SPANGAS PROPYLENE IN AIR (35% LEL)
Revision: 02/12/2009
SAFETY DATA SHEET
1 Identification of the substance or preparation and of the company/undertaking
Product Name: SPANGAS PROPYLENE IN AIR (35% LEL)
589077 4. 0. 0
Datasheet Number:
Use of the substance/preparation: Span gas
Product Part Number: 589077 (SG 10)
Name of Supplier: Wilhelmsen Ships Service AS
Address of Supplier: Willem Barentszstraat 50
3165AB
Rotterdam
The Neherlands
Telephone: +31 10 4877 777
Fax: +31 10 4877 888
Responsible Person: Patrick Rijsdijk, Product HSE Manager,Tel.:+31 6 349 440 35
Email: Patrick.Rijsdijk@Wilhelmsen.com
Name of Manufacturer: Wilhelmsen Ships Service AS
Address of Manufacturer: Strandveien 20
P.O. Box 33
NO-1324 LYSAKER
Norway
Telephone: +47 67 584550
Emergency Telephone: **ONLY TO BE USED IN CASE OF AN INCIDENT**
NCEC: +44 1865 407333, CHEMTREC (800) 424 9300
American Chemistry Council +1 703 527 3887,
Greece +30 210 7793777
2 Hazards identification
- Odour: Odourless
- Appearance: Compressed gas
- Contact with eyes: May cause irritation
- Contact with skin: In cases of severe exposure, irritation may develop
- Inhalation: In cases of severe exposure, headache may develop
- Ingestion: Not regarded as a potential route of exposure.
3 Composition/information on ingredients
Chemical Name Concentration CAS Number EC Number R Phrases* Symbols
Air 99.3 132259-10-0 - - -
Propylene 0.7 115-07-1 204-062-1 12 F+
*See Section 16
4 First aid measures
Contact with skin
- No special precautions are required for this product
Contact with eyes
- No special precautions are required for this product
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SPANGAS PROPYLENE IN AIR (35% LEL)
Revision: 02/12/2009
4 First aid measures (....)
Ingestion
- Not regarded as a potential route of exposure.
Inhalation
- Remove patient to fresh air
- When in doubt or symptoms persist, seek medical attention
General
- In case of accident or if you feel unwell, seek medical advice immediately (show the label where
possible) (S45)
Notes to Physicians
Do not give andrenalin or equivalent medicines.
5 Fire-fighting measures
- Auto-ignition point # deg C at 760 mm Hg
- Not flammable
- Portable containers should be moved if possible and without risk
- Keep container(s) exposed to fire cool, by spraying with water
- Inform Fire Brigade of potential danger of exploding and rocketing cylinders
6 Accidental release measures
Personal Precautions
- Shut off source of leak if safe to do so
Environmental Precautions
- No special precautions are required for this product
Clean Up Actions
- Shut off source of leak if safe to do so
- Allow product to evaporate
- Ventilate area
7 Handling and storage
Handling
- Restricted to professional users
- Ensure adequate ventilation
Storage
- Keep in a cool, dry, well ventilated place
- Pressurised container: protect from sunlight and do not expose to temperatures exceeding 50
deg C
8 Exposure controls and personal protection
Exposure Limits
- TLV (TWA) 500 ppm, 900 mg/m3 (Propylene)
Exposure controls
- No special requirements
Occupational exposure controls
- Wear safety boots when handling cylinders.
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SPANGAS PROPYLENE IN AIR (35% LEL)
Revision: 02/12/2009
8 Exposure controls and personal protection (....)
Boots Gloves
9 Physical and chemical properties
- Odour: Odourless
- Appearance: Compressed gas
- pH - not applicable
- Vapour pressure - not known
- Vapour density (air = 1) 1.01
- Insoluble in water
- Density # kg/m3 at 20 癈
- Not flammable
- Auto-ignition point # deg C at 760 mm Hg
10 Stability and reactivity
- This article is considered stable under normal conditions
- Avoid overheating
11 Toxicological information
Toxicological information
- Non-toxic
Inhalation
- In cases of severe exposure, headache may develop
Contact with skin
- Not hazardous
Contact with eyes
- Not hazardous
Ingestion
- Not regarded as a potential route of exposure.
Carcinogenicity
- No evidence of carcinogenic effects
12 Ecological information
Ecotoxicity
- On available data, substance is not harmful to aquatic life
Mobility
- This substance is volatile
- Insoluble in water
Other Adverse Effects
- Presents no hazard to the environment
13 Disposal considerations
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SPANGAS PROPYLENE IN AIR (35% LEL)
Revision: 02/12/2009
13 Disposal considerations (....)
Disposal considerations
- Uncontaminated material may be returnable. Contact supplier
- Disposal should be in accordance with local, state or national legislation
- No special precautions are required for this product
14 Transport information
Non-Flammable Compressed Gas
Proper Shipping Name:
Emergency Action Code
UN
Road/Rail (ADR/RID)
Proper Shipping Name: COMPRESSED GAS, N.O.S. (PROPYLENE IN AIR, 35% of LEL)
ADR UN No.: 1956 ADR Hazard Class: 2
ADR Packing Group: ADR subrisk:
ADR-RID Labels: ADR Flashpoint:
Sea (IMDG)
Proper Shipping Name: COMPRESSED GAS, N.O.S. (PROPYLENE IN AIR, 35% of LEL)
IMDG UN No.: 1956 IMDG Hazard Class.: 2.2
IMDG Pack Group.: N/A IMDG EmS: F-C, S-V
IMDG subrisk: N/A IMDG Labels: 2.2
IMDG Flashpoint: N/A
Air (ICAO/IATA)
Proper Shipping Name: COMPRESSED GAS, N.O.S. (PROPYLENE IN AIR, 35% of LEL)
ICAO Un No.: 1956 ICAO Hazard Class.: 2.2
ICAO Packing Group.: N/A ICAO subrisk: N/A
ICAO Labels: 2.2 ICAO Flashpoint: N/A
DOT / CFR (US Department of Transportation)
DOT Proper Shipping Name: COMPRESSED GAS, N.O.S. (PROPYLENE IN AIR, 35% of LEL)
Hazardous Material: Propane Hazard Class: 2.2
Identification Number: UN1956 Product RQ (lbs): N/A
DOT subrisk: N/A DOT Labels: 2.2
DOT Flashpoint: N/A
Transport information
- Gas cylinders must be equipped with valve protection caps during transport.
15 Regulatory information
Risk Phrases
- Not applicable
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SPANGAS PROPYLENE IN AIR (35% LEL)
Revision: 02/12/2009
15 Regulatory information (....)
Safety Phrases
- Not applicable
16 Other information
Text of R and S phrase codes used in this safety data sheet:- R12: Extremely Flammable.
The information provided about the product on this Safety Data Sheet has been compiled from
knowledge of the individual constituents
The data given here is based on current knowledge and experience. This Safety Data Sheet describes
the product in terms of safety requirements and does not signify any warranty with regard to the
product's properties
The data given here only applies when product used for proper application(s). The product is not sold as
suitable for other applications - usage in such may cause risks not mentioned in this sheet. Do not use for
other application(s) without seeking advice from manufacturer
This Safety Data Sheet is provided in compliance with The Dangerous Substances Directive
(67/548/EEC)
This Safety Data Sheet is provided in compliance with The Dangerous Preparations Directive
(88/379/EEC)
This Safety Data Sheet is provided in compliance with The Safety Data Sheets Directive (2001/58EC)
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