MSDS Number: SLP010
Southern Lithoplate Inc.
Material Safety Data Sheet
Clear Subtractive Developer
Section 1 - Chemical Product and Company Identification
MSDS Name: Clear Subtractive Developer
Company Identification:
Southern Lithoplate Inc.
105 Jeffrey Way
Youngsville, N.Carolina. 27596
For information in North America, call: 919-556-9400
For emergencies in the US, call CHEMTREC: 800-424-9300
Section 2 - Composition, Information on Ingredients
CAS# Chemical Name Percent EINECS/ELINCS
7732-18-5 Water >50 231-791-2
108-32-7 Propylene Carbonate 10-20 203-572-1
67-48-1 Choline Chloride 10-20 200-655-4
57-55-6 Propylene Glycol 1-5 200-338-0
9003-11-6 Methyl-oxirane polymer with oxirane 1-5
Section 3 - Hazards Identification
EMERGENCY OVERVIEW
Appearance: colorless or pale yellow liquid.
Warning! May cause eye and skin irritation.
Target Organs: Eyes, skin.
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MSDS Number: SLP010
Potential Health Effects
Eye: May cause eye irritation and inflammation.
Skin: May cause skin irritation, drying, defatting.
Ingestion: May cause gastrointestinal irritation with nausea, vomiting and diarrhea.
Inhalation: N/A
Chronic: No information
Section 4 - First Aid Measures
Eyes: In case of contact, immediately flush eyes with plenty of water for at least 15
minutes. Get medical aid.
Skin: In case of contact, flush skin with plenty of water. Remove contaminated
clothing and shoes. Get medical aid if irritation develops and persists. Wash clothing
before reuse.
Ingestion: If swallowed, do not induce vomiting unless directed to do so by medical
personnel. Never give anything by mouth to an unconscious person. Get medical aid.
Inhalation: Inhalation of this product is unlikely, however in case of exposure,
remove from exposure and move to fresh air immediately. If not breathing, give
artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician: Treat symptomatically and supportively.
Section 5 - Fire Fighting Measures
General Information: As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
During a fire, irritating and highly toxic gases may be generated by thermal
decomposition or combustion.
Extinguishing Media: Use water, foam, dry chemical, or carbon dioxide.
Flash Point: Not applicable.
Autoignition Temperature: Not available.
Explosion Limits, Lower: Not available.
Upper: Not available.
NFPA Rating: (estimated) Health: 1; Flammability: 0; Instability: 0
Section 6 - Accidental Release Measures
General Information: Use proper personal protective equipment as indicated in
Section 8.
Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then
place in suitable container. Avoid runoff into storm sewers and ditches which lead to
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MSDS Number: SLP010
waterways. Clean up spills immediately, observing precautions in the Protective
Equipment section. Provide ventilation. Observe local, state and federal regulations
regarding disposal.
Section 7 - Handling and Storage
Handling: Avoid contact with eyes, skin, and clothing. Keep container tightly closed.
Avoid ingestion and inhalation. Use with adequate ventilation. Wash clothing before
reuse.
Storage: Store in a cool, dry place. Store in a tightly closed container. Storage at
elevated temperatures may cause the release of propylene oxide and carbon dioxide
that may lead to rupture of the container.
Section 8 - Exposure Controls, Personal Protection
Engineering Controls: Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate ventilation to keep
airborne concentrations low.
Exposure Limits
Chemical Name ACGIH NIOSH OSHA - Final PELs
Water none listed none listed none listed
Propylene carbonate none listed none listed none listed
Propylene glycol none listed none listed none listed
Choline Chloride none listed none listed none listed
Methyl-oxirane
none listed none listed none listed
polymer with oxirane
OSHA Vacated PELs: Principle ingredients: No OSHA Vacated PELs are listed for
these chemicals.
Personal Protective Equipment
Eyes: Wear chemical splash goggles.
Skin: Wear appropriate protective gloves to prevent skin exposure.
Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or
European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149
approved respirator if exposure limits are exceeded or if irritation or other symptoms
are experienced.
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MSDS Number: SLP010
Section 9 - Physical and Chemical Properties
Physical State: Liquid
Appearance: colorless or pale yellow
Odor: odorless or slight odor
pH: 4.6 ?5.0 @25癈
Vapor Pressure: Not available.
Vapor Density: Not available.
Evaporation Rate: Not available.
Viscosity: Not available.
Boiling Point: ~212F.
Freezing/Melting Point: <32F
Decomposition Temperature: Not available.
Solubility: Soluble.
Specific Gravity/Density: 1.072 ?1.078
Volatile Organic Compounds (VOC) 1.73lb/gallon
Section 10 - Stability and Reactivity
Chemical Stability: Stable at room temperature and under normal storage and
handling conditions. May release gas at elevated temperatures.
Conditions to Avoid: Incompatible materials, strong acids
Incompatibilities with Other Materials: None
Hazardous Decomposition Products: Carbon monoxide, carbon dioxide, nitrogen
oxides, propylene oxide
Hazardous Polymerization: Will not occur.
Section 11 - Toxicological Information
RTECS#:
CAS# 7732-18-5: ZC0110000
LD50/LC50:
CAS# 7732-18-5:
Oral, rat: LD50 = >90 mL/kg;
.
RTECS#:
CAS# 108-32-7: FF9650000
LD50/LC50:
CAS# 108-32-7:
Draize test, rabbit, eye: 60 mg Moderate;
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MSDS Number: SLP010
Draize test, rabbit, skin: 500 mg Moderate;
Inhalation, rat: LC50 = >5 gm/m3;
Oral, mouse: LD50 = 20700 mg/kg;
Oral, rat: LD50 = 29100 uL/kg;
Skin, rabbit: LD50 = >20 mL/kg;
.
RTECS#:
CAS# 57-55-6: TY2000000
LD50/LC50:
CAS# 57-55-6:
Draize test, rabbit, eye: 100 mg Mild;
Draize test, rabbit, eye: 500 mg/24H Mild;
Oral, mouse: LD50 = 22 gm/kg;
Oral, mouse: LD50 = 20300 mg/kg;
Oral, rabbit: LD50 = 18500 mg/kg;
Oral, rat: LD50 = 20 gm/kg;
Skin, rabbit: LD50 = 20800 mg/kg;
Skin, rabbit: LD50 = 20800 mg/kg;
RTECS#:
CAS# 67-48-1: KH2975000
LD50/LC50:
CAS# 67-48-1:
Oral, mouse: LD50 = 3900 mg/kg;
Oral, rat: LD50 = 3400 mg/kg;
RTECS#:
CAS# 9003-11-6
LD50/LC50:
CAS# 9003-11-6:
Oral, rat: LD50 = >2000 mg/kg;
Skin irritation: rabbit, non-irritant (Draize test)
Eye irritation: rabbit, non-irritant (Draize test)
Carcinogenicity:
CAS# 108-32-7, CAS# 57-55-6,CAS# 67-48-1, CAS# 9003-11-6: Not listed by
ACGIH, IARC, NTP, or CA Prop 65.
CAS# 57-55-6:
Epidemiology: No information found
Teratogenicity: An expert panel convened by the NTP's Center for the Evaluation of
Risks to Human Reproduction concluded 2/13/03 that developmental and
reproductive risks stemming from exposure to the chemicals propylene glycol and
ethylene glycol are negligible.
Reproductive Effects: When propylene glycol was given at 30 percent in the diet, it
affected reproduction in rates in rats. It has generally not affected fertility or
reproduction, except at very high doses where effects could be attributed to
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MSDS Number: SLP010
nutritional deficiency.
Mutagenicity: DNA Inhibition: Subcutaneous, mouse = 8000 mg/kg.; Cytogenetic
Analysis: Subcutaneous, mouse = 8000 mg/kg.; Cytogenetic Analysis: Hamster,
Fibroblast = 32 gm/L.
Neurotoxicity: No information found
Other Studies:
Section 12 - Ecological Information
CAS# 57-55-6
Ecotoxicity: Water flea Daphnia: EC50 > 10000 mg/L; 48 Hr; UnspecifiedBacteria:
Phytobacterium phosphoreum: EC50 = 710 mg/L; 30 min; Microtox testFish:
Goldfish: LC50 > 5000 mg/L; 24 Hr; UnspecifiedFish: Guppy: LC50 > 1000 mg/L; 48
Hr; Unspecified If released to water, 1,2-propanediol is expected to degrade
relatively rapidly via biodegradation. If released to soil, relatively rapid
biodegradation should also occur. Significant leaching in soil can be predicted.
Environmental: If released to the atmosphere, it is degraded rapidly by reaction
with photochemically produced hydroxyl radicals (typical half-life of 32 hr). Physical
removal from air by rainfall is possible.
Physical: No information available.
Other: No information available.
CAS# 9003-11-6
Acute & prolonged toxicity to fish: Golden orfe/LC50 (96h): >100mg/L
Section 13 - Disposal Considerations
Chemical waste generators must determine whether a discarded chemical is
classified as a hazardous waste. US EPA guidelines for the classification
determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must
consult state and local hazardous waste regulations to ensure complete and accurate
classification. In its original supplied form the product is not considered a hazardous
waste.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
Section 14 - Transport Information
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MSDS Number: SLP010
US DOT Canada TDG
Not regulated as a hazardous Not regulated as a hazardous
Shipping Name:
material material
Hazard Class:
UN Number:
Packing Group:
Section 15 - Regulatory Information
US FEDERAL
TSCA
CAS# 7732-18-5; 108-32-7; 67-48-1; 57-55-6; 9003-11-6 are listed on the TSCA
inventory.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
None of the chemicals in this product have a TPQ.
SARA Codes
CAS # 108-32-7: immediate.
Section 313 No chemicals are reportable under Section 313.
Clean Air Act:
This material does not contain any hazardous air pollutants.
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals listed are Hazardous Substances under the CWA.
None of the chemicals in this product are listed as Priority Pollutants under the CWA.
None of the chemicals in this product are listed as Toxic Pollutants under the CWA.
OSHA:
None of the chemicals in this product are considered highly hazardous by OSHA.
STATE
CAS# 7732-18-5 is not present on state lists from CA, PA, MN, MA, FL, or NJ.
CAS# 57-55-6 can be found on the following state right to know lists:
Pennsylvania, Minnesota,
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MSDS Number: SLP010
California Prop 65
California No Significant Risk Level: None of the chemicals in this product are listed.
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
XI
Risk Phrases:
R 36 Irritating to eyes
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately with plenty of
water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face protection.
S 45 In case of accident or if you feel unwell, seek medical advice
immediately (show the label where possible).
WGK (Water Danger/Protection)
CAS# 67-48-1: 1
Canada - DSL/NDSL
CAS# 7732-18-5; 108-32-7; 57-55-6; 67-48-1; 9003-11-6 are listed on Canada's
DSL List.
Canada - WHMIS
This product has a WHMIS classification of Not controlled.
This product has been classified in accordance with the hazard criteria of the
Controlled Products Regulations and the MSDS contains all of the information
required by those regulations.
Canadian Ingredient Disclosure List
CAS# 108-32-7; 57-55-6; 67-48-1 are listed on the Canadian Ingredient
Disclosure List.
Section 16 - Additional Information
MSDS Revision Date 6/25/2009
The information above is believed to be accurate and represents the best information currently available to us.
However, we make no warranty of merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users should make their own investigations to
determine the suitability of the information for their particular purposes. In no event shall Southern Lithoplate
Inc. be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect,
incidental, consequential or exemplary damages, howsoever arising, even if Southern Lithoplate Inc has been
advised of the possibility of such damages.
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