MEGUIAR'S D161 - DETAILER SILICONE FREE DRESSING
ChemWatch Material Safety Data Sheet CHEMWATCH 4827-24
Issue Date: Tue 15-Mar-2005 CD 2005/1 Page 1 of 10
Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME
MEGUIAR'S D161 - DETAILER SILICONE FREE DRESSING
SYNONYMS
Manufacturer's Code: D161
PRODUCT USE
Maintenance product.
SUPPLIER
Company: Meguiar's Australia P/L
Address:
35 Slough Business Park
Holker St, Silverwater
NSW, 2128
AUSTRALIA
Telephone: (+61 2) 9737 9422
Telephone: 1800 804 182
Fax: 02 9737 9414
Section 2 - HAZARDS IDENTIFICATION
STATEMENT OF HAZARDOUS NATURE
NON-HAZARDOUS SUBSTANCE. NON-DANGEROUS GOODS.
According to the Criteria of NOHSC, and the ADG Code.
POISONS SCHEDULE
None
RISK
SAFETY
Avoid exposure - obtain special instructions before use.
In case of contact with eyes, rinse with plenty of water and contact Doctor or
Poisons Information Centre.
Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS
NAME CAS RN %
glycerol 56-81-5 20
2-propoxyethanol 2807-30-9 1.3
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MEGUIAR'S D161 - DETAILER SILICONE FREE DRESSING
ChemWatch Material Safety Data Sheet CHEMWATCH 4827-24
Issue Date: Tue 15-Mar-2005 CD 2005/1 Page 2 of 10
Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS ...
water 7732-18-5 >60
Section 4 - FIRST AID MEASURES
SWALLOWED
?Immediately give a glass of water.
?First aid is not generally required. If in doubt, contact a Poisons
Information Centre or a doctor.
EYE
If this product comes in contact with the eyes:
?Wash out immediately with fresh running water.
?Ensure complete irrigation of the eye by keeping eyelids apart and away from
eye and moving the eyelids by occasionally lifting the upper and lower lids.
?If pain persists or recurs seek medical attention.
?Removal of contact lenses after an eye injury should only be undertaken by
skilled personnel.
SKIN
If skin contact occurs:
?Immediately remove all contaminated clothing, including footwear
?Flush skin and hair with running water (and soap if available).
?Seek medical attention in event of irritation.
INHALED
?If fumes or combustion products are inhaled remove from contaminated area.
?Other measures are usually unnecessary.
NOTES TO PHYSICIAN
Treat symptomatically.
Section 5 - FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA
The product contains a substantial proportion of water, therefore there are no
restrictions on the type of extinguishing media which may be used. Choice of
extinguishing media should take into account surrounding areas.
Though the material is non-combustible, evaporation of water from the mixture,
caused by the heat of nearby fire, may produce floating layers of combustible
substances.
In such an event consider:
?foam
?dry chemical powder
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MEGUIAR'S D161 - DETAILER SILICONE FREE DRESSING
ChemWatch Material Safety Data Sheet CHEMWATCH 4827-24
Issue Date: Tue 15-Mar-2005 CD 2005/1 Page 3 of 10
Section 5 - FIRE FIGHTING MEASURES ...
?carbon dioxide
FIRE FIGHTING
?Alert Fire Brigade and tell them location and nature of hazard.
?Wear breathing apparatus plus protective gloves for fire only.
?Prevent, by any means available, spillage from entering drains or water
courses.
?Use fire fighting procedures suitable for surrounding area.
?DO NOT approach containers suspected to be hot.
?Cool fire exposed containers with water spray from a protected location.
?If safe to do so, remove containers from path of fire.
?Equipment should be thoroughly decontaminated after use.
FIRE/EXPLOSION HAZARD
?Non combustible.
?Not considered to be a significant fire risk.
?Expansion or decomposition on heating may lead to violent rupture of
containers.
?Decomposes on heating and may produce toxic fumes of carbon monoxide (CO).
?May emit acrid smoke.
Decomposition may produce toxic fumes of
carbon dioxide (CO2)
other pyrolysis products typical of burning organic material
May emit poisonous fumes.
May emit corrosive fumes.
FIRE INCOMPATIBILITY
None known.
HAZCHEM
None
Personal Protective Equipment
PERSONAL PROTECTION EQUIPMENT
Breathing apparatus.
Chemical splash suit.
Section 6 - ACCIDENTAL RELEASE MEASURES
EMERGENCY PROCEDURES
MINOR SPILLS
?Clean up all spills immediately.
?Avoid breathing vapours and contact with skin and eyes.
?Control personal contact by using protective equipment.
?Contain and absorb spill with sand, earth, inert material or vermiculite.
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MEGUIAR'S D161 - DETAILER SILICONE FREE DRESSING
ChemWatch Material Safety Data Sheet CHEMWATCH 4827-24
Issue Date: Tue 15-Mar-2005 CD 2005/1 Page 4 of 10
Section 6 - ACCIDENTAL RELEASE MEASURES ...
?Wipe up.
?Place in a suitable labelled container for waste disposal.
MAJOR SPILLS
Moderate hazard.
?Clear area of personnel and move upwind.
?Alert Fire Brigade and tell them location and nature of hazard.
?Wear breathing apparatus plus protective gloves.
?Prevent, by any means available, spillage from entering drains or water
course.
?Stop leak if safe to do so.
?Contain spill with sand, earth or vermiculite.
?Collect recoverable product into labelled containers for recycling.
?Neutralise/decontaminate residue.
?Collect solid residues and seal in labelled drums for disposal.
?Wash area and prevent runoff into drains.
?After clean up operations, decontaminate and launder all protective clothing
and equipment before storing and re-using.
?If contamination of drains or waterways occurs, advise emergency services.
Personal Protective Equipment advice is contained in Section 8 of the MSDS.
Section 7 - HANDLING AND STORAGE
PROCEDURE FOR HANDLING
?Avoid all personal contact, including inhalation.
?Wear protective clothing when risk of exposure occurs.
?Use in a well-ventilated area.
?Avoid contact with moisture.
?Avoid contact with incompatible materials.
?When handling, DO NOT eat, drink or smoke.
?Keep containers securely sealed when not in use.
?Avoid physical damage to containers.
?Always wash hands with soap and water after handling.
?Work clothes should be laundered separately. Launder contaminated clothing
before re-use.
?Use good occupational work practice.
?Observe manufacturer's storing and handling recommendations.
?Atmosphere should be regularly checked against established exposure standards
to ensure safe working conditions are maintained.
DO NOT allow clothing wet with material to stay in contact with skin
SUITABLE CONTAINER
?Polyethylene or polypropylene container.
?Packing as recommended by manufacturer
?Check all containers are clearly labelled and free from leaks.
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MEGUIAR'S D161 - DETAILER SILICONE FREE DRESSING
ChemWatch Material Safety Data Sheet CHEMWATCH 4827-24
Issue Date: Tue 15-Mar-2005 CD 2005/1 Page 5 of 10
Section 7 - HANDLING AND STORAGE ...
STORAGE INCOMPATIBILITY
None known
STORAGE REQUIREMENTS
?Store in original containers.
?Keep containers securely sealed.
?Store in a cool, dry, well-ventilated area.
?Store away from incompatible materials and foodstuff containers.
?Protect containers against physical damage and check regularly for leaks.
?Observe manufacturer's storing and handling recommendations.
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE CONTROLS
No data available for glycerol as (CAS: 56-81-5) / (CAS: 2807-30-9) / (CAS: 7732-18-5)
Not available. Refer to individual constituents.
REPRODUCTIVE HEALTH GUIDELINES
Established occupational exposure limits frequently do not take into
consideration reproductive end points that are clearly below the thresholds for
other toxic effects. Occupational reproductive guidelines (ORGs) have been
suggested as an additional standard. These have been established after a
literature search for reproductive no-observed-adverse effect-level (NOAEL) and
the lowest-observed-adverse-effect-level (LOAEL). In addition the US EPA's
procedures for risk assessment for hazard identification and dose-response
assessment as applied by NIOSH were used in the creation of such limits.
TLV
Ingredient ORG UF Endpoint CR Adeq
2-propoxyethanol 25.6 mg/m? 100 D NA -
These exposure guidelines have been derived from a screening level of risk
assessment and should not be construed as unequivocally safe limits. ORGS
represent an 8-hour time-weighted average unless specified otherwise.
CR = Cancer Risk/10000; UF = Uncertainty factor:
TLV believed to be adequate to protect reproductive health:
LOD: Limit of detection
Toxic endpoints have also been identified as:
D = Developmental; R = Reproductive; TC = Transplacental carcinogen
Jankovic J., Drake F.: A Screening Method for Occupational Reproductive
American Industrial Hygiene Association Journal 57: 641-649 (1996)
INGREDIENT DATA
GLYCEROL:
TLV TWA: 10 mg/m?[ACGIH]
PEL Total particulate: 15mg/m?[OSHA Z1]
PEL Respirable fraction : 5mg/m?[OSHA Z1]
TLV TWA: 10 mg/m?(mist)
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MEGUIAR'S D161 - DETAILER SILICONE FREE DRESSING
ChemWatch Material Safety Data Sheet CHEMWATCH 4827-24
Issue Date: Tue 15-Mar-2005 CD 2005/1 Page 6 of 10
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION ...
ES TWA: 10 mg/m?(mist)
OES TWA: 10 mg/m?(mist)
The mist is considered to be a nuisance particulate which appears to have
little adverse effect on the lung and does produce significant organic
disease or toxic effects. OSHA concluded that this limit would protect the
worker form kidney damage and perhaps, testicular effects.
2-PROPOXYETHANOL:
No exposure limits set by NOHSC or ACGIH
REL TWA: 25 ppm, (skin) [UCAR]
Exposure limits with "skin" notation indicate that vapour and liquid may be
absorbed through intact skin. Absorption by skin may readily exceed vapour
inhalation exposure. Symptoms for skin absorption are the same as for
inhalation. Contact with eyes and mucous membranes may also contribute to
overall exposure and may also invalidate the exposure standard.
MAK Value: 20 ppm, 86 mg/m?br>
Designated H in List of MAK values: Danger of cutaneous absorption.
Absorption of such substances through the skin can pose an incomparably larger
danger of toxicity than their inhalation. To avoid health risks when handling
such substances, meticulous cleaning of the skin, hair and clothing is
imperative.
MAK Category I Peak Limitation: For local irritants Allows excursions of twice
the MAK value for 5 minutes at a time, 8 times per shift.
MAK Group C: There is no reason to fear risk of damage to the developing embryo
when MAK and BAT values are observed.
MAK values, and categories and groups are those recommended within the
Federal Republic of Germany
WATER:
No exposure limits set by NOHSC or ACGIH
PERSONAL PROTECTION
EYE
?Safety glasses with side shields.
?Chemical goggles.
?Contact lenses pose a special hazard; soft lenses may absorb irritants and all
lenses concentrate them. DO NOT wear contact lenses.
HANDS/FEET
Wear chemical protective gloves, eg. PVC.
Wear safety footwear or safety gumboots, eg. Rubber
OTHER
?Overalls.
?P.V.C. apron.
?Barrier cream.
?Skin cleansing cream.
?Eye wash unit.
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MEGUIAR'S D161 - DETAILER SILICONE FREE DRESSING
ChemWatch Material Safety Data Sheet CHEMWATCH 4827-24
Issue Date: Tue 15-Mar-2005 CD 2005/1 Page 7 of 10
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION ...
GLOVE SELECTION INDEX
Glove selection is based on a modified presentation of the:
"Forsberg Clothing Performance Index".
The effect(s) of the following substance(s) are taken into account in the
computer-generated selection:
Substance
________________________________________
glycerol
water
NATURAL RUBBER C
* CPI - Chemwatch Performance Index
A: Best Selection
B: Satisfactory; may degrade after 4 hours continuous immersion
C: Poor to Dangerous Choice for other than short term immersion
NOTE: As a series of factors will influence the actual performance of the glove,
a final selection must be based on detailed observation. -
* Where the glove is to be used on a short term, casual or infrequent basis,
factors such as "feel" or convenience (e.g. disposability), may dictate a choice
of gloves which might otherwise be unsuitable following long-term or frequent
use. A qualified practitioner should be consulted.
RESPIRATOR
Selection of the Class and Type of respirator will depend upon the level of
breathing zone contaminant and the chemical nature of the contaminant.
Protection Factors (defined as the ratio of contaminant outside and inside the
mask) may also be important.
Breathing Zone Maximum Protection Half-face Full-Face
Level ppm (volume) Factor Respirator Respirator
1000 10 A-AUS P -
1000 50 - A-AUS P
5000 50 Airline * -
5000 100 - A-2 P
10000 100 - A-3 P
100+ Airline**
* - Continuous Flow ** - Continuous-flow or positive pressure demand
The local concentration of material, quantity and conditions of use determine
the type of personal protective equipment required. For further information
consult site specific CHEMWATCH data (if available), or your Occupational
Health and Safety Advisor.
ENGINEERING CONTROLS
General exhaust is adequate under normal operating conditions. Local exhaust
ventilation may be required in specific circumstances. If risk of overexposure
exists, wear approved respirator. Correct fit is essential to obtain adequate
protection. Provide adequate ventilation in warehouse or closed storage areas.
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MEGUIAR'S D161 - DETAILER SILICONE FREE DRESSING
ChemWatch Material Safety Data Sheet CHEMWATCH 4827-24
Issue Date: Tue 15-Mar-2005 CD 2005/1 Page 8 of 10
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE
Red liquid with a pleasant odour; mixes with water.
PHYSICAL PROPERTIES
Liquid.
Mixes with water.
Molecular Weight: Not Applicable Boiling Range (癈): 100
Melting Range (癈): Not Available Specific Gravity (water=1): 1.0
Solubility in water (g/L): Miscible pH (as supplied): 8.5
pH (1% solution): Not Available Vapour Pressure (kPa): 2.3 @ 20C
Volatile Component (%vol): Not Available Evaporation Rate: >1 Ether = 1
Relative Vapour Density (air=1): 1.2 Flash Point (癈): Not Applicable
Lower Explosive Limit (%): Not Applicable Upper Explosive Limit (%): Not Applicable
Autoignition Temp (癈): Not Applicable Decomposition Temp (癈): Not Available
State: Liquid
Section 10 - CHEMICAL STABILITY AND REACTIVITY INFORMATION
CONDITIONS CONTRIBUTING TO INSTABILITY
?Presence of incompatible materials.
?Product is considered stable.
?Hazardous polymerisation will not occur.
Section 11 - TOXICOLOGICAL INFORMATION
POTENTIAL HEALTH EFFECTS
ACUTE HEALTH EFFECTS
SWALLOWED
(No Oral LD50, any animal species) The material has NOT been classified by EC
Directives or other classification systems as "harmful by ingestion". This is
because of the lack of corroborating animal or human evidence. The material may
still be damaging to the health of the individual, following ingestion,
especially where pre-existing organ (eg. liver, kidney) damage is evident.
Present definitions of harmful or toxic substances are generally based on doses
producing mortality rather than those producing morbidity (disease, ill-health).
Gastrointestinal tract discomfort may produce nausea and vomiting. In an
occupational setting however, ingestion of insignificant quantities is not
thought to be cause for concern.
EYE
The material may be irritating to the eye, with prolonged contact causing
inflammation. Repeated or prolonged exposure to irritants may produce
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MEGUIAR'S D161 - DETAILER SILICONE FREE DRESSING
ChemWatch Material Safety Data Sheet CHEMWATCH 4827-24
Issue Date: Tue 15-Mar-2005 CD 2005/1 Page 9 of 10
Section 11 - TOXICOLOGICAL INFORMATION ...
conjunctivitis.
SKIN
Skin contact is not thought to have harmful health effects (as classified under
EC Directives); the material may still produce health damage following entry
through wounds, lesions or abrasions.
Entry into the blood-stream, through, for example, cuts, abrasions or lesions,
may produce systemic injury with harmful effects. Examine the skin prior to the
use of the material and ensure that any external damage is suitably protected.
The material may cause skin irritation after prolonged or repeated exposure and
may produce on contact skin redness, swelling, the production of vesicles,
scaling and thickening of the skin.
INHALED
Not normally a hazard due to non-volatile nature of product
The material is not thought to produce adverse health effects or irritation of
the respiratory tract (as classified by EC Directives using animal models).
Nevertheless, good hygiene practice requires that exposure be kept to a minimum
and that suitable control measures be used in an occupational setting.
CHRONIC HEALTH EFFECTS
Substance accumulation, in the human body, may occur and may cause some concern
following repeated or long-term occupational exposure.
Meguiar's D161 - Detailer Silicone Free Dressing
Not available. Refer to individual constituents.
unless otherwise specified data extracted from RTECS - Register of Toxic Effects
of Chemical Substances
GLYCEROL:
TOXICITY IRRITATION
Oral (human) TDLo: None 1428 mg/kg
Oral (rat) LD50: None 12600 mg/kg
Skin (rabbit): 500 mg/24h mild
Eye (rabbit): 126 mg mild
Eye (rabbit): 500 mg/24h mild
2-PROPOXYETHANOL:
reduced.
TOXICITY IRRITATION
Oral (rat) LD50: 3089 mg/kg Skin (rabbit): 500 mg/24h -mild
Inhalation (rat) LC50: 2000 ppm/4 hour Eye (rabbit): 0.75 mg/24h SEVERE
Dermal (rabbit) LD50: 960 mg/kg Eye (rabbit): 100 mg - SEVERE
There have been no specific human studies, but the consistency of the
animal experiments emphasizes that human exposure should be dramatically
WATER:
No significant acute toxicological data identified in literature search.
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MEGUIAR'S D161 - DETAILER SILICONE FREE DRESSING
ChemWatch Material Safety Data Sheet CHEMWATCH 4827-24
Issue Date: Tue 15-Mar-2005 CD 2005/1 Page 10 of 10
Section 12 - ECOLOGICAL INFORMATION
DO NOT discharge into sewer or waterways.
Section 13 - DISPOSAL CONSIDERATIONS
?Recycle wherever possible.
?Consult manufacturer for recycling options or consult local or regional waste
management authority for disposal if no suitable treatment or disposal facility
can be identified.
?Dispose of by: Burial in a licenced land-fill or Incineration in a licenced
apparatus (after admixture with suitable combustible material)
?Decontaminate empty containers. Observe all label safeguards until containers
are cleaned and destroyed.
Puncture containers to prevent re-use and bury at an authorised landfill.
Section 14 - TRANSPORTATION INFORMATION
Shipping Name:
None
Dangerous Goods Class: None
UN/NA Number: None
ADR Number: None
Packing Group: None
Additional Shipping Information:
International Transport Regulations:
IMO: None
HAZCHEM
None
Section 15 - REGULATORY INFORMATION
POISONS SCHEDULE
None
Section 16 - OTHER INFORMATION
This document is copyright. Apart from any fair dealing for the purposes of
private study, research, review or criticism, as permitted under the Copyright
Act, no part may be reproduced by any process without written permission from
CHEMWATCH. TEL (+61 3) 9572 4700.
Issue Date: Tue 15-Mar-2005
Print Date: Wed 16-Mar-2005
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