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MSDS Material Safety Data Sheet
CAS

67-64-1 149-57-5 22221-10-9 58823-74-8

File Name: 67-64-1_149-57-5_22221-10-9_58823-74.asp

 
LOCTITE CORPORATION 07/02/97
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100

MATERIAL SAFETY DATA SHEET Page 01 of 05

Locquic(R) Primer N 7649
19266

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Name: Locquic(R) Primer N 7649
Item No.: 19266
Product Type: Accelerator

2. COMPOSITION, INFORMATION ON INGREDIENTS


Ingredients CAS No. %

ACETONE 67-64-1 95-100
2-Ethylhexanoic acid 149-57-5 0.1-1
Organo-copper compound 22221-10-9 0.1-1
Trialkylammonium Carboxylate 58823-74-8 0.1-1


Ingredients which have exposure limits

Exposure Limits (TWA) ACGIH OSHA OTHER
Ingredients (TLV) (PEL)

ACETONE 750 ppm TWA 750 ppm TWA None
1780 mg/m3 1800 mg/m3
Organo-copper compound Cu 0.2mg/m3fume Cu 0.1mg/m3 None
Cu 1 mg/m3 dust Cu 1 mg/m3 dust

Exposure Limits (STEL) ACGIH OSHA
Ingredients (TLV) (PEL)

ACETONE 1000 ppm 1000 ppm
2380 mg/m3 2400 mg/m3

3. HAZARDS IDENTIFICATION

Toxicity: Harmful if inhaled or swallowed.
Possible eye and respiratory irritant.
Narcotic at high concentrations.
Prolonged inhalation may cause headaches.
Moderately toxic by ingestion
Liquid may defat skin.
Primary Routes of Entry: Inhalation, ingestion, contact.
Signs and symptoms
of Exposure: Vapors irritate eyes, nose and throat.
Liquid is an eye irritant and may irritate skin.
Existing Conditions
Aggravated by Exposure: None known










LOCTITE CORPORATION 07/02/97
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100

MATERIAL SAFETY DATA SHEET Page 02 of 05

Product Name: Locquic(R) Primer N 7649
Item No.: 19266

3. HAZARDS IDENTIFICATION (continued)

Literature Referenced Carcinogen
Ingredients Target Organ and Other Health Effects NTP IARC OSHA

ACETONE BLO CNS IRR NO NO NO
2-Ethylhexanoic acid IRR NO NO NO
Organo-copper compound No Data NO NO NO
Trialkylammonium Carboxylate No Data NO NO NO
-------------------------------------------------------------------------------

Abbreviations

BLO Blood CNS Central nervous system
IRR Irritant


4. FIRST AID MEASURES

Ingestion: Give water to dilute. Do not induce vomiting.
Keep individual calm. Obtain medical attention.
Inhalation: Remove to fresh air. If symptoms persist, obtain
medical attention.
Skin Contact: Wash with soap and water.
Eye Contact: Flush with water for at least 15 minutes. Obtain
medical attention.

5. FIRE FIGHTING MEASURES

Flash Point: Approximately -4癋 Method: Tag Closed Cup
Recommended
Extinguishing Agents: Carbon dioxide, foam, dry chemical
Hazardous Products formed
by Fire or Thermal Decomp Irritating organic vapors
Unusual Fire or
Explosion Hazards: None

Explosive Limits:
(% by volume in air)Lower 2.6%
(% by volume in air)Upper 13%

6. ACCIDENTAL RELEASE MEASURES

Steps to be taken in case
of spill or leak: Avoid flame and sparks. Maintain adequate
ventilation. Soak up in an inert absorbent and
store in a closed container until disposal.










LOCTITE CORPORATION 07/02/97
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100

MATERIAL SAFETY DATA SHEET Page 03 of 05

Product Name: Locquic(R) Primer N 7649
Item No.: 19266

7. HANDLING AND STORAGE

Safe Storage: Store away from flame and sparks.
Keep below 100癋
(Contact Loctite Customer Service 1-800-243-4874 for shelf Life information)
Handling: Avoid prolonged breathing of fumes. Avoid skin
or eye contact. Do not use near heat, sparks, or
open flame.

8. EXPOSURE CONTROLS, PERSONAL PROTECTION

Eyes: Safety glasses or goggles.
Skin: Rubber or plastic gloves.
Ventilation: Sufficient to maintain vapor concentration
below TLV.

See Section 2 for Exposure Limits.

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance: Green liquid
Odor: Acetone
Boiling Point: 133癋
pH: Does not apply
Solubility in Water: Miscible
Specific Gravity 0.7936
Volatile Organic Compound
(EPA Method 24) 1.48%; 11.7 grams per liter of material
Vapor Pressure: Approximately 172mm Hg at 68癋
Vapor Density: Not available
Evaporation Rate
(Ether = 1) 1.9

10. STABILITY AND REACTIVITY

Stability: Stable
Hazardous Polymerization: Will not occur
Incompatibility: Strong oxidizers, peroxides
Conditions to Avoid: Not available
Hazardous Decomposition
Products (non-thermal): None

11. TOXICOLOGICAL INFORMATION

See Section 3.












LOCTITE CORPORATION 07/02/97
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100

MATERIAL SAFETY DATA SHEET Page 04 of 05

Product Name: Locquic(R) Primer N 7649
Item No.: 19266

12. ECOLOGICAL INFORMATION

No data available

13. DISPOSAL CONSIDERATIONS

Recommended methods of
disposal: Incinerate following EPA and local regulations.
EPA Hazardous Waste
Number D001 - Hazardous waste per 40CFR 261.21

14. TRANSPORTATION INFORMATION

DOT (49 CFR 172)
Domestic Ground Transport
Proper Shipping Name: Comsumer Commodity (Not more than one liter);
Acetone solution (More than one liter)
Hazard Class or
Division: ORM-D (Not more than one liter);
Class 3, Packing Group II (More than one liter)
Identification Number: None (Not more than one liter);
UN 1090 (More than one liter)
Marine Pollutant: None
IATA
Proper Shipping Name: Consumer Commodity (Not more than 500 ml);
Acetone solution (More than 500 ml)
Class or Division: Class 9 (Not more than 500 ml);
Class 3, Packing Group II (More than 500 ml)
UN or ID Number: ID 8000 (Not more than 500 ml);
UN 1090 (More than 500 ml)

15. REGULATORY INFORMATION

CA Proposition 65: No California Proposition 65 chemicals are known
to be present.

16. OTHER INFORMATION

Estimated NFPA(R) Code:
Health Hazard: 2
Fire Hazard: 3
Reactivity Hazard: 0
Specific Hazard: Does not apply

Estimated HMIS(R) Code:
Health Hazard: 2*
Flammability Hazard: 3
Reactivity Hazards: 0
Personal Protection: See Section 8.








LOCTITE CORPORATION 07/02/97
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100

MATERIAL SAFETY DATA SHEET Page 05 of 05

Product Name: Locquic(R) Primer N 7649
Item No.: 19266

16. OTHER INFORMATION (continued)

NFPA is a registered trademark of the National Fire Protection Assn.
HMIS is a registered trademark of the National Paint and Coatings Assn.

Prepared By: Stephen Repetto
Title: Research Chemist, Environmental Health & Safety
Company: Loctite Corp., 1001 Tr Br Cr, Rocky Hill CT 06067
(24hr.) Phone: (860) 571-5100
Revision Date: January 22, 1996 Revision: 0007















































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