3, Carcinogen, JAN1999.
OELNORWAY: TWA 0.3 mg/m3, JAN1999. OEL-THE PHILLIPINES: TWA 0.3
mg/m3, Skin, JAN1993.
OEL-POLAND: TWA 0.1 mg/m3, JAN1999.
OEL-RUSSIA: STEL 0.2 mg/m3, Skin, JAN1993.
OEL-SWEDEN: NGV 0.03 mg/m3, KTV 0.1 mg/m3, Skin, JAN1999.
OEL-SWITZERLAND: MAK-W 0.03 mg/m3, Skin, Carcinogen, JAN1999.
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OEL-UNITED KINGDOM: TWA 0.3 mg/m3, Skin, Carcinogen, SEP2000.
OEL in ARGENTINA, BULGARIA, COLOMBIA, JORDAN, KOREA, NEW
ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV.
Information For Pure Sodium Dodecyl Sulfate
CANADA: Domestic Substances List / Non-Confidential.
Listed on chemical list(s) in the following countries: AUSTRALIA; CHINA; JAPAN;
KOREA; PHILIPPINES
INTERNATIONAL PHRASES
R - 45 May cause cancer.
46 May cause heritable genetic damage.
20/21 Harmful by inhalation and in contact with skin.
25 Toxic if swallowed.
36/37/38 Irritating to eyes, respiratory system and skin.
43 May cause sensitization by skin contact.
S - 23 Do not breathe gas/fumes/vapor/spray
24/25 Avoid contact with skin and eyes.
26 In case of contact with eyes, rinse immediately with plenty of water and seek
medical advice
36/37/39 Wear suitable protective clothing, gloves & eye/face protection.
38 In case of insufficient ventilation, wear suitable respiratory equipment.
EINECS Numbers: See page 1 of this document.
SARA TITLE III RATINGS for Pure Tris-hydroxymethyl-amino-methane
Immediate Delayed Fire Pressure Reactivity SARA 313
Hazard Hazard Hazard Hazard Hazard Chemical
X
SARA TITLE III RATINGS for Pure Acrylamide
Immediate Delayed Fire Pressure Reactivity SARA 313
Hazard Hazard Hazard Hazard Hazard Chemical
X X X X X
SARA TITLE III RATINGS for Pure Sodium Dodecyl Sulfate
Immediate Delayed Fire Pressure Reactivity SARA 313
Hazard Hazard Hazard Hazard Hazard Chemical
X
C.B.S. Scientific Company, ClearPAGE Gels, MSDS, Revision A, January 2, 2007 Page 11 of
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NFPA RATINGS for Pure Components
Component Health Flammability Reactivity Special Hazards
Tris-hydroxymethyl- - - - -
amino-methane ("Tris")
Acrylamide 2 2 2 -
Sodium Dodecyl Sulfate - - - -
HMIS Ratings for Pure Components
Component Health Flammability Reactivity Personal Protection Equipment
Tris- 1 0 0 E+n
hydroxymethyl-
amino-methane
("Tris")
Acrylamide 3 1 1 K
Sodium Dodecyl 2 0 0 I
Sulfate
16. OTHER INFORMATION
Abbreviations:
ND- No Determined
NA- Not Applicable
SARA- Superfund and Reauthorization Act
HMIS- Hazard Material Information System
WHMIS- Workplace Hazard MateriaFK Information System
NTP- National Toxicology Program
OSHA- Occupational Health and Safety Administration
IARC- International Agency for Research on Cancer
PROP 65- California Safe Drinking Water and Toxic Enforcement Act 0f 1986
EINECS- European Inventory of Existing Commercial Chemical Substances
This information is based on our present knowledge. However, this shall not constitute a
guarantee for any specific product features and shall not establish a legally valid contractual
relationship.
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