www.Titebond.comFranklin International
MATERIAL SAFETY DATA SHEET
MSDS Name: Titebond Heavy Duty Construction Adhesive
MSDS Number: 45261
Revision Date: 7/1/04
SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Product Name: Titebond Heavy Duty Construction
Adhesive
CAS Number: none
HMIS Hazard Rating: Health: 2 Fire: 3 Reactivity: 0
Company Identification: Franklin International
2020 Bruck Street
Columbus OH 43207
Contact: Franklin Technical Services
Telephone/Fax: (800) 877-4583 (614) 445-1493
Emergency Phone (24 Hour): Franklin Security
(614) 445-1300
Chemtrec (24 Hour): (800) 424-9300
Chemtrec International: (703) 527-3887
Product Class solvent based
Product Use: construction adhesive
Product Code: 3195
Division: Construction Adhesives & Sealants
SECTION 2 - COMPOSITION AND INFORMATION ON INGREDIENTS
Hazardous Ingredients CAS Number Percent
acetone 67-64-1 13.35
hexane 110-54-3 13.18
toluene 108-88-3 8.31
OSHA PELs & ACGIH TLVs are listed in Section 8 where applicable.
SECTION 3 - HAZARD IDENTIFICATION
NOTE:
Repeated and prolonged overexposure to the mixture of solvent(s)
listed in Section 2 can result in systemic effects including
permanent brain, nervous system, liver, and kidney damage.
Intentional misuse by deliberately concentrating & inhaling the
contents may be harmful or fatal.
EMERGENCY OVERVIEW:
Product is a beige, medium viscosity mastic.
DANGER: EXTREMELY FLAMMABLE, VAPOR HARMFUL. CONTAINS ACETONE,
TOLUENE AND HEXANE. Vapors can cause flash fire. Vapors can ignite
explosively. Prevent buildup of vapors by opening all windows and
doors to create cross-ventilation. Keep away from heat, sparks and
open flame. Do not smoke. Turn off stoves, heaters and sparking
electric motors. Keep container tightly closed when not in use.
Avoid prolonged breathing of vapor. KEEP OUT OF THE REACH OF
CHILDREN.
ROUTES OF ENTRY:
Ingestion: Yes
Inhalation: Yes
Skin: Yes
Eye: Yes
INHALATION:
Avoid breathing vapor or mists.
May cause headaches and dizziness.
High vapor concentrations are irritating to the nose, throat and
lungs and can cause systemic effects.
Vapors can readily accumulate in confined or poorly ventilated areas.
INGESTION:
Ingestion is not a probable route of exposure. Harmful if swallowed.
SKIN:
May be harmful if absorbed through skin, may produce kidney, liver and
central nervous system damage.
A single exposure is not likely to result in the material
being absorbed through the skin in harmful amounts.
EYE:
Substance may cause severe eye irritation.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE:
Preexisting neurological conditions, skin disorders, and respiratory
diease.
CARCINOGENICITY:
IARC: No
NTP: No
OSHA: No
REPRODUCTIVE TOXICITY:
Toluene may be harmful to the human fetus based on positive test
results with laboratory animals. Case studies show that prolonged
intentional abuse of toluene during pregnancy can cause birth defects
in humans.
TARGET ORGANS:
Prolonged or repeated overexposure may cause eye, skin, respiratory
system, central nervous system, peripheral nervous system, liver and
kidney damage.
SECTION 4 - FIRST AID MEASURES
Epinepherine and other sympathomimetic drugs may initiate cardiac
arrhythmias (irregular beating) in persons exposed to high
concentrations of hexane (e.g. in enclosed spaces or with deliberate
abuse). If used, monitor heart action closely. Consider use of other
drugs with less arrhythmogenic potential.
INHALATION:
Remove to fresh air. If difficulty persists seek medical attention.
INGESTION:
Call poison control center immediately. Follow their specific
instructions. Do not induce vomiting.
SKIN:
Wash with soap and water. Contact a physician if irritation develops
or persists.
EYE:
Hold eyelids apart and flush with plenty of water for at least 15
minutes. Seek medical attention.
SECTION 5 - FIRE-FIGHTING MEASURES
Flammability Class (OSHA) IB
Flash Point: < 0 F
Setaflash
Explosive Range: Lower explosive limit 1.2%
Upper explosive limit 12.8%
Flammable liquid. Can form explosive mixtures at temperatures at or
above the flashpoint
EXTINGUISHING MEDIA:
Use alcohol foam, carbon dioxide, or dry chemical when fighting fires
involving this product.
HAZARDOUS COMBUSTION PRODUCTS:
Oxides of carbon may be released during combustion.
FIRE FIGHTING PROCEDURES:
Wear a NIOSH approved self contained breathing apparatus. Wear
appropriate personal protective equipment.
Water may be ineffective, but may be used to cool exposed containers
to prevent pressure build-up and possible auto ignition or explosion
when exposed to extreme heat.
SECTION 6 - ACCIDENTAL RELEASE MEASURES
CONTAINMENT TECHNIQUES:
Use inert absorbent to dike the spill. Keep away from drains.
CLEAN-UP:
If possible pump liquid into an approved container or spread absorbent
over spill and shovel (use non-sparking equipment) product/ absorbent
mixture into an approved container. If product has dried, scrape up
and place in an approved container.
EMERGENCY MEASURES:
Isolate hazard area. Keep unnecessary and unprotected personnel from
entering area. Wear all appropriate personal protection equipment
(PPE) (see Section 8).
SECTION 7 - HANDLING AND STORAGE
HANDLING:
Avoid breathing vapors from the headspace of containers.
Keep lid closed when not in use.
Use only in well ventilated area.
Follow all MSDS/label precautions even after container is emptied.
Containers may retain product residues and vapors.
STORAGE:
Keep away from sources of ignition.
Do not store above 110F. Store large quantities in buildings designed
& protected for storage of NFPA Class 1-B flammable materials.
SECTION 8 - EXPOSURE CONTROLS AND PERSONAL PROTECTION
Occupational Exposure Limits
ACGIH TLV ACGIH TLV-C ACGIH STEL OSHA STEL OSHA PEL
acetone
500.00 PPM N/est 1000.00 PPM N/est 1000.00 PPM
hexane
50.00 PPM N/est N/est N/est 500.00 PPM
toluene
50.00 PPM N/est N/est N/est 200.00 PPM
The OSHA Ceiling for toluene is 300 ppm.
ENGINEERING CONTROLS:
Use local exhaust as needed to maintain occupational exposure limits.
Maintain standard plant ventilation.
OTHER:
Facilities storing or utilizing any chemical should be equipped with
an eyewash facility and a safety shower.
RESPIRATORY PROTECTION:
Where exposure limits may be exceeded select a NIOSH approved
respirator with appropriate Protection Factor and cartridge for the
specific contaminents. Follow requirements for respiratory protection
in OSHA 1910.134.
EYE PROTECTION:
Chemical splash goggles (ANSI Z87.1 or approved equivalent).
SKIN PROTECTION:
Where skin contact can occur, wear impervious gloves.
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
Form: Mastic
Appearance/Color: Beige
Odor: Solvent
Solubility (in water): Nil
pH Value: Not Applicable
Boiling Range/Point: 121.疐
Evaporation Rate: Faster than n-Butyl Acetate
% Volatile: 34.%
Specific Gravity: 1.06
VOC: 282 g/l
SECTION 10 - STABILITY AND REACTIVITY
Stability: This product is stable
Hazardous Polymerization: Hazardous polymerization will not occur
CONDITIONS TO AVOID:
Heat, sparks, open flame
INCOMPATIBLITY:
Strong oxidizing agents, acids and bases.
HAZARDOUS DECOMPOSITION PRODUCTS:
Will not occur.
SECTION 11 - TOXICOLOGICAL INFORMATION
Acetone - Acute:
Acetone has a low order of acute and inhalation toxicity. Acetone is a
slight skin irritant and moderately severe eye irritant. Excessive
inhalation can cause headache, drunkenness, and weakness.
Acetone - Chronic:
Kidney damage and anemia can result from sustained high level
exposure. Acetone is reported to potentiate the liver toxicity of
chloroform.
Hexane - Acute:
Ingestion of hexane can cause nausea, vomiting, stomach pain, and
diarrhea. Hexane can irritate the skin and eyes. Acutely, the most
common toxic effects are central nervous system depression and
chemical pneumonitis resulting from aspiration into the lungs
following ingestion.
Hexane - Chronic:
Dermal irritation and central nervous system depression accompanied by
peripheral system damage (polyneuropathy) are common traits of
sustained overexposure.
Toluene - Acute:
Toluene is a central nervous system depressant and skin and mucous
membrane irritant. Severe dermatitis may result from its drying
and defatting action. Toluene is an aspiration hazard causing
chemical pneumonitis.
Toluene - Chronic:
Toluene can cause cardiac sensitization. It is toxic to the kidney,
liver and can cause effects on the blood system such as increased
clotting time.
Toluene may be harmful to the human fetus based on positive test
results in laboratory animals. Case studies show that prolonged
intentional abuse of toluene during pregnancy can cause birth defects
in humans.
SECTION 12 - ECOLOGICAL INFORMATION
This formulation has not been tested for environmental effects.
SECTION 13 - DISPOSAL CONSIDERATIONS
WASTE DISPOSAL:
Disposal of this product must comply with all applicable federal,
state and local regulations.
CONTAINER DISPOSAL:
Disposal of this container should comply with all applicable federal,
state and local regulations.
SECTION 14 - TRANSPORT INFORMATION
For any 10.5-ounce size of this product and for all 29-ounce to 1
gallon sizes of this product not shipped by air:
DOT:
UN Number: None
UN Pack Group: Not applicable
UN Class: ORM-D
Shipping Name: Consumer Commodity
AIR:
UN Number: ID8000
UN Pack Group: Not applicable
UN Class: 9
ICAO/IATA Class: 9
Shipping Name: Consumer Commodity
MARITIME:
UN Number: UN1133
UN Pack Group: III
UN Class: 3
IMDG Class: Limited Quantity
Shipping Name: Adhesives, containing a Flammable Liquid, Limited
Quantity
For air shipments of 29-ounce to 1 gallon sizes of this product or any
shipment of this product in a 1 gal to 5 gal container:
UN Number: UN1133
UN Pack Group: III
UN Class: 3
ICAO/IATA Class: 3
IMDG Class: 3
Shipping Name: Adhesives containing a Flammable Liquid
Packaging may not be approved for shipping by air. Please contact
Franklin International for further information.
SECTION 15 - REGULATORY INFORMATION
SARA TITLE III SECTION 313:
This product contains the following toxic chemicals subject to the
reporting requirements of Section 313 of the Emergency Planning and
Community Right to Know Act of 1986 and of 40 CFR 372:
Chemical Name CAS Number Percent
hexane 110-54-3 13.18
toluene 108-88-3 8.31
- PROP 65 (TERATOGEN)
WARNING: This product contains a chemical known to the state of
Caifornia to cause birth defects or other reproductive harm.
Chemical Name CAS Number Percent
toluene 108-88-3 8.31
TSCA (Toxic Substances Control Act Inventory):
All components of this product are listed on the TSCA inventory except
as exempted.
PENNSYLVANIA:
Hazardous components required to be listed at 1% or more:
acetone; 2-propanone; 67-64-1
toluene; benzene, methyl-; 108-88-3
kaolin clay; kaolin; 1332-58-7
hexane; hexane; 110-54-3
crystalline silica; quartz; 14808-60-7
Non-hazardous ingredients required to be listed at 3%:
petroleum hydrocarbon resin 68131-99-7; petroleum hydrocarbon resin
68132-00-3; styrene-butadiene rubber 9003-55-8
NEW JERSEY:
clay 1332-58-7, petroleum hydrocarbon resin 68131-99-7,
styrene-butadiene rubber 9003-55-8, acetone 67-64-1, hexane 110-54-3
SECTION 16 - OTHER INFORMATION
DISCLAIMER:
While the information and recommendations set forth herein are
believed to be accurate as of the data hereof, Franklin International
makes no warranty, express or implied, with respect thereto and
disclaims all liability from reliance thereon.
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