MATERIAL SAFETY DATA SHEET
SECTION 1 -- CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Cleaner with Bleach 6 / 32 oz.
PRODUCT NAME PACK
7005721
PRODUCT CODE
EMERGENCY TELEPHONE NUMBERS
05-09-01
ISSUE DATE
Medical Information: (800) 228-5635 x161
MANUFACTURER Transportation: (800) 424-9300 *
Sysco Chemical
STREET ADDRESS 1390 Enclave Parkway * For spill, leak, fire or transport accident emergencies.
CITY, STATE, ZIP Product Information: (281) 584-1790
Houston, Texas 77077
SECTION 2 -- COMPOSITION / INFORMATION ON INGREDIENTS
HAZARDOUS COMPONENT EXPOSURE LIMITS
* -- (see note below) CAS No. % by wt. OSHA PEL ACGIH TLV NIOSH REL
Sodium hypochlorite 7681-52-9 23 None None None
(10% available chlorine) (see next entry) (see next entry) (see next entry)
* Chlorine (see above) 7782-50-5 2.2 - 0.5 ppm TWA 0.5 ppm TWA 0.5 ppm TWA
2.5 1.0 ppm STEL 1.0 ppm STEL 1.0 ppm STEL
Lauryl dimethyl amine oxide 1643-20-5 <5 None None None
Sodium n-decyl diphenyloxide 36445-71-3 <5 None None None
disulfonate
* -- Asterisked ingredients are those considered hazardous according to the criteria of 29CFR 1910.1200.
Other ingredients are listed for informational purposes to assist emergency medical response personnel.
SECTION 3 -- HAZARDS IDENTIFICATION
EMERGENCY Corrosive; may cause skin and eye irritation or chemical burns to broken skin.
Vapors irritating to eyes and respiratory tract.
OVERVIEW
Harmful and potentially fatal if swallowed.
POTENTIAL HEALTH EFFECTS
Can cause corrosion of mucous membranes, severe esophageal burns and
INGESTION .................
perforation of esophagus or stomach.
Inhalation of vapors can cause bronchial irritation, coughing, difficulty in
INHALATION ...............
breathing, nausea and pulmonary edema.
Corrosive to the eyes; may cause severe and permanent damage.
EYE CONTACT ............
Irritant; prolonged contact can produce blistering and eczema.
SKIN CONTACT ..........
Cleaner with Bleach 7005721
PRODUCT CODE PAGE 2 OF 4
MSDS
SECTION 4 -- FIRST AID MEASURES
If swallowed, DO NOT induce vomiting. Immediately drink a large quantity of water. Do not
INGESTION
use acidic antidotes or sodium bicarbonate (baking soda). Call a physician or poison control
center immediately.
If exposed to excessive vapor levels, remove to fresh air and seek medical attention if cough or
INHALATION
other symptoms develop.
Immediately flush eye with plenty of cool, running water. Remove contact lenses if applicable,
EYE CONTACT
and continue flushing for at least 15 minutes. Get medical attention immediately.
Flush affected skin area with copious amounts of water and wash with soap and water. If
SKIN CONTACT
irritation develops or persists, get medical attention. Remove clothing and wash before reuse.
Information pertaining to ingestion toxicology, therapy, symptomatology and treatment can be
NOTE TO
found in Clinical Toxicology of Commercial Products, authored by Gosselin, Smith and Hodge
PHYSICIAN
and published by Williams & Wilkins, Baltimore, Maryland.
See listing for Hypochlorite in Therapeutics Index, Section III.
SECTION 5 -- FIRE FIGHTING MEASURES
None / N.A. Not flammable or
FLASH POINT / METHOD FLAMMABLE
combustible
LIMITS
If involved in a fire, alcohol foam, carbon dioxide, dry chemical or water fog.
EXTINGUISHING MEDIA
Use extinguishing media that is appropriate for surrounding fire.
Avoid fumes from spilled or exposed liquid. Firefighters should wear full protective
SPECIAL FIRE FIGHTING
clothing and OSHA/NIOSH self-contained breathing apparatus. Cool fire-exposed
PROCEDURES
containers with water spray from a safe distance.
Sodium hypochlorite bleach is a strong oxidizing agent and decomposes when
FIRE AND EXPLOSION
heated. Decomposition products may cause containers to explode. Vigorous
HAZARDS
reactions may occur with organic materials or oxidizable materials, causing fires.
SECTION 6 -- ACCIDENTAL RELEASE MEASURES
Small spills: Dilute product by flooding area with large quantity of water and flush to sanitary sewer.
RESPONSE
Large spills: Contain run-off by diking with suitable material. Soak up liquid on inert absorbent and
TO SPILLS
transfer to approved container. Prevent spill from entering sewers or waterways.
SECTION 7 -- HANDLING AND STORAGE
Wash after handling and before eating.
HANDLING
Use personal protective equipment and wear suitable chemical-resistant clothing.
PRECAUTIONS
Keep container tightly closed when not in use. Follow label directions closely.
Store upright in a cool (below 85 F), dry, well-ventilated area. Keep away from heat or direct
STORAGE
sunlight. Separate from incompatible materials, such as acids, ammonia, soap-based products
PRECAUTIONS
or organic materials. Protect containers from physical damage. Keep away from children.
Cleaner with Bleach 7005721
MSDS PRODUCT CODE PAGE 3 OF 4
SECTION 8 -- EXPOSURE CONTROLS / PERSONAL PROTECTION
Avoid breathing vapors. Do not store near food stuffs, water or feed.
HYGIENIC PRACTICES
Protect eyes, skin and clothing from contact with this product.
Use local ventilation to remove vapors at the source.
ENGINEERING CONTROLS
Facilities using this product must be equipped with an eyewash station.
PERSONAL PROTECTIVE EQUIPMENT
X Not normally necessary; use NIOSH approved respirator for concentrated vapors
RESPIRATOR
X GOGGLES / FACE SHIELD Required; goggles should be chemical splash type. Face shield also helpful.
X Recommended to avoid skin contact and protect clothing from damage
APRON
X GLOVES Required; use impervious PVC or Neoprene with long gauntlet
X Recommended to protect shoes and feet when using product for floor cleaning
BOOTS
SECTION 9 -- PHYSICAL AND CHEMICAL PROPERTIES
Hazy pale yellow liquid Not established
APPEARANCE BOILING POINT
Chlorine Not established
ODOR FREEZING POINT
12.0 Not established
pH VAPOR PRESSURE
1.060 Not applicable
SPECIFIC GRAVITY VAPOR DENSITY
Complete Not applicable
SOLUBILITY IN WATER EVAPORATION RATE
SECTION 10 -- STABILITY AND REACTIVITY
X
STABLE UNSTABLE
CHEMICAL STABILITY
Heat or direct sunlight; temperatures above 85 F.
CONDITIONS TO AVOID
Do not mix with solutions containing ammonia.
Acids, ammonia, ether, urea, oxidizable materials, soaps, oils, greases, phenolic
INCOMPATIBILITY
disinfectants and metals (including nickel, copper, tin, aluminum and iron.
Chlorine gas -- from contact with highly acidic materials.
HAZARDOUS PRODUCTS
Chloramines -- from contact with ammonia.
OF DECOMPOSITION
Polychlorinated phenols -- from contact with phenolic disinfectants.
X
WILL NOT OCCUR MAY OCCUR
POLYMERIZATION
Not applicable
CONDITIONS TO AVOID
SECTION 11 -- TOXICOLOGICAL INFORMATION
CARCINOGENICITY
THIS PRODUCT CONTAINS A KNOWN OR SUSPECTED CARCINOGEN
X THIS PRODUCT DOES NOT CONTAIN ANY KNOWN OR ANTICIPATED CARCINOGENS ACCORDING TO
THE CRITERIA OF THE NTP ANNUAL REPORT ON CARCINOGENS AND OSHA 29 CFR 1910, Z
OTHER EFFECTS
Toxicity arises from corrosive activity; stems from oxidizing potency, a function of concentration
ACUTE
Not determined
CHRONIC
Cleaner with Bleach 7005721
PRODUCT CODE PAGE 4 OF 4
MSDS
SECTION 12 -- ECOLOGICAL INFORMATION
X
CONSIDERED BIODEGRADABLE NOT BIODEGRADABLE
BIODEGRADABILITY
Not established
BOD / COD VALUE
No data available
ECOTOXICITY
SECTION 13 -- DISPOSAL CONSIDERATIONS
Small amounts of unused product may be flushed to the sanitary sewer with plenty of water.
WASTE DISPOSAL Contact local water board before flushing large amounts. If solidified, large amounts may be
METHOD disposed of in a sanitary landfill. Contact state or local authorities for additional restrictions.
Non-hazardous
RCRA CLASSIFICATION
X 2 - HDPE
YES CODE NO
RECYCLE CONTAINER
SECTION 14 -- TRANSPORT INFORMATION
X
HAZARDOUS NOT HAZARDOUS
DOT CLASSIFICATION
Not applicable
DESCRIPTION
None
SYSCO HM CODE
SECTION 15 -- REGULATORY INFORMATION
REGULATORY STATUS
EPA REGISTERED (UNDER FIFRA)
FDA REGULATED
KOSHER
X SARA TITLE III MATERIAL Sodium hypochlorite (Section 304)
USDA AUTHORIZED
X Controlled Product, Class E - Corrosive Material
CANADA WHMIS
SECTION 16 -- OTHER INFORMATION
NFPA CLASSIFICATION
2 HEALTH HAZARD
BLUE
0 FLAMMABILITY
RED
1 REACTIVITY
YELLOW
OX SPECIAL HAZARD
WHITE
Information contained in this MSDS refers only to the specific material designated and does not relate to any process or use involving other
materials. This information is based on data believed to be reliable, and the Product is intended to be used in a manner that is customary
and reasonably foreseeable. Since actual use and handling are beyond our control, no warranty, express or implied, is made and no liability
is assumed by Sysco in connection with the use of this information.
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