SIGMA-ALDRICH
MATERIAL SAFETY DATA SHEET
Date Printed: 09/03/2008
Date Updated: 02/02/2006
Version 1.1
Section 1 - Product and Company Information
Product Name ATRAZIN SOLUTION 100 NG/MYL, IN METHANOL
Product Number 31212
Brand FLUKA
Company Sigma-Aldrich
Address 3050 Spruce Street
SAINT LOUIS MO 63103 US
Technical Phone: 800-325-5832
Fax: 800-325-5052
Emergency Phone: 314-776-6555
Section 2 - Composition/Information on Ingredient
Substance Name CAS # SARA 313
ATRAZIN SOLUTION 100 NG/MYL, IN None Yes
METHANOL
Ingredient Name CAS # Percent SARA 313
METHANOL 67-56-1 > 99 Yes
ATRAZINE 1912-24-9 0.01 Yes
Section 3 - Hazards Identification
EMERGENCY OVERVIEW
Flammable (USA) Highly Flammable (EU). Toxic.
Toxic by inhalation, in contact with skin and if swallowed. Toxic:
danger of very serious irreversible effects through inhalation, in
contact with skin and if swallowed. Irritating to eyes and skin.
Target organ(s): Eyes. Kidneys.
HMIS RATING
HEALTH: 2*
FLAMMABILITY: 3
REACTIVITY: 0
NFPA RATING
HEALTH: 2
FLAMMABILITY: 3
REACTIVITY: 0
*additional chronic hazards present.
For additional information on toxicity, please refer to Section 11.
Section 4 - First Aid Measures
ORAL EXPOSURE
If swallowed, wash out mouth with water provided person is
conscious. Call a physician immediately.
INHALATION EXPOSURE
If inhaled, remove to fresh air. If not breathing give
artificial respiration. If breathing is difficult, give oxygen.
DERMAL EXPOSURE
In case of skin contact, flush with copious amounts of water for
at least 15 minutes. Remove contaminated clothing and shoes.
Call a physician.
EYE EXPOSURE
In case of contact with eyes, flush with copious amounts of
water for at least 15 minutes. Assure adequate flushing by
separating the eyelids with fingers. Call a physician.
Section 5 - Fire Fighting Measures
FLAMMABLE HAZARDS
Flammable Hazards: Yes
EXPLOSION HAZARDS
Vapor may travel considerable distance to source of ignition and
flash back. Container explosion may occur under fire conditions.
FLASH POINT
52 癋 11 癈 Method: closed cup
EXPLOSION LIMITS
Lower: 5.5 % Upper: 31 %
AUTOIGNITION TEMP
455 癈
FLAMMABILITY
N/A
EXTINGUISHING MEDIA
Suitable: Water spray. Carbon dioxide, dry chemical powder, or
appropriate foam.
FIREFIGHTING
Protective Equipment: Wear self-contained breathing apparatus
and protective clothing to prevent contact with skin and eyes.
Specific Hazard(s): Flammable liquid. Emits toxic fumes under
fire conditions.
Section 6 - Accidental Release Measures
PROCEDURE TO BE FOLLOWED IN CASE OF LEAK OR SPILL
Evacuate area. Shut off all sources of ignition.
PROCEDURE(S) OF PERSONAL PRECAUTION(S)
Wear self-contained breathing apparatus, rubber boots, and heavy
rubber gloves.
METHODS FOR CLEANING UP
Cover with dry-lime, sand, or soda ash. Place in covered
containers using non-sparking tools and transport outdoors.
Ventilate area and wash spill site after material pickup is
complete.
ENVIRONMENTAL PRECAUTION(S)
Do not allow material to enter drains or water courses. Avoid
contaminating sewers and waterways with this material.
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Section 7 - Handling and Storage
HANDLING
User Exposure: Do not breathe vapor. Avoid contact with eyes,
skin, and clothing. Avoid prolonged or repeated exposure. Do not
use if skin is cut or scratched. Wash thoroughly after handling.
STORAGE
Suitable: Keep tightly closed. Keep away from heat, sparks, and
open flame.
Store at 2-8癈
Section 8 - Exposure Controls / PPE
ENGINEERING CONTROLS
Safety shower and eye bath. Use nonsparking tools. Use only in a
chemical fume hood.
PERSONAL PROTECTIVE EQUIPMENT
Respiratory: Use respirators and components tested and approved
under appropriate government standards such as NIOSH (US) or CEN
(EU). Use supplied-air or SCBA respirators. Europe permits the use
of type AXBEK full-face cartridge respirators (EN 14387).
Hand: Compatible chemical-resistant gloves.
Eye: Chemical safety goggles.
GENERAL HYGIENE MEASURES
Wash thoroughly after handling. Discard contaminated clothing and
shoes.
EXPOSURE LIMITS
Country Source Type Value
Poland NDS 100 MG/M3
Poland NDSCh 300 MG/M3
Poland NDSP -
Section 9 - Physical/Chemical Properties
Appearance Physical State: Liquid
Property Value At Temperature or Pressure
Molecular Weight N/A
pH N/A
BP/BP Range 64.0 - 65.0 癈 760 mmHg
MP/MP Range N/A
Freezing Point N/A
Vapor Pressure N/A
Vapor Density N/A
Saturated Vapor Conc. N/A
SG/Density 0.79 g/cm3
Bulk Density N/A
Odor Threshold N/A
Volatile% N/A
VOC Content N/A
Water Content N/A
Solvent Content N/A
Evaporation Rate N/A
Viscosity N/A
Surface Tension N/A
Partition Coefficient N/A
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Decomposition Temp. N/A
Flash Point 52 癋 11 癈 Method: closed cup
Explosion Limits Lower: 5.5 %
Upper: 31 %
Flammability N/A
Autoignition Temp 455 癈
Refractive Index N/A
Optical Rotation N/A
Miscellaneous Data N/A
Solubility Solubility in Water:Miscible.
N/A = not available
Section 10 - Stability and Reactivity
STABILITY
Stable: Stable.
Materials to Avoid: Acids, Acid chlorides, Acid anhydrides,
Oxidizing agents, Alkali metals, Reducing agents.
HAZARDOUS DECOMPOSITION PRODUCTS
Hazardous Decomposition Products: Carbon monoxide, Carbon dioxide.
HAZARDOUS POLYMERIZATION
Hazardous Polymerization: Will not occur
Section 11 - Toxicological Information
ROUTE OF EXPOSURE
Skin Contact: May cause skin irritation.
Skin Absorption: Toxic if absorbed through skin.
Eye Contact: May cause eye irritation.
Inhalation: Material may be irritating to mucous membranes and
upper respiratory tract. Toxic if inhaled.
Ingestion: Toxic if swallowed.
TARGET ORGAN(S) OR SYSTEM(S)
Eyes. Kidneys. Liver. Heart.
SIGNS AND SYMPTOMS OF EXPOSURE
Nausea, headache, and vomiting. Gastrointestinal disturbances.
Dizziness. Weakness. Confusion. Drowsiness. Unconsciousness. To
the best of our knowledge, the chemical, physical, and
toxicological properties have not been thoroughly investigated.
Ingestion can cause: Methyl alcohol may be fatal or cause
blindness if swallowed. Cannot be made non-poisonous.
Section 12 - Ecological Information
No data available.
Section 13 - Disposal Considerations
APPROPRIATE METHOD OF DISPOSAL OF SUBSTANCE OR PREPARATION
Contact a licensed professional waste disposal service to dispose
of this material. Burn in a chemical incinerator equipped with an
afterburner and scrubber but exert extra care in igniting as this
material is highly flammable. Observe all federal, state, and
local environmental regulations.
Section 14 - Transport Information
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DOT
Proper Shipping Name: Methanol
UN#: 1230
Class: 3
Packing Group: Packing Group II
Hazard Label: Flammable liquid
PIH: Not PIH
IATA
Proper Shipping Name: Methanol
IATA UN Number: 1230
Hazard Class: 3
Packing Group: II
Section 15 - Regulatory Information
EU ADDITIONAL CLASSIFICATION
Symbol of Danger: F-T
Indication of Danger: Highly Flammable. Toxic.
R: 11-23/24/25-39/23/24/25
Risk Statements: Highly flammable. Toxic by inhalation, in
contact with skin and if swallowed. Toxic: danger of very
serious irreversible effects through inhalation, in contact with
skin and if swallowed.
S: 7-16-36/37-45
Safety Statements: Keep container tightly closed. Keep away from
sources of ignition - no smoking. Wear suitable protective
clothing and gloves. In case of accident or if you feel unwell,
seek medical advice immediately (show the label where possible).
US CLASSIFICATION AND LABEL TEXT
Indication of Danger: Flammable (USA) Highly Flammable (EU).
Toxic.
Risk Statements: Toxic by inhalation, in contact with skin and
if swallowed. Toxic: danger of very serious irreversible effects
through inhalation, in contact with skin and if swallowed.
Irritating to eyes and skin.
Safety Statements: Keep container tightly closed. Keep away from
sources of ignition - no smoking. Avoid contact with skin. Take
precautionary measures against static discharges. Wear suitable
protective clothing and gloves. In case of accident or if you
feel unwell, seek medical advice immediately (show the label
where possible).
US Statements: Target organ(s): Eyes. Kidneys.
UNITED STATES REGULATORY INFORMATION
SARA LISTED: Yes
NOTES: This product is or contains a component that is subject
to SARA313 reporting requirements.
CANADA REGULATORY INFORMATION
WHMIS Classification: This product has been classified in
accordance with the hazard criteria of the CPR, and the MSDS
contains all the information required by the CPR.
DSL: Yes
NDSL: No
Section 16 - Other Information
DISCLAIMER
For R&D use only. Not for drug, household or other uses.
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WARRANTY
The above information is believed to be correct but does not
purport to be all inclusive and shall be used only as a guide. The
information in this document is based on the present state of our
knowledge and is applicable to the product with regard to
appropriate safety precautions. It does not represent any
guarantee of the properties of the product. Sigma-Aldrich Inc.,
shall not be held liable for any damage resulting from handling or
from contact with the above product. See reverse side of invoice
or packing slip for additional terms and conditions of sale.
Copyright 2008 Sigma-Aldrich Co. License granted to make unlimited
paper copies for internal use only.
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