SAFETY DATA SHEET
Based on Directive 2001/58/EC of the Commission of the European Communities
Soudafix VE280-SF, B component
1. Identification of the substance/preparation and of the company/undertaking
1.1 Identification of the substance or preparation:
Product name: Soudafix VE280-SF, B component
1.2 Use of the substance or the preparation:
Hardener
1.3 Company/undertaking identification:
SOUDAL N.V.
Everdongenlaan 18-20
B-2300 Turnhout
Tel. : +32 14 42 42 31
Fax : +32 14 44 39 71
1.4 Telephone number for emergency:
+32 14 58 45 45
Brandweerinformatiecentrum voor gevaarlijke stoffen (B.I.G.)
Technische Schoolstraat 43A, B-2440 Geel
2. Composition/information on ingredients
Hazardous ingredients CAS No. Conc. in Hazard Risks
% symbol
EINECS/ELINCS No. (R-phrases)
dibenzoyl peroxide 94-36-0 1 - <20 E;Xi 02-36-43 (1)
202-327-6
2-ethylhexyl benzoate 5444-75-7 1 - <20 - 53 (1)
226-641-8
dinch 166412-78-8 20 - <50 Xi 38 (1)
431-890-2
oxydipropyl dibenzoate 27138-31-4 0.1 - <2.5 N 51/53 (1)
248-258-5
(1) For R-phrases in full: see heading 16
3. Hazards identification
- May cause fire
- Irritating to skin
- May cause sensitisation by skin contact
Printing date : 02-2008 1/9
Compiled by : Brandweerinformatiecentrum voor Gevaarlijke Stoffen vzw (BIG)
Technische Schoolstraat 43 A, B-2440 Geel
! +32 14 58 45 47 http://www.big.be E-mail: info@big.be
MSDS established : 20-02-2007 Revised on : -
Reference number : BIG\44842GB Revision number : 000
Reason for revision : -
Soudafix VE280-SF, B component
4. First aid measures
4.1 Eye contact:
- Rinse immediately with plenty of water
- Seek medical advice
4.2 Skin contact:
- Rinse immediately with plenty of water
- If irritation persists: seek medical advice
4.3 After inhalation:
- Remove the victim into fresh air
- Seek medical advice
4.4 After ingestion:
- Never give water to an unconscious person
- Do not induce vomiting
- Seek medical advice
5. Fire-fighting measures
5.1 Suitable extinguishing media:
- Quantities of water
- Water spray
- Alcohol-resistant foam
- ABC powder
- Carbon dioxide
5.2 Unsuitable extinguishing media:
- None
5.3 Special exposure hazards:
- Combustible
- On heating: oxidation resulting in increased fire or explosion risk
- Upon combustion CO and CO2 are formed
5.4 Instructions:
- If exposed to fire cool the closed containers by spraying with water
- Take account of toxic firefighting water
- Extinguish/cool from behind cover/unmanned monitors
5.5 Special protective equipment for firefighters:
- Heat/fire exposure: compressed air/oxygen apparatus
- Protective clothing for exposure to chemicals
6. Accidental release measures
6.1 Personal protection/precautions:
See heading 8.2/13
6.2 Environmental precautions:
- Use appropriate containment to avoid environmental contamination
6.3 Methods for cleaning up:
- Start with disposal only in the presence of experts
- Spill must not return in its original container
- Carefully collect the spill/leftovers
- Scoop solid spill into closing containers
- Take collected spill to manufacturer/competent authority
- Clean contaminated surfaces with an excess of water
- Wash clothing and equipment after handling
Printing date : 02-2008 2/9
Soudafix VE280-SF, B component
7. Handling and storage
7.1 Handling:
- Observe very strict hygiene - avoid contact
- Avoid prolonged and repeated contact with skin
- Do not discharge the waste into the drain
- Handle and open the container with care
- Remove contaminated clothing immediately
7.2 Storage:
- Keep container tightly closed
- Keep out of direct sunlight
- Store in a cool area
- Store in a dry area
- Keep away from: heat sources, ignition sources
Storage temperature : < 50 癈
Quantity limits : N.D. kg
Storage life : 365 days
Materials for packaging :
- suitable : synthetic material
7.3 Specific uses:
- See information supplied by the manufacturer
8. Exposure controls/Personal protection
8.1 Exposure limit values:
DIBENZOYL PEROXIDE:
mg/m3
TLV-TWA :5 ppm
mg/m3
TLV-STEL :- ppm
mg/m3
WEL-LTEL :5 ppm
-
mg/m3
WEL-STEL :- ppm
-
mg/m3
MAK : 5E ppm
3
MAC-TGG 8 h :5 mg/m
mg/m3
VME-8 h :5 ppm
-
mg/m3
VLE-15 min. :- ppm
-
mg/m3
GWBB-8 h :5 ppm
-
mg/m3
GWK-15 min. :- ppm
-
8.2 Exposure controls:
8.2.1 Occupational exposure controls:
- Use only in well ventilated area
8.2.1.1 Respiratory protection:
- Wear gas mask with filter type A if conc. in air > exposure limit
8.2.1.2 Hand protection:
- Gloves
Suitable materials: GIVE GOOD RESISTANCE:
Nitrile rubber
8.2.1.3 Eye protection:
- Face shield
8.2.1.4 Skin protection:
- Protective clothing
Suitable materials: GIVE GOOD RESISTANCE:
Nitrile rubber
8.2.2 Environmental exposure controls: see heading 13
Printing date : 02-2008 3/9
Soudafix VE280-SF, B component
9. Physical and chemical properties
9.1 General information:
Appearance (at 20癈) : Paste
Odour : Characteristic
Colour : Black
9.2 Important health, safety and environmental information:
pH value : N.D.
癈
Boiling point/boiling range : N.D.
癈
Flashpoint : > 60
vol%
Explosion limits : N.D.
hPa
Vapour pressure (at 20癈) : N.D.
hPa
Vapour pressure (at 50癈) : N.D.
Relative density (at 20癈) : N.D.
Water solubility : Insoluble
Soluble in : No data available
Relative vapour density : N.D.
Pa.s
Viscosity : N.D.
Partition coefficient n-octanol/water : N.D.
Evaporation rate
ratio to butyl acetate : N.D.
ratio to ether : N.D.
9.3 Other information:
癈
Melting point/melting range : N.D.
癈 3
Auto-ignition point : N.D.
g/m
Saturation concentration : N.D.
10. Stability and reactivity
10.1 Conditions to avoid:
- Stable under normal conditions
10.2 Materials to avoid:
- Keep away from: heat sources, ignition sources
-
10.3 Hazardous decomposition products:
- On heating: oxidation resulting in increased fire or explosion risk
- Upon combustion CO and CO2 are formed
- Violent to explosive reaction with many compounds e.g.: with combustible
materials, (some) metals, (some) acids/bases and with (strong) reducers
Printing date : 02-2008 4/9
Soudafix VE280-SF, B component
11. Toxicological information
11.1 Acute toxicity:
DIBENZOYL PEROXIDE:
LD50 oral rat mg/kg
: 7710
LD50 dermal rat mg/kg
: N.D.
LD50 dermal rabbit mg/kg
: N.D.
LC50 inhalation rat mg/l/4 h
: N.D.
LC50 inhalation rat ppm/4 h
: N.D.
11.2 Chronic toxicity:
DIBENZOYL PEROXIDE:
EC carc. cat. : not listed
EC muta. cat. : not listed
EC repr. cat. : not listed
Carcinogenicity (TLV) : A4
Carcinogenicity (MAC) : not listed
Carcinogenicity (VME) : not listed
Carcinogenicity (GWBB) : not listed
Carcinogenicity (MAK) : not listed
Mutagenicity (MAK) : not listed
Teratogenicity (MAK) : not listed
IARC classification :3
11.3 Routes of exposure: ingestion, inhalation, eyes and skin
11.4 Acute effects/symptoms:
AFTER SKIN CONTACT:
- Tingling/irritation of the skin
11.5 Chronic effects:
- May cause sensitization by skin contact
- Not listed in carcinogenicity class (IARC,EC,TLV,MAK)
- Not listed in mutagenicity class (EC,MAK)
- Not listed in teratogenicity class (EC,MAK)
- Not classified as toxic to reproduction (EC)
ON CONTINUOUS/REPEATED EXPOSURE/CONTACT:
- Skin rash/inflammation
Printing date : 02-2008 5/9
Soudafix VE280-SF, B component
12. Ecological information
12.1 Ecotoxicity:
DIBENZOYL PEROXIDE:
- LC50 (96 h) : 2 mg/l (POECILIA RETICULATA)
12.2 Mobility:
- Volatile organic compounds (VOC): 0%
- Insoluble in water
For other physicochemical properties see heading 9
12.3 Persistence and degradability:
- biodegradation BOD5 : % ThOD
N.D.
- water : No data available
- soil : T ? days
N.D.
12.4 Bioaccumulative potential:
- log Pow : N.D.
- BCF : N.D.
12.5 Other adverse effects:
- WGK :1 (Classification based on the components in compliance
with Verwaltungsvorschrift wassergef鋒rdender Stoffe
(VwVwS) of 17 May 1999)
- Effect on the ozone layer : Not dangerous for the ozone layer
(1999/45/EC)
- Greenhouse effect : no data available
- Effect on waste water purification : no data available
13. Disposal considerations
13.1 Provisions relating to waste:
- Waste material code (91/689/EEC, Council Decision 2001/118/EC, O.J. L47 of
16/2/2001): 16 05 08* (discarded organic chemicals consisting of or
containing dangerous substances) 16 09 03* (peroxides, for example hydrogen
peroxide)
- Hazardous waste (91/689/EEC)
13.2 Disposal methods:
- Incinerate under surveillance
13.3 Packaging/Container:
- Waste material code packaging (91/689/EEC, Council Decision 2001/118/EC,
O.J. L47 of 16/2/2001): 15 01 10* (packaging containing residues of or
contaminated by dangerous substances)
Printing date : 02-2008 6/9
Soudafix VE280-SF, B component
14. Transport information
14.1 Classification of the substance in compliance with UN Recommendations
UN number : 3108
CLASS : 5.2
SUB RISKS :-
PACKING :-
PROPER SHIPPING NAME :
UN 3108, Organic peroxide type E, solid
14.2 ADR (transport by road)
CLASS : 5.2
PACKING :
CLASSIFICATION CODE : P1
DANGER LABEL TANKS : -
DANGER LABEL PACKAGES : 5.2
14.3 RID (transport by rail)
CLASS : 5.2
PACKING :
CLASSIFICATION CODE : P1
DANGER LABEL TANKS : -
DANGER LABEL PACKAGES : 5.2
14.4 ADNR (transport by inland waterways)
CLASS : 5.2
PACKING :
CLASSIFICATION CODE : P1
DANGER LABEL TANKS : -
DANGER LABEL PACKAGES : 5.2
14.5 IMDG (maritime transport)
CLASS : 5.2
SUB RISKS : -
PACKING : -
MFAG : -
EMS : F-J, S-R
MARINE POLLUTANT : -
14.6 ICAO (air transport)
CLASS : 5.2
SUB RISKS : -
PACKING : -
PACKING INSTRUCTIONS PASSENGER AIRCRAFT : 510
PACKING INSTRUCTIONS CARGO AIRCRAFT : 513
14.7 Special precautions in connection with : Rail and road transport: not
transport allowed in tanks
14.8 Limited quantities (LQ) :
When substances and their packaging meet the conditions established by
ADR/RID/ADNR in chapter 3.4, only the following prescriptions shall be
complied with:
each package shall display a diamond-shaped figure with the following
inscription:
- `UN 3108'
or, in the case of different goods with different identification numbers
within a single package:
- the letters 'LQ'
Printing date : 02-2008 7/9
Soudafix VE280-SF, B component
15. Regulatory information
15.1 EU legislation:
Classification according to directives 67/548/EEC and 1999/45/EC
Oxidising Irritant
contains : dibenzoyl peroxide
R07 : May cause fire
R38 : Irritating to skin
R43 : May cause sensitisation by skin contact
S(02) : (Keep out of reach of children)
S03/07 : Keep container tightly closed in a cool place
S14 : Keep away from reducing agents/(strong) acids/(strong)
bases/metals
S35 : This material and its container must be disposed of in
a safe way
S36/37/39 : Wear suitable protective clothing gloves, and eye/face
protection
S(46) : (If swallowed, seek medical advice immediately and show
this container or label)
S50 : Do not mix with peroxidation accelerator
15.2 National provisions:
The Netherlands:
Waterbezwaarlijkheid: 9
Germany:
WGK :1 (Classification based on the components in compliance
with Verwaltungsvorschrift wassergef鋒rdender Stoffe
(VwVwS) of 17 May 1999)
Printing date : 02-2008 8/9
Soudafix VE280-SF, B component
16. Other information
The information provided on this MSDS is correct to the best of our knowledge, information and belief
at the date of its publication. The information given is designed only as a guidance for safe
handling, use, processing, storage, transportation, disposal and release and is not to be considered
as a warranty or quality specification. The information relates only to the specific material
designated and may not be valid for such material used in combination with any other material or in
any process, unless specified in the text.
= NOT APPLICABLE
N.A.
= NOT DETERMINED
N.D.
= INTERNAL CLASSIFICATION (NFPA)
(*)
Exposure limits:
: Threshold Limit Value - ACGIH USA
TLV
: Workplace Exposure Limits - United Kingdom
WEL
: Maximale Arbeitsplatzkonzentrationen - Germany
MAK
: Maximale aanvaarde concentratie - The Netherlands
MAC
: Valeurs limites de Moyenne d'Exposition - France
VME
: Valeurs limites d'Exposition ?court terme - France
VLE
GWBB : Grenswaarde beroepsmatige blootstelling - Belgium
: Grenswaarde kortstondige blootstelling - Belgium
GWK
: Indicative occupational exposure limit values - directive 2000/39/EC
EC
Inhalable fraction = T: Total dust = E: Einatembarer Aerosolanteil
I :
Respirable fraction = A: Alveoleng鋘giger Aerosolanteil/Alveolar dust
R :
Ceiling limit
C :
aerosol rook/Rauch (fume)
a: r:
damp (vapour) stof/Staub (dust)
d: st:
dust vezel (fibre)
du: ve:
Faser (fibre) vapour
fa: va:
fibre oil mist
fi: om:
fume olienevel/謑nebel (oil mist)
fu: on:
poussi鑢e (dust) particles
p: part:
Chronic toxicity:
: List of the carcinogenic substances and processes - The Netherlands
K
Full text of any R-phrases referred to under heading 2:
R02 : Risk of explosion by shock, friction, fire or other sources of ignition
R36 : Irritating to eyes
R38 : Irritating to skin
R43 : May cause sensitisation by skin contact
51/53 : Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment
53 : May cause long-term adverse effects in the aquatic environment
Printing date : 02-2008 9/9
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