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MSDS0020         Jan. 15, 1997

                             SA-50 Brand Amine 2,4-D

                         MATERIAL SAFETY DATA SHEET

Southern Agricultural Insecticides, Inc.                          Phone           941-722-3285

PO Box 218, Palmetto, Fla. 34220                                  Chemtrec        800-424-9300

I. MATERIAL IDENTITY

Product name: SA-50 Brand Amine 2,4-D                EPA Reg. No. 48273-4-l829

Chemical Name: Dimethyamine salt of 2,4-dichlorophenoxy acetic acid

Chemical Family: Chlorinated phenoxy

Synonyms: 2,4-D, 2,4,-D-DMA

II. COMPOSITION/ INFORMATION ON INGREDIENTS

Dimethylamine salt of 2,4-dichlorophenoxy acetic acid  49.3%

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2,4-dichlorophenoxy acetic acid         CAS# 94-75-7 OSHA (TWA) 10mg/M

Ingredients listed as carcinogens: NTP no, IARC no, OSHA no.

III. PHYSICAL DATA:

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Boiling Point (approx.) 214 F                    Vapor pressure Approx. 17 mmHg @20 C

Vapor Density (Air=1) >1 (H2O vapor)             Solubility in water: Soluble

Density 9.6 LB/gal                               Appearance/Odor Straw colored liquid

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Freezing point approximately 30 F                Pungent odor

IV. FIRE AND EXPLOSION HAZARD DATA

Flash Point      None to boiling (TOC)

Flammable limits LEL not determined UEL not determined

Extinguish media Water, foam, or fog. Use water to cool containers. Run off from fire control and

dilution water may cause pollution.

Special fire fighting procedures: Positive pressure breathing apparatus and protective clothing

Unusual Fire and explosion hazards: Noxious fumes may be evolved at high temperatures

V. REACTIVITY DATA

Materials to avoid: Strong acids and oxidizing agents

Hazardous decomposition products: Hydrogen chloride and oxides of nitrogen

Hazardous polymerization: Will not occur

Stability; Stable under normal storage conditions. Avoid excessive heat.

VI. ENVIRONMENTAL AND DISPOSAL INFORMATION

If spilled: Dike and absorb spilled material. Shovel into appropriate container.

Vapors, spray drift or runoff may adversely affect non-target plants labeled container for

disposal Pesticide wastes are toxic. Improper disposal of excess pesticide, spray mixture, or rinse

water is a violation of federal law. If these wastes cannot be disposed of according to label

instructions, contact your state pesticide or environmental control agency or hazardous waste

representative of the nearest EPA regional office for guidance.. Do not apply directly to water, to

areas where surface water is present, or to intertidal areas below the mean high water mark. Do

not contaminate irrigation or domestic water.

VII. HEALTH HAZARD DATA

Primary routes of entry: Ingestion, inhalation, eye and skin.

INGESTION: The oral LD50 for 2,4-D acid for rats is 1492 mg/Kg

EYE: May cause severe irritation with corneal injury which may result in permanent impairment of

vision, even blindness.

SKIN CONTACT: Prolonged exposure may cause skin irritation.

SKIN ABSORPTION: A single prolonged exposure may result in the material being absorbed in

harmful amounts. The dermal LD50 for rabbits is approx. 2800 mg/kg.

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INHALATION: Single exposure to vapors is not likely to be hazardous. OSHA TWA 10 mg/M







SA-50 Brand Amine 2,4-D                                                           Page 2 0f 2

CHRONIC EFFECTS: Excessive exposure may cause liver, kidney, gastrointestinal and

muscular effects. Signs and symptoms of excessive exposure may be nausea and/or vomiting

and abdominal cramps and diarrhea.         Did not cause cancer in long term animal studies. Birth

defects are unlikely. Although in laboratory animals other adverse effects were observed in the

mother and fetus at exaggerated doses, exposures having no effects on the mother should have

no effect on the fetus High dietary levels of 2,4-D caused toxic effects (weight and viability

reduction) in rats on a reproduction test. Has been shown to be negative in some invitro ("test

tube" mutagenic tests and positive in others. Results of mutagenic tests in animals have been

inconclusive.

VIII. FIRST AID

EYES: Immediate and continuous irrigation with flowing water for at least 30 minutes is

imperative. Lift eye lids while irrigating. Prompt medical consultation is essential.

SKIN: In case of contact immediately flush skin with plenty of water for at least 15 minutes while

removing contaminated clothing and shoes. Call a physician if irritation persists. Wash clothing

before reuse. Destroy contaminated leather items.

INGESTION: Induce vomiting only at advice of physician Give large amounts of water, or milk if

available. When substantial amount is ingested vomiting usually occurs. Transport to a medical

facility.

INHALATION: Remove to fresh air if effects occur. Consult a physician.

NOTE TO PHYSICIAN: Corrosive. May cause stricture. Symptomatic treatment. If lavage is

performed, suggest endotracheal and/or esophagoscopic control. If burn is present, teat as a

thermal burn, after decontamination. Supportive care. Treatment based on judgment of the

physician in response to reactions of the patient. No specific antidote.

IX. HANDLING PRECAUTIONS

Read and observe all label directions and precautions

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EXPOSURE GUIDELINES: 2,4-dichlorophenoxy acetic acid OSHA (TWA) 10 mg/M

VENTILATION: Use only with good ventilation Product is intended for use outdoors. Where

exposure guidelines would be exceeded wear and approved air-purifying respirator..

SKIN PROTECTION: Coveralls over short sleeve shirt and short pants. Water proof gloves.

Chemically resistant footwear plus socks. Protective eye wear. Chemical resistant headgear for

overhead exposure. Chemical resistant apron for loading and sprayer maintenance.

EYE Protection: Use chemical goggles. Eye wash fountain should be available in work area.

STORAGE: Store in original container in a cool locked storage area inaccessible to children or

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pets. Do not store with food, feed or clothing. Store at temperatures above 32 F.

X. SELECTED REGULATORY INFORMATION

Sara 313 information: This product contains the following toxic substance subject to the reporting

requirements. 2,4-D CAS# 94-75-7

Under applicable definitions it meets the following SARA Hazard categories;

An immediate health hazard. A delayed health hazard.

2,4-D Acid and salts listed in the table of hazardous substances 40CFR 302.4 , RQ 100 lb.

RCRA waste number U240

2,4-Dichlorophenoxy acetic acid is listed In table Z-1-A (OSHA) 29 CFR 1910.1000

XI, TRANSPORTATION

Shipments of 2 x 2 1/2 gallon containers or less are not DOT regulated for domestic land

shipment.

Freight Class NMFC, Herbicides, liquid, N.O.I. 50320

This information relates solely to this specific material. It does not include combinations with other

materials. This information is given without warranty or representation. Information is based on

data we believe to be correct as of the date hereof. This information is furnished solely for your

consideration, investigation, and verification. Before using any product READ THE

LABEL.