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CHEMetrics, Inc. After Hours Emergency Nos.: (703) 447-9550
4295 Catlett Rd., Calverton, VA 20138 (540) 272-3874
(800) 356-3072 (540) 788-9026 Creation Date: 05/28/05 (2942-3)
Fax (540) 788-4856 E-mail technical@chemetrics.com Revision Date: 08/14/09
MATERIAL SAFETY DATA SHEET
I. CHEMICAL IDENTIFICATION IV. FIRST AID MEASURES
TRADE NAMES: NITRATE Vacu-vials?and CADMIUM FOIL PACKS EYE AND SKIN CONTACT: Immediately flush eyes and skin with water for 15
minutes. Wash skin with soap and plenty of water. Call physician.
CATALOG NOS.: K-6903, K-6923, and K-6933 INGESTION: Give milk or beaten egg whites at frequent intervals. Induce
vomiting, if directed by medical personnel. If cadmium has been ingested, give
DESCRIPTION: Reagent ampoules and cadmium foil packs for the determi- plenty of water and induce vomiting. Never give anything by mouth to or induce
nation of nitrate in water. The K-6903 and K-6933 Vacu-vials?contain vomiting in an unconscious person. Seek medical attention.
approximately 2 mL of liquid reagent sealed under vacuum. The K-6923 INHALATION: Remove to fresh air. If necessary, give artificial respiration by
Vacu-vials?contain approximately 4.5 mL of liquid reagent sealed under mechanical means, do not use mouth to mouth resuscitation, seek medical
vacuum. Each cadmium foil pack contains approximately 0.3 g of powder. attention.
V. FIRE FIGHTING MEASURES
In the Ampoule:
NFPA RATINGS: HEALTH: 1 FLAMMABILITY: 0 REACTIVITY: 0
FLASH POINT: N/A AUTOIGNITION POINT: Not determined
In the Foil Pack: FLAMMABILITY LIMITS: UPPER: N/A LOWER: N/A
NFPA RATINGS: HEALTH: 3 FLAMMABILITY: 1 REACTIVITY: 0 SUSCEPTIBILITY TO SPONTANEOUS HEATING: None
EXTINGUISHING MEDIA: Carbon dioxide or dry chemical
II. COMPOSITION/INFORMATION ON INGREDIENTS
VI. ACCIDENTAL RELEASE MEASURES
In the Ampoule:
COMPONENT: Cyclohexanediamine Tetraacetic Acid, Disodium Take up with absorbent material. Place in small containers for disposal.
Magnesium Salt
VII. HANDLING AND STORAGE
CAS NO.: 63451-33-2 PERCENT: < 0.5
COMPONENT: 2,5-Dihydroxybenzoic Acid Always wear eye protection when working with these ampoules.
CAS NO.: 490-79-9 PERCENT: < 2.0 WARNING: Do not break the tip of the ampoule unless it is completely
immersed in your sample. Breaking the tip in the air may cause the glass
COMPONENT: 4,5-Dihydroxynaphthalene-2,7-disulfonic acid ampoule to shatter.
CAS NO.: 5808-22-0 PERCENT: < 2.0 If this product is used as directed, the user will not come in contact with or be
exposed to any of its chemical components.
COMPONENT: Sulfanilic Acid Sodium Salt, Hydrate Wash thoroughly after handling. Avoid contact with eyes, skin and clothing.
CAS NO.: 123333-70-0 PERCENT: < 4.0 Fragile. Liquid in glass. Handle with care.
Protect foil pack from moisture. Do not inhale dust.
COMPONENT: Isopropyl Alcohol Exposure of this product to temperatures up to 120EF (49EC) or even below
CAS NO.: 67-63-0 PERCENT: 5.0 32EF (0EC) will not create a safety hazard. For optimum analytical accuracy,
the product should be stored in the dark at room temperature, and if applicable,
COMPONENT: Ethylene Glycol product components should not be used beyond expiration date.
CAS NO.: 107-21-1 PERCENT: < 18.0
VIII. EXPOSURE CONTROLS/PERSONAL PROTECTION
COMPONENT: Deionized Water
OSHA PEL: 400 ppm TWA Isopropyl Alcohol, 0.005 mg/m3 TWA Cadmium
CAS NO.: 7732-18-5 PERCENT: > 67.5
ACGIH TLV: 100 mg/m3 C Ethylene Glycol, 200 ppm TWA Isopropyl Alcohol,
0.01 mg/m3 TWA Cadmium
COMPONENT: Other components
CAS NO.: N/A PERCENT: < 1.0 PROTECTIVE EQUIPMENT: Safety glasses, protective gloves, hood, lab coat
OTHER CONTROL MEASURES: See OSHA Standard 29 CFR 1910.1027 for
Any component of this mixture not specifically listed (e.g. "other components") control measures related to cadmium exposure.
is not considered to present a carcinogen hazard.
IX. PHYSICAL AND CHEMICAL PROPERTIES
In the Foil Pack:
COMPONENT: CDTA Trisodium Salt In the Ampoule:
CAS NO.: 36679-96-6 PERCENT: <10.0 STATE: Liquid APPEARANCE: Colorless to brown tint ODOR: None
SOLUBILITY IN WATER: Miscible pH: 3.5
COMPONENT: Cadmium Metal Powder BOILING POINT: 125EC MELTING POINT: -2EC
CAS NO.: 7440-43-9 PERCENT: <10.0 VAPOR PRESSURE: N/A SPECIFIC GRAVITY: 1.02
VAPOR DENSITY: N/A
COMPONENT: Magnesium Sulfate, Heptahydrate
CAS NO.: 10034-99-8 PERCENT: <10.0 In the Foil Pack:
STATE: Solid APPEARANCE: Blue Metallic Powder ODOR: None
COMPONENT: Tartaric Acid SOLUBILITY IN WATER: Soluble pH: 3.4
CAS NO.: 87-69-4 PERCENT: <35.0 BOILING POINT: N/A MELTING POINT: Not determined
VAPOR PRESSURE: N/A SPECIFIC GRAVITY: Not determined
COMPONENT: Sodium Tartrate, Dihydrate
X. STABILITY AND REACTIVITY
CAS NO.: 6106-24-7 PERCENT: <25.0
COMPONENT: Sodium Sulfate, Anhydrous INCOMPATIBILITIES: strong oxidants, strong acids and bases
CAS NO.: 7757-82-6 PERCENT: <30.0 HAZARDOUS DECOMPOSITION PRODUCTS: toxic gases, oxides of
cadmium, nitrogen, carbon and sulfur
III. HAZARDS IDENTIFICATION Stable under normal conditions.
XI. TOXICOLOGICAL INFORMATION
Danger! Toxic, may affect central nervous system, gastrointestinal and
respiratory tracts, liver and spleen. Harmful or fatal if swallowed.
ACUTE TOXICITY: Irritation, shortness of breath, chest pain, vomiting, CARCINOGENIC STATUS: Isopropyl alcohol: IARC - Group 3, not classifiable
corneal injury, cardiac disturbances, CNS effects, kidney failure as to its carcinogenicity to humans.
CHRONIC TOXICITY: Irritation, skin sensitization, danger of cumulative Ethylene glycol: ACGIH - Group A4, not classifiable as a human carcinogen.
effects, cancer, bone, liver or kidney damage, may cause reproductive or fetal Cadmium: IARC - Group 1, carcinogenic to humans; ACGIH - Group A2,
effects, may cause allergic reaction. suspected human carcinogen; NTP - known to be a human carcinogen;
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Respiratory California Proposition 65 - carcinogen.
conditions, liver or kidney disorders TOXICOLOGICAL STATUS: Cadmium: California Proposition 65 - repro-
ductive toxicant (developmental, male).
No other data available at this time.
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CHEMetrics, Inc. After Hours Emergency Nos.: (703) 447-9550
4295 Catlett Rd., Calverton, VA 20138 (540) 272-3874
(800) 356-3072 (540) 788-9026 Creation Date: 05/28/05 (2942-3)
Fax (540) 788-4856 E-mail technical@chemetrics.com Revision Date: 08/14/09
XII. ECOLOGICAL INFORMATION
Ethylene glycol biodegrades rapidly, may leach to ground water, and is not
expected to bioconcentrate. Isopropyl alcohol is not expected to adsorb to
sediment or bioconcentrate, dangerous to aquatic life in high concentration.
Cadmium is toxic to aquatic organisms, may cause long-term adverse effects
in the aquatic environment.
No other data available at this time.
XIII. DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with Federal, State, and Local Regulations.
XIV. TRANSPORT INFORMATION
Not regulated.
XV. REGULATORY INFORMATION
EUROPEAN INFORMATION:
EU Symbols: Xi - IRRITATING, Xn - HARMFUL, T - TOXIC, N - DANGER-
OUS FOR THE ENVIRONMENT
Risk Phrases: Harmful by inhalation and if swallowed. Irritating to eyes. May
cause sensitization by skin contact. May cause cancer by inhalation. Toxic
to aquatic organisms, may cause long-term adverse effects in the aquatic
environment. Possible risk of impaired fertility. Possible risk of harm to the
unborn child. Vapors may cause drowsiness and dizziness.
Safety Phrases: Avoid contact with skin and eyes. In case of contact with
skin or eyes, rinse immediately with plenty of water and seek medical advice.
Do not breath dust. This material and its container must be disposed of in a
safe way (cadmium). Wear suitable protective clothing, gloves and eye/face
protection. In case of accident or if you feel unwell, seek medical advice
immediately (show the label where possible).
CANADIAN INFORMATION:
WHMIS Classification: D2A, D2B, E
All chemical components of this product are listed on Canada's DSL or are
exempt.
U.S. INFORMATION:
RCRA: Contains RCRA regulated substances. EPA Waste ID No. (Foil
Pack): D006
OSHA: This product meets the criteria for a hazardous substance as defined
in the Hazard Communication Standard (29 CFR 1910.1200).
SARA Section 313: This product contains isopropyl alcohol, ethylene glycol,
and cadmium which are subject to the reporting requirements of Section 313
of SARA Title III.
CALIFORNIA PROPOSITION 65: This product contains a chemical known to
the State of California as a carcinogen and reproductive toxicant.
All chemical components of this product are listed on the TSCA Inventory.
XVI. OTHER INFORMATION
THE ABOVE INFORMATION IS BELIEVED TO BE ACCURATE AND REPRESENTS THE BEST
INFORMATION CURRENTLY AVAILABLE TO US. ALL PRODUCTS ARE OFFERED IN
ACCORDANCE WITH THE MANUFACTURER'S CURRENT PRODUCTION SPECIFICATIONS
AND ARE INTENDED SOLELY FOR USE IN ANALYTICAL TESTING. THE MANUFACTURER
SHALL IN NO EVENT BE LIABLE FOR ANY INJURY, LOSS OR DAMAGE RESULTING FROM
THE HANDLING, USE OR MISUSE OF THESE PRODUCTS.
Vacu-vials?is a registered trademark of CHEMetrics, Inc.
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