3M Canada Company
1840 Oxford Street East, Post Office Box 5757
London, Ontario N6A 4T1
Medical Emergency Telephone: (519) 451-2500, Ext. 2222
Transportation Emergency Telephone (CANUTEC): (613) 996-6666
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Material Safety Data Sheet
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Document id : 10-2821-6 Issue date : 2008/06/10
Version : 15.00 Supersedes date : 2007/06/08
Copyright, 1997, 3M Canada Company. All rights reserved. Copying
and/or downloading of this information for the purpose of properly
utilizing 3M products is allowed provided that: (1) the information
is copied in full with no changes unless prior written agreement is
obtained from 3M, and (2) neither the copy nor the original is resold
or otherwise distributed with the intention of earning a profit
thereon.
Prepared by: Corporate Regulatory Services, 3M Canada Company
Telephone: (800) 364-3577, Fax: (800) 603-7758, Web Site: www.3M.ca
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1 Product Identification
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Tradename:
SCOTCHGARD(TM) SPOT REMOVER & UPHOLSTERY CLEANER
Product ID:
FZ-0100-0399-8 XN-1015-6743-8 FZ-0100-0469-0 FZ-0100-0470-8
FZ-0100-0472-4 XN-1014-3527-1 61-5000-0319-1 61-5000-6133-0
FZ-0100-0471-6 70-0709-9785-6 70-0709-9786-4 70-0711-6295-5
Intended Use of Product:
Cleaner;
Division:
COMMERCIAL CARE DIVISION
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2 Composition/Information on Ingredients
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Ingredient Name CAS Number Percentage
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WATER 7732-18-5 60 - 100
PETROLEUM GASES, LIQUEFIED, SWEETENED 68476-86-8 3 - 7
2-BUTOXYETHANOL 111-76-2 1 - 5
SODIUM OLEYLMETHYLTAURIDE 137-20-2 0.5 - 1.5
STYRENE MALEIC ANHYDRIDE RESIN, 52720-34-0 0.1 - 1.5
AMMONIUM SALT
AMMONIA 7664-41-7 0.1 - 1
SODIUM OLEATE 143-19-1 0.1 - 1
SODIUM LAURYL SULFATE 151-21-3 0.1 - 1
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NOTE:
Each percentage is expressed as the ratio of the weight of the
ingredient to the weight of the controlled product.
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3 Hazards Identification
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Critical Hazards:
Aerosol container contains gas under pressure.
Moderate Eye Irritation: Signs/symptoms may include redness,
swelling, pain, tearing, and blurred or hazy vision.
May be absorbed through skin and cause target organ effects.
May be absorbed following inhalation and cause target organ effects.
Very toxic by inhalation.
See Sections 7 and 11 for further information.
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4 First Aid Measures
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Instructions for Eye Contact:
Flush eyes with large amounts of water. If signs/symptoms persist,
get medical attention.
Instructions for Skin Contact:
Wash affected area with soap and water. If signs/symptoms develop,
get medical attention.
Instructions for Inhalation:
Remove person to fresh air. If signs/symptoms develop, get medical
attention.
Instructions for Ingestion:
Do not induce vomiting unless instructed to do so by medical
personnel. Give victim two glasses of water. Never give anything
by mouth to an unconscious person. Get medical attention.
Special Instructions:
Exposure may increase myocardial irritability. Do not administer
sympathomimetic drugs unless absolutely necessary.
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5 Fire Fighting Measures
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Flash point: Not applicable
(NON-FLAMMABLE ACCORDING TO
FLAME PROJECTION TEST)
Lower Explosive Limit (%): Not Available
Upper Explosive Limit (%): Not Available
Autoignition temperature: Not Available
Suitable Extinguishing Media:
Use fire extinguishers with class B extinguishing agents (e.g., dry
chemical, carbon dioxide).
Exposure Hazards during Fire:
Closed containers exposed to heat from fire may build pressure and
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explode. Aerosol container contains gas under pressure.
Combustion Products from Fire:
Carbon Monoxide;
Carbon Dioxide;
Fire Fighting Procedures:
Water may not effectively extinguish fire; however, it should be
used to keep fire-exposed containers and surfaces cool and prevent
explosive rupture. Wear full protective equipment (Bunker Gear) and
a self-contained breathing apparatus (SCBA).
NFPA: Health 2
NFPA: Fire 2
NFPA: Reactivity 0
NFPA: Unusual Reaction Hazard none
Special Instructions:
Aerosol container contains flammable material under pressure.
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6 Accidental Release Measures
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Personal Precautions:
Observe precautions from other sections. Call 3M- HELPS line
(1-800-364-3577) for more information on handling and managing the
spill.
Spill Response:
Evacuate unprotected and untrained personnel from hazard area. The
spill should be cleaned up by qualified personnel. Ventilate the
area with fresh air. If possible, seal leaking container. Place
leaking containers in a well-ventilated area, preferably an
operating exhaust hood, or if necessary outdoors on an impermeable
surface until appropriate packaging for the leaking container or
its contents is available. Clean up residue with water. Collect the
resulting residue containing solution. Dispose of collected
material as soon as possible.
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7 Handling and Storage
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Storage Requirements:
Store at temperatures below 120 degrees F (49 degrees C).
Incompatible Materials:
Store away from heat;
Store out of direct sunlight.
Store away from acids;
Store away from oxidizing agents.
Sparks and/or Flames;
Ventilation:
No data available.
Fire Prevention:
Aerosol container contains gas under pressure. Do not spray near
flames or sources of ignition.
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Use Instructions:
Do not pierce or burn container, even after use. Avoid contact with
oxidizing agents. For industrial or professional use only.
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8 Exposure Controls/Personal Protection
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Personal Protection
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Eye Protection:
Avoid eye contact with vapours, mists, or spray.
The following should be worn alone or in combination, as
appropriate, to prevent eye contact:
Safety glasses with side shields
Hand Protection:
Gloves not normally required.
Skin Protection:
Avoid prolonged or repeated skin contact.
Respiratory Protection:
Avoid breathing of vapours, mists or spray.
Under normal use conditions, airborne exposures are not expected to
be significant enough to require respiratory protection.
Ingestion (Prevention):
Do not eat, drink or smoke when using this product. Wash exposed
areas thoroughly with soap and water.
Keep out of the reach of children.
Recommended Ventilation:
Use in a well-ventilated area.
Do not use in a confined area or areas with little or no air
movement.
Ingredient Exposure Data
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WATER (7732-18-5)
LD50 (rat, oral) > 90 ml/kg
LC50 (rat, inhalation/4 hours) No data available.
Exposure Limits
No data available.
PETROLEUM GASES, LIQUEFIED, SWEETENED (68476-86-8)
Specific Ingredient Data
No data available.
LD50 (rat, oral) No data available.
LC50 (rat, inhalation/4 hours) No data available.
Exposure Limits
No data available.
2-BUTOXYETHANOL (111-76-2)
LD50 (rat, oral) 470 mg/kg
LD50 (dermal, rabbit) � 99 mg/kg
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LC50 (rat, inhalation/4 hours) 450 ppm
Exposure Limits
ACGIH: TWA � 25 ppm (Table A3) 20 ppm
SODIUM OLEYLMETHYLTAURIDE (137-20-2)
LD50 (rat, oral) 1700 mg/kg
LC50 (rat, inhalation/4 hours) No data available.
Exposure Limits
No data available.
STYRENE MALEIC ANHYDRIDE RESIN, AMMONIUM SALT (52720-34-0)
Specific Ingredient Data
No data available.
LD50 (rat, oral) No data available.
LC50 (rat, inhalation/4 hours) No data available.
Exposure Limits
No data available.
AMMONIA (7664-41-7)
LD50 (rat, oral) 350 mg/kg
LC50 (rat, inhalation/4 hours) 2000 ppm
Exposure Limits
ACGIH: TWA 25 ppm
ACGIH: TWA 17 mg/m3
ACGIH: STEL 35 ppm
ACGIH: STEL 24 mg/m3
SODIUM OLEATE (143-19-1)
LD50 (rat, oral) No data available.
LC50 (rat, inhalation/4 hours) No data available.
Exposure Limits
No data available.
SODIUM LAURYL SULFATE (151-21-3)
LD50 (rat, oral) 1288 mg/kg
LC50 (rat, inhalation/4 hours) No data available.
Exposure Limits
No data available.
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9 Physical and Chemical Properties
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Physical form,Color,Odour: Gas; Aerosol; Clear; mild
odour;
Odour Threshold: No data available.
pH: 8.5 - 9.5
Boiling point/boiling range: Approximately 100 C
Melting point/melting range: Not applicable
Vapour pressure: Not Available
Water Solubility: Complete
Specific gravity: 1 Water=1
Vapour density: Not Available
Volatile organic compounds: < 7 % CARB
Evaporation rate: Not Available
Viscosity: Not Available
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Percent Volatile: 60 - 100 %
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10 Stability and Reactivity
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Conditions to Avoid:
Heat;
Sparks and/or Flames;
Store out of direct sunlight.
Materials to Avoid:
Strong oxidizing agents;
Strong acids;
Hazardous Decomposition:
Carbon Monoxide;
Carbon Dioxide;
Stability and Reactivity:
Stable. Hazardous polymerization will not occur.
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11 Toxicological Information
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Effects from Eye Contact:
Moderate Eye Irritation: Signs/symptoms may include redness,
swelling, pain, tearing, and blurred or hazy vision.
Effects from Skin Contact:
Mild Skin Irritation: Signs/symptoms can include localized redness,
swelling, and itching.
May be absorbed through skin and cause target organ effects.
Effects from Inhalation:
May be absorbed following inhalation and cause target organ effects.
Respiratory Tract Irritation: Signs/symptoms may include cough,
sneezing, nasal discharge, headache, hoarseness, and nose and
throat pain.
Effects from Ingestion:
Gastrointestinal Irritation: Signs/symptoms may include abdominal
pain, stomach upset, nausea, vomiting and diarrhea.
Sensitization Information:
No data available.
Carcinogenicity:
No data available.
Mutagenicity:
No data available.
Reproductive Effects:
No data available.
Component Based Information:
No data available.
Product Based Information:
Very toxic by inhalation.
Other Effects & Information:
Central Nervous System (CNS) Depression: Signs/symptoms may include
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headache, dizziness, drowsiness, incoordination, nausea, slowed
reaction time, slurred speech, giddiness, and unconsciousness.
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12 Ecological Information
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Environmental Data:
Persistence/Biodegradability:
The surfactant(s) contained in this preparation comply with the
biodegradability criteria as laid down in Regulation (EC)
No.648/2004 on detergents.
Ecotoxicity Data:
Not determined.
Ecofate Data:
Not determined.
Special statements for 2001/58/EC:
One or more components of this product have significant known or
predicted environmental hazards, but a conservative assessment
indicates a low environmental risk. Intended use and proper
disposal are unlikely to cause the environmentally hazardous
component(s) to enter the environment in quantities or by routes
that could cause the adverse environmental impacts.
Other Effects and Information:
Product usages, or other lifecycle stages, are expected to release
volatile organic compounds (VOCs) to the atmosphere. Regulations
may restrict the release of VOCs because they contribute to the
formation of ozone and smog. Regulatory definitions for VOC vary.
Because of smog and other impacts, releases through evaporation or
other means should be minimized to the extent possible.
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13 Disposal Considerations
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Product as Sold:
Incinerate in an industrial or commercial facility. Facility must
be capable of handling aerosol cans. Dispose of empty product
containers in a sanitary landfill.
Product Packaging:
No data available.
Special Instructions:
Since regulations vary, consult applicable regulations or
authorities before disposal.
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14 Transport Information
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Transportation of Dangerous Goods
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TDG Classification: Consumer Commodity
Class/Division: 2.2
Special Information:
International Dangerous Goods Classification
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15 Regulatory Information
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WHMIS Classification: A, D1A, D2B
XN101567438
Exempt (Consumer Product)
NOTE:
This product has been classified in accordance with the hazard
criteria of the Controlled Products Regulations (CPR) and the MSDS
contains all the information required by the CPR.
Product Certifications:
The product on this MSDS, or all its components, is included on the
following countries' chemical inventories, as noted:
DSL - Domestic Substances List (Canada)
CICS - Chinese Inventory of Chemical Substances
EINECS - European Inventory of Existing Commercial Chemical
Substances
MITI - Ministry of International Trade and Industry (JAPAN)
TSCA - Toxic Substances Control Act (USA)
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16 Other Information
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Reason for Reissue:
The following Sections and topics have been updated or revised:
Added French translation to MSDS
The information in this Material Safety Data Sheet (MSDS) is believed
to be correct as of the date issued. 3M MAKES NO WARRANTIES,
EXPRESSED OR IMPLIED, STATUTORY OR OTHERWISE, INCLUDING, BUT NOT
LIMITED TO, ANY IMPLIED WARRANTY OR CONDITION OF MERCHANTABILITY OR
FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. User is responsible for determining whether the 3M product is
fit for a particular purpose and suitable for user's method of use or
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application. Given the variety of factors that can affect the use
and application of a 3M product, some of which are uniquely within
the user's knowledge and control, it is essential that the user
evaluate the 3M product to determine whether it is fit for a
particular purpose and suitable for user's method of use or
application.
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