Material Safety Data Sheet
21105D
Revision Date: 12/18/2009
Issuing Date: 12/18/2009
FUNGITROL 920 FUNGICIDE
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Company/Undertaking International Specialty Products
Identification: 1361 Alps Rd.
Wayne, N.J. 07470
U.S.A.
Telephone: (973) 628-4000
Emergency Telephone: CHEMTREC: 1-800-424-9300 or 703-527-3887 (Outside of the USA)
(Spill Related Emergencies)
PROSAR: 1-800-241-7439 (Health Related Emergencies)
Prepared By: Product Stewardship
Product Code: 21105D
Product Name: FUNGITROL 920 FUNGICIDE
Product Use Description: Biocide
2. HAZARDS IDENTIFICATION
Emergency Overview
CAUTION!
HARMFUL IF INHALED.
HARMFUL IF SWALLOWED.
HARMFUL IF ABSORBED THROUGH SKIN.
MODERATE EYE IRRITANT
CAUSES SKIN IRRITATION.
White
Dispersion
Hazard Summary
Target Organs: Eyes
Skin
Gastrointestinal Tract
Respiratory System
Primary Routes of Entry: Eyes. Skin. Inhalation.
Acute Health Hazard: Harmful if inhaled.
Harmful if swallowed.
Harmful if absorbed through skin
Moderate eye irritant
Causes skin irritation.
Chronic Health Hazard: Unknown
Symptoms of Overexposure
Eye Contact: Moderate eye irritant
Skin contact: Causes skin irritation.
Harmful if absorbed through skin
Ingestion: Harmful if swallowed.
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Inhalation: Harmful if inhaled.
3. COMPOSITION/INFORMATION ON INGREDIENTS
Components: Weight %
Titanium dioxide 3-7
13463-67-7
Carbamic acid. butyl-, 3-iodo- 10-30
2-propynyl ester
55406-53-6
4. FIRST AID MEASURES
Eye Contact: Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove
contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Call a
physician or poison control centre immediately
Skin Contact: Remove contaminated clothing and shoes. Rinse skin immediately with plenty of water
for 15-20 minutes. Call a doctor for medical advice.
Ingestion: Do not induce vomiting. If conscious, give 2 glasses of water. Get immediate medical
attention.
Inhalation: If inhaled, remove to fresh air. If breathing is irregular or stopped, administer artificial
respiration. Get medical attention.
5. FIRE FIGHTING MEASURES
Suitable Extinguishing Media: water fog, carbon dioxide, foam, dry chemical
Combustion/Explosion Hazards: None Known
Special Protective Equipment For Wear self-contained breathing apparatus and protective suit.
Fire-Fighters:
6. ACCIDENTAL RELEASE MEASURES
Personal Precautions: Wear suitable protective equipment.
Environmental Precautions: The product should not be allowed to enter drains, water courses or the soil.
Methods for Cleaning Up: Soak up with inert absorbent material. Keep in suitable, closed containers for disposal.
7. HANDLING AND STORAGE
Handling: Do not swallow. Do not get in eyes, on skin, or on clothing. Avoid breathing vapors,
mist or gas. Move to fresh air in case of accidental inhalation of vapors. Wash hands
before eating, drinking, chewing gum, using tobacco or using the toilet. Remove PPE
immediately after handling this product. Wash the outside of gloves before removing.
As soon as possible, wash thoroughly and change into clean clothes. Do not
contaminate water, food or feed by storage or disposal.
Storage: Keep container tightly closed. Keep in a dry, cool place. Keep away from direct
sunlight.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Engineering Measures: Use only in well-ventilated areas.
Respiratory Protection: Use only in well-ventilated areas. Wear NIOSH approved respirator appropriate for
airborne exposure at the point of use.
Hand Protection: Impervious gloves
Eye Protection: Chemical goggles; also wear a face shield if splashing hazard exists.
Exposure Limits:
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Components: ACGIH - Threshold Limit Values - Time U.S. - OSHA - Final PELs - Time Weighted
Weighted Averages (TLV-TWA) Averages (TWAs)
10 mg/m 3 15 mg/m 3 total dust
Titanium dioxide
13463-67-7 (3-7)
Carbamic acid. butyl-, 3-iodo-2- No TLV/TWA Established No TLV/TWA Established
propynyl ester
55406-53-6 (10-30)
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Dispersion
Color: White
Odor: None
Odor Threshold: Not available
pH: 5.0-6.0 (10% solution)
Specific Gravity: 1.10-1.15 @ 25癈
Bulk Density: 9.4 lbs/gal
Boiling Point (癋): 212癋(100癈)
Melting/Freezing Point (癋): 35.6?2癈)
Vapor Pressure: 20.5 torr @ 68?F
Solubility: Miscible in Water
Flash Point (癋): Not determined
10. STABILITY AND REACTIVITY
Chemical Stability: Stable under normal conditions.
Conditions to Avoid: None known
Materials to Avoid: Strong bases, Strong oxidizing agents, Strong acids, Corrodes metal packaging
containers, Non-protected steel
Hazardous decomposition Carbon monoxide Carbon dioxide (CO2) Iodine vapors.
products:
11. TOXICOLOGICAL INFORMATION
Toxicity Test:
Acute Oral Toxicity: 2389 mg/kg (Rat) (similar product)
Acute Dermal Toxicity: >5000 mg/kg (Rat)(similar product)
Acute Inhalation Toxicity: 1.80 mg/l (4 hour) (Rat) (similar product)
Eye Irritation: Moderately irritating to rabbit eye. (similar product)
Skin Irritation: Moderately irritating to rabbit skin. (similar product)
Sensitization: Non- sensitizing to guinea pig skin. (similar product)
Mutagenicity: Non-mutagenic (Bacterial Reverse Mutation Assay, Chromosomal Aberration Study,
Unscheduled DNA Synthesis) (IPBC)
Teratogenicity: Does not cause reproductive or developmental toxicity or teratogenicity when
administered orally to mice or rats. (IPBC)
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Carcinogenicity: This material contains titanium dioxide, a component that has been tested in several
carcinogenicity studies. Lung tumors were observed in rats following high dose
exposure by inhalation and in female rats exposed by intratracheal instillation. Other
studies have shown no tumors in rats following inhalation exposure and no tumors in
mice or rats following oral exposure.
Components: IARC Monographs on NTP Report on Carcinogens U.S. - OSHA - Carcinogens
Occupational Exposures to List -
Chemical Agents List -
Titanium dioxide Group 2B (Possibly Listed
13463-67-7 (3-7) Carcinogenic to Humans)
Other Information: 13-Week Oral Toxicity: given to rats by gavage for 5 days/week for 13 weeks at 20, 50
or 125 mg/kg/day with a NOEL of 20 mg/kg/day.
4-Week Feeding Study: administered to rats via the diet at 60, 125 or 250 mg/kg/day
for 4 weeks resulted in treatment-related effects at all doses. A NOEL was not
established. (IPBC)
12. ECOLOGICAL INFORMATION
Persistence and Degradability: Not readily biodegradable.
Ecotoxicity: (IPBC)
Bioconcentration: low potential for concentration in aquatic biota
LC50 = 0.067ppm (96 hr) Rainbow trout (IPBC)
LC50 = 0.23 ppm (96 hr) Bluegill (IPBC)
LC50 = 0.645 ppm (48 hr) Daphnia magna (IPBC)= 0.133 ppm (21 day) Daphnia magna
(IPBC)
Avian Toxicity: was not toxic when ingested by quail or malard ducks
13. DISPOSAL CONSIDERATIONS
Waste Disposal Methods: PESTICIDE DISPOSAL: Pesticide wastes are acutely hazardous. Improper disposal of
excess pesticide, spray mixture or rinsate is a violation of federal law. If these wastes
cannot be disposed of by use according to label instructions, contact your State
Pesticide or Environmental Control Agency or the Hazardous Waste representative at
the nearest EPA office for guidance.
CONTAINER DISPOSAL: Triple rinse (or equivalent). Then offer for recycling or
reconditioning or puncture and dispose of in a sanitary landfill or by other procedures
approved by state, provincial and local authorities.
Components: RCRA Class-
Carbamic acid. butyl-, 3-iodo-2- Listed
propynyl ester
55406-53-6 (10-30)
14. TRANSPORT INFORMATION
Land Transport:
DOT (Non-Bulk):
UN/NA Number: UN3082
Proper Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCES, LIQUID, N.O.S. (3-Iodo-2-
propynyl butyl carbamate)
Hazard Class: 9
Packing Group: III
DOT (Bulk):
UN/NA Number: UN3082
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Proper Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCES, LIQUID, N.O.S. (3-Iodo-2-
propynyl butyl carbamate)
Hazard Class: 9
Packing Group: III
DOT Marine Pollutant: Marine pollutant
Air Transport (IATA):
UN Number: 3082
Proper Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCES, LIQUID, N.O.S. (3-Iodo-2-
propynyl butyl carbamate)
Hazard Class: 9
Packing Group: III
Sea Transport (IMO):
UN/ID Number: 3082
Proper Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCES, LIQUID, N.O.S. (3-Iodo-2-
propynyl butyl carbamate)
Hazard Class: 9
Packing Group: III
Marine Pollutant: Marine pollutant
TDG (Canada):
UN Number: 3082
Proper Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCES, LIQUID, N.O.S. (3-Iodo-2-
propynyl butyl carbamate)
Hazard Class: 9
Packing Group: III
TDG Marine Pollutant: Marine pollutant
15. REGULATORY INFORMATION
Inventories Status
TSCA Not Listed
DSL Listed
NDSL Not Listed
ENCS Not Listed
AICS Not Listed
EINECS Not Listed
ELINCS Not Listed
NZIoC Not Listed
KECI Not Listed
PICCS Not Listed
IECSC Not Listed
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15. REGULATORY INFORMATION
California Proposition 65 This product does not contain any chemicals known to State of California to cause
Carcinogens & Reproductive cancer, birth, or any other reproductive defects.
Toxicity (CRT) List:
EPCRA (SARA Title III):
EPCRA (SARA Title III) Section EPCRA (SARA Title III) Section EPCRA (SARA Title III) Section
Components:
313 Toxic Chemical Data - De 302 Hazardous Substances 302 Extremely Hazardous
minimis concentration: Substance
Carbamic acid. butyl-, 3-iodo- 1.0 %
2-propynyl ester
55406-53-6 (10-30)
WHMIS Ingredient Disclosure List: None of the components of this product is listed on WHMIS Ingredient Disclosure list.
16. OTHER INFORMATION
NFPA Rating: Health: 2 Flammability: 1 Reactivity: 0.
HMIS RATING:
HEALTH 2*
FLAMMABILITY 1
PHYSICAL HAZARD 0
Prepared By: Product Stewardship
MSDS sections updated: This data sheet contains changes from the previous version in section(s) 1, 2, 3, 4, 5,
6, 7, 8, 9, 10, 11, 12, 13 and 14.
Legend: N.Av.= Not Available; N.A.= Not Applicable
Disclaimer: For purposes of this MSDS, International Specialty Products, as responsible party,
provides the information herein which is intended for use by persons who have or should
obtain professional knowledge and experience in the subjects discussed. ISP s
industrial products are used as materials in the production of products by industrial
customers. ISP usually has only limited information about the products of its
customers and their composition, methods of manufacture and use. Accordingly, ISP
MAKES NO WARRANTY, EXPRESS OR IMPLIED, AS TO THE ACCURACY,
COMPLETENESS OR RELIABILITY OF INFORMATION HEREIN EXCEPT THAT
SUCH INFORMATION IS, TO THE BEST OF ISP'S KNOWLEDGE AND BELIEF,
ACCURATE AS OF THE DATE INDICATED. ISP recommends that customers
independently test and evaluate its products and their products and processes in which
ISP products are used in order to decide their safety and effectiveness.
***End of Safety Data Sheet***
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