MATERIAL SAFETY DATA SHEET
ENVIRONMENTAL RESOURCE ASSOCIATES?br>
May be used to comply with OSHA's Hazard Communication Standard, 29 CFR 1910.1200. Standard must be consulted for specific requirements.
SECTION 1: PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME and PART NUMBER:
Waters Absorbance Detector 3 mm PQ Solution Part Number: WAT047636
MATRIX: Methanol/Water (60:40 v/v)
MANUFACTURER: Environmental Resource Associates PHONE FOR INFO: 800-554-2511
th
ADDRESS: 6000 W. 54 Avenue EMERGENCY PHONE: 800-554-2511
Arvada, CO, USA 80002 FAX: 303-431-5423 info@eraqc.com
DATE PREPARED: September 20, 2007 SUPERCEDES: na
Product is prepared and manufactured for Waters Corporation, 34 Maple Street, Milford, MA, 01757 and used for Waters Instrument Check and
Qualification Standards.
SECTION 2: COMPOSITION/INFORMATION ON INGREDIENTS
COMPONENT CAS NO. % conc LD50 OSHA PEL ACGIH TLV RTECS# Codes
Methanol 67-56-1 >52.0 12900 mg/kg oral mouse 200 ppm 200 ppm PC1400000 G
Water 7732-18-5 >44.0 >90 mL/kg oral rat NA NA ZC0110000
Acetone 67-64-1 <3.7 9750 mg/kg oral rat 1000 ppm 750 ppm AL3150000 G
Acetophenone 98-86-2 <0.02 900 mg/kg oral rat NA 10 ppm AM5250000 G
Propiophenone 93-55-0 <0.02 NA NA NA NA
Butyrophenone 495-40-9 <0.02 NA NA NA NA
Codes: A-OSHA regulated carcinogen; B-IARC Group 1 carcinogen; C-IARC Group 2A carcinogen; D-IARC Group 2B carcinogen; E-NTP Group
1 carcinogen; F-NTP Group 2 carcinogen; G-SARA Title III compound; H-California Prop 65 compound.
SECTION 3: HAZARDS IDENTIFICATION
CLASSIFICATION: Toxic; irritant This preparation is a certified reference material used in instruments.
Causes irritation via all routes of entry including inhalation, skin, eye and ingestion. All chemicals should be considered hazardous ?direct
physical contact should be avoided.
SECTION 4: FIRST-AID MEASURES
INHALATION: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical
attention if needed and contact a physician.
SKIN: Flush skin with plenty of water using soap if needed, remove contaminated clothing and contact physician.
EYES: Flush eyes with plenty of water and contact physician.
INGESTION: Contact poison control center or physician immediately.
Always get medical attention if conditions warrant.
SECTION 5: FIRE-FIGHTING MEASURES
EXTINGUISHING MEDIA: Use extinguishing media that is appropriate to the surrounding fire. Such as carbon dioxide, dry chemical
powder, or water spray.
UNUSUAL FIRE AND EXPLOSION HAZARDS: None ?non-combustible
HAZARDOUS DECOMPOSITION OR BY-PRODUCTS: None
SECTION 6: ACCIDENTAL RELEASE MEASURES
Ventilate area of spill; absorb spill using sand, vermiculite or other non-combustible absorbent material. Place in container for disposal.
PERSONAL PRECAUTIONS: Wear safety glasses and protective gloves when using preparation.
ENVIRONMENTAL PRECAUTIONS AND CLEANUP METHODS: Clean up spills with an absorbent material.
Note: See Section 8 for personal protective equipment and section 13 for waste disposal.
ERA ?MSDS Waters WAT047636 PAGE 1 of 3
MATERIAL SAFETY DATA SHEET
ENVIRONMENTAL RESOURCE ASSOCIATES?br>
May be used to comply with OSHA's Hazard Communication Standard, 29 CFR 1910.1200. Standard must be consulted for specific requirements.
SECTION 7: HANDLING AND STORAGE
HANDLING: Avoid contact with skin and eyes. STORAGE: Keep in a tightly closed container, stored at room temperature.
This product is intended for use only by people trained in the safety and handling of chemicals.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
ENGINEERING MEASURES: Provide exhaust ventilation via local exhaust to prevent exceeding recommended exposure limits or use in a fume
hood.
AIRBORNE OCCUPATIONAL EXPOSURE LIMITS see Section 2
RESPIRATORY PROTECTION: None
HYGIENIC PRACTICES: Demonstrate good laboratory practices when using this product. Wash skin thoroughly after handling product.
SKIN AND BODY: Wear lab coat and general protective lab clothing.
HANDS: Wear protective gloves.
EYES: Wear safety glasses or lab goggles.
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
DATA FOR MIX/MATRIX
PHYSICAL STATE: Liquid VAPOR DENSITY (AIR = 1): NA
COLOR: Colorless VAPOR PRESSURE: NA
ODOR: NA EVAPORATION RATE: NA
BOILING POINT: NA SOLUBILITY IN WATER: Soluble
MELTING POINT: NA PH: NA
DENSITY (H2O = 1) : 0.875 FLASHPOINT: NA
SECTION 10: STABILITY AND REACTIVITY
STABILITY: STABLE __X__ UNSTABLE ____
INCOMPATABILITY YES ____ NO __X__
SECTION 11: TOXICOLOGICAL INFORMATION
This product is a preparation or mixture and the information on the ingredients are found in Section II.
SECTION 12: ECOLOGICAL INFORMATION
No information available
SECTION 13: DISPOSAL CONSIDERATIONS
Asses what may be saved for recovery or recycling. Disposal should be handled as hazardous waste and sent to an appropriate approved
waste facility. Processing, use or contamination of this product may change the waste management options or requirements. Follow all
federal, state, and local laws governing disposal.
SECTION 14: TRANSPORT INFORMATION
Shipment Name/Type: Flammable liquids, NOS (Methanol)
UN NUMBER: UN1993 SHIPPING CLASS: 3 PACKING GROUP: III
SECTION 15: REGULATORY INFORMATION
EU Directives Classification
R: 10-23/24/25-39/23/24/25 Risk Statement: Flammable. Toxic by inhalation, in contact with skin and if swallowed.
S: 7-16-36/37-45 Safety Statement: Keep away from sources of ignition ?No smoking. Wear protective clothing and gloves
when handling. In case of accident or sickness, seek medical attention immediately.
ERA ?MSDS Waters WAT047636 PAGE 2 of 3
MATERIAL SAFETY DATA SHEET
ENVIRONMENTAL RESOURCE ASSOCIATES?br>
May be used to comply with OSHA's Hazard Communication Standard, 29 CFR 1910.1200. Standard must be consulted for specific requirements.
SECTION 16: OTHER INFORMATION
DISCLAIMER: To the best of our knowledge, the information contained herein is accurate. However, this information is intended to be used
only as a guide and does not purport to be complete. Environmental Resource Associates shall not be held liable for the completeness
or accuracy of this information or for any damage resulting from contact or use of the above products. All chemicals may present unknown
health hazards and should be used with caution. Individuals receiving this information and the user of these products have the sole
responsibility to exercise their own judgment to determine the suitability of the materials for any use and the results of its use.
ERA ?MSDS Waters WAT047636 PAGE 3 of 3
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