MSDS
Material Safety Data Sheet
PERMABOND LH 050
READ MATERIAL SAFETY DATA SHEET BEFORE HANDLING PRODUCT!
Issue Date 10/10/06
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NUMBER
PRODUCT NAME PERMABOND LH 050
Manufacturer PERMABOND LLC
20 World's Fair Drive
Somerset, NJ 08873
EMERGENCY PHONES:
MEDICAL ?1-866-827-6282
TRANSPORT ?(CHEMTREC) ?1-800-424-9300
MSDS REQUESTS: HELP LINE: 1-800-640-7599
SYNONYMS None
2. COMPOSITION/INFORMATION ON INGREDIENTS
CHEMICAL FAMILY Anaerobic Adhesive/Sealant
COMPONENT CAS NUMBER CONCENTRATION (%)
Tetraethylene glycol dimethacrylate, 85% 109-17-1 30 - 60
Tetrasodium ethylenediaminetetraacetate 64-02-8 1-5
Saccharin 81-07-2 0.1 - 1
Dimethylbenzyl alcohol 617-94-7 0.01 - 0.1
3. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
EYE IRRITANT.
SKIN IRRITANT.
SKIN SENSITIZER.
White Paste Mild, pleasant odor
EYE Will cause eye irritation. May cause permanent damage if eye is not
immediately irrigated.
SKIN CONTACT Repeated and/or prolonged contact may cause irritation and skin sensitisation.
INHALATION Irritating and/or toxic vapors may be released at elevated temperatures. Unlikely
to be hazardous by inhalation because of the low vapor pressure of the material
at ambient temperature.
INGESTION May cause nausea, vomiting and diarrhea.
4. FIRST-AID MEASURES
EYE Immediately irrigate with eyewash solution or clean water, holding the eyelids
apart, for at least 10 minutes. Obtain immediate medical attention.
SKIN CONTACT Flush exposed areas thoroughly with soap and water until all chemical is
removed. Remove contaminated clothing and launder before reuse.
INHALATION Using proper respiratory protection, immediately remove the affected victim
from exposure. Administer artificial respiration if breathing has stopped. Keep
at rest. Call for proper medical attention. Remove to fresh air. If breathing is
difficult, give oxygen. If breathing has stopped, give artificial respiration. Get
medical attention.
PAGE 1 OF 5
MSDS
Material Safety Data Sheet
PERMABOND LH 050
READ MATERIAL SAFETY DATA SHEET BEFORE HANDLING PRODUCT!
Issue Date 10/10/06
4. FIRST-AID MEASURES ?CONT'D
INGESTION DO NOT induce vomiting. If individual is conscious, give milk or water to
dilute stomach contents. Keep warm and quiet. Get prompt medical attention.
DO NOT attempt to give anything by mouth to an unconscious person.
5. FIREFIGHTING MEASURES
AUTOIGNITION None Established
FLASH POINT 230 F (Setaflash Closed Tester)
EXTINGUISHING MEDIA CO2; Dry Chemical; Foam; Water Fog
SPECIAL FIREFIGHTING PROCEDURES Fire fighters should be equipped with self-contained breathing
apparatus to protect against potentially toxic and irritating
fumes.; Cool exposed equipment with water spray.
FIRE & EXPLOSION HAZARDS Polymerization may take place at elevated temperatures.
FLAMMABILITY HAZARD CLASS 1 = Slight.
6. ACCIDENTAL RELEASE MEASURES
SPILL AND LEAK PROCEDURES Wear protective clothing. Stop leak if you can do it without risk. For small
spills take up with sand or other inert absorbent material and place in a
container for later disposal. Note: in bulk quantities, product absorbed on
inert material may polymerize generating significant heat and pressure.
Vent disposal container to prevent buildup of pressure. Can carefully
solidify with anaerobic surface conditioner and dispose of as solid waste.
For safety and environmental precautions, please review entire Material Safety Data Sheet for necessary information.
7. HANDLING AND STORAGE
STORAGE TEMPERATURE <= 27 C
80 F
HANDLING/STORAGE Keep away from heat, sources of ignition and direct
sunlight. Keep material refrigerated at the storage
temperature referenced above. Do not freeze.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
COMPONENT EXPOSURE LIMITS
ACGIH-TWA: 10 mg/m3 OSHA-PEL: 15 mg/m3
Saccharin
ACGIH-TWA Respirable: 3 OSHA-PEL Respirable: 5 mg/m3
mg/m3
VENTILATION REQUIREMENTS General.
EYE PROTECTION REQUIREMENTS Safety glasses, goggles or face shield to protect against splashing.
GLOVE REQUIREMENTS Employee must wear appropriate protective gloves to prevent contact
with this substance.
CLOTHING REQUIREMENTS No special clothing required for low volume activity.
WASH REQUIREMENTS Wash before eating, drinking, or using toilet facilities.
RESPIRATOR REQUIREMENTS None required under normal handling conditions. Use NIOSH
approved respirator if vapor or mist levels are irritating.
PAGE 2 OF 5
MSDS
Material Safety Data Sheet
PERMABOND LH 050
READ MATERIAL SAFETY DATA SHEET BEFORE HANDLING PRODUCT!
Issue Date 10/10/06
9. PHYSICAL AND CHEMICAL PROPERTIES
PURE SUBSTANCE OR MIXTURE Mixture
PHYSICAL FORM Paste
COLOR White
ODOR Mild, pleasant
ODOR THRESHOLD Not available
MOLECULAR WEIGHT Not applicable
PH AS IS Not applicable
pH IN (1%) SOLUTION Not applicable
OXIDIZING PROPERTIES Not applicable
MELTING/FREEZING POINT None Established
SOLUBILITY IN WATER Insoluble
PARTITION COEFFICIENT (n-octanol/water) None Established
VISCOSITY 200000 cPs
SPECIFIC GRAVITY (WATER=1) 1.07
BULK DENSITY 8.91 lb/gal
EVAPORATION RATE None Established
VAPOR PRESSURE (mmHg) 0.01
VAPOR DENSITY (air = 1) 1.01
VOLATILES <1%
VOLATILE ORGANIC COMPOUNDS 0.09 lb/gal
AUTOIGNITION None Established
FLASH POINT 230 F (Setaflash Closed Tester)
10. STABILITY AND REACTIVITY
STABILITY Stable
MATERIALS TO AVOID Metals and their salts, Permabond anaerobic surface
conditioners
REACTIVITY HAZARD CLASS 2 = Reactive material.
HAZARDOUS DECOMPOSITION PRODUCTS Thermal decomposition could produce carbon monoxide,
carbon dioxide, and unidentified organic compounds.
HAZARDOUS POLYMERIZATION Note! PERMA-LOK(R) products are anaerobic and
CONDITIONS polymerize in the absence of air. Sunlight, excessive heat, and
contamination by metals or anaerobic surface conditioner in
large quantities, will also cause polymerization.
11. TOXICOLOGICAL INFORMATION
ROUTE OF ENTRY Skin Contact; Eye Contact; Ingestion
CHRONIC (LONG TERM) EFFECTS OF EXPOSURE
TARGET ORGANS Skin; Eyes
SKIN SENSITIZATION Sensitizer.
CARCINOGEN Possible cancer hazard. Risk of cancer depends on duration
and level of exposure.
PAGE 3 OF 5
MSDS
Material Safety Data Sheet
PERMABOND LH 050
READ MATERIAL SAFETY DATA SHEET BEFORE HANDLING PRODUCT!
Issue Date 10/10/06
11. TOXICOLOGICAL INFORMATION ?CONT'D
COMPONENT ORAL TOXICITY NOTES ON ORAL TOXICITY
Tetraethylene glycol Low oral toxicity.
dimethacrylate, 85%
Saccharin Oral LD50: Mouse 17 g/kg No hazard in normal industrial use.
COMPONENT DERMAL TOXICITY NOTES ON DERMAL TOXICITY
Tetraethylene glycol Irritating to the skin. Repeated and/or prolonged
dimethacrylate, 85% contact may cause skin sensitization.
Tetrasodium Severely irritating; may cause permanent skin
ethylenediaminetetraacetat damage.
e
Saccharin Repeated and/or prolonged contact may cause skin
sensitization. May cause photosensitization
evidenced by repeated occurrence of dermatitic rash
on exposure to sunlight.
COMPONENT INHALATION TOXICITY NOTES ON INHALATION TOXICITY
Tetraethylene glycol May cause irritation to eyes and respiratory system.
dimethacrylate, 85% Vapors and/or aerosols which may be formed at
elevated temperatures may be irritating to eyes and
respiratory tract.
Tetrasodium Vapor may be irritant to the respiratory tract. Avoid
ethylenediaminetetraacetat breathing vapors or mists.
e
Saccharin Dust is irritant to the respiratory tract.
COMPONENT NOTES ON EYE IRRITATION
Tetraethylene glycol Irritating, but does not injure eye tissue.
dimethacrylate, 85%
Tetrasodium Severe/very severe irritant.
ethylenediaminetetraacetat
e
Saccharin Particulates may scratch eye surfaces and cause
mechanical irritation.
12. ECOLOGICAL INFORMATION
POTENTIAL TO BIOACCUMULATE Unknown.
AQUATIC TOXICITY None Established
13. DISPOSAL CONSIDERATIONS
WASTE DISPOSAL METHODS Disposal should be in accordance with local, state or national legislation.
EMPTY CONTAINER WARNINGS Empty containers may contain product residue; follow MSDS and label
warnings even after they have been emptied.
PAGE 4 OF 5
MSDS
Material Safety Data Sheet
PERMABOND LH 050
READ MATERIAL SAFETY DATA SHEET BEFORE HANDLING PRODUCT!
Issue Date 10/10/06
14. TRANSPORTATION INFORMATION
U.S. DEPARTMENT OF TRANSPORTATION GROUND (49CFR)
Proper Shipping Name: Unrestricted
Hazard Class or Division: None
Identification Number: None
Packing Group: None
INTERNATIONAL AIR SHIPMENT TRANSPORTATION (ICAO/IATA)
Proper Shipping Name: Unrestricted
Hazard Class or Division: None
Identification Number: None
Packing Group: None
WATER TRANSPORTATION (IMO/IMDG)
Proper Shipping Name: Unrestricted
Hazard Class or Division: None
Identification Number: None
Packing Group: None
Marine Pollutant None
15. REGULATORY INFORMATION
USA
TSCA All components are on the TSCA inventory.
SARA/TITLE III CAS NUMBER CONCENTRATION (%)
Saccharin (Manufacturing, no supplier notification) 81-07-2 0.6
[1,2-Benzisothiazol-3(2H)-one,1,1-dioxide].
CALIFORNIA PROPOSITION 65
WARNING: This product contains the following chemicals that are known to the State of California to cause
cancer, birth defects or other reproductive harm:
COMPONENT CAS NUMBER
SACCHARIN 81-07-2
16. OTHER INFORMATION
MSDS DATE 10/10/06
This MSDS contains changes from the previous one in section 14; Update on Transportation Information.
FOR INFORMATION CONTACT: Permabond LLC
HELP Line: 1-800-640-7599
ADDITIONAL INFORMATION: The information given and the recommendations made herein apply to our
product(s) alone and are not combined with other product(s). Such are based on our research and on data from other
reliable sources and are believed to be accurate. No guaranty of accuracy is made. It is the purchaser's responsibility
before using any product to verify this data under their own operating conditions and to determine whether the
product is suitable for their purposes.
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