SIGMA-ALDRICH
Material Safety Data Sheet
Date Printed: 03/FEB/2005
Date Updated: 13/MAR/2004
Version 1.1
According to 91/155/EEC
Classified as Hazardous according to the criteria of EU Annex 1 and
NOHSC.
1 - Product and Company Information
Product Name BERYLLIUM,METALLIC SLIVERS, LESS THAN
10MM, 99.9%
Product Number 265063
Company Sigma-Aldrich Pty, Ltd
Unit 2, 14 Anella Avenue
Castle Hill NSW 1765
Australia
Technical Phone # +61 2 9841 0555
Fax +61 2 9841 0500
Emergency Phone # +61 2 9841 0566
2 - Composition/Information on Ingredients
Product Name CAS # EC no Annex I
Index Number
BERYLLIUM 7440-41-7 231-150-7 004-001-00-7
Formula Be
Molecular Weight 9.01 AMU
Synonyms Beryllium-9 * Beryllium (ACGIH:OSHA) * Glucinium
* Glucinum * RCRA waste number P015
3 - Hazards Identification
SPECIAL INDICATION OF HAZARDS TO HUMANS AND THE ENVIRONMENT
May cause cancer by inhalation. Toxic if swallowed. Very toxic by
inhalation. Irritating to eyes, respiratory system and skin. May
cause sensitization by skin contact. Toxic: danger of serious
damage to health by prolonged exposure through inhalation.
Carc. Cat.2
4 - First Aid Measures
AFTER INHALATION
If inhaled, remove to fresh air. If breathing becomes difficult,
call a physician.
AFTER SKIN CONTACT
In case of contact, immediately wash skin with soap and copious
amounts of water.
AFTER EYE CONTACT
In case of contact with eyes, flush with copious amounts of
water for at least 15 minutes. Assure adequate flushing by
separating the eyelids with fingers. Call a physician.
AFTER INGESTION
If swallowed, wash out mouth with water provided person is
conscious. Call a physician.
5 - Fire Fighting Measures
EXTINGUISHING MEDIA
Unsuitable: Do not use carbon dioxide extinguisher on this
material.
SPECIAL RISKS
Specific Hazard(s): Emits toxic fumes under fire conditions.
SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS
Wear self-contained breathing apparatus and protective clothing
to prevent contact with skin and eyes.
6 - Accidental Release Measures
PERSONAL PRECAUTION PROCEDURES TO BE FOLLOWED IN CASE OF LEAK OR SPILL
Evacuate area.
PROCEDURE(S) OF PERSONAL PRECAUTION(S)
Wear self-contained breathing apparatus, rubber boots, and heavy
rubber gloves. Wear disposable coveralls and discard them after
use.
METHODS FOR CLEANING UP
Sweep up, place in a bag and hold for waste disposal. Avoid
raising dust. Ventilate area and wash spill site after material
pickup is complete.
7 - Handling and Storage
HANDLING
Directions for Safe Handling: Do not breathe dust. Do not get in
eyes, on skin, on clothing. Avoid prolonged or repeated exposure.
STORAGE
Conditions of Storage: Keep tightly closed.
8 - Exposure Controls / Personal Protection
ENGINEERING CONTROLS
Use only in a chemical fume hood. Safety shower and eye bath.
GENERAL HYGIENE MEASURES
Wash contaminated clothing before reuse. Wash thoroughly after
handling.
EXPOSURE LIMITS
Country Source Type Value
Poland NDS 0.001 MG/M3
Poland NDSCh 0.003 MG/M3
Poland NDSP -
EXPOSURE LIMITS - DENMARK
Source Type Value
OEL TWA 0.001 mg/m3
Remarks: K
EXPOSURE LIMITS - NORWAY
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Source Type Value
OEL 0.001 mg/m3
Remarks: K
EXPOSURE LIMITS - SWEDEN
Source Type Value
LLV (Level0.002 mg/m3
Remarks: K, S
EXPOSURE LIMITS - SWITZERLAND
Source Type Value
OEL OEL 0.002 mg/m3
Remarks: E K
EXPOSURE LIMITS - UNITED KINGDOM
Source Type Value
OEL TWA 0.002 mg/m3
Remarks: Carcinogen.
PERSONAL PROTECTIVE EQUIPMENT
Respiratory Protection: Government approved respirator in
nonventilated areas and/or for exposure above the TLV or PEL.
Hand Protection: Compatible chemical-resistant gloves.
Eye Protection: Chemical safety goggles.
9 - Physical and Chemical Properties
Appearance Color: Grey
Form: Powder
Property Value At Temperature or Pressure
pH N/A
BP/BP Range N/A
MP/MP Range N/A
Flash Point N/A
Flammability N/A
Autoignition Temp 648 掳C
Oxidizing Properties N/A
Explosive Properties N/A
Explosion Limits N/A
Vapor Pressure N/A
SG/Density 1.848 g/cm3
Partition Coefficient N/A
Viscosity N/A
Vapor Density N/A
Saturated Vapor Conc. N/A
Evaporation Rate N/A
Bulk Density N/A
Decomposition Temp. N/A
Solvent Content N/A
Water Content N/A
Surface Tension N/A
Conductivity N/A
Miscellaneous Data N/A
Solubility N/A
10 - Stability and Reactivity
STABILITY
Stable: Stable.
Materials to Avoid: Alkali metals.
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HAZARDOUS DECOMPOSITION PRODUCTS
Hazardous Decomposition Products: Nature of decomposition products
not known.
HAZARDOUS POLYMERIZATION
Hazardous Polymerization: Will not occur
11 - Toxicological Information
RTECS NUMBER: DS1750000
ACUTE TOXICITY
LD50
Intravenous
Rat
496 UG/KG
Remarks: Liver:Hepatitis (hepatocellular necrosis), zonal.
LD50
Intratracheal
Rat
51 MG/KG
SENSITIZATION
Skin: May cause allergic skin reaction.
SIGNS AND SYMPTOMS OF EXPOSURE
Inhalation can cause acute lung disease and/or berylliosis, a
serious lung disease, with cough, chest pain, shortness of
breath, weight loss, weakness, and fatigue. Contact with eyes or
skin may cause irritation, rash, or ulcers. Implantation in the
skin will cause wart-like granulomas. Ingestion can irritate or
burn the mouth, esophagus and stomach.
ROUTE OF EXPOSURE
Skin Contact: Causes skin irritation.
Skin Absorption: May be harmful if absorbed through the skin.
Eye Contact: Causes eye irritation.
Inhalation: May be fatal if inhaled. Material is irritating to
mucous membranes and upper respiratory tract.
Ingestion: Toxic if swallowed.
TARGET ORGAN INFORMATION
Lungs.
CHRONIC EXPOSURE - CARCINOGEN
Rat
Route of Application: Intratracheal
Result: Tumorigenic:Neoplastic by RTECS criteria. Lungs, Thorax,
or Respiration:Tumors. Lungs, Thorax, or
Respiration:Bronchiogenic carcinoma.
Rabbit
Route of Application: Intravenous
Result: Tumorigenic:Equivocal tumorigenic agent by RTECS
criteria. Musculoskeletal:Tumors.
IARC CARCINOGEN LIST
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Rating: Group 1
CHRONIC EXPOSURE - MUTAGEN
Human
30 UMOL/L
Cell Type: HeLa cell
DNA
Mouse
30 UMOL/L
Cell Type: Ascites tumor
DNA
CMR CAT.: Carc. Cat.2
12 - Ecological Information
No data available.
13 - Disposal Considerations
SUBSTANCE DISPOSAL
Material in the elemental state should be recovered for reuse or
recycling. Observe all federal, state, and local environmental
regulations.
14 - Transport Information
RID/ADR
UN#: 1567
Class: 6.1
PG: II
Proper Shipping Name: Beryllium, powder
IMDG
UN#: 1567
Class: 6.1
PG: II
Subrisk: 4.1
Proper Shipping Name: BERYLLIUM POWDER
Marine Pollutant: No
Severe Marine Pollutant: No
IATA
UN#: 1567
Class: 6.1
PG: II
Subrisk: 4.1
Proper Shipping Name: BERYLLIUM POWDER
Inhalation Packing Group I: No
15 - Regulatory Information
CLASSIFICATION AND LABELING ACCORDING TO EU DIRECTIVES
ANNEX I INDEX NUMBER: 004-001-00-7
NOTA: E
INDICATION OF DANGER: T+
Very toxic.
R-PHRASES: 49 25 26 36/37/38 43 48/23
May cause cancer by inhalation. Toxic if swallowed. Very toxic
by inhalation. Irritating to eyes, respiratory system and skin.
May cause sensitization by skin contact. Toxic: danger of
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serious damage to health by prolonged exposure through
inhalation.
S-PHRASES: 53 45
Restricted to professional users. Attention - Avoid exposure -
obtain special instructions before use. In case of accident or
if you feel unwell, seek medical advice immediately (show the
label where possible).
SWITZERLAND
SWISS POISON CLASS: 1*
16 - Other Information
WARRANTY
The above information is believed to be correct but does not
purport to be all inclusive and shall be used only as a guide. The
information in this document is based on the present state of our
knowledge and is applicable to the product with regard to
appropriate safety precautions. It does not represent any
guarantee of the properties of the product. Sigma-Aldrich Inc.,
shall not be held liable for any damage resulting from handling or
from contact with the above product. See reverse side of invoice
or packing slip for additional terms and conditions of sale.
Copyright 2005 Sigma-Aldrich Co. License granted to make unlimited
paper copies for internal use only.
DISCLAIMER
For R&D use only. Not for drug, household or other uses.
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