Solvent Blend 19334
Material Safety Data Sheet
CITGO Petroleum Corporation
19334
MSDS No.
1701 Golf Road, Suite 1-1101 Hazard Rankings
Rolling Meadows, IL 60008-4295 Revision Date 8/2/2005
HMIS NFPA
IMPORTANT: Read this MSDS before handling or disposing of this product and pass this 1 1
Health Hazard *
information on to employees, customers and users of this product.
Fire Hazard 3 3
Emergency Overview 0
Reactivity 0
Physical State Liquid.
* = Chronic Health Hazard
Transparent, Characteristic hydrocarbon
Color Odor
colorless. solvent odor.
WARNING: Protective Equipment
Flammable liquid; vapor may cause flash fire.
Minimum Recommended
Harmful or fatal if swallowed - can enter lungs and cause See Section 8 for Details
damage.
Can cause eye, skin or respiratory tract irritation.
Overexposure can cause central nervous system (CNS)
depression and/or other target organ effects.
Harmful to aquatic organisms.
SECTION 1. PRODUCT IDENTIFICATION
Solvent Blend 19334 (800) 967-7601
Trade Name Technical Contact
(8am - 4pm CT M-F)
Product Number Medical Emergency
19334 (832) 486-4700
Mixture. (800) 424-9300
CAS Number CHEMTREC Emergency
(United States Only)
Petroleum hydrocarbon solvent
Product Family
Petroleum hydrocarbon solvent;
Synonyms
CITGO?Material Code No.: 19334
Former product code(s): 2334
SECTION 2. COMPOSITION
This product may be composed, in whole or in part, of any of the following refinery streams:
Heavy hydrodesulfurized naphtha (petroleum) [CAS No.: 64742-82-1]
Petroleum hydrocarbon distillates [CAS No.: 8052-41-3]
Light aliphatic solvent naphtha (petroleum) [CAS No.: 64742-89-8]
This product contains the following chemicals as components of the refinery streams listed above:
Concentration (%)
Component Name(s) CAS Registry No.
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Solvent Blend 19334
Nonane, all isomers Mixture 5 - 20
Heptane, all isomers 142-82-5 1 - 15
Ethylmethylbenzene, all isomers 25550-14-5 <10
Trimethylbenzenes, all isomers 25551-13-7 <10
n-Propylbenzene 103-65-1 <2
Octanes, all isomers Mixture <2
Naphthalene 91-20-3 <0.3
Ethylbenzene 100-41-4 <0.3
SECTION 3. HAZARDS IDENTIFICATION
Also see Emergency Overview and Hazard Ratings on the top of Page 1 of this MSDS.
Major Route(s) of Entry Skin contact. Inhalation.
Signs and Symptoms of Acute Exposure
Breathing high concentrations may be harmful. Mist or vapor can irritate the throat and lungs.
Inhalation
Breathing this material may cause central nervous system depression with symptoms
including nausea, headache, dizziness, fatigue, drowsiness, or unconsciousness. Breathing
high concentrations of this material, for example, in an enclosed space or by intentional
abuse, can cause irregular heartbeats which can cause death.
Eye Contact This product can cause transient mild eye irritation with short-term contact with liquid sprays
or mists. Symptoms include stinging, watering, redness, and swelling.
This material can cause skin irritation. The severity of irritation will depend on the amount of
Skin Contact
material that is applied to the skin and the speed and thoroughness that it is removed.
Symptoms include redness, itching, and burning of the skin. Repeated or prolonged skin
contact can produce moderate irritation (dermatitis).
Ingestion If swallowed, this material may irritate the mucous membranes of the mouth, throat, and
esophagus. It can be readily absorbed by the stomach and intestinal tract. Symptoms
include a burning sensation of the mouth and esophagus, nausea, vomiting, dizziness,
staggering gait, drowsiness, loss of consciousness, and delirium, as well as additional
central nervous system (CNS) effects. Due to its light viscosity, there is a danger of
aspiration into the lungs during vomiting. Aspiration can result in severe lung damage or
death.
Chronic Health Effects Chronic effects of ingestion and subsequent aspiration into the lungs may cause
Summary pneumatocele (lung cavity) formation and chronic lung dysfunction.
Reports have associated repeated and prolonged occupational overexposure to solvents with
irreversible brain and nervous system damage (sometimes referred to as "Solvent or
Painter's Syndrome"). Intentional misuse by deliberately concentrating and inhaling this
product may be harmful or fatal.
This material, or a component of this material, has been shown to cause cancer in laboratory
animals. The relevance of this to humans is not clear.
Disorders of the following organs or organ systems that may be aggravated by significant
Conditions Aggravated
exposure to this material or its components include: Skin, Respiratory System, Liver,
by Exposure
Kidneys, Central Nervous System (CNS)
Target Organs May cause damage to the following organs: kidneys, lungs, liver, mucous membranes, upper
respiratory tract, skin, central nervous system (CNS), eye, lens or cornea
Carcinogenic Potential This material may contain ethylbenzene and naphthalene at concentrations above 0.1%.
IARC has identified ethylbenzene and naphthalene as possibly carcinogenic to humans
(Group 2B) based on laboratory animal studies.
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Solvent Blend 19334
OSHA Hazard Classification is indicated by an "X" in the box adjacent to the hazard title. If no "X" is present,
the product does not exhibit the hazard as defined in the OSHA Hazard Communication Standard (29 CFR
1910.1200).
OSHA Physical Hazard Classification
OSHA Health Hazard Classification
Combustible Explosive Pyrophoric
Irritant Sensitizer
X
Highly Toxic Water-reactive
Toxic Oxidizer
X
Flammable
Corrosive Carcinogenic Compressed Gas Organic Peroxide Unstable
SECTION 4. FIRST AID MEASURES
Take proper precautions to ensure your own health and safety before attempting rescue or providing first aid.
For more specific information, refer to Exposure Controls and Personal Protection in Section 8 of this MSDS.
Immediately move victim to fresh air. If victim is not breathing, immediately begin rescue
Inhalation
breathing. If heart has stopped, immediately begin cardiopulmonary resuscitation (CPR). If
breathing is difficult, 100 percent humidified oxygen should be administered by a qualified
individual. Seek medical attention immediately.
Flush eyes with cool, clean, low-pressure water for at least 15 minutes. Hold eyelids apart to
Eye Contact
ensure complete irrigation of the eye and eyelid tissue. If easily accomplished, check for and
remove contact lenses. If contact lenses cannot be removed, seek immediate medical
attention. Do not use eye ointment. Seek medical attention.
Remove contaminated shoes and clothing. Flush affected area with large amounts of water.
Skin Contact
If skin surface is damaged, apply a clean dressing and seek medical attention. Do not use
ointments. If skin surface is not damaged, clean affected area thoroughly with mild soap and
water. Seek medical attention if tissue appears damaged or if pain or irritation persists.
Do not induce vomiting. If spontaneous vomiting is about to occur, place victim's head below
Ingestion
knees. If victim is drowsy or unconscious, place on the left side with head down. Never give
anything by mouth to a person who is not fully conscious. Do not leave victim unattended.
Seek medical attention immediately.
INHALATION: Inhalation overexposure can produce toxic effects. Monitor for respiratory
Notes to Physician
distress. If cough or difficulty in breathing develops, evaluate for upper respiratory tract
inflammation, bronchitis, and pneumonitis. Administer supplemental oxygen with assisted
ventilation, as required.
This material (or a component) sensitizes the heart to the effects of sympathomimetic amines.
Epinephrine and other sympathomimetic drugs may initiate cardiac arrhythmias in individuals
exposed to this material. Administion of sympathomimetic drugs should be avoided.
INGESTION: If ingested, this material presents a significant aspiration and chemical
pneumonitis hazard. Induction of emesis is not recommended. Consider activated charcoal
and/or gastric lavage. If patient is obtunded, protect the airway by cuffed endotracheal
intubation or by placement of the body in a Trendelenburg and left lateral decubitus position.
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Solvent Blend 19334
SECTION 5. FIRE FIGHTING MEASURES
NFPA Class-IC flammable liquid.
NFPA Flammability
Classification
Closed cup: 32癈 (90癋). (Tagliabue.)
Flash Point
Upper Flammable Limit
Lower Flammable Limit AP 0.9 % AP 7 %
Autoignition Not available.
Temperature
Hazardous Combustion Carbon dioxide, carbon monoxide, smoke, fumes, and/or unburned hydrocarbons.
Products
Special Properties Flammable Liquid! This material releases vapors at or below ambient temperatures. When
mixed with air in certain proportions and exposed to an ignition source, its vapor can cause a
flash fire. Use only with adequate ventilation. Vapors are heavier than air and may travel
long distances along the ground to an ignition source and flash back. A vapor and air
mixture can create an explosion hazard in confined spaces such as sewers. If container is
not properly cooled, it can rupture in the heat of a fire.
Extinguishing Media SMALL FIRE: Use dry chemicals, carbon dioxide, foam, or inert gas (nitrogen). Carbon
dioxide and inert gas can displace oxygen. Use caution when applying carbon dioxide or
inert gas in confined spaces.
LARGE FIRE: Use foam, water fog, or water spray. Water May Be Ineffective. Water may
not extinguish the fire. Water fog and spray are effective in cooling containers and adjacent
structures. However, water can be used to cool the external walls of vessels to prevent
excessive pressure, autoignition or explosion. DO NOT use a solid stream of water directly
on the fire as the water may spread the fire to a larger area.
Firefighters must use full bunker gear including NIOSH-approved positive pressure
Protection of Fire
self-contained breathing apparatus to protect against potential hazardous combustion or
Fighters
decomposition products and oxygen deficiencies. Evacuate area and fight the fire from a
maximum distance or use unmanned hose holders or monitor nozzles. Cover pooling liquid
with foam. Containers can build pressure if exposed to radiant heat; cool adjacent containers
with flooding quantities of water until well after the fire is out. Withdraw immediately from the
area if there is a rising sound from a venting safety device or discoloration of vessels, tanks,
or pipelines. Be aware that burning liquid will float on water. Notify appropriate authorities of
potential fire and explosion hazard if liquid enter sewers or waterways.
SECTION 6. ACCIDENTAL RELEASE MEASURES
Take proper precautions to ensure your own health and safety before attempting spill control or clean-up. For
more specific information, refer to the Emergency Overview on Page 1, Exposure Controls and Personal
Protection in Section 8 and Disposal Considerations in Section 13 of this MSDS.
Flammable Liquid! Release causes an immediate fire or explosion hazard. Evacuate all
non-essential personnel from immediate area and establish a "regulated zone" with site
control and security. A vapor-suppressing foam may be used to reduce vapors. Eliminate all
ignition sources. All equipment used when handling this material must be grounded. Stop the
leak if it can done without risk. Do not touch or walk through spilled material. Remove
spillage immediately from hard, smooth walking areas. Prevent spilled material from entering
waterways, sewers, basements, or confined areas. Absorb or cover with dry earth, sand, or
other non-combustible material and transfer to appropriate waste containers. Use clean,
non-sparking tools to collect absorbed material.
For large spills, secure the area and control access. Prevent spilled material from entering
sewers, storm drains, other drainage systems, and natural waterways. Dike far ahead of a
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Solvent Blend 19334
liquid spill to ensure complete collection. Water mist or spray may be used to reduce or
disperse vapors; but, it may not prevent ignition in closed spaces. This material will float on
water and its run-off may create an explosion or fire hazard. Verify that responders are
properly HAZWOPER-trained and wearing appropriate respiratory equipment and
fire-resistant protective clothing during cleanup operations. In an urban area, cleanup spill as
soon as possible; in natural environments, cleanup on advice from specialists. Pick up free
liquid for recycle and/or disposal if it can be accomplished safely with explosion-proof
equipment. Collect any excess material with absorbant pads, sand, or other inert
non-combustible absorbent materials. Place into appropriate waste containers for later
disposal. Comply with all applicable local, state and federal laws and regulations.
SECTION 7. HANDLING AND STORAGE
A spill or leak can cause an immediate fire or explosion hazard. Keep containers closed and
Handling
do not handle or store near heat, sparks, or any other potential ignition sources. Do not
contact with oxidizable materials. Do not breathe vapor. Use only with adequate ventilation
and personal protection. Never siphon by mouth. Avoid contact with eyes, skin, and clothing.
Prevent contact with food and tobacco products. Do not take internally.
When performing repairs and maintenance on contaminated equipment, keep unnecessary
persons away from the area. Eliminate all potential ignition sources. Drain and purge
equipment, as necessary, to remove material residues. Follow proper entry procedures,
including compliance with 29 CFR 1910.146 prior to entering confined spaces such as tanks
or pits. Use gloves constructed of impervious materials and protective clothing if direct
contact is anticipated. Provide ventilation to maintain exposure potential below applicable
exposure limits. Use appropriate respiratory protection when concentrations exceed any
established occupational exposure level (See Section 8). Promptly remove contaminated
clothing. Wash exposed skin thoroughly with soap and water after handling.
A static electrical charge can accumulate when this material is flowing through pipes, nozzles
or filters and when it is agitated. A static spark discharge can ignite accumulated vapors
particularly during dry weather conditions. Always bond receiving containers to the fill pipe
before and during loading. Always keep nozzle in contact with the container throughout the
loading process. Do not fill any portable container in or on a vehicle. Do NOT use
compressed air for filling, discharging or other handling operations.
Product container is not designed for elevated pressure. Do not pressurize, cut, weld, braze
solder, drill, or grind on containers. Do not expose product containers to flames, sparks, heat
or other potential ignition sources. Empty containers may contain product residues that can
ignite with explosive force. Observe label precautions. Consult appropriate federal, state and
local authorities before reusing, reconditioning, reclaiming, recycling or disposing of empty
containers and/or waste residues of this product.
Store and transport in accordance with all applicable laws. Keep containers tightly closed and
Storage
store in a cool, dry, well-ventilated place, plainly labeled, and out of closed vehicles. Keep
away from all ignition sources. Ground all equipment containing this material. Containers
should be able to withstand pressures expected from warming and cooling in storage. This
flammable liquid should be stored in a separate safety cabinet or room. A refrigerated room
is preferable for materials with a flash point temperature lower than 70癋 (21癈). All electrical
equipment in areas where this material is stored or handled should be installed in accordance
with applicable regulatory requirements and the National Electrical Code.
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Solvent Blend 19334
SECTION 8. EXPOSURE CONTROLS AND PERSONAL PROTECTION
Engineering Controls Provide ventilation or other engineering controls to keep the airborne concentrations of
vapor or mists below the applicable workplace exposure limits indicated below. All electrical
equipment should comply with the National Electric Code. An emergency eye wash station
and safety shower should be located near the work-station.
Personal Protective Personal protective equipment should be selected based upon the conditions under which
Equipment this material is used. A hazard assessment of the work area for PPE requirements should
be conducted by a qualified professional pursuant to OSHA regulations. The following
pictograms represent the minimum requirements for personal protective equipment. For
certain operations, additional PPE may be required.
Eye Protection Safety glasses equipped with side shields are recommended as minimum protection in
industrial settings. Chemical goggles should be worn during transfer operations or when
there is a likelihood of misting, splashing, or spraying of this material. A suitable emergency
eye wash water and safety shower should be located near the work station.
Hand Protection Avoid skin contact. Use heavy duty gloves constructed of chemical resistant materials such
as Viton?or heavy nitrile rubber. Wash hands with plenty of mild soap and water before
eating, drinking, smoking, use of toilet facilities or leaving work. DO NOT use gasoline,
kerosene, solvents or harsh abrasives as skin cleaners.
Avoid skin contact. Wear long-sleeved fire-retardant garments (e.g., Nomex? while
Body Protection
working with flammable and combustible liquids. Additional chemical-resistant protective
gear may be required if splashing or spraying conditions exist. This may include an apron,
boots and additional facial protection. If product comes in contact with clothing, immediately
remove soaked clothing and shower. Promptly remove and discarded contaminated leather
goods.
Odor is not an adequate warning for potentially hazardous air concentrations. For unknown
Respiratory Protection
vapor concentrations, use a positive-pressure, pressure-demand, self-contained breathing
apparatus (SCBA), especially when entering a confined space or area where the oxygen
concentration may be reduced because of an accumulation of gas vapors. For known vapor
concentrations above the occupational exposure guidelines (see below), use a
NIOSH-approved organic vapor respirator, if adequate protection is provided. Respirators
should be used in accordance with OSHA requirements (29 CFR 1910.134).
Warning! Use of this material in spaces without adequate ventilation may result in
General Comments
generation of hazardous levels of combustion products and/or inadequate oxygen levels for
breathing. Odor is an inadequate warning for hazardous conditions.
Occupational Exposure Guidelines
Substance Applicable Workplace Exposure Levels
Petroleum hydrocarbon distillates ACGIH TLV (United States).
TWA: 100 ppm 8 hour(s).
OSHA PEL Z2 (United States).
TWA: 500 ppm 8 hour(s).
Nonane, all isomers ACGIH (United States).
TWA: 200 ppm 8 hour(s).
Heptane, all isomers ACGIH (United States).
TWA: 400 ppm 8 hour(s).
STEL: 500 ppm 15 minute(s).
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Solvent Blend 19334
OSHA (United States).
TWA: 500 ppm 8 hour(s).
Trimethylbenzenes, all isomers ACGIH (United States).
TWA: 25 ppm 8 hour(s).
Octanes, all isomers ACGIH (United States).
TWA: 300 ppm 8 hour(s).
OSHA (United States).
TWA: 500 ppm 8 hour(s).
Naphthalene ACGIH (United States). Skin
TWA: 10 ppm 8 hour(s).
STEL: 15 ppm 15 minute(s).
OSHA (United States).
TWA: 10 ppm 8 hour(s).
Ethylbenzene ACGIH (United States).
TWA: 100 ppm 8 hour(s).
STEL: 125 ppm 15 minute(s).
OSHA (United States).
TWA: 100 ppm 8 hour(s).
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES (TYPICAL)
Characteristic hydrocarbon
Odor
Color
Liquid. Transparent,
Physical State
solvent odor.
colorless.
>1 (Air = 1)
Vapor
0.79 (Water = 1) Not applicable
Specific Gravity pH
Density
Not available.
Boiling Range 112 to 203癈 (234 to 397癋) Melting/Freezing
Point
Volatility 790 g/l VOC (w/v)
0.1 kPa (1 mm Hg) (at 20癈)
Vapor Pressure
Viscosity
Very slightly soluble in cold water. (<0.1 % Not available.
Solubility in
w/w) (cSt @ 40癈)
Water
Closed cup: 32癈 (90癋). (Tagliabue.)
Flash Point
Paraffin, Isoparaffin and Cycloparaffin Hydrocarbons Content = >85 Wt.% (ASTM D-1319);
Additional
Aromatic Hydrocarbon Content = <15 Wt. % (ASTM D-1319);
Properties
Average Density at 60癋 = 6.53 lbs./gal. (Calculated via ASTM D-287);
Aniline Cloud Point Temperature = 129 癋 (54癈) (ASTM D-611);
Kauri-Butanol (KB) Value = 38.0 (ASTM D-1133)
Dry Point Temperature = 397癋 (203癈) (ASTM D-86, D-850 or D-1078);
Evaporation Rate = <1 (n-Butyl acetate = 1.0)
SECTION 10. STABILITY AND REACTIVITY
Hazardous Polymerization Not expected to occur.
Stable.
Chemical Stability
Keep away from heat, flame and other potential ignition sources. Keep away from strong
Conditions to Avoid
oxidizing conditions and agents.
Strong acids, alkalies, and oxidizers such as liquid chlorine and oxygen.
Materials
Incompatibility
No additional hazardous decomposition products were identified other than the combustion
Hazardous
products identified in Section 5 of this MSDS.
Decomposition
Products
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Solvent Blend 19334
SECTION 11. TOXICOLOGICAL INFORMATION
For other health-related information, refer to the Emergency Overview on Page 1 and the Hazards Identification
in Section 3 of this MSDS.
Toxicity Data
Heptane, all isomers:
n-Heptane was not mutagenic in the Salmonella/microsome (Ames) assay and is not
considered to be carcinogenic.
Trimethylbenzenes, all isomers:
Studies of Workers:
Levels of total hydrocarbon vapors present in the breathing atmosphere of these workers
ranged from 10 to 60 ppm. The TCLo for humans is 10 ppm, with somnolence and
respiratory tract irritation noted.
Studies in Laboratory Animals:
In inhalation studies with rats, four of ten animals died after exposures of 2400 ppm for 24
hours. An oral dose of 5 mL/kg resulted in death in one of ten rats. Minimum lethal
intraperitoneal doses were 1.5 to 2.0 mL/kg in rats and 1.13 to 12 mL/kg in guinea pigs.
Mesitylene (1, 3, 5 Trimethylbenzene) inhalation at concentrations of 1.5, 3.0, and 6.0 mg/L
for six hours was associated with dose-related changes in white blood cell counts in rats. No
significant effects on the complete blood count were noted with six hours per day exposure
for five weeks, but elevations of alkaline phosphatase and SGOT were observed. Central
nervous system depression and ataxia were noted in rats exposed to 5,100 to 9,180 ppm for
two hours.
Naphthalene:
Studies in Humans Overexposed to Naphthalene:
Severe jaundice, neurotoxicity (kernicterus) and fatalities have been reported in young
children and infants as a result of hemolytic anemia from over-exposure to naphthalene.
Persons with Glucose 6-phosphate dehydrogenase (G6PD) deficiency are more prone to the
hemolytic effects of naphthalene. Adverse effects on the kidney have also been reported
from over-exposure to naphthalene but these effects are believed to be a consequence of
hemolytic anemia, and not a direct effect.
Studies in Laboratory Animals:
Hemolytic anemia has been observed in laboratory animals exposed to naphthalene.
Laboratory rodents exposed to naphthalene vapor for 2 years (lifetime studies) developed
non-neoplastic and neoplastic tumors and inflammatory lesions of the nasal and respiratory
tract. Cataracts and other adverse effects on the eye have been observed in laboratory
animals exposed to high levels of naphthalene. Findings from a large number of bacterial
and mammalian cell mutation assays have been negative. A few studies have shown
chromosomal effects (elevated levels of Sister Chromatid Exchange or chromosomal
aberrations) in vitro.
Ethylbenzene:
Effects from Acute Exposure:
ORAL (LD50), Acute: 3,500 mg/kg [Rat].
DERMAL (LD50), Acute: 17,800 uL/kg [Rabbit].
INTRAPERITONEAL (LD50), Acute: 2,624 mg/kg [Rat].
Effects from Prolonged or Repeated Exposure:
Findings from a 2-year inhalation study in rodents conducted by NTP were as follows: Effects
were observed only at the highest exposure level (750 ppm). At this level the incidence of
renal tumors was elevated in male rats (tubular carcinomas) and female rats (tubular
adenomas). Also, the incidence of tumors was elevated in male mice (alveolar and
bronchiolar carcinomas) and female mice (hepatocellular carcinomas). IARC has classified
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Solvent Blend 19334
ethyl benzene as "possibly carcinogenic to humans" (Group 2B). Studies in laboratory
animals indicate some evidence of post-implantation deaths following high levels of maternal
exposure. The relevance of these findings to humans is not clear at this time. Studies in
laboratory animals indicate limited evidence of renal malformations, resorptions, and
developmental delays following high levels of maternal exposure. The relevance of these
findings to humans is not clear at this time. Studies in laboratory animals indicate some
evidence of adverse effects on the liver, kidney, thyroid, and pituitary gland.
SECTION 12. ECOLOGICAL INFORMATION
This mixture contains components that are potentially toxic to freshwater and saltwater
Ecotoxicity
ecosystems.
Environmental Fate This product will normally float on water. Components will evaporate rapidly. This material
may be harmful to aquatic organisms and may cause long term adverse effects in the aquatic
environment. The octanol-water partition coefficient (log Kow) for this product is expected to
be in the range of 2.1 to 5.
SECTION 13. DISPOSAL CONSIDERATIONS
Hazard characteristic and regulatory waste stream classification can change with product use. Accordingly, it is
the responsibility of the user to determine the proper storage, transportation, treatment and/or disposal
methodologies for spent materials and residues at the time of disposition.
Maximize material recovery for reuse or recycling. Recovered non-usable material may be
regulated by US EPA as a hazardous waste due to its ignitibility (D001) and/or its toxic
(D018) characteristics. Conditions of use may cause this material to become a "hazardous
waste", as defined by federal or state regulations. It is the responsibility of the user to
determine if the material is a RCRA "hazardous waste" at the time of disposal.
Transportation, treatment, storage and disposal of waste material must be conducted in
accordance with RCRA regulations (see 40 CFR 260 through 40 CFR 271). State and/or
local regulations may be more restrictive. Contact your regional US EPA office for guidance
concerning case specfic disposal issues.
SECTION 14. TRANSPORT INFORMATION
The shipping description below may not represent requirements for all modes of transportation, shipping
methods or locations outside of the United States.
A U.S. Department of Transportation regulated material.
US DOT Status
Petroleum Distillates, n.o.s. (Naphtha Solvent), 3, UN1268 PG III
Proper Shipping Name
3 III
Hazard Class Packing Group(s)
UN 1268
UN/NA Number
Reportable Quantity A Reportable Quantity (RQ) has not been established for this material.
Placard(s) 128
Emergency Response
Guide No.
Not determined.
MARPOL III Status
FLAMMABLE LIQUID
3
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SECTION 15. REGULATORY INFORMATION
TSCA Inventory This product and/or its components are listed on the Toxic Substances Control Act (TSCA)
inventory.
The Superfund Amendments and Reauthorization Act of 1986 (SARA) Title III requires
SARA 302/304
facilities subject to Subparts 302 and 304 to submit emergency planning and notification
Emergency Planning
information based on Threshold Planning Quantities (TPQs) and Reportable Quantities
and Notification
(RQs) for "Extremely Hazardous Substances" listed in 40 CFR 302.4 and 40 CFR 355. No
components were identified.
The Superfund Amendments and Reauthorization Act of 1986 (SARA) Title III requires
SARA 311/312 Hazard
facilities subject to this subpart to submit aggregate information on chemicals by "Hazard
Identification
Category" as defined in 40 CFR 370.2. This material would be classified under the following
hazard categories:
fire, Acute (Immediate) Health Hazard, Chronic (Delayed) Health Hazard
This product contains the following components in concentrations above de minimis levels
SARA 313 Toxic
that are listed as toxic chemicals in 40 CFR Part 372 pursuant to the requirements of Section
Chemical Notification
313 of SARA:
and Release Reporting
1, 2, 4 Trimethylbenzene [CAS No.: 95-63-6] Concentration: <5%
Naphthalene [CAS No.: 91-20-3] Concentration: <0.3%
Ethylbenzene [CAS No.: 100-41-4] Concentration: <0.3%
The Comprehensive Environmental Response, Compensation, and Liability Act of 1980
CERCLA
(CERCLA) requires notification of the National Response Center concerning release of
quantities of "hazardous substances" equal to or greater than the reportable quantities (RQ's)
listed in 40 CFR 302.4. As defined by CERCLA, the term "hazardous substance" does not
include petroleum, including crude oil or any fraction thereof which is not otherwise
specifically designated in 40 CFR 302.4. Chemical substances present in this product or
refinery stream that may be subject to this statute are:
Cumene [CAS No.: 98-82-8] RQ = 5000 lbs. (2268 kg) Concentration: <1%
Xylene, all isomers [CAS No.: 1330-20-7] RQ = 100 lbs. (45.36 kg) Concentration: <0.5%
Naphthalene [CAS No.: 91-20-3] RQ = 100 lbs. (45.36 kg) Concentration: <0.3%
Clean Water Act This material is classified as an oil under Section 311 of the Clean Water Act (CWA) and the
Oil Pollution Act of 1990 (OPA). Discharges or spills which produce a visible sheen on waters
(CWA)
of the United States, their adjoining shorelines, or into conduits leading to surface waters must
be reported to the EPA's National Response Center at (800) 424-8802.
California This material may contain the following components which are known to the State of California
Proposition 65 to cause cancer, birth defects or other reproductive harm, and may be subject to the
requirements of California Proposition 65 (CA Health & Safety Code Section 25249.5):
Naphthalene: <0.3%
Ethylbenzene: <0.3%
Benzene: <0.005%
Toluene: <0.005%
New Jersey For New Jersey R-T-K labeling requirements, refer to components listed in Section 2.
Right-to-Know Label
Federal Hazardous Substances Act, related statutes, and Consumer Product Safety
Additional Regulatory
Commission regulations, as defined by 16 CFR 1500.14(b)(3) and 1500.83(a)(13): This
Remarks
product contains "Petroleum Distillates" which may require special labeling if distributed in a
manner intended or packaged in a form suitable for use in the household or by children.
Precautionary label dialogue should display the following: DANGER: Contains Petroleum
Distillates! Harmful or fatal if swallowed! Call Physician Immediately. KEEP OUT OF
REACH OF CHILDREN!
MSDS No. Revision Date
19334 Page Number: 10
8/2/2005 Continued on Next Page
Solvent Blend 19334
SECTION 16. OTHER INFORMATION
Refer to the top of Page 1 for the HMIS and NFPA Hazard Ratings for this product.
REVISION INFORMATION
2.1
Version Number
8/2/2005
Revision Date
Printed on 8/2/2005.
Print Date
ABBREVIATIONS
AP: Approximately EQ: Equal >: Greater Than <: Less Than NA: Not Applicable ND: No Data NE: Not Established
ACGIH: American Conference of Governmental Industrial Hygienists AIHA: American Industrial Hygiene Association
IARC: International Agency for Research on Cancer NTP: National Toxicology Program
OSHA: Occupational Safety and Health Administration
NIOSH: National Institute of Occupational Safety and Health
NPCA: National Paint and Coating Manufacturers Association HMIS: Hazardous Materials Information System
NFPA: National Fire Protection Association EPA: US Environmental Protection Agency
DISCLAIMER OF LIABILITY
THE INFORMATION IN THIS MSDS WAS OBTAINED FROM SOURCES WHICH WE BELIEVE ARE RELIABLE.
HOWEVER, THE INFORMATION IS PROVIDED WITHOUT ANY WARRANTY, EXPRESSED OR IMPLIED
REGARDING ITS CORRECTNESS. SOME INFORMATION PRESENTED AND CONCLUSIONS DRAWN HEREIN ARE
FROM SOURCES OTHER THAN DIRECT TEST DATA ON THE SUBSTANCE ITSELF. THIS MSDS WAS PREPARED
AND IS TO BE USED ONLY FOR THIS PRODUCT. IF THE PRODUCT IS USED AS A COMPONENT IN ANOTHER
PRODUCT, THIS MSDS INFORMATION MAY NOT BE APPLICABLE. USERS SHOULD MAKE THEIR OWN
INVESTIGATIONS TO DETERMINE THE SUITABILITY OF THE INFORMATION OR PRODUCTS FOR THEIR
PARTICULAR PURPOSE.
THE CONDITIONS OR METHODS OF HANDLING, STORAGE, USE, AND DISPOSAL OF THE PRODUCT ARE
BEYOND OUR CONTROL AND MAY BE BEYOND OUR KNOWLEDGE. FOR THIS AND OTHER REASONS, WE DO
NOT ASSUME RESPONSIBILITY AND EXPRESSLY DISCLAIM LIABILITY FOR LOSS, DAMAGE OR EXPENSE
ARISING OUT OF OR IN ANY WAY CONNECTED WITH HANDLING, STORAGE, USE OR DISPOSAL OF THE
PRODUCT.
***** END OF MSDS *****
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