MATERIAL SAFETY DATA SHEET PAGE 1 OF 5
KOP-COAT, INC EMERGENCIES
MARINE GROUP EAST HEALTH/SPILLS......: 800-548-0489
36 PINE STREET CHEMTREC ASSISTANCE: 800-424-9300
ROCKAWAY CHEMTREC OUTSIDE US: 703-527-3887
NJ 07866 CANUTEC............: 613-996-6666
KOP-COAT, INC
PRODUCT INFORMATION: 800-221-4466
OUTSIDE USA........: 973-625-3100
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1 PRODUCT IDENTIFICATION
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PRODUCT NAME: 1275 Trinidad Blue
PRODUCT USE.: Antifouling bottom paint
APPEARANCE..: Blue liquid with hydrocarbon odor
CAS NUMBER..: Mixture
SYNONYMS....: None REVISION...: 3
DATE.......: 7/23/08
MSDS NUMBER: 1127500
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2 HAZARDOUS INGREDIENTS
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HAZARDOUS COMPONENT REG AGENCY PPM NOTES MG/M3 NOTES
Ethylbenzene ACGIH STEL 125 543
CAS NUMBER:100-41-4 ACGIH-TWA 100 434
PERCENT BY WGT: <1 NIOSH 100 435
NIOSH STEL 125 545
OSHA STEL 125 545
OSHA TWA 100 435
Cupric oxide (None established.)
CAS NUMBER:1317-38-0
PERCENT BY WGT: 1 TO 5
Cuprous oxide (as Cu dust ACGIH-TLV 1.0
and mists) OSHA-TWA 1.0
CAS NUMBER:1317-39-1
PERCENT BY WGT: 65 TO 70
Titanium dioxide ACGIH-TWA - 10
CAS NUMBER:13463-67-7 NIOSH - (+) - (+)
PERCENT BY WGT: 5 TO 10 OSHA TWA - 10 1
Petroleum distillates ACGIH TLV 100 STS
CAS NUMBER:64742-94-5 OSHA PEL 500 STS
PRODUCT NAME: 1275 Trinidad Blue PAGE 2 OF 5
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2 HAZARDOUS INGREDIENTS
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HAZARDOUS COMPONENT REG AGENCY PPM NOTES MG/M3 NOTES
PERCENT BY WGT: 10 TO 15
Petroleum distillates ACGIH TLV 100 STS
CAS NUMBER:64742-95-6 OSHA-PEL 500 STS
PERCENT BY WGT: 1 TO 5
Copper (as Cu dusts & ACGIH TWA - 1
mists) NIOSH - 1
CAS NUMBER:7440-50-8 OSHA TWA - 1
PERCENT BY WGT: 1 TO 5
Naphthalene ACGIH STEL 15 79
CAS NUMBER:91-20-3 ACGIH TWA 10 52
PERCENT BY WGT: <1 OSHA STEL 15 75
OSHA TWA 10 50
NOTES:
1) Total dust
(+)) NIOSH Occupational Carcinogen
STS) Recommend that exposure limits for stoddard solvent be used as a guideline.
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3 HAZARDS IDENTIFICATION
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EMERGENCY OVERVIEW: WARNING! Combustible liquid and vapor. Harmful or fatal if
swallowed or inhaled. May cause eye, skin and respiratory tract irritation.
EYES: May cause eye irritation. Not expected to cause permanent damage if
promptly rinsed from eyes.
SKIN: May cause skin irritation. Prolonged and/or repeated skin contact may
cause irritation characterized by redness, cracking and blistering. May be
absorbed in toxic amounts through the skin and cause systemic effects.
INHALATION: May cause respiratory tract irritation. Exposure to high
concentrations may cause central nervous system effects, including headache,
drowsiness, nausea, and dizziness.
INGESTION: May cause gastrointestinal disturbances such as nausea, vomiting,
diarrhea, and effects similar to those described in INHALATION. Aspiration of
this product into the lungs during ingestion or vomiting may cause mild to
severe pulmonary injury, possibly progressing to death.
CHRONIC: Reports have associated repeated or prolonged occupational exposure
to solvents with permanent brain or nervous system damage, liver and kidney
damage or may cause cardiac arrhythmia. Ethylbenzene, titanium dioxide and
naphthalene are classified by IARC as possibly carcinogenic to humans (2B) based
PRODUCT NAME: 1275 Trinidad Blue PAGE 3 OF 5
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3 HAZARDS IDENTIFICATION
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on inadequate evidence of carcinogenicity in humans and sufficient evidence of
carcinogenicity in laboratory animals.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Individuals with pre-existing
disease in or a history of ailments involving the nervous system, liver, kidney,
respiratory system or eyes are at a greater risk of developing adverse effects
when exposed to this material.
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4 FIRST AID MEASURES
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EYE CONTACT: Hold eye open and rinse slowly and gently with water for 15-20
minutes. Remove contact lenses, if present, after the first five minutes, then
continue rinsing the eye. Contact a poison control center for treatment advice.
SKIN CONTACT: Take off contaminated clothing. Rinse skin immediately with
plenty of water for 15-20 minutes. Call a poison control center or doctor for
treatment advice. Wash contaminated clothing before reuse.
INHALATION: Move person to fresh air. If person is not breathing, call 911 or
an ambulance, then give artifical respiration, preferably mouth-to-mouth. Call
a poison control center or doctor for further treatment advice.
INGESTION: Immediately call a poison control center or doctor. Do not induce
vomiting unless told to do so by a poison control center or doctor. Do not give
any liquid to the person. Do not give anything by mouth to an unconscious
person.
NOTE TO PHYSICIAN: There is no specific antidote for effects from overexposure
to this material. Treatment should be directed at the control of symptoms and
the clinical condition.
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5 FIRE FIGHTING MEASURES
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FLASH POINT: 104 F/40C
EXTINGUISHING MEDIA: Use dry chemical, carbon dioxide, water spray or foam.
FIRE FIGHTING PROCEDURES: As in any fire, wear complete fire service protective
equipment, including full-face MSHA/NIOSH approved or equivalent self-contained
breathing apparatus. Use water to cool fire-exposed container/structure/protect
personnel.
FIRE AND EXPLOSION HAZARDS: Can release vapors that form explosive mixtures.
Vapors can travel to a source of ignition and flash back. Closed containers may
explode when exposed to extreme heat (fire). Toxic vapors may be given off in a
fire.
PRODUCT NAME: 1275 Trinidad Blue PAGE 4 OF 5
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6 SPILL AND LEAK PROCEDURES
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Stop spill/leak if no risk involved. Avoid breathing vapors. Eliminate ALL
sources of ignition such as flares, flames (including pilot lights), and
electrical sparks. Ventilate area. Take up carefully to avoid heat and sparks.
Use an inert absorbent to complete a clean-up. This material reacts with
oxidizing materials. Dispose of contaminated absorbent, container and unused
contents in accordance with local, state and federal regulations.
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7 HANDLING AND STORAGE
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HANDLING: Avoid breathing of vapors, mists or fumes. Do not get on skin, in
eyes or on clothing. Spray paint in accordance with OSHA 29 CFR 1910.107. Use
with adequate ventilation. Wash thoroughly after handling.
STORAGE: Store in areas/buildings designed to comply with OSHA 1910.106. Keep
in a closed, labeled container within a cool (well-shaded), dry, ventilated
area. Protect from physical damage. Keep containers closed when material is
not in use. Maintain good housekeeping.
OTHER: Keep away from heat and open flame. If post application/use processing
of this product generates dust or if spray application is made, " Exposure
Limits " in Section 2 apply. Do not use until manufacturer's precautions have
been read/understood. Containers of this material may be hazardous when
empty. Since emptied containers retain product residues (vapor, liquid), all
hazard precautions given in the data sheet must be observed. DO NOT PRESSURIZE,
CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME
SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. THEY CAN EXPLODE AND
CAUSE INJURY OR DEATH. All five gallon pails and larger containers, should be
grounded and/or bonded when material is transferred.
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8 EXPOSURE CONTROLS/PERSONAL PROTECTION
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ENGINEERING CONTROLS: Ventilation (general and/or local exhaust) is required
when handling or using this product to keep exposure to airborne contaminants
below the exposure limit. Ventilation rates should be matched to use conditions.
Supplementary local exhaust ventilation may be needed in poorly ventilated
spaces or during spraying.
RESPIRATORY PROTECTION: If engineering controls do not maintain airborne
exposure concentrations to an acceptable level, wear an appropriate, properly
fitted respirator (NIOSH/MSHA-approved or equivalent) during and after sanding
and application. Respirator selection, use and maintenance should be in
accordance with the requirements in 29 CFR 1910.134 and NIOSH 42 CFR 84,
whenever workplace conditions warrant a respirator's use.
EYE PROTECTION: Industrial safety glasses minimum, goggles, faceshield, as
necessary.
PRODUCT NAME: 1275 Trinidad Blue PAGE 5 OF 5
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8 EXPOSURE CONTROLS/PERSONAL PROTECTION
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HAND PROTECTION: Chemical-resistant, flexible-type gloves (heavy duty neoprene
or equal) to prevent contact. Gloves should be rinsed and removed immediately
after use. Wash hands after removing gloves.
SKIN PROTECTION: Wear industrial-type work clothing, which may include long-
sleeved shirt and long pants, chemical-resistant apron, footwear and socks.
OTHER: Facilities utilizing this material should be equipped with an eyewash
station and safety shower. Thoroughly clean shoes and wash contaminated clothes
before reuse.
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9 PHYSICAL AND CHEMICAL PROPERTIES
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Weight Per Gallon (lbs): 21.680 % VOL by Weight.: 15.7
Vapor Density.: (air=1)>1 Boiling Point...: Not determined
Vapor Pressure: Not determined Evaporation Rate: (ether=1)<1
pH............: Not determined Specific Gravity: 2.603
Solubility In Water: Negligible Viscosity.......: Not determined
VOC Content................: 407 g/L
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10 STABILITY AND REACTIVITY DATA
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STABILITY: This material is stable.
HAZARDOUS POLYMERIZATION: None
INCOMPATIBILITY: Avoid acids, reducing agents, oxidizing agents, chlorates,
bromates, potassium nitrate, hydrogen peroxide, heat, sparks and open flame.
HAZARDOUS DECOMPOSITION PRODUCT(S): Carbon monoxide, carbon dioxide, noxious
copper compounds, and irritating vapors of acetic acid and other toxic organic
compounds during fires.
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11 TOXICOLOGICAL INFORMATION
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No additional information. See Section 3 for health hazards.
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12 ECOLOGICAL INFORMATION
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This material is toxic to fish. Do not apply directly to water by cleaning
of equipment or disposal of wastes. Do not allow chips and dust generated
during paint removal to enter water. Dispose of paint debris in an approved
landfill. Do not discharge effluent containing this product into lakes,
streams, ponds, estuaries, oceans and other waters unless in accordance with
PRODUCT NAME: 1275 Trinidad Blue PAGE 6 OF 5
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12 ECOLOGICAL INFORMATION
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the requirements of a National Pollution Discharge Elimination System (NPDES)
permit and the permitting authority has been notified in writing prior to
discharge. Do not discharge effluent to sewer system without previously
notifying the local sewage treatment plant authority. For guidance contact
your State Water Board or Regional Office of the EPA.
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13 DISPOSAL CONSIDERATIONS
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Dispose of unusable product in accordance with local, state and federal
regulations.
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14 TRANSPORTATION INFORMATION
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DEPARTMENT OF TRANSPORTATION REPORTABLE QUANTITIES
REPORTABLE QTY (LBS) HAZARDOUS SUBSTANCE
100 Xylene
10 Dibutyl Phthalate
100 Naphthalene
Shipment by Ground-Domestic:
Combustible liquid - Exempt from DOT Regulations in non-bulk (< 119 gallons)
containers.
Shipment by Air:
PROPER SHIPPING NAME: UN1263, Paint, Class 3, PG III
LABEL: Flammable liquid
Shipment by Sea:
PROPER SHIPPING NAME: UN1263, Paint, Class 3, PG III, MARINE POLLUTANT (cuprous
oxide)
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15 REGULATORY INFORMATION
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SARA TITLE III SECTION 313 CHEMICALS
Ethylbenzene
Cupric oxide
Cuprous oxide (as Cu dust and mists)
Copper (as Cu dusts & mists)
Naphthalene
WARNING: THIS PRODUCT CONTAINS CHEMICALS KNOWN TO THE
STATE OF CALIFORNIA TO CAUSE CANCER.
WARNING: THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF
CALIFORNIA TO CAUSE BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
PRODUCT NAME: 1275 Trinidad Blue PAGE 7 OF 5
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15 REGULATORY INFORMATION
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EPA Registration Number 60061-49.
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16 OTHER INFORMATION
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Ethylbenzene is considered a Group 2B carcinogen (possibly carcinogenic to
humans). This category generally includes agents for which there is limited
evidence in humans in the absence of sufficient evidence in experimental
animals.
NOTICE: This document is generated for the purpose of distributing health,
safety and environmental data. The information on this MSDS was obtained from
sources which we believe are reliable. However, the information is provided
without any warranty, expressed or implied, regarding its correctness. Some
information presented and conclusions drawn herein are from sources other than
direct test data on the substance itself. Kop-Coat makes no warranty with
respect thereto and disclaims all liability from reliance thereon.
PREPARED BY: Manager of Health, Safety and Environmental Affairs
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