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File Name: fluorideaction_org_trifluralin.lebanon.treflan.5g.asp

----------------------- MATERIAL SAFETY DATA SHEET -----------------------
Lebanon Turf LEBANON TREFLAN 5G
---------------------------------------------------------------------------------------------------------------------------
Lebanon Treflan 5G Biodac is also known as Treflan 5G KEROSENE:
Ornamentals Herbicide OSHA PEL: NE ppm
----------------------------------------------------------- ACGIH TLV: NE ppm
PRODUCT: 24-40436 BG40LB PL 40 Lebanon Treflan 5G Biodac BG STEL: NG ppm
MSDS NO.: 988 PERCENT OF PRODUCT: NG
DOW CAS NO.: Not Given
02/17/1994 FOR ALL COMPONENTS: NE = NOT ESTABLISHED.
FORMULA: Not Given OSHA PEL: NG ppm
MANUFACTURER: LEBANON SEABOARD CORP ACGIH TLV: NG ppm
1600 E CUMBERLAND ST STEL: NG ppm
LEBANON, PA 17042 PERCENT OF PRODUCT: NG
PHONE: 800-532-0090 CAS NO.: Not Given
EMERGENCY: 800-424-9300 CHEMTREC -----------------------------------------------------------
PHYSICAL/CHEMICAL CHARACTERISTICS: Text Section(s)
BOILING POINT: NA Not Applicable -----------------------------------------------------------
MELTING POINT: NG IDENTIFICATION
FREEZING POINT: NG -----------------------------------------------------------
POUR POINT: NG SEE DATA SECTIONS FOR ADDITIONAL INFORMATION.
SOFTENING POINT: NG PRODUCT NAME: TREFLAN* 5G ORNAMENTALS HERBICIDE.
SPECIFIC GRAVITY: NA Not Applicable * Trademark of Dow AgroSciences
VAPOR PRESSURE: NA Not Applicable EPA REG. NUMBER: 961-405
VAPOR DENSITY: NA Not Applicable PRODUCT CODE:
PERCENT VOLATILES: NG MSDS NUMBER:
EVAPORATION RATE: NG EMERGENCY PHONE: 800-424-9300 CHEMTREC
pH: EQ 7.7 Aqueous 50/50. GENERAL PHONE: 800-532-0090
MOLECULAR WEIGHT: NG MANUFACTURER NAME AND ADDRESS: LEBANON SEABOARD CORP.
VISCOSITY: NG 1600 E CUMBERLAND ST
SOLUBILITY IN WATER: Not soluble in water LEBANON, PA 17042
ODOR/APPEARANCE/OTHER CHARACTERISTICS: Aromatic -----------------------------------------------------------
odor/Bright yellow free-flowing granule INGREDIENTS
FIRE AND EXPLOSION DATA: -----------------------------------------------------------
CLOSED CUP FLASH PT.: NA Not Applicable (% W/W, UNLESS OTHERWISE NOTED).
OPEN CUP FLASH POINT: NA Not Applicable SEE COMPONENT SECTION(S) FOR ADDITIONAL INFORMATION.
FIRE POINT: NG This document is prepared pursuant to the OSHA Hazard
AUTO IGNITION: N* No Ign. up to 1382 deg F Communication Standard (29 CFR 1910.1200). In addition,
LOWER EXPLOSION LIMIT: NA Not Applicable other substances not 'Hazardous' per this OSHA Standard
UPPER EXPLOSION LIMIT: NA Not Applicable may be listed. Where proprietary ingredients shows, the
SHIPPING REGULATIONS: identity may be made available as provided in this
UN/NA NUMBER: NG standard.
DOT HAZARD CLASS: NG -----------------------------------------------------------
SHIPPING LABEL: Not Given PHYSICAL DATA
SHIPPING NAME: Not Given -----------------------------------------------------------
PREPARED: SEE DATA SECTIONS FOR ADDITIONAL INFORMATION.
PREPARER'S NAME & TITLE: Not Given -----------------------------------------------------------
PREPARATION DATE: 3/31/00 FIRE AND EXPLOSION HAZARD DATA
COMPONENT(S): -----------------------------------------------------------
ALPHA, ALPHA, ALPHA-TRIFLUORO-2,6-DINITRO-N,N-DIPROPYL-P- SEE DATA SECTIONS FOR ADDITIONAL INFORMATION.
TOLUIDINE: AUTO-IGNITION TEMPERATURE: No ignition up to 1382 deg F,
OSHA PEL: NE ppm 750 deg C.
ACGIH TLV: NE ppm EXTINGUISHER MEDIA: CO2 or dry chemical.
STEL: NG ppm FIRE AND EXPLOSION HAZARDS: If product is involved in fire,
PERCENT OF PRODUCT: EQ 5% noxious, toxic fumes may be produced.
CAS NO.: 1582098 FIRE-FIGHTING EQUIPMENT: Wear positive-pressure, self-
NOTE: *(TRIFURALIN). contained breathing apparatus and use full protective
OTHER INGREDIENTS, INCLUDING THE FOLLOWING: equipment.
OSHA PEL: NG ppm -----------------------------------------------------------
ACGIH TLV: NG ppm REACTIVITY DATA
STEL: NG ppm -----------------------------------------------------------
PERCENT OF PRODUCT: EQ 95% STABILITY (CONDITIONS TO AVOID): None known.
CAS NO.: Not Given INCOMPATIBILITY (SPECIFIC MATERIALS TO AVOID): None known.
NAPHTHA SOLVENT: HAZARDOUS DECOMPOSITION PRODUCTS: Will emit toxic vapors as
OSHA PEL: NG ppm it burns.
ACGIH TLV: NG ppm HAZARDOUS POLYMERIZATION: Does not occur.
STEL: NG ppm
PERCENT OF PRODUCT: NG
CAS NO.: 64742069
CLAY:
OSHA PEL: NG ppm
ACGIH TLV: NG ppm
STEL: NG ppm
PERCENT OF PRODUCT: NG
CAS NO.: 8031183




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Page 1 of 3
----------------------- MATERIAL SAFETY DATA SHEET -----------------------
Lebanon Turf LEBANON TREFLAN 5G BIODAC
---------------------------------------------------------------------------------------------------------------------------
----------------------------------------------------------- INHALATION: Remove individual to fresh air. If breathing
ENVIRONMENTAL AND DISPOSAL INFORMATION difficulty occurs, get medical attention. If not
----------------------------------------------------------- breathing, provide cardiopulmonary resuscitation
ENVIRONMENTAL DATA: This pesticide is toxic to fish. Do not assistance (mouth-to-mouth) and get medical attention
apply directly to water or wetlands (swamps, bogs or immediately.
marshes). Drift or runoff from treatment areas may be NOTE TO PHYSICIAN: No specific antidote. Supportive care.
hazardous to aquatic organisms in neighboring aquatic Treatment based on judgment of the physician in response
sites. Do not contaminate water when disposing of to reactions of the patient.
equipment washwaters. MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE: No
ACTION TO TAKE FOR SPILLS: Contain and sweep up material of corroborative information is available that would
small spills and dispose as waste. Large spills report to establish the aggravation of a medical condition by
CHEMTREC and DowElanco for assistance. Prevent runoff. exposure to TREFLAN 5G; however, it is a reasonable
DISPOSAL METHOD: Do not contaminate water, food or feed by assumption that highly allergic individuals would be at a
storage or disposal. Wastes resulting from the use of somewhat greater risk for demonstrating an allergic
this product may be disposed of on site or at an approved reaction when exposed.
waste disposal facility in accordance with applicable -----------------------------------------------------------
regulations. HANDLING PRECAUTIONS
----------------------------------------------------------- -----------------------------------------------------------
HEALTH HAZARD DATA EXPOSURE GUIDELINE(S): Trifluralin, PEL and TLV not
----------------------------------------------------------- established; Kerosene, PEL not established, TLV not
EYES: May cause slight irritation with transient corneal established (NIOSH recommended 10 hour TWA: 14 ppm).
injury. VENTILATION: Provide general and/or local exhaust
SKIN CONTACT: Prolonged exposure not likely to cause ventilation to control airborne levels below the
significant skin irritation. Prolonged or frequently recommended exposure guideline.
repeated skin contact may cause allergic skin reactions RESPIRATORY PROTECTION: In dusty atmospheres, use an
in some individuals. With the dilute mix, no allergic approved dust respirator.
skin reaction is expected. SKIN PROTECTION: Use protective clothing such as coveralls,
SKIN ABSORPTION: A single prolonged exposure is not likely a long sleeved shirt, and impermeable gloves when
to result in the material being absorbed through skin in handling this product.
harmful amounts. The LD50 for skin absorption in rabbits EYE PROTECTION: Use safety glasses.
is >2000 mg/kg. -----------------------------------------------------------
INGESTION: Single dose oral toxicity is believed to be low. ADDITIONAL INFORMATION
The oral LD50 for the components are >5000 mg/kg in rats. -----------------------------------------------------------
Small amounts swallowed incidental to normal handling SPECIAL PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE:
operations are not likely to cause injury; swallowing Keep out of reach of children. Causes eye irritation.
amounts larger than that may cause injury. Harmful if swallowed, inhaled or absorbed through the
INHALATION: Dust may cause irritation to upper respiratory skin. Avoid breathing particulate material and contact
tract. with eyes, skin or clothing. Wash thoroughly with soap
SYSTEMIC (OTHER TARGET ORGAN) EFFECTS: In animals, active and water after handling. Remove contaminated clothing
ingredient has been shown to cause kidney effects. and wash before reuse.
Repeated excessive exposures to dust may cause upper MSDS STATUS: Revised regsheet 8/93.
respiratory tract irritation. May contain silica which REGULATORY INFORMATION: (Not meant to be all-inclusive--
may cause lung effects with repeated excessive exposure. selected regulations represented).
CANCER INFORMATION: A low incidence of urinary tract tumors -----------------------------------------------------------
was seen in only 1 of 5 chronic studies in rats with the NOTICE: The information herein is presented in good faith
active ingredient, and it is not anticipated to be a and believed to be accurate as the effective date shown
carcinogenic risk. The clay component may contain above. However, no warranty, express or implied, is
crystalline silica, which has caused cancer in laboratory given. Regulatory requirements are subject to change and
animals and is listed as a potential carcinogen by IARC. may differ from one location to another; it is the
TERATOLOGY (BIRTH DEFECTS): The active ingredient did not buyer's responsibility to ensure that its activities
cause birth defects; other fetal effects occurred only at comply with federal, state or provincial, and local laws.
doses toxic to the mother. The following specific information is made for the
REPRODUCTIVE EFFECTS: The active ingredient did not purpose of complying with numerous federal, state or
interfere with reproduction in animal studies. provincial, and local laws and regulations. See MSD Sheet
MUTAGENICITY (EFFECTS ON GENETIC MATERIAL): Mutagenicity for health and safety information.
testing with the active ingredient has been negative in -----------------------------------------------------------
most in vivo and in vitro systems. Positive results in a SARA 313 INFORMATION: This product contains the following
Drosophilam study are contradicted by results in in-vivo substances subject to the reporting requirements of
mammalian tests. Section 313 of Title III of the Superfund Amendments
----------------------------------------------------------- and Reauthorization Act of 1986 and 40 CFR Part 372:
FIRST AID CHEMICAL NAME CAS NUMBER CONCENTRATION
----------------------------------------------------------- -----------------------------------------------------------
EYES: Flush eyes with plenty of water; call a physician. TRIFLURALIN 001582-09-8 5%
SKIN: Wash off in flowing water or shower; use soap if -----------------------------------------------------------
available. Get medical attention if irritation develops. SARA HAZARD CATEGORY: This product has been reviewed
Wash all contaminated clothing before reuse. according to the EPA "Hazard Categories" promulgated
INGESTION: Call a physician or Poison Control Center. Drink under Section 311 and 312 of the Superfund Amendment
1 or 2 glasses of water and induce vomiting by touching and Reauthorization Act of 1986 (SARA Title III) and is
back of throat with finger. Do not induce vomiting or considered, under applicable definitions, to meet the
give anything by mouth to an unconscious person. following categories: An immediate health hazard.




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Page 2 of 3
----------------------- MATERIAL SAFETY DATA SHEET -----------------------
Lebanon Turf LEBANON TREFLAN 5G BIODAC
---------------------------------------------------------------------------------------------------------------------------
TOXIC SUBSTANCES CONTROL ACT (TSCA): All ingredients are
on the TSCA inventory or are not required to be listed
on the TSCA inventory.
OSHA HAZARD COMMUNICATION STANDARD: This product is a
"Hazardous Chemical" as defined by the OSHA Hazard
Communication Standard, 29 CFR 1910.1200.
NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) RATINGS:
HEALTH: 2
FLAMMABILITY: 1
REACTIVITY: 0
-----------------------------------------------------------
SPECIAL NOTES
-----------------------------------------------------------

-----------------------------------------------------------
ADDITIONAL/IMPORTANT INFORMATION
-----------------------------------------------------------

-----------------------------------------------------------
DISCLAIMER OF EXPRESSED AND IMPLIED WARRANTIES: although
preparer and owner have taken reasonable care in the
preparation of this document, we extend no warranties and
make no representation as to the accuracy or completeness
of the information contained herein, and assume no
responsibility regarding the suitability of this
information for the user's intended purposes or for the
consequences of its use. Each user should make a
determination as to the suitability of the information for
their particular purpose(s). A request has been made to the
manufacturer to approve the contents of this material
safety data sheet. Upon receipt of any changes a new MSDS
will be made available.
-----------------------------------------------------------
COMPAS Code: 43390020




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Page 3 of 3

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