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MSDS Material Safety Data Sheet
CAS

56-81-5

File Name: 56-81-5.asp

                                        SYN?AKE
Material Safety Data Sheet:
Product ID: 5036011
800628

* * * Section 1 - Chemical Product and Company Identification * * *

Product Use: Cosmetic ingredient
Manufacturer Information
DSM Nutritional Products, Inc. Phone: 908-475-7373
45 Waterview Blvd.
Parsippany, NJ 07054-1298 Emergency # 1-800-424-9300 (24 HR CHEMTREC)


* * * Section 2 - Hazards Identification * * *
Emergency Overview
Product is a colorless liquid. Liquid is not irritative.
Potential Health Effects: Eyes
This product is non-irritating
Potential Health Effects: Skin
This product is non-irritating and non-sensitizing
Potential Health Effects: Ingestion
No significant adverse effects are expected upon ingestion of small amounts of this product. Ingestion of very
large amounts may cause gastrointestinal irritation, nausea, vomiting and diarrhea.
Potential Health Effects: Inhalation
Inhalation of high concentrations of mists or vapors may cause irritation to the respiratory tract.
HMIS Ratings: Health: 1 Fire: 0 Reactivity: 0
Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe * = Chronic hazard
* * * Section 3 - Composition / Information on Ingredients * * *

CAS # Component Percent
56-81-5 Glycerin 60-100

Component Information/Information on Non-Hazardous Components
This product is considered not hazardous under 29 CFR 1910.1200 (Hazard Communication).

This product is not regulated according to criteria of the Canadian Controlled Products Regulations.
* * * Section 4 - First Aid Measures * * *
First Aid: Eyes
Flush with water for 15 minutes while holding the eyelids wide open. Seek medical attention if irritation develops.
First Aid: Skin
Immediately take off all contaminated clothing. For skin contact, wash immediately with soap and water. Do not
use solvents to remove product residues from skin. If irritation persists, get medical attention.
First Aid: Ingestion
Product is not considered hazardous in small amounts. Call a physician if symptoms develop or persist. If
ingestion of a large amount does occur, seek medical attention.
First Aid: Inhalation
Move person to non-contaminated air. Call a physician if symptoms develop or persist.
First Aid: Notes to Physician
Provide general supportive measures and treat symptomatically.
* * * Section 5 - Fire Fighting Measures * * *
General Fire Hazards
See Section 9 for Flammability Properties.

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Page 1 of 5 Issue Date: 01/27/09 Revision: 2.0000
SYN?AKE
Material Safety Data Sheet:
Product ID: 5036011
800628

Product does not readily ignite.
Hazardous Combustion Products
Hazardous combustion products may include carbon monoxide, carbon dioxide and hydrocarbon fragments.
Extinguishing Media
Water, carbon dioxide, foam, dry powder.
Fire Fighting Equipment/Instructions
Fire fighters should wear full-face, self contained breathing apparatus and impervious protective clothing. Fire
fighters should avoid inhaling any combustion products.

NFPA Ratings: Health: 1 Fire: 0 Reactivity: 0
Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe
* * * Section 6 - Accidental Release Measures * * *
Containment Procedures
Stop the flow of material, if this is without risk.
Clean-Up Procedures
Absorb spill with inert material. Shovel material into appropriate container for disposal. Thoroughly wash the area
with water after a spill or leak clean-up.
Evacuation Procedures
None necessary.
Special Procedures
Regulations vary. Consult local authorities before disposal.
* * * Section 7 - Handling and Storage * * *
Handling Procedures
Product should be processed in closed systems, if possible in an inert atmosphere. Avoid eye contact. Avoid
breathing vapors or mists of this product. Wash thoroughly after handling.
Storage Procedures
Keep the container tightly closed and in a cool, well-ventilated place.
* * * Section 8 - Exposure Controls / Personal Protection * * *
A: Component Exposure Limits
Consult local authorities for acceptable exposure limits.
Glycerin (56-81-5)
ACGIH: 10 mg/m3 TWA (mist)
OSHA: 10 mg/m3 TWA (total dust); 5 mg/m3 TWA (respirable fraction)
Alberta: 10 mg/m3 TWA
British Columbia: 10 mg/m3 TWA; 3 mg/m3 TWA (respirable)
Manitoba: 10 mg/m3 TWA (mist)
New Brunswick: 10 mg/m3 TWA
NW Territories: 10 mg/m3 TWA (mist)
20 mg/m3 STEL (mist)
Nova Scotia: 10 mg/m3 TWA (mist)
Nunavut: 10 mg/m3 TWA (mist)
20 mg/m3 STEL (mist)
Ontario: 10 mg/m3 TWAEV
Quebec: 10 mg/m3 TWAEV (mist)
Saskatchewan: 10 mg/m3 TWA (mist)
20 mg/m3 STEL (mist)
Yukon: 30 mppcf TWA; 10 mg/m3 TWA

Engineering Controls
Ventilation should effectively remove and prevent buildup of any vapor or mist generated from the handling of this
product.
____________________________________________________________
Page 2 of 5 Issue Date: 01/27/09 Revision: 2.0000
SYN?AKE
Material Safety Data Sheet:
Product ID: 5036011
800628

PERSONAL PROTECTIVE EQUIPMENT
Personal Protective Equipment: Eyes/Face
Wear safety glasses with side shields.
Personal Protective Equipment: Skin
Use impervious gloves.
Personal Protective Equipment: Respiratory
If ventilation is not sufficient to effectively prevent buildup of mists or vapors, appropriate NIOSH respiratory
protection must be provided.
Personal Protective Equipment: General
Eye wash fountain and emergency showers are recommended.
* * * Section 9 - Physical & Chemical Properties * * *

Appearance: Colorless liquid Odor: Slight
Physical State: liquid pH: 4.5-5.5
Vapor Pressure: Not Available Vapor Density: Not Available
Boiling Point: About 115癈 (239癋) Melting Point: Not Available
Solubility (H2O): Soluble Specific Gravity: 1.21
Flash Point: >220癈 (428癋) Flash Point Method: Not Available
OSHA Flammability IIIB
Classification:

* * * Section 10 - Chemical Stability & Reactivity Information * * *
Chemical Stability
Stable under normal conditions.
Chemical Stability: Conditions to Avoid
Avoid extremes in temperature.
Incompatibility
None identified.
Hazardous Decomposition
Hazardous combustion products may include carbon monoxide, carbon dioxide and hydrocarbon fragments.
Possibility of Hazardous Reactions
Will not occur.
* * * Section 11 - Toxicological Information * * *
Acute Dose Effects
A: General Product Information
SYN?AKE is expected to be safe for cosmetic use.
B: Component Analysis - LD50/LC50
Glycerin (56-81-5)
Inhalation LC50 Rat: >570 mg/m3/1H; Oral LD50 Rat:12600 mg/kg; Dermal LD50 Rat:>21900 mg/kg

Carcinogenicity
A: General Product Information
No information available for the product.
B: Component Carcinogenicity
None of this product's components are listed by ACGIH, IARC, OSHA, NIOSH, or NTP.
Mutagenicity
Not mutagenic




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Material Safety Data Sheet:
Product ID: 5036011
800628

* * * Section 12 - Ecological Information * * *
Ecotoxicity
A: General Product Information
This product is not expected to produce significant ecotoxicity upon exposure to aquatic organisms and aquatic
systems.
B: Component Analysis - Ecotoxicity - Aquatic Toxicity
Glycerin (56-81-5)
Test & Species Conditions
96 Hr LC50 Oncorhynchus mykiss 51000-57000 mg/L
24 Hr EC50 Daphnia magna >500 mg/L

* * * Section 13 - Disposal Considerations * * *
US EPA Waste Number & Descriptions
A: General Product Information
Material, if discarded, is not expected to be a characteristic hazardous waste under RCRA.
B: Component Waste Numbers
No EPA Waste Numbers are applicable for this product's components.
Disposal Instructions
Dispose of waste material according to Local, State, Federal, and Provincial Environmental Regulations.
See Section 7 for Handling Procedures. See Section 8 for Personal Protective Equipment recommendations.
* * * Section 14 - Transportation Information * * *
International Transportation Regulations
Not classified as hazardous material under DOT, IATA, IMDG, and TDG.
* * * Section 15 - Regulatory Information * * *
US Federal Regulations
A: General Product Information
Components of this product have been checked against the non-confidential TSCA inventory by CAS Registry
Number. Components not identified on this non-confidential inventory are either exempt from listing (i.e.
polymers, hydrates) or are listed on the confidential inventory as declared by the supplier.
B: Component Analysis
None of this products components are listed under SARA Section 302 (40 CFR 355 Appendix A), SARA Section
313 (40 CFR 372.65), or CERCLA (40 CFR 302.4).

Acute Health: No Chronic Health: No Fire: No Pressure: No Reactive: No
State Regulations
A: General Product Information
Other state regulations may apply. Check individual state requirements.
B: Component Analysis - State
The following components appear on one or more of the following state hazardous substances lists:

Component CAS CA MA MN NJ PA RI
Glycerin 56-81-5 No Yes Yes Yes Yes Yes

Component Analysis - WHMIS IDL
No components are listed in the WHMIS IDL.
Additional Regulatory Information
A: General Product Information
No additional information available.

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Page 4 of 5 Issue Date: 01/27/09 Revision: 2.0000
SYN?AKE
Material Safety Data Sheet:
Product ID: 5036011
800628

B: Component Analysis - Inventory
Component CAS # TSCA CAN EEC
Glycerin 56-81-5 Yes DSL EINECS

* * * Section 16 - Other Information * * *
Other Information
The information herein is presented in good faith and believed to be accurate as of the effective date given.
However, no warranty, expressed or implied, is given. It is the buyer's responsibility to ensure that its activities
comply with Federal, State or provincial, and local laws.
Key/Legend
ACGIH = American Conference of Governmental Industrial Hygienists. CERCLA = Comprehensive
Environmental Response, Compensation and Liability Act. CFR = Code of Federal Regulations. DSL =
Canadian Domestic Substance List. DOT= Department of Transportation. EINECS = European Inventory of
New and Existing Chemical Substances. EPA = Environmental Protection Agency. HEPA = High Efficiency
Particulate Air. HMIS = Hazardous Material Identification System. IARC = International Agency for Research on
Cancer. IATA= International Air Transport Association. IMDG= International Maritime Dangerous Good. NFPA =
National Fire Protection Association. NIOSH = National Institute of Occupational Safety and Health. NJTSR =
New Jersey Trade Secret Registry. NTP = National Toxicology Program. OSHA = Occupational Safety and
Health Administration. NA = Not available or Not Applicable. SARA = Superfund Amendments and
Reauthorization Act. TLV = Threshold Limit Value. TSCA = Toxic Substance Control Act. WHMIS = Workplace
Hazardous Materials Information System.


End of Sheet 5036011




____________________________________________________________
Page 5 of 5 Issue Date: 01/27/09 Revision: 2.0000

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