Sanonda (Australia) Pty.Ltd.
A.C.N. 059 813 973
SANONDA Suite 822 St Kilda Road Towers,
MATERIAL SAFETY DATA No. 1 Queens Road,
Melbourne, VIC 3004
PRODUCT NAME:
Aminoz 625, Selective Weedkiller by Sanonda
Hazardous according to criteria of Worksafe Australia
Emergency Phone: 000 or 131126 State Poisons Information Centre
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IDENTIFICATION SECTION
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MSDS No. 032a Date: 23.06.2010 Supersedes: 032
Manufacturer's Name/Address:
Sanonda (Australia) Pty. Ltd.
Suite 822 St Kilda Road Towers,
No. 1 Queens Road,
Melbourne, VIC 3004
Emergency phone Number: 03 9863 8081
PRODUCT INFORMATION
_____________________________________________________________________________
Trade Name:
Aminoz 625, Selective Weedkiller by Sanonda.
Chemical Name:
625 g/L 2,4-D present as the Dimethylamine salt and Diethanolamine salt.
Chemical Family of active Constituent:
Carboxylic acid, aromatic Halogen
UN No: NA. Packing Group: NA
Hazchem Code: NA. SUSDP: Classification S5
ADG Classification: None Allocated. Not a Dangerous Good.
Risk Phrases: R/20/21/22. Harmful by inhalation, in contact with skin, and if swallowed.
Safety Phrases: S20, S24, S38. When using, do not eat or drink. Avoid with skin. In cast of
insufficient ventilation, wear suitable respiratory.
INGREDIENTS:
Chemical Entity: CAS NO: PROPORTION:
2,4-D present as the Isopropylamine salt 94-75-7 62.5 w/v
Inert Components and water - To 100
SANONDA Sanonda (Australia) Pty. Ltd.
MATERIAL SAFETY DATA A.C.N. 059 813 973
Suite 822 St Kilda Road Towers,
No. 1 Queens Road,
Melbourne, VIC 3004
Emergency phone Number: 03 9863 8081
Aminoz 625, Selective Weedkiller by Sanonda
PRODUCT NAME:
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FIRST AID PROCEDURES
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INHALATION: Remove from exposure area to fresh air immediately. If breathing has stopped,
give artificial respiration. Maintain airway and blood pressure and administer
oxygen if available. Keep affected person warm and at rest. Treat
symptomatically and supportively. Administration of oxygen should be performed
by qualified personnel. Get medical attention immediately.
SKIN CONTACT: Remove contaminated clothing and shoes immediately. Wash affected area
with soap or mild detergent and large amounts of water until no evidence of
chemical remains (approximately 15-20 minutes). Get medical attention
immediately.
EYE CONTACT: Wash eyes immediately with large amounts of water or normal saline,
occasionally lifting upper and lower lids, until no evidence of chemical remains
(approximately 15-20 minutes). Get medical attention immediately.
INGESTION: If the person is conscious and not convulsing, induce emesis by giving syrup
of Ipecac (keeping the head below the hips to prevent aspiration) followed by
water. Repeat in 20 minutes if not effective initially. In patients with depressed
respiration or if emesis is not produced, perform gastric lavage with activated
charcoal. Follow with a saline cathartic. Treat symptomatically and supportively.
Gastric lavage should be performed by qualified medical personnel. Get medical
attention immediately.
NOTE TO PHYSICIAN
ANTIDOTE: No specific antidote. Treat symptomatically and supportively.
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FIRE AND EXPLOSION INFORMATION
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FIRE AND EXPLOSION HAZARD: Non Flammable.
EXTINGUISHING MEDIA:
Dry chemical, water spray or regular foam. For larger fires, use water spray, fog
or regular foam.
FIREFIGHTING:
Move container from fire area if you can do it without risk. Fight fire from maximum distance.
Stay away from ends of tanks. Dam fire-control water for later disposal; do not scatter the
material.
Use agents suitable for type of fire. Avoid breathing vapours or dusts, keep upwind.
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SANONDA Sanonda (Australia) Pty. Ltd.
MATERIAL SAFETY DATA A.C.N. 059 813 973
Suite 822 St Kilda Road Towers,
No. 1 Queens Road,
Melbourne, VIC 3004
Emergency phone Number: 03 9863 8081
Aminoz 625, Selective Weedkiller by Sanonda
PRODUCT NAME:
FIRE AND EXPLOSION INFORMATION Contd.
HAZARDOUS COMBUSTION PRODUCTS:
Thermal decomposition products may include highly toxic fumes of phosgene, toxic and corrosive
fumes of chlorides, and oxides of carbon.
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SPILL CONTROL AND PRODUCT/WASTE DISPOSAL
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OCCUPATIONAL SPILL:
Do not touch spilled material. Stop leak if you can do it without risk. Use water spray to reduce
vapours. For small spills, take up with sand or other absorbent material and place into containers
for later disposal. For small dry spills, with a clean shovel place material into clean, dry containers
and cover. Move containers from spill area. For larger spills, dam far ahead of spill for later
disposal. Keep unnecessary people away. Isolate hazard area and deny entry. Ventilate closed
spaces before entering.
SOIL SPILL:
Dig holding area such as lagoon, pond or pit for containment.
Use protective cover such as a plastic sheet to prevent material from dissolving in fire
extinguishing water or rain.
WATER SPILL:
Trap spilled material at bottom in deep water pockets, excavated holding areas or within sand bag
barriers.
Use activated carbon to absorb spilled substance that is dissolved.
Use suction hoses to remove trapped spill material.
Use mechanical dredges or lifts to extract immobilised masses of pollution and precipitates.
WASTE DISPOSAL PROCEDURE:
Wastes that cannot be used or chemically re-processed should be disposed of in landfill approved
for pesticide disposal. Dispose of in accordance with local law.
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SANONDA Sanonda (Australia) Pty. Ltd.
MATERIAL SAFETY DATA A.C.N. 059 813 973
Suite 822 St Kilda Road Towers,
No. 1 Queens Road,
Melbourne, VIC 3004
Emergency phone Number: 03 9863 8081
PRODUCT NAME: Aminoz 625, Selective Weedkiller by Sanonda
_____________________________________________________________________________
HANDLING AND STORAGE
Observe all federal, state and local regulations when storing this substance. Store in accordance
with Dangerous Goods Regulations in recommended procedures for the disposal and storage of
pesticides and pesticide containers.
Store away from incompatible substances.
Shipping Name: Phenoxy pesticide, liquid, toxic, N.O.S
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TRANSPORT INFORMATION
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ADG Code: This Product is not classified as a Dangerous Good. No special transport conditions
are necessary unless required by other regulations.
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REGULATORY INFORMATION
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AICS: All of the significant ingredients in this formulation are to be found in the public AICDS
Database.
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HEALTH HAZARD INFORMATION
VENTILATION:
Provide local exhaust ventilation and/or general dilution ventilation to meet published exposure
limits.
EYE PROTECTION:
Employee must wear splash-proof or dust-resistant safety goggles to prevent contact with this
substance.
EMERGENCY WASH FACILITIES:
Where there is any possibility that an employee's eye may be exposed to this substance, the
employer should provide an eye wash fountain within the immediate work area for emergency
use.
CLOTHING:
Employee must wear appropriate protective (impervious) clothing and equipment to prevent
repeated or prolonged skin contact with this substance.
GLOVES:
Employee must wear appropriate protective gloves to prevent contact with this substance.
RESPIRATOR:
The specific respirator selected must be based on contamination levels found in the work place,
must not exceed the working limits of the respirator and must be approved.
Any chemical cartridge respirator with organic vapour cartridge(s) in combination with a dust, mist,
and fume filter.
Any supplied-air respirator.
Any self-contained breathing apparatus with or without a full face piece.
Escape - Any air-purifying, full face piece respirator (gas mask) with a chin-style, front or back
mounted organic vapour canister having a high-efficiency particulate filter.
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SANONDA Sanonda (Australia) Pty. Ltd.
MATERIAL SAFETY DATA A.C.N. 059 813 973
Suite 822 St Kilda Road Towers,
No. 1 Queens Road,
Melbourne, VIC 3004
Emergency phone Number: 03 9863 8081
Aminoz 625, Selective Weedkiller by Sanonda
PRODUCT NAME:
HEALTH HAZARD INFORMATION Contd.
FOR FIREFIGHTING AND OTHER IMMEDIATELY DANGEROUS TO LIFE OR HEALTH
CONDITIONS:
Any self-contained breathing apparatus that has a full face piece and is operated in a pressure-
demand or other positive-pressure mode.
Any supplied-air respirator that has a full face piece and is operated in a pressure-demand or
other positive-pressure mode in combination with an auxiliary self-contained breathing apparatus
operated in pressure-demand or other positive-pressure mode.
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STABILITY AND REACTIVITY
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REACTIVITY:
Stable under normal temperatures and pressures.
INCOMPATIBILITIES:
METALS: May corrode.
HAZARDOUS DECOMPOSITION:
Thermal decomposition products may include highly toxic fumes of phosgene, toxic and corrosive
fumes of chlorides, and oxides of carbon.
POLYMERISATION:
Hazardous polymerisation has not been reported to occur under normal temperatures and
pressures.
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TOXICOLOGY INFORMATION
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Toxicology: 2,4-D (2,4-dichlorphenoxyacetic acid)
LD50 (oral, rat) 699mg/Kg
LD50 (dermal, rabbit) >2,00mg/Kg
LC50 (inhalation, rat) >1.79mg/L (4hr)
Not toxic to bees
LC50 (rainbow trout) -100 mg/L
LC50 (mallard duck) >5,000mg/Kg in diet
LD50 (mallard duck) >1,000mg/Kg
Dimethylamine
Acute oral LD50 700 mg/Kg (rat)
Diethanolamine
Acute oral LD50 710 mg/Kg (rat)
2,4-D (2,4-dichlorphenoxyacetic acid) dimethylamine salt
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SANONDA Sanonda (Australia) Pty. Ltd.
MATERIAL SAFETY DATA A.C.N. 059 813 973
Suite 822 St Kilda Road Towers,
No. 1 Queens Road,
Melbourne, VIC 3004
Emergency phone Number: 03 9863 8081
Aminoz 625, Selective Weedkiller by Sanonda
PRODUCT NAME:
_______________________________________________________________________
TOXICOLOGY INFORMATION cont;
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Toxicology: Acute LC50 (48hr) (daphnia) 184mg/L
In trials using 2,4-D as a drug, studies on volunteers have shown that doses
of between 5 and 36mg/kg body weight do not cause any acute toxic effects.
Formulated 2,4-D products can be absorbed by ingestion, inhalation (spray mist)
and through the skin. Studies of users (sprayers) has shown that absorption
through the skin is the most common route. When used with good agricultural
spraying practice and good personal hygiene, absorption of 2,4-D is very low.
2,4-D does not accumulate in the body; a single dose of 2,4-D is rapidly excreted
(in a few days), mainly in the urine.
The Australian acceptable daily intake (ADI) of 2,4-D for a human is
0.01mg/ Kg/day set for the public for daily, lifetime exposure. This is based on
the NOEL of 1 mg/kg/day, the level determined to show no effects during long
term exposure for the most sensitive indicators and the most sensitive species.
(Ref: Comm. Dept of Health and Ageing, TGA, `ADI List', September 2002).
Environ. Protection:
2,4-D products do not appear to pose any threat to birds.
2,4-D products do not appear to pose any threat to fish other than in very high
concentrations.
DO NOT spray in high winds.
Do not contaminate dams, rivers or streams with pesticide or used containers.
Do not use this container for any other purpose.
Wash out the container and dispose of it in an approved manner.
Equipment that has been used for this chemical should not be used for the
Application of other materials to sensitive plants, unless it has been well washed
Out with hot soapy water or 1% solution of ammonia, followed by several clear
water rinses.
Do not use on or in situations where damage to susceptible crops plants
cotton, tobacco, tomatoes, flowers, vines, fruit trees or other susceptible crop
Plants may result from direct application or drift.
Packaging and Labelling:
CAUTION
KEEP OUT OF REACH OF CHILDREN
READ SAFETY DIRECTONS BEFORE OPENING OR USING
Not to be used for any purpose or in any manner contrary to the label unless
authorised under appropriate legislation.
The product has been assessed according to the Worksafe criteria for classifying
Hazardous substances and is classified as hazardous:
Risk Phrases:
R20/21/22 ?Harmful by inhalation, in contact with skin and if swallowed.
Safety Phrases:
S2 - Keep out of reach of children
S13 - Keep away from food, drink and animal feeding stuffs
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SANONDA Sanonda (Australia) Pty. Ltd.
MATERIAL SAFETY DATA A.C.N. 059 813 973
Suite 822 St Kilda Road Towers,
No. 1 Queens Road,
Melbourne, VIC 3004
Emergency phone Number: 03 9863 8081
Aminoz 625, Selective Weedkiller by Sanonda
PRODUCT NAME:
PHYSICAL AND CHEMICAL INFORMATION
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PHYSICAL DESCRIPTION/PROPERTIES
Physical Description/Colour: Clear, red-brown liquid
Odour: Mild amine odour
Boiling Point: > 100?C (for water)
Freezing/Melting point: <0篊
Volatiles: Water component
Vapour Pressure: 16mmHg (for water), 2,4-D amine salt is non volatile
Specific Gravity: 1.25 approx
Water Solubility: Completely soluble in water
Autoignition temp: Not applicable ?does not burn
Flash Point Non flammable
Flamm. Limit LEL Non flammable
The information presented herein, while not guaranteed, was prepared from literature available by
technically knowledgeable personnel and to the best of our knowledge is true and accurate.
Sanonda (Australia) Pty. Ltd. makes no representation as to the completeness or accuracy
thereof. It is not intended to be all inclusive and the manner and conditions of use and handling
may involve other or additional considerations. Sanonda (Australia) will not be responsible for
damages of any nature whatsoever resulting from use or reliance of information given in this
Material Safety Data Sheet. Physical data of material may vary from batch to batch.
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