MATERIAL SAFETY 3M
DATA SHEET 3M Center
St. Paul, Minnesota
55144-1000
1-800-364-3577 or (651) 737-6501 (24 hours)
Copyright, 1999, Minnesota Mining and Manufacturing Company.
All rights reserved. Copying and/or downloading of this
information for the purpose of properly utilizing 3M products
is allowed provided that:
1) the information is copied in full with no changes unless
prior agreement is obtained from 3M, and
2) neither the copy nor the original is resold or otherwise
distributed with the intention of earning a profit thereon.
DIVISION: INDUSTRIAL TAPE AND SPECIALTIES DIVISION
TRADE NAME:
3M 90 High Strength Adhesive (obsolete)
ISSUED: August 10, 1999
SUPERSEDES: August 11, 1998
DOCUMENT: 08-7154-1
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1. INGREDIENT C.A.S. NO. PERCENT
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DIMETHYL ETHER (PROPELLANT)............. 115-10-6 50.0 - 60.0
PENTANE................................. 109-66-0 10.0 - 20.0
ACETONE................................. 67-64-1 10.0 - 20.0
NON-VOLATILE COMPONENTS - NEW JERSEY
TRADE SECRET (T.S.) REGISTRY NO.
04499600-5548P ++..................... TradeSecret 7.0 - 13.0
CYCLOHEXANE............................. 110-82-7 3.0 - 7.0
++ synthetic elastomers, hydrocarbon resin, antioxidant, and
u.v. absorber. Not hazardous according to Canadian WHMIS
criteria. Non-WHMIS controlled.
This product contains the following toxic chemical or chemicals subject to
the reporting requirements of Section 313 of Title III of the Emergency
Planning and Community Right-To-Know Act of 1986 and 40 CFR Part 372:
CYCLOHEXANE
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2. PHYSICAL DATA
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BOILING POINT:................. Compressed gas
VAPOR PRESSURE:................ Compressed gas
VAPOR DENSITY:................. N/D
EVAPORATION RATE:.............. N/D
SOLUBILITY IN WATER:........... Nil
SPECIFIC GRAVITY:.............. ca. .7 Water=1
PERCENT VOLATILE:.............. ca. 89 % by wt
pH:............................ N/A
VISCOSITY:..................... N/A - aerosol
MELTING POINT:................. N/D
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Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
MSDS: 3M 90 High Strength Adhesive (obsolete)
August 10, 1999 PAGE 2
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2. PHYSICAL DATA (continued)
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APPEARANCE AND ODOR:
Clear liquid in aerosol, solvent odor
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3. FIRE AND EXPLOSION HAZARD DATA
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FLASH POINT:................... <-40F (Closed Cup/Propellant)
FLAMMABLE LIMITS - LEL:........ N/A
FLAMMABLE LIMITS - UEL:........ Flammable Gas
AUTOIGNITION TEMPERATURE:...... N/D
EXTINGUISHING MEDIA:
Water spray, Carbon dioxide, Dry chemical, Foam
SPECIAL FIRE FIGHTING PROCEDURES:
Wear full protective clothing, including helmet, self-contained,
positive pressure or pressure demand breathing apparatus, bunker coat
and pants, bands around arms, waist and legs, face mask, and
protective covering for exposed areas of the head. Water may not
effectively extinguish fire; however, it should be used to keep fire-
exposed containers and surfaces cool and prevent explosive rupture.
UNUSUAL FIRE AND EXPLOSION HAZARDS:
Closed containers exposed to heat from fire may build pressure and
explode. Vapors may travel long distances along the ground or floor
to an ignition source and flash back.
NFPA HAZARD CODES: HEALTH: 2 FIRE: 4 REACTIVITY: 1 AEROSOL STORAGE: 3
UNUSUAL REACTION HAZARD: none
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4. REACTIVITY DATA
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STABILITY: Stable
INCOMPATIBILITY - MATERIALS/CONDITIONS TO AVOID:
Heat.
HAZARDOUS POLYMERIZATION: Hazardous polymerization will not occur.
HAZARDOUS DECOMPOSITION PRODUCTS:
Carbon Monoxide and Carbon Dioxide, Aldehydes, Ketones, Hydrocarbons.
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Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
MSDS: 3M 90 High Strength Adhesive (obsolete)
August 10, 1999 PAGE 3
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5. ENVIRONMENTAL INFORMATION
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SPILL RESPONSE:
Refer to other sections of this MSDS for information regarding
physical and health hazards, respiratory protection, ventilation, and
personal protective equipment. Ventilate area. Extinguish all
ignition sources. Cover with absorbent material. Collect using non-
sparking tools. Place in a U.S. DOT-approved container.
RECOMMENDED DISPOSAL:
Incinerate in a permitted hazardous waste incinerator in the presence
of a combustible material. Facility must be capable of handling
aerosol cans. Dispose of empty cans in a sanitary landfill. Dispose
of completely absorbed waste product in a facility permitted to
accept chemical wastes.
RECYCLE EMPTY AEROSOL CONTAINERS WHERE AVAILABLE.
ENVIRONMENTAL DATA:
Not determined.
REGULATORY INFORMATION:
Volatile Organic Compounds: ca. 77 % calculated per SCAQMD rule 443.1.
Volatile Organic Compounds: ca. 540 gms/liter calculated per SCAQMD rule
443.1.
VOC Less H2O & Exempt Solvents: ca. 600 gms/liter calculated per SCAQMD
rule 443.1.
Hazardous Air Pollutants: ca. 0 #/# solids calculated.
Since regulations vary, consult applicable regulations or authorities
before disposal. U.S. EPA Hazardous Waste Number = D001 (Ignitable)
EPCRA HAZARD CLASS:
FIRE HAZARD: Yes PRESSURE: Yes REACTIVITY: No ACUTE: Yes CHRONIC: Yes
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6. SUGGESTED FIRST AID
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EYE CONTACT:
Immediately flush eyes with large amounts of water. Get immediate
medical attention.
SKIN CONTACT:
Flush skin with large amounts of water. If irritation persists, get
medical attention.
INHALATION:
Remove person to fresh air. If not breathing, give artificial
respiration. If breathing is difficult, get immediate medical
attention.
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Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
MSDS: 3M 90 High Strength Adhesive (obsolete)
August 10, 1999 PAGE 4
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6. SUGGESTED FIRST AID (continued)
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IF SWALLOWED:
Do not induce vomiting. Drink two glasses of water. Call a physician.
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7. PRECAUTIONARY INFORMATION
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EYE PROTECTION:
Avoid eye contact with vapor, spray, or mist. Wear safety glasses
with side shields.
SKIN PROTECTION:
Avoid prolonged or repeated skin contact.
RECOMMENDED VENTILATION:
Do not use in a confined area or areas with little or no air
movement. If exhaust ventilation is not adequate, use appropriate
respiratory protection. Provide ventilation adequate to control vapor
concentrations below recommended exposure limits and/or control spray
or mist.
RESPIRATORY PROTECTION:
Avoid breathing of vapors, mists or spray. Select one of the
following NIOSH approved respirators based on airborne concentration
of contaminants and in accordance with OSHA regulations: half-mask
organic vapor respirator.
PREVENTION OF ACCIDENTAL INGESTION:
Do not ingest.
RECOMMENDED STORAGE:
Store at temperatures below 120 degrees F (49 degrees C). Store out
of direct sunlight. Keep out of the reach of children.
FIRE AND EXPLOSION AVOIDANCE:
Aerosol container contains flammable gas under pressure. Keep away
from heat, sparks, open flame, and other sources of ignition.
Extremely flammable liquid and vapor. Do not pierce or burn
container, even after use. No smoking while handling this material.
Avoid static discharge.
EXPOSURE LIMITS
INGREDIENT VALUE UNIT TYPE AUTH SKIN*
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DIMETHYL ETHER (PROPELLANT).......... 1000 PPM TWA CMRG
DIMETHYL ETHER (PROPELLANT).......... 500 PPM TWA AIHA
DIMETHYL ETHER (PROPELLANT).......... 942 MG/M3 TWA AIHA
PENTANE.............................. 600 PPM TWA ACGIH
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Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
MSDS: 3M 90 High Strength Adhesive (obsolete)
August 10, 1999 PAGE 5
EXPOSURE LIMITS (continued)
INGREDIENT VALUE UNIT TYPE AUTH SKIN*
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PENTANE.............................. 600 PPM TWA OSHA
PENTANE.............................. 750 PPM STEL OSHA
ACETONE.............................. 500 PPM TWA ACGIH
ACETONE.............................. 750 PPM STEL ACGIH
ACETONE.............................. 750 PPM TWA OSHA
ACETONE.............................. 1000 PPM STEL OSHA
NON-VOLATILE COMPONENTS - NEW
JERSEY TRADE SECRET (T.S.)
REGISTRY NO. 04499600-5548P ++..... NONE NONE NONE NONE
CYCLOHEXANE.......................... 300 PPM TWA ACGIH
CYCLOHEXANE.......................... 300 PPM TWA OSHA
* SKIN NOTATION: Listed substances indicated with 'Y' under SKIN refer to
the potential contribution to the overall exposure by the cutaneous route
including mucous membrane and eye, either by airborne or, more particularly,
by direct contact with the substance. Vehicles can alter skin absorption.
SOURCE OF EXPOSURE LIMIT DATA:
- ACGIH: American Conference of Governmental Industrial Hygienists
- AIHA: American Industrial Hygiene Assoc. Workplace Environmental
Exposure Level Guideline
- CMRG: Chemical Manufacturer Recommended Exposure Guidelines
- OSHA: Occupational Safety and Health Administration
- NONE: None Established
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8. HEALTH HAZARD DATA
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EYE CONTACT:
Moderate Eye Irritation: signs/symptoms can include redness, swelling,
pain, tearing, and hazy vision.
SKIN CONTACT:
Mild Skin Irritation (after prolonged or repeated contact):
signs/symptoms can include redness, swelling, and itching.
INHALATION:
Intentional concentration and inhalation may be harmful or fatal.
Kidney Effects: signs/symptoms can include reduced urine volume,
blood in urine and back pain.
Liver Effects: signs/symptoms can include yellow skin(jaundice) and
tenderness of upper abdomen.
Central Nervous System Depression: signs/symptoms can include
headache, dizziness, drowsiness, incoordination, slowed reaction time,
slurred speech, giddiness and unconsciousness.
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Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
MSDS: 3M 90 High Strength Adhesive (obsolete)
August 10, 1999 PAGE 6
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8. HEALTH HAZARD DATA (continued)
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Irritation (upper respiratory): signs/symptoms can include soreness
of the nose and throat, coughing and sneezing.
IF SWALLOWED:
Ingestion is not a likely route of exposure to this product.
WHILE THE FOLLOWING EFFECTS ARE ASSOCIATED WITH ONE OR MORE OF THE
INDIVIDUAL INGREDIENTS IN THIS PRODUCT AND ARE REQUIRED TO BE
INCLUDED ON THE MSDS BY THE U.S. OSHA HAZARD COMMUNICATION STANDARD,
THEY ARE NOT EXPECTED EFFECTS DURING FORESEEABLE USE OF THIS PRODUCT.
Irritation of Gastrointestinal Tissues: signs/symptoms can include
pain, vomiting, abdominal tenderness, nausea, blood in vomitus, and
blood in feces.
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SECTION CHANGE DATES
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PRECAUTIONARY INFO. SECTION CHANGED SINCE August 11, 1998 ISSUE
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Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
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The information in this Material Safety Data Sheet (MSDS) is believed to
be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR
IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF
MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF
PERFORMANCE OR USAGE OF TRADE. User is responsible for determining
whether the 3M product is fit for a particular purpose and suitable for
user's method of use or application. Given the variety of factors that
can affect the use and application of a 3M product, some of which are
uniquely within the user's knowledge and control, it is essential that
the user evaluate the 3M product to determine whether it is fit for a
particular purpose and suitable for user's method of use or application.
3M provides information in electronic form as a service to its customers.
Due to the remote possibility that electronic transfer may have resulted
in errors, omissions or alterations in this information, 3M makes no
representations as to its completeness or accuracy. In addition,
information obtained from a database may not be as current as the
information in the MSDS available directly from 3M.
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