MSDS
Material Safety Data Sheet
PERMABOND?HH 040
READ MATERIAL SAFETY DATA SHEET BEFORE HANDLING PRODUCT!
Issue Date 07/21/08
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NUMBER
PRODUCT NAME PERMABOND ?HH 040
Manufacturer PERMABOND LLC
20 World's Fair Drive
Somerset, NJ 08873
EMERGENCY PHONES:
MEDICAL ?1-866-827-6282
TRANSPORT ?(CHEMTREC) ?1-800-424-9300
MSDS REQUESTS: HELP LINE: 1-800-640-7599
SYNONYMS None
2. COMPOSITION/INFORMATION ON INGREDIENTS
CHEMICAL FAMILY Anaerobic Adhesive/Sealant
COMPONENT CAS NUMBER CONCENTRATION (%)
Tetraethylene glycol dimethacrylate, 85% 109-17-1 60 - 100
2-Hydroxyethyl methacrylate 868-77-9 10 - 30
Cumene hydroperoxide 80-15-9 1-5
Saccharin 81-07-2 1-5
Diethylene glycol monomethacrylate (2351-43-1) 2351-43-1 0.1 - 1
Dimethylbenzyl alcohol 617-94-7 0.1 - 1
Methacrylic acid 79-41-4 0.1 - 1
3. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
WARNING.
EYE IRRITANT.
HARMFUL IF SWALLOWED.
Liquid
EYE Will cause eye irritation. May cause permanent damage if eye is not
immediately irrigated.
SKIN CONTACT Repeated and/or prolonged contact may cause irritation and skin sensitisation.
Repeated and/or prolonged contact may cause skin sensitization.
INHALATION Irritating and/or toxic vapors may be released at elevated temperatures. Unlikely
to be hazardous by inhalation because of the low vapor pressure of the material
at ambient temperature.
INGESTION May cause nausea, vomiting and diarrhea.
PAGE 1 OF 6
MSDS
Material Safety Data Sheet
PERMABOND?HH 040
READ MATERIAL SAFETY DATA SHEET BEFORE HANDLING PRODUCT!
Issue Date 07/21/08
4. FIRST-AID MEASURES
EYE Immediately irrigate with eyewash solution or clean water, holding the eyelids apart,
for at least 10 minutes. Obtain immediate medical attention.
SKIN CONTACT Flush exposed areas thoroughly with soap and water until all chemical is removed.
Remove contaminated clothing and launder before reuse.
INHALATION Using proper respiratory protection, immediately remove the affected victim from
exposure. Administer artificial respiration if breathing has stopped. Keep at rest.
Call for proper medical attention. Remove to fresh air. If breathing is difficult, give
oxygen. If breathing has stopped, give artificial respiration. Get medical attention.
INGESTION DO NOT induce vomiting. If individual is conscious, give milk or water to dilute
stomach contents. Keep warm and quiet. Get prompt medical attention. DO NOT
attempt to give anything by mouth to an unconscious person.
5. FIREFIGHTING MEASURES
FLASH POINT 230 F (Setaflash Closed Tester)
EXTINGUISHING MEDIA CO2; Dry Chemical; Foam; Water Fog
SPECIAL FIREFIGHTING PROCEDURES Fire fighters should be equipped with self-contained breathing
apparatus to protect against potentially toxic and irritating
fumes.; Cool exposed equipment with water spray.
FIRE & EXPLOSION HAZARDS Polymerization may take place at elevated temperatures.
FLAMMABILITY HAZARD CLASS 1 = Slight.
6. ACCIDENTAL RELEASE MEASURES
SPILL AND LEAK Wear protective clothing. Stop leak if you can do it without risk. For small spills
PROCEDURES take up with sand or other inert absorbent material and place in a container for
later disposal. Note: in bulk quantities, product absorbed on inert material may
polymerize generating significant heat and pressure. Vent disposal container to
prevent buildup of pressure. Can carefully solidify with anaerobic surface
conditioner and dispose of as solid waste.
For safety and environmental precautions, please review entire Material Safety Data Sheet for necessary information.
7. HANDLING AND STORAGE
STORAGE TEMPERATURE Room
HANDLING/STORAGE Store out of direct sunlight in a dry area. Maximum
storage temperature is 100F.
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MSDS
Material Safety Data Sheet
PERMABOND?HH 040
READ MATERIAL SAFETY DATA SHEET BEFORE HANDLING PRODUCT!
Issue Date 07/21/08
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
COMPONENT EXPOSURE LIMITS
Manufacturer: 3 ppm
2-Hydroxyethyl methacrylate
ACGIH-TWA: 10 mg/m3 OSHA-PEL: 15 mg/m3
Saccharin
ACGIH-TWA Respirable: 3 mg/m3 OSHA-PEL Respirable: 5 mg/m3
ACGIH-TWA: 20 ppm (Skin) OSHA-PEL: 20 ppm
Methacrylic acid
VENTILATION REQUIREMENTS General.
EYE PROTECTION REQUIREMENTS Safety glasses, goggles or face shield to protect against splashing.
GLOVE REQUIREMENTS Employee must wear appropriate protective gloves to prevent contact
with this substance.
CLOTHING REQUIREMENTS No special clothing required for low volume activity.
WASH REQUIREMENTS Wash before eating, drinking, or using toilet facilities.
RESPIRATOR REQUIREMENTS None required under normal handling conditions. Use NIOSH
approved respirator if vapor or mist levels are irritating.
9. PHYSICAL AND CHEMICAL PROPERTIES
PURE SUBSTANCE OR MIXTURE Mixture
PHYSICAL FORM Liquid
PH AS IS Not applicable
pH IN (1%) SOLUTION Not applicable
OXIDIZING PROPERTIES Not applicable
BOILING POINT 癋
MELTING/FREEZING POINT Not available
SOLUBILITY IN WATER Insoluble
VISCOSITY 5000 cP
SPECIFIC GRAVITY (WATER=1) 1.07
BULK DENSITY 8.91 lb/gal
VAPOR PRESSURE (mmHg) 0.01
VAPOR DENSITY (air = 1) 1.01
VOLATILES <1%
VOLATILE ORGANIC COMPOUNDS 0.09 lb/gal
FLASH POINT 230 癋 (Setaflash Closed Tester)
10. STABILITY AND REACTIVITY
STABILITY Stable
REACTIVITY HAZARD CLASS 2 = Reactive material.
HAZARDOUS DECOMPOSITION PRODUCTS Thermal decomposition could produce carbon monoxide,
carbon dioxide, and unidentified organic compounds.
PAGE 3 OF 6
MSDS
Material Safety Data Sheet
PERMABOND?HH 040
READ MATERIAL SAFETY DATA SHEET BEFORE HANDLING PRODUCT!
Issue Date 07/21/08
11. TOXICOLOGICAL INFORMATION
ROUTE OF ENTRY Skin Contact; Eye Contact; Ingestion
CHRONIC (LONG TERM) EFFECTS OF EXPOSURE
TARGET ORGANS Skin; Eyes
CARCINOGEN Possible cancer hazard. Risk of cancer depends on duration
and level of exposure.
COMPONENT ORAL TOXICITY NOTES ON ORAL TOXICITY
Tetraethylene glycol Low oral toxicity.
dimethacrylate, 85%
2-Hydroxyethyl Oral LD50: Rat > 5 g/kg Low oral toxicity.
methacrylate
Cumene hydroperoxide Oral LD50: Rat 800 mg/kg Corrosive to mouth, throat and stomach.
Oral LD50: Rat 382 mg/kg
Saccharin Oral LD50: Mouse 17 g/kg No hazard in normal industrial use.
Methacrylic acid Oral LD50: Rat 1060 mg/kg Corrosive to mouth, throat and stomach.
COMPONENT DERMAL TOXICITY NOTES ON DERMAL TOXICITY
Tetraethylene glycol Irritating to the skin. Repeated and/or prolonged contact
dimethacrylate, 85% may cause skin sensitization.
2-Hydroxyethyl Dermal LD50: Rabbit Repeated or prolonged skin contact may result in
methacrylate > 5 g/kg moderate irritation. Repeated and/or prolonged contact
may cause skin sensitization. Can be rapidly absorbed
through skin.
Cumene hydroperoxide Corrosive, causes permanent skin damage.
Saccharin Repeated and/or prolonged contact may cause skin
sensitization. May cause photosensitization evidenced by
repeated occurrence of dermatitic rash on exposure to
sunlight.
Methacrylic acid Dermal LD50: Rabbit Corrosive, causes permanent skin damage. Repeated
500 mg/kg and/or prolonged contact may cause skin sensitization.
Can be rapidly absorbed through skin.
COMPONENT INHALATION TOXICITY NOTES ON INHALATION TOXICITY
Tetraethylene glycol May cause irritation to eyes and respiratory system.
dimethacrylate, 85% Vapors and/or aerosols that may be formed at
elevated temperatures may be irritating to eyes and
respiratory tract.
2-Hydroxyethyl Vapors and/or aerosols may cause irritation. Vapors
methacrylate and/or aerosols which may be formed at elevated
temperatures may be irritating to eyes and respiratory
tract. Avoid breathing vapors or mists.
Cumene hydroperoxide Inhalation LC50 (6.00hr): Inhalation of dust or vapor may cause severe
Rat 700 ppm irritation to the nasal passages and/or the respiratory
system. Exposure to high concentrations may pro-
duce lung damage. Avoid breathing vapors or mists.
Saccharin Dust is irritant to the respiratory tract.
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MSDS
Material Safety Data Sheet
PERMABOND?HH 040
READ MATERIAL SAFETY DATA SHEET BEFORE HANDLING PRODUCT!
Issue Date 07/21/08
11. TOXICOLOGICAL INFORMATION ?cont'd
Methacrylic acid May cause irritation to eyes and respiratory system.
Possible respiratory sensitizer. Irritating and/or toxic
vapors may be released at elevated temperatures.
COMPONENT NOTES ON EYE IRRITATION
Tetraethylene glycol Irritating, but does not injure eye tissue.
dimethacrylate, 85%
2-Hydroxyethyl Severe/very severe irritant.
methacrylate
Cumene hydroperoxide Extremely severe irritant/corrosive. May cause
severe burns which could lead to permanent damage
or total loss of vision.
Saccharin Particulates may scratch eye surfaces and cause
mechanical irritation.
Methacrylic acid Extremely severe irritant/corrosive. May cause
severe burns which could lead to permanent damage
or total loss of vision.
12. ECOLOGICAL INFORMATION
POTENTIAL TO BIOACCUMULATE Unknown.
AQUATIC TOXICITY None Established
13. DISPOSAL CONSIDERATIONS
WASTE DISPOSAL METHODS Disposal should be in accordance with local, state or national legislation.
EMPTY CONTAINER WARNINGS Empty containers may contain product residue; follow MSDS and label
warnings even after they have been emptied.
14. TRANSPORTATION INFORMATION
U.S. DEPARTMENT OF TRANSPORTATION GROUND (49CFR)
Proper Shipping Name: Unrestricted
Hazard Class or Division: None
Identification Number: None
Packing Group: None
PAGE 5 OF 6
MSDS
Material Safety Data Sheet
PERMABOND?HH 040
READ MATERIAL SAFETY DATA SHEET BEFORE HANDLING PRODUCT!
Issue Date 07/21/08
4. TRANSPORTATION INFORMATION ?CONT'D
INTERNATIONAL AIR SHIPMENT TRANSPORTATION (ICAO/IATA)
Proper Shipping Name: Unrestricted
Hazard Class or Division: None
Identification Number: None
Packing Group: None
WATER TRANSPORTATION (IMO/IMDG)
Proper Shipping Name: Unrestricted
Hazard Class or Division: None
Identification Number: None
Packing Group: None
Marine Pollutant None
15. REGULATORY INFORMATION
USA
TSCA All components are on the TSCA inventory.
SARA/TITLE III CAS NUMBER CONCENTRATION (%)
Cumene hydroperoxide 80-15-9 2.47
Saccharin (Manufacturing, no supplier notification) 81-07-2 1.45
[1,2-Benzisothiazol-3(2H)-one,1,1-dioxide].
CALIFORNIA PROPOSITION 65
WARNING: This product contains the following chemicals that are known to the State of California to cause
cancer, birth defects or other reproductive harm:
COMPONENT CAS NUMBER
SACCHARIN 81-07-2
16. OTHER INFORMATION
MSDS DATE 07/21/08
This MSDS contains changes from the previous one in section 9; Viscosity was corrected
FOR INFORMATION CONTACT: Permabond LLC
HELP Line: 1-800-640-7599
ADDITIONAL INFORMATION: The information given and the recommendations made herein apply to our
product(s) alone and are not combined with other product(s). Such are based on our research and on data from other
reliable sources and are believed to be accurate. No guaranty of accuracy is made. It is the purchaser's responsibility
before using any product to verify this data under their own operating conditions and to determine whether the
product is suitable for their purposes.
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