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MSDS Material Safety Data Sheet
CAS

107-41-5 67-63-0 631-61-8 7722-76-1 7783-20-2 114460-21-8 10035-04-8 56-81-5 75277-39-3 288-32-4 10102-25-7 16674-78-5 7791-18-6 557-39-1 25322-68-3 7778-77-0 6381-59-5 6131-90-4 6131-99-3 6132-04-3 141-53-7 10049-21-5 1185-53-1 5970-45-6

File Name: 107-41-5_67-63-0_631-61-8_7722-76-1_7783-20-2_114460-21-8_10035-04.asp

                                                             Material Safety Data Sheet
MSDS Update: 11/10/2009
Version: 1.0
Date Printed:



SECTION 1 - Chemical Product & Company Identification

TM
Product Name Crystal Screen Cryo


Product Number HR2-122


Company Hampton Research
Street Address 34 Journey
City, State, Zip, Country Aliso Viejo, CA 92656, U.S.A.
Technical Phone 949 425 1321
Fax 949 425 1611
Emergency Phone 949 425 1321
For CHEMTREC Assistance, call: 800 424 9300
For International CHEMTREC Assistance, call: 703 527 3887


SECTION 2 - Composition / Information on Ingredient


Substance Name CAS # EC No SARA RTECS LD50
(+/-)-2-Methyl-2,4-pentanediol 107-41-5 203-489-0 No SA0810000 3,700 mg/kg - Rat - Oral

2-Propanol 67-63-0 200-661-7 Yes NT8050000 5,045 mg/kg - Rat - Oral

Ammonium acetate 631-61-8 211-162-9 Yes AF3675000 736 mg/kg - Mouse - Intraperitoneal

Ammonium phosphate monobasic 7722-76-1 231-764-5 No N/A 5,750 mg/kg - Rat - Oral

Ammonium sulfate 7783-20-2 231-984-1 No BS4500000 2,840 mg/kg - Rat - Oral

Calcium acetate hydrate 114460-21-8 200-540-9 No AF7525000 75 mg/kg - Mouse - Intraperitoneal

Calcium chloride dihydrate 10035-04-8 233-140-8 No EV9810000 N/A

Glycerol 56-81-5 200-289-5 No MA8050000 12,600 mg/kg - Rat - Oral

HEPES sodium 75277-39-3 278-169-7 No N/A N/A

Imidazole 288-32-4 206-019-2 No NI3325000 220 mg/kg - Rat - Oral

Lithium sulfate monohydrate 10102-25-7 233-820-4 No N/A N/A

Magnesium acetate tetrahydrate 16674-78-5 205-554-9 No AI5600000 111 mg/kg - Mouse - Intravenous

Magnesium chloride hexahydrate 7791-18-6 232-094-6 No OM2975000 8,100 mg/kg - Rat - Oral

Magnesium formate dihydrate 557-39-1 N/A No N/A N/A

Polyethylene glycol 400 25322-68-3 500-038-2 No TQ3675000 N/A

Polyethylene glycol 1,500 25322-68-3 500-038-2 No TQ4030000 44,200 mg/kg - Rat - Oral



Crystal Screen Cryo - HR2-122 www.hamptonresearch.com Page 1 of 8
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(CONTINUED) - SECTION 2 - Composition / Information on Ingredient

Substance Name CAS # EC No SARA RTECS LD50
Polyethylene glycol 4,000 25322-68-3 500-038-2 No TQ4050000 50,000 mg/kg - Rat - Oral

Polyethylene glycol 8,000 25322-68-3 500-038-2 No TQ4105000 > 50,000 mg/kg - Rat - Oral

Potassium phosphate monobasic 7778-77-0 231-913-4 No TC6615500 4,640 mg/kg - Rabbit - Dermal

Potassium sodium tartrate tetrahydrate 6381-59-5 206-156-8 No N/A N/A

Sodium acetate trihydrate 6131-90-4 204-823-8 No AJ4580000 N/A

Sodium cacodylate trihydrate 6131-99-3 204-708-2 Yes CH7890000 2,000 mg/kg - Rat - Oral

Sodium citrate tribasic dihydrate 6132-04-3 200-675-3 No N/A N/A

Sodium formate 141-53-7 205-488-0 No LR0350000 11,200 mg/kg - Mouse - Oral

Sodium phosphate monobasic
10049-21-5 231-449-2 No N/A N/A
monohydrate

TRIS hydrochloride 1185-53-1 214-684-5 No N/A N/A

Zinc acetate dihydrate 5970-45-6 209-170-2 No ZG8750000 794 mg/kg - Rat - Oral



N/A = NOT AVAILABLE



SECTION 3 - Hazards Identification

HMIS RATING HAZARD RATINGS
HEALTH HAZARD: 0 0 - LEAST
FLAMMABILITY: 0 1 - SLIGHT
REACTIVITY: 0 2 - MODERATE
3 - HIGH
NFPA RATING 4 - EXTREME
HEALTH HAZARD: 0
FLAMMABILITY: 0
REACTIVITY: 0


For additional information on toxicity, please refer to SECTION 11.



SECTION 4 - First Aid Measures

ORAL EXPOSURE
?If swallowed, wash out mouth with water provided person is conscious.
?DO NOT INDUCE VOMITING.
?Call a physician.




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TM
(CONTINUED) - SECTION 4 - First Aid Measures

INHALATION EXPOSURE
?If inhaled, remove to fresh air.
?If breathing is difficult, GIVE OXYGEN.
?Call a physician.


DERMAL EXPOSURE
?In case of contact, immediately wash skin with soap and copious amounts of water for at least 15 minutes.
?Take off contaminated clothing and shoes immediately.
?Call a physician.


EYE EXPOSURE
?In case of contact with eyes, flush with copious amounts of water for at least 15 minutes.
?Assure adequate flushing by separating the eyelids with fingers.
?Call a physician.


SECTION 5 - Fire Fighting Measures

FLASH POINT
N/A


FLAMMABILITY
N/A


AUTOIGNITION TEMPERATURE
N/A


EXTINGUISHING MEDIA
?Suitable: Water spray, Carbon dioxide, dry chemical powder, or appropriate foam.


FIREFIGHTING
?Protective Equipment: Wear self-contained breathing apparatus and protective clothing to prevent contact
with skin and eyes.
?Specific Hazard(s): Emits toxic fumes under fire conditions.


SECTION 6 - Accidental Release Measures

PROCEDURE(S) OF PERSONAL PRECAUTIONS
?Exercise appropriate precautions to minimize direct contact with skin or eyes and prevent inhalation of dust.


METHODS FOR CLEANING UP
?Wash spill site with soap solution. Flush spill area with copious amounts of water.
?Place in appropriate container.
?Ventilate area and wash spill site after material pickup is complete.

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SECTION 7 - Handling & Storage

HANDLING
?User Exposure - Ensure adequate inhalation.
- Avoid inhalation.
- Avoid contact with eyes, skin, and clothing.
- Avoid prolonged or repeated exposure.


STORAGE
?Suitable: Keep container tightly closed.


SECTION 8 - Exposure Controls / PPE

ENGINEERING CONTROLS
?Mechanical exhaust required.
?Safety shower and eye bath


PERSONAL PROTECTIVE EQUIPMENT
?Respiratory: Use respirators and components tested and approved under appropriate government standards
such as (NIOSH) or CEN (EU). Respiratory protection is not required. Where protection from
nuisance levels of dust are desired, use type N95 (US) or type (P1) (EN 143) dust masks.
?Hand: Compatible chemical-resistant gloves.
?Eye: Chemical safety goggles.


GENERAL HYGIENE MEASURES
?Wash thoroughly before and after handling.



SECTION 9 - Physical / Chemical Properties

APPEARANCE PHYSICAL STATE: Liquid


PROPERTY VALUE AT TEMPERATURE OR PRESSURE
Molecular Weight N/A
pH N/A
BP / BP Range N/A
MP / MP Range N/A
Freezing Point N/A
Vapor Pressure N/A
Vapor Density N/A
Saturated Vapor Concentration N/A
SG / Density N/A
Bulk Density N/A
Odor Threshold N/A



Crystal Screen Cryo - HR2-122 www.hamptonresearch.com Page 4 of 8
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(CONTINUED) - SECTION 9 - Physical / Chemical Properties

PROPERTY VALUE AT TEMPERATURE OR PRESSURE
Volatile % N/A
VOC Content N/A
Water Content N/A
Solvent Content N/A
Evaporation Rate N/A
Viscosity N/A
Surface Tension N/A
Partition Coefficient N/A
Decomposition Temperature N/A
Flash Point N/A
Explosion Limits N/A
Flammability N/A
Autoignition Temperature N/A
Refractive Index N/A
Optical Rotation N/A
Miscellaneous Data N/A
Solubility N/A


N/A = NOT AVAILABLE


SECTION 10 - Stability & Reactivity

STABILITY
?Stable: Stable under recommended storage conditions.


HAZARDOUS DECOMPOSITION PRODUCTS
?No data available.


HAZARDOUS EXOTHERMIC REACTIONS
?Will not occur.


HAZARDOUS POLYMERIZATION
?Will not occur.


SECTION 11 - Toxicological Information

ACUTE TOXICITY
?No data available.


IRRITATION AND CORROSION
?No data available.

Crystal Screen Cryo - HR2-122 www.hamptonresearch.com Page 5 of 8
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(CONTINUED) - SECTION 11 - Toxicological Information

SENSITISATION
?No data available.


CHRONIC EXPOSURE
?No data available.


ROUTE OF EXPOSURE
?Skin Contact: May cause skin irritation
?Skin Absorption: May be harmful if absorbed through the skin.
?Eye Contact: May cause eye irritation.
?Inhalation: Material may be irritating to mucous membranes and upper respiratory tract.
May be harmful if inhaled.
?Ingestion: May be harmful if swallowed.


SIGNS & SYMPTOMS OF EXPOSURE
?To the best of our knowledge, the chemical, physical, and toxicological properties have NOT been thoroughly
investigated.



SECTION 12 - Ecological Information

?No data available.


SECTION 13 - Disposal Considerations

APPROPRIATE METHOD OF DISPOSAL OF SUBSTANCE OR PREPARATION
?Contact a licensed professional waste disposal service to dispose of this material.
?Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an
afterburner and a scrubber.
?Observe all federal, state, and local environmental regulations.


SECTION 14 - Transportation Information

DOT (US)
?UN- Number: 3316 ?Class: N/A
?Proper Shipping Name: Chemical kits or First aid kits (containing hazardous materials)
?Non-Hazardous for Transport: This substance is considered to be non-hazardous for transport.


IATA
?UN- Number: 3316 ?Class: N/A
?Proper Shipping Name: Chemical kits or First aid kits (containing hazardous materials)
?Non-Hazardous for Transport: Non-hazardous for air transport.

Crystal Screen Cryo - HR2-122 www.hamptonresearch.com Page 6 of 8
TM
SECTION 15 - Regulatory Information

OSHA HAZARDS
?N/A


TSCA STATUS
?N/A

EU ADDITIONAL INFORMATION

Substance Name CAS # R-Phrase S-Phrase
HAZARD Code
(+/-)-2-Methyl-2,4-pentanediol 107-41-5 Xi 36/38 26-36

2-Propanol 67-63-0 F, Xi 11-36-67 7-16-24/25-26

Ammonium acetate 631-61-8

Ammonium phosphate monobasic 7722-76-1

Ammonium sulfate 7783-20-2

Calcium acetate hydrate 114460-21-8 Xi 36/37/38 26-36

Calcium chloride dihydrate 10035-04-8 Xi 36 26

Glycerol 56-81-5

HEPES sodium 75277-39-3 22-24/25

Imidazole 288-32-4 C 22-34 26-36/37/39-45

Lithium sulfate monohydrate 10102-25-7 Xn 22

Magnesium acetate tetrahydrate 16674-78-5 22-24/25

Magnesium chloride hexahydrate 7791-18-6

Magnesium formate dihydrate 557-39-1

Polyethylene glycol 400 25322-68-3

Polyethylene glycol 1,500 25322-68-3

Polyethylene glycol 4,000 25322-68-3

Polyethylene glycol 8,000 25322-68-3

Potassium phosphate monobasic 7778-77-0
Potassium sodium tartrate
6381-59-5 22-24/25
tetrahydrate
Sodium acetate trihydrate 6131-90-4

Sodium cacodylate trihydrate 6131-99-3 T, N 23/25-50/53 20/21-28-45-60-61

Sodium citrate tribasic dihydrate 6132-04-3

Sodium formate 141-53-7
Sodium phosphate monobasic
10049-21-5
monohydrate
TRIS hydrochloride 1185-53-1 Xi 36/37/38 26-36

Zinc acetate dihydrate 5970-45-6 Xn, N 22-36-50/53 26-60-61




Crystal Screen Cryo - HR2-122 www.hamptonresearch.com Page 7 of 8
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(CONTINUED) - SECTION 15 - Regulatory Information

UNITED STATES REGULATORY INFORMATION
?SARA LISTED: No
?SARA LISTED: For additional information on toxicity, please refer to SECTION 2.
?TSCA INVENTORY ITEM: N/A


CANADA REGULATORY INFORMATION
?WHMIS Classification: This product has been classified in accordance with the hazard criteria of the CPR,
and the MSDS contains all the information required by the CPR.


SECTION 16 - Other Information

DISCLAIMER
?For R&D use only. Not for drug, household, or other use.


WARRANTY
?The above information is believed to be correct but does no purport to be all inclusive and shall be used only
as a guide. The information in this document is based on the present state of our knowledge and is applicable
to the product with regard to appropriate safety precautions. It does not represent any guarantee of the proper-
ties of this product. Hampton Research Corp., shall not be held liable for any damage resulting from handling
or from contact with the above product. See reverse side of invoice or packing slip for additional terms and
conditions of sale.


?License granted to make unlimited paper copies for internal use only.


?1991-2009 Hampton Research Corp.




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