Material Safety Data Sheet
0103MAR019
MSDS ID NO.:
09/11/2008
Revision date:
1. CHEMICAL PRODUCT AND COMPANY INFORMATION
Marathon Polymer Grade Propylene
Product name:
Polymer Grade Propylene
Synonym:
Olefinic Hydrocarbon
Chemical Family:
CH3CHCH2
Formula:
Formula:
Manufacturer:
Marathon Petroleum Company LLC
539 South Main Street
Findlay OH 45840
419-421-3070
Other information:
877-627-5463
Emergency telephone number:
2. COMPOSITION/INFORMATION ON INGREDIENTS
Propylene is an olefinic petroleum hydrocarbon.
Product information:
Name CAS Number Weight % ACGIH Exposure OSHA - Vacated Other:
Limits: PELs - Time
Weighted Ave
Marathon Polymer Grade Propylene 115-07-1 100 = 500 ppm TWA ACGIH Simple
asphyxiant
Component Information:
Name CAS Number Weight % ACGIH Exposure OSHA - Vacated Other:
Limits: PELs - Time
Weighted Ave
Propylene 115-07-1 99.5-100 = 500 ppm TWA
Propane 74-98-6 0-0.5 = 1000 ppm TWA = 1000 ppm TWA
Aliphatic Hydrocarbon = 1800 mg/m3 TWA
Gas [Alkane C1-C4]
The manufacturer has voluntarily elected to reflect exposure limits contained in
Notes:
OSHA's 1989 air contaminants standard in its MSDS's, even though certain of those
exposure limits were vacated in 1992.
MSDS ID NO.: 0103MAR019 Product name: Marathon Polymer Grade Page 1 of 8
Propylene
3. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
PROPYLENE IS A COLORLESS GAS OR LIQUID WITH A SLIGHT HYDROCARBON ODOR. IT IS SHIPPED OR
TRANSPORTED AS A LIQUIFIED GAS UNDER PRESSURE. THIS PRODUCT IS EXTREMELY FLAMMABLE AND
EXPLOSIVE. AT HIGH CONCENTRATIONS THIS PRODUCT ACTS AS A SIMPLE ASPHYXIANT, WHICH
DISPLACES OXYGEN FROM THE BREATHNG ATMOSPHERE. MAY CAUSE SKIN AND EYE BURNS UPON LIQUID
CONTACT. LARGE RELEASES CAN CREATE A FLAMMABLE VAPOR CLOUD.
OSHA WARNING LABEL:
DANGER!
EXTREMELY FLAMMABLE.
LIQUID AND GAS UNDER PRESSURE.
LIQUID CAN CAUSE FROST BURNS.
CONSUMER WARNING LABEL:
A CONSUMER WARNING LABEL IS NOT APPLICABLE FOR THIS PRODUCT.
Product is an anesthetic at high concentrations, producing dizziness, headache,
Inhalation:
incoordination and narcosis; extremely high concentrations can cause asphyxiation
and death by displacement of oxygen from the breathing atmosphere.
Ingestion not likely.
Ingestion:
Vapor is generally non-irritating to skin. Direct contact with liquified product can
Skin contact:
cause "cold burn" or frostbite.
Vapor is generally non-irritating to eyes. Direct contact with liquified product can
Eye contact:
cause "cold burn" or frostbite.
Carcinogenic Evaluation:
Product information:
Name IARC NTP ACGIH - OSHA - Select
Carcinogens: Carcinogens: Carcinogens: Carcinogens:
Marathon Polymer Grade Propylene NE Listed A4 - Not Classifiable as a
115-07-1 Human Carcinogen
The International Agency for Research on Cancer (IARC) has concluded that
Notes:
propylene is not classifiable as to its carcinogenicity to humans (Group 3).
Component Information:
Name IARC NTP ACGIH - OSHA - Select
Carcinogens: Carcinogens: Carcinogens: Carcinogens:
Propylene Listed A4 - Not Classifiable as a
115-07-1 Human Carcinogen
4. FIRST AID MEASURES
If affected, move person to fresh air. If breathing is difficult, administer oxygen. If not
Inhalation:
breathing or if no heartbeat, give artificial respiration or cardiopulmonary
resuscitation (CPR). Immediately call a physician.
MSDS ID NO.: 0103MAR019 Product name: Marathon Polymer Grade Page 2 of 8
Propylene
If liquified product has caused a "frost burn", remove contaminated clothing. Thaw
Skin contact:
frostbitten areas slowly with lukewarm water or by wrapping affected areas with
blankets. Do not rub affected areas. Let circulation reestablish itself naturally,
exercising area if possible. Call a physician.
Ingestion not likely. If swallowed, immediately call a physician.
Ingestion:
Flush with large amounts of tepid water for at least 15 minutes. Immediately consult a
Eye contact:
physician if frostbite is suspected (cloudy lens or greyish white tissue around the
eye).
Gas: Call a physician if symptoms or irritation occur.
Inhalation of high vapor concentrations of components of this product in animals has
Medical conditions aggravated
produced cardiac sensitization. Such sensitization may cause changes in heart
by exposure:
rhythms. This latter effect was shown to be enhanced by oxygen deficiency or the
injection of adrenalin-like agents.
5. FIRE FIGHTING MEASURES
For small fires, Class B fire extinguishing media such as
Suitable extinguishing media:
CO2 or dry chemical can be used. For large fires use water
spray or fog. Fire fighting should be attempted only by those
who are adequately trained and equipped with proper
protective equipment.
This product has been determined to be a flammable
Specific hazards:
gas/liquid per the OSHA Hazard Communication Standard,
and should be handled accordingly. For additional fire
related information see NFPA 30 or North American
Emergency Response Guide 115.
Bleve`s (boiling liquid expanding vapor explosions) can
Special protective equipment for firefighters:
occur when a liquid in a pressurized container in close
proximity to a fire reaches a temperature well above its
boiling point. Its effect could lead to a catastrophic failure of
the vessel resulting in flying equipment fragments, a shock
wave and a fireball causing serious damage and death.
Isolate hazard area. If safe to do so, stop the flow of gas
and allow fire to burn out. Extinguishing the flame before
shutting off the supply can cause the formation of explosive
mixtures. In some cases it may be preferred to allow the
flame to continue to burn. Use extreme caution when fighting
liquefied petroleum gas fires. Keep surrounding area cool
with water spray from a distance and prevent further ignition
of combustible material. Avoid use of solid water streams.
Contact with water and liquified product can cause increased
vaporization.
-162 F
Flash point:
927 F
Autoignition temperature:
2.0
Flammable limits in air - lower (%):
11.0
Flammable limits in air - upper (%):
NFPA rating:
Health: 1
Flammability: 4
Instability: 0
Other: -
MSDS ID NO.: 0103MAR019 Product name: Marathon Polymer Grade Page 3 of 8
Propylene
6. ACCIDENTAL RELEASE MEASURES
Keep public away. Isolate and evacuate area. Shut off source if safe to do so.
Personal precautions:
Leaking containers should be moved outdoors or to well-ventilated area and contents
transferred to a suitable container. Product vapor is heavier than air and can collect
in low areas that are without sufficient ventilation. Advise authorities and National
Response Center (800-424-8802) if the product has entered a water course or
sewer. Notify local health and pollution control agencies, if appropriate.
7. HANDLING AND STORAGE
Handling:
Product is stored as a liquid but used in the gaseous state. Comply with all applicable EPA, OSHA, NFPA and consistent
state and local requirements. Use appropriate grounding and bonding practices. Store in properly closed containers that
are appropriately labeled and in a cool well-ventilated area. Do not expose to heat, open flames, strong oxidizers or other
sources of ignition. Avoid overpressurizing or overfilling cylinders. Do not cut, drill, grind or weld on empty containers
since they may contain explosive residues.
Avoid repeated and prolonged skin contact. Exercise good personal hygiene including removal of soiled clothing and
prompt washing with soap and water.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
PERSONAL PROTECTIVE EQUIPMENT
Local or general exhaust required in an enclosed area or when there is inadequate
Engineering measures:
ventilation.
Use atmosphere supplying respirators in the event of oxygen deficiency, when
Respiratory protection:
material produces vapors that exceed permissible limits or when excessive vapors
are generated. Observe respirator assigned protection factors (APFs) criteria cited in
federal OSHA 1910.134. Self-contained breathing apparatus should be used for fire
fighting.
Wear insulated gloves to prevent skin contact and frostbite.
Skin and body protection:
Use goggles or face-shield if there is a potential for splashing.
Eye protection:
Use mechanical ventilation equipment that is explosion-proof.
Hygiene measures:
9. PHYSICAL AND CHEMICAL PROPERTIES:
Colorless Liquified Gas
Appearance:
Liquid
Physical state (Solid/Liquid/Gas):
Pure
Substance type (Pure/Mixture):
Colorless
Color:
Slight Hydrocarbon
Odor:
42
Molecular weight:
Neutral
pH:
-54 F
Boiling point/range (5-95%):
-301 F
Melting point/range:
Not applicable.
Decomposition temperature:
.52 Liquido
Specific gravity:
4.35 lbs/gal @ 32 F
Density:
No data available.
Bulk density:
1.48
Vapor density:
MSDS ID NO.: 0103MAR019 Product name: Marathon Polymer Grade Page 4 of 8
Propylene
9. PHYSICAL AND CHEMICAL PROPERTIES:
7600 mm Hg @ 68 F
Vapor pressure:
No data available.
Evaporation rate:
Appreciable 44%
Solubility:
No data available.
Solubility in other solvents:
No data available.
Partition coefficient (n-octanol/water):
No data available.
VOC content(%):
No data available.
Viscosity:
10. STABILITY AND REACTIVITY
The material is stable at 70 F, 760 mm pressure.
Stability:
Does not polymerize except under special conditions
Polymerization:
(extreme temperatures, pressure, oxidizers).
Carbon monoxide
Hazardous decomposition products:
Strong oxidizers such as nitrates, perchlorates, chlorine,
Materials to avoid:
fluorine.
Sources of heat or ignition.
Conditions to avoid:
11. TOXICOLOGICAL INFORMATION
Acute toxicity:
Product information:
Name CAS Number Inhalation: Dermal: Oral:
Marathon Polymer Grade Propylene 115-07-1 LC50>400,000 ppm No data available No data available
Hrs [Rats]
Propylene was not carcinogenic in mice and rats exposed in a two-year inhalation study at concentrations of 5,000 and
10,000 ppm. Noncancerous changes (epithelial hyperplasia/metaplasia) in the nasal cavity were observed in rats but not
mice at the dose levels tested.
At extremely high concentrations and excessive exposure conditions components of this product may produce cardiac
sensitization.
12. ECOLOGICAL INFORMATION
Liquid product is not toxic to aquatic life or waterfowl. This product does not
Ecotoxicity effects:
concentrate or accumulate in the food chain.
13. DISPOSAL CONSIDERATIONS
MSDS ID NO.: 0103MAR019 Product name: Marathon Polymer Grade Page 5 of 8
Propylene
13. DISPOSAL CONSIDERATIONS
This product as produced is not specifically listed as an EPA
Cleanup Considerations:
RCRA hazardous waste according to federal regulations (40
CFR 261). However, when discarded or disposed of, it may
meet the criteria of an "characteristic" hazardous waste. This
material could become a hazardous waste if mixed or
contaminated with a hazardous waste or other substance(s).
It is the responsibility of the user to determine if disposal
material is hazardous according to federal, state and local
regulations.
Bleeding off small amounts of this product into the
atmosphere or controlled incineration of large amounts are
potential disposal methods provided all regulatory
requirements are met.
14. TRANSPORT INFORMATION
49 CFR 172.101:
DOT:
This material when transported via US commerce would be regulated by DOT
Transport Information:
Regulations.
Propylene
Proper shipping name:
UN 1077
UN/Identification No:
2.1
Hazard Class:
Not applicable.
Packing group:
Not applicable.
DOT reportable quantity (lbs):
TDG (Canada):
Propylene
Proper shipping name:
UN 1077
UN/Identification No:
2.1
Hazard Class:
Not applicable.
Packing group:
Not applicable.
Regulated substances:
15. REGULATORY INFORMATION
US Federal Regulatory
Information:
US TSCA Chemical Inventory Section 8(b): This product and/or its components are listed on the TSCA
Chemical Inventory.
OSHA Hazard Communication Standard: This product has been evaluated and determined to be
hazardous as defined in OSHA's Hazard Communication
Standard.
EPA Superfund Amendment & Reauthorization Act (SARA):
This product contains the following component(s) that have been listed on EPA's
SARA Section 302:
Extremely Hazardous Substance (EHS) List:
Name CERCLA/SARA - Section 302 Extremely Hazardous Substances and TPQs
Propylene NA
Propane NA
MSDS ID NO.: 0103MAR019 Product name: Marathon Polymer Grade Page 6 of 8
Propylene
This product contains the following component(s) identified either as an EHS or a
SARA Section 304:
CERCLA Hazardous substance which in case of a spill or release may be subject to
SARA reporting requirements:
Name CERCLA/SARA - Hazardous Substances and their Reportable Quantities
Propylene NA
Propane NA
The following EPA hazard categories apply to this product:
SARA Section 311/312:
Acute Health Hazard
Fire Hazard
Sudden Release Of Pressure
This product contains the following component(s) that may be subject to reporting on
SARA Section 313:
the Toxic Release Inventory (TRI) From R:
Name CERCLA/SARA 313 Emission reporting:
Propylene = 1.0 % de minimis concentration
Propane None
State and Community Right-To-Know Regulations:
The following component(s) of this material are identified on the regulatory lists below:
Propylene
Louisiana Right-To-Know: Not Listed
California Proposition 65: Not Listed
New Jersey Right-To-Know: Listed
Pennsylvania Right-To-Know: Listed
Massachusetts Right-To Know: Listed
Florida substance List: Not Listed.
Rhode Island Right-To-Know: Listed
Michigan critical materials register list: Not Listed.
Massachusetts Extraordinarily Hazardous Not Listed
Substances:
California - Regulated Carcinogens: Not Listed
Pennsylvania RTK - Special Hazardous Not Listed
Substances:
New Jersey - Special Hazardous Substances: Listed
New Jersey - Environmental Hazardous Listed
Substances List:
Illinois - Toxic Air Contaminants Not Listed
New York - Reporting of Releases Part 597 - Not Listed
List of Hazardous Substances:
Propane
Louisiana Right-To-Know: Not Listed
California Proposition 65: Not Listed
New Jersey Right-To-Know: Listed
Pennsylvania Right-To-Know: Listed
Massachusetts Right-To Know: Listed
Florida substance List: Not Listed.
Rhode Island Right-To-Know: Listed
Michigan critical materials register list: Not Listed.
Massachusetts Extraordinarily Hazardous Not Listed
Substances:
California - Regulated Carcinogens: Not Listed
MSDS ID NO.: 0103MAR019 Product name: Marathon Polymer Grade Page 7 of 8
Propylene
Propylene
Pennsylvania RTK - Special Hazardous Not Listed
Substances:
New Jersey - Special Hazardous Substances: Listed
New Jersey - Environmental Hazardous Listed
Substances List:
Illinois - Toxic Air Contaminants Not Listed
New York - Reporting of Releases Part 597 - Not Listed
List of Hazardous Substances:
Canadian Regulatory Information:
Canada DSL/NDSL Inventory: This product and/or its components are listed either on the Domestic Substances List
(DSL) or are exempt.
Name Canada - WHMIS: Classifications of Substances: Canada - WHMIS: Ingredient Disclosure:
Propylene A, B1, D2B
Propane A, B1
16. OTHER INFORMATION
No data available.
Additional Information:
Craig M. Parker Manager, Toxicology and Product Safety
Prepared by:
The information and recommendations contained herein are based upon tests believed to be reliable. However,
Marathon Petroleum Company LLC (MPC) does not guarantee their accuracy or completeness nor shall any of this
information constitute a warranty, whether expressed or implied, as to the safety of the goods, the merchantability of the
goods, or the fitness of the goods for a particular purpose. Adjustment to conform to actual conditions of usage maybe
required. MPC assumes no responsibility for results obtained or for incidental or consequential damages, including lost
profits arising from the use of these data. No warranty against infringement of any patent, copyright or trademark is made
or implied.
End of Safety Data Sheet
MSDS ID NO.: 0103MAR019 Product name: Marathon Polymer Grade Page 8 of 8
Propylene
|