SAFETY DATA SHEET according to EC directive 2001/58/EC
DEBUT庐
Version 2.1
Revision Date 24.06.2004 Ref. 130000000832
This SDS adheres to the standards and regulatory requirements of Great Britain and may not meet the regulatory
requirements in other countries.
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND THE COMPANY/UNDERTAKING
Product information
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Product name : DEBUT
Synonyms : B10048183
Use of the : herbicide
Substance/Preparation
Company : Du Pont (U.K.) Limited
Wedgwood Way
SG1 4QN Stevenage
Telephone : +4401438734450
Telefax :
Emergency telephone : +44-(0)2871-861.313
number
2. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name CAS-No. EC-No. Classification Concentration [%]
Triflusulfuron methyl 126535-15-7 N; R50/53 50
For the full text of the R phrases mentioned in this Section, see Section 16.
3. HAZARDS IDENTIFICATION
Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
4. FIRST AID MEASURES
General advice : Never give anything by mouth to an unconscious person. If breathing is irregular
or stopped, administer artificial respiration. For specialist advice physicians
should contact the National Poisons Information Service, (24-hr), Tel: 0870-600-
6266.
Inhalation : Move to fresh air. Consult a physician.
Skin contact : Wash off immediately with soap and plenty of water. If skin irritation persists, call
a physician.
Eye contact : Rinse thoroughly with plenty of water, also under the eyelids. If eye irritation
persists, consult a specialist.
Ingestion : Drink 1 or 2 glasses of water. Do not induce vomiting without medical advice.
Consult a physician.
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SAFETY DATA SHEET according to EC directive 2001/58/EC
DEBUT庐
Version 2.1
Revision Date 24.06.2004 Ref. 130000000832
5. FIRE-FIGHTING MEASURES
Suitable extinguishing : water spray, dry chemical, foam, carbon dioxide (CO2),
media
Extinguishing media which : high volume water jet, (contamination risk),
must not be used for safety
reasons
Special protective : In the event of fire, wear self-contained breathing apparatus.
equipment for fire-fighters
Further information : (on small fires) If area is heavily exposed to fire and if conditions permit, let fire
burn itself out since water may increase the area contaminated. Cool containers
/ tanks with spray water.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions : Wear personal protective equipment.
Environmental precautions : Do not flush into surface water or sanitary sewer system. Do not allow material
to contaminate ground water system.
Methods for cleaning up : Clean up promptly by scoop or vacuum. Use approved industrial vacuum
cleaner for removal. Shovel into suitable container for disposal. If spill area is on
ground near valuable plants or trees, remove 5 cm of top soil after initial clean-
up.
7. HANDLING AND STORAGE
Handling
Advice on safe handling : Provide appropriate exhaust ventilation at places where dust is formed. Wear
personal protective equipment.
Advice on protection : Keep away from heat and sources of ignition.
against fire and explosion
Storage
Requirements for storage : Keep containers tightly closed in a dry, cool and well-ventilated place. Store in a
areas and containers place accessible by authorized persons only. Keep away from food, drink and
animal feedingstuffs. Keep out of reach of children.
Advice on common storage : No materials to be specially mentioned.
Other data : Stable under recommended storage conditions.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
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SAFETY DATA SHEET according to EC directive 2001/58/EC
DEBUT庐
Version 2.1
Revision Date 24.06.2004 Ref. 130000000832
Engineering measures
Ensure adequate ventilation.
Personal protective equipment
Respiratory protection : In the case of dust or aerosol formation use respirator with an approved filter.
Half mask with a particle filter P2 (EN 143).
Hand protection : Material: nitrile rubber
Glove thickness: 0,4 - 0,7 mm
Wearing time: 480 min
Do not wear cotton or leather gloves., The suitability for a specific workplace
should be discussed with the producers of the protective gloves.
Eye protection : safety glasses with side-shields
Hygiene measures : Wash hands before breaks and immediately after handling the product. When
using, do not eat, drink or smoke. Wash contaminated clothing before re-use.
Protective measures : All chemical protective clothing should be visually inspected prior to use.
Clothing and gloves should be replaced in case of chemical or physical damage
or if contaminated.
9. PHYSICAL AND CHEMICAL PROPERTIES
Form : solid, dry flowable water dispersible granules,
Colour : brown,
Odour : none,
pH : 8,3 at 10 g/l ( 20 掳C)
Flash point : not applicable
Explosive properties : Not explosive
Bulk density : 600 kg/m3
Water solubility : , dispersible
10. STABILITY AND REACTIVITY
Hazardous decomposition : carbon dioxide (CO2), nitrogen oxides (NOx), hydrogen fluoride, Sulphur oxides,
products
Hazardous reactions : Dust may form explosive mixture in air. No decomposition if stored and applied
as directed.
11. TOXICOLOGICAL INFORMATION
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Acute oral toxicity : LD50/rat : > 5 000 mg/kg
Acute inhalation toxicity : LC50/4 h/rat : > 2 mg/l
Acute dermal toxicity : LD50/rat : > 2 000 mg/kg
Skin irritation : No skin irritation
Eye irritation : No eye irritation
Sensitization : Did not cause sensitization on laboratory animals.
12. ECOLOGICAL INFORMATION
Ecotoxicity effects
Toxicity to fish : LC50/96 h/Rainbow trout: 150 mg/l
Toxicity to algae : EC50/72 h/selenastrum capricornutum: 0,43 mg/l
Toxicity to algae
鈥? Triflusulfuron methyl : EC50/72 h/selenastrum capricornutum: 0,425 mg/l
Aquatic toxicity : EC50/48 h/Daphnia: > 1 200 mg/l
13. DISPOSAL CONSIDERATIONS
Product : In accordance with local and national regulations. Must be incinerated in a
suitable incineration plant holding a permit delivered by the competent
authorities. Dispose of rinse water as waste water. Do not contaminate ponds,
waterways or ditches with chemical or used container.
Contaminated packaging : Do not re-use empty containers.
14. TRANSPORT INFORMATION
ADR
Class: 9
Packaging group: III
Classification Code: M7
HI No:: 90
UN-No: 3077
Labelling No.: 9
Proper shipping name: Environmentally hazardous substance, solid, n.o.s. (contains Triflusulfuron methyl)
IATA_C
Class: 9
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SAFETY DATA SHEET according to EC directive 2001/58/EC
DEBUT庐
Version 2.1
Revision Date 24.06.2004 Ref. 130000000832
Packaging group: III
UN-No: 3077
Labelling No.: 9MI
Proper shipping name: Environmentally hazardous substance, solid, n.o.s. (contains Triflusulfuron methyl)
IMDG
Class: 9
Packaging group: III
UN-No: 3077
Labelling No.: 9
Proper shipping name: Environmentally hazardous substance, solid, n.o.s. (contains Triflusulfuron methyl)
15. REGULATORY INFORMATION
Labelling according to EEC Directive
Symbol(s) : N Dangerous for the environment
Hazardous components: Triflusulfuron methyl
R-phrase(s) : R50/53 Very toxic to aquatic organisms, may cause long-term
adverse effects in the aquatic environment.
S-phrase(s) : S35 This material and its container must be disposed of in a safe
way.
S57 Use appropriate containment to avoid environmental
contamination.
Exceptional labelling of : To avoid risks to man and the environment, comply with the instructions for use.
special preparations
Further information : The product is classified and labelled in accordance with Directive 1999/45/EC.
16. OTHER INFORMATION
Text of R phrases mentioned in Section 2
R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at
the date of its publication. The information given is designed only as a guidance for safe handling, use, processing,
storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The
information relates only to the specific material designated and may not be valid for such material used in
combination with any other materials or in any process, unless specified in the text.
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SAFETY DATA SHEET according to EC directive 2001/58/EC
DEBUT庐
Version 2.1
Revision Date 24.06.2004 Ref. 130000000832
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