Product name: DIOCTYL ADIPATE (DOA) Page 1 / 7
Solutia Inc. Material Safety Data Sheet Date: 12/03/2004
Reference Number: 000000000366 Version 5./E
Solutia Inc.
Material Safety Data Sheet
1. PRODUCT AND COMPANY IDENTIFICATION
Product name: DIOCTYL ADIPATE (DOA)
Reference Number: 000000000366 Date: 12/03/2004
Company Information:
United States: Canada:
Solutia Inc. Solutia Canada Inc.
575 Maryville Center Drive, P.O. Box 66760 6800 St. Patrick Street
St. Louis, MO 63166-6760 LaSalle, PQ H8N 2H3
Emergency telephone: Chemtrec: 1-800-424-9300 Emergency telephone: CANUTEC: 1-613-996-6666
Non-Emergency telephone: 1-314-674-6661 Non-Emergency telephone: 1-314-674-6661
Mexico: Brazil:
Solutia MEXICO, S. DE R.L. DE C.V. Solutia Brazil Ltd.
Paseo de la Reforma No. 2654 Piso 3-A Avenue Carlos Marcondes, 1200
Col. Lomas Altas CEP: 12241-420-S鉶 Jos?dos Campos/SP-Brazil
C.P. 11950 Mexico D.F. Emergency telephone: 55 12 3932 7100 (PABX)
Emergency telephone: SETIQ: (in Mexico) 01-800-002-1400 Non-Emergency telephone: 55 11 3365 1800 (PABX)
Non-Emergency telephone: (in Mexico) 01-55-5259-6800
2. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Form: oily, liquid
Colour: clear to colourless
Odour: bland
WARNING STATEMENTS
No significant hazards associated with this material
POTENTIAL HEALTH EFFECTS
Likely routes of exposure: eye and skin contact
inhalation
Eye contact: No more than slightly irritating to eyes.
Skin contact: No more than slightly irritating to skin.
Product name: DIOCTYL ADIPATE (DOA) Page 2 / 7
Solutia Inc. Material Safety Data Sheet Date: 12/03/2004
Reference Number: 000000000366 Version 5./E
No more than slightly toxic if absorbed.
Inhalation: No more than slightly irritating
No more than slightly toxic if inhaled.
Ingestion: No more than slightly toxic if swallowed.
Significant adverse health effects are not expected to develop if only small
amounts (less than a mouthful) are swallowed.
Refer to Section 11 for toxicological information.
3. COMPOSITION/INFORMATION ON INGREDIENTS
Components CAS No. Average Concentration Units
concentration range
bis(2-ethylhexyl) adipate 103-23-1 >=99.0 %
4. FIRST AID MEASURES
If in eyes: Immediate first aid is not likely to be required.
This material can be removed with water.
If on skin: Immediate first aid is not likely to be required.
This material can be removed with soap and water.
Wash heavily contaminated clothing before reuse.
If inhaled: Immediate first aid is not likely to be required.
If symptoms occur, remove to fresh air.
Remove material from eyes, skin and clothing.
If swallowed: Immediate first aid is not likely to be required.
A physician or Poison Control Center can be contacted for advice.
Wash heavily contaminated clothing before reuse.
5. FIRE FIGHTING MEASURES
Fire point: 232 C Cleveland Open Cup
Hazardous products of combustion: carbon dioxide; carbon monoxide (CO)
Extinguishing media: Water spray, foam, dry chemical, or carbon dioxide
Unusual fire and explosion hazards: None known
Fire fighting equipment: Firefighters, and others exposed, wear self-contained breathing apparatus.
Equipment should be thoroughly decontaminated after use.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions: Use personal protection recommended in section 8.
Environmental Keep out of drains and water courses.
precautions:
Product name: DIOCTYL ADIPATE (DOA) Page 3 / 7
Solutia Inc. Material Safety Data Sheet Date: 12/03/2004
Reference Number: 000000000366 Version 5./E
Methods for cleaning up: Contain large spills with dikes and transfer the material to appropriate containers for
reclamation or disposal. Absorb remaining material or small spills with an inert material
and then place in a chemical waste container.
Refer to Section 13 for disposal information and Sections 14 and 15 for reportable quantity information.
7. HANDLING AND STORAGE
Handling
Handle in accordance with good industrial hygiene and safety practices.
These practices include avoiding unnecessary exposure and removal of material from eyes, skin and clothing.
Emptied containers retain vapour and product residue. Observe all recommended safety precautions until container
is cleaned, reconditioned or destroyed. The reuse of this material's container for non industrial purposes is
prohibited and any reuse must be in consideration of the data provided in this material safety data sheet.
Storage
General: Stable under normal conditions of handling and storage.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Airborne exposure limits: (ml/m3 = ppm)
DIOCTYL ADIPATE No specific occupational exposure limit has been established.
(DOA)
Eye protection: Does not cause significant eye irritation or eye toxicity requiring special protection.
Use good industrial practice to avoid eye contact.
Hand protection: Although this product does not present a significant skin concern, minimize skin
contamination by following good industrial practice.
Wearing protective gloves is recommended.
Consult the glove/clothing manufacturer to determine the appropriate type
glove/clothing for a given application.
Body protection: Although this product does not present a significant skin concern, minimize skin
contamination by following good industrial practice.
Wash contaminated skin thoroughly after handling.
Respiratory protection: Avoid breathing vapour or mist.
Use approved respiratory protection equipment when airborne exposure is excessive.
Consult the respirator manufacturer to determine the appropriate type of equipment for
a given application.
Observe respirator use limitations specified by the manufacturer.
Ventilation: Provide natural or mechanical ventilation to minimize exposure.
If practical, use local mechanical exhaust ventilation at sources of air contamination
such as processing equipment.
Components referred to herein may be regulated by specific Canadian provincial legislation. Please refer to exposure
limits legislated for the province in which the substance will be used.
Product name: DIOCTYL ADIPATE (DOA) Page 4 / 7
Solutia Inc. Material Safety Data Sheet Date: 12/03/2004
Reference Number: 000000000366 Version 5./E
9. PHYSICAL AND CHEMICAL PROPERTIES
Flash point: 192 C Cleveland Open Cup
Specific gravity: 0.924 @ 25 C
Boiling point : 224 C @ 13 hPa
Surface tension: 29 mN/m @ 20 C
Vapour pressure: 3.1 hPa @ 200 C
13.3 hPa @ 224 C
43 hPa @ 250 C
Water solubility: <0.1 g/l @ 25 C
Viscosity : 11.4 mPa.s @ 25 C
VOC Content: 4.2 % ; ASTM D-2369
NOTE: These physical data are typical values based on material tested but may vary from sample to sample.
Typical values should not be construed as a guaranteed analysis of any specific lot or as specifications for the
product.
10. STABILITY AND REACTIVITY
Conditions to avoid: None known
Materials to avoid: None known
Hazardous reactions: Hazardous polymerization does not occur.
Hazardous decomposition carbon dioxide; carbon monoxide (CO)
products:
11. TOXICOLOGICAL INFORMATION
This product has been tested for toxicity. Results from Solutia sponsored studies or from the available public
literature are described below.
Acute animal toxicity data
Oral: LD50 , rat, 11,100 mg/kg , Practically nontoxic following oral administration.
Dermal: LD50 , rabbit, > 7,940 mg/kg , Practically nontoxic after skin application in animal
studies.
Inhalation: LC50 , rat, > 0.2 mg/l , 6 h,
Eye irritation: rabbit , Practically non irritating to eyes (rabbit).,
Skin irritation: rabbit , Slightly irritating to skin (rabbit)., 24 h
Skin sensitization: guinea pig , This material did not produce skin sensitization in laboratory animals.
Product name: DIOCTYL ADIPATE (DOA) Page 5 / 7
Solutia Inc. Material Safety Data Sheet Date: 12/03/2004
Reference Number: 000000000366 Version 5./E
Repeat dose toxicity: rat, diet, 13 weeks,
Produced effects on body weight, serum enzymes and/or organ weights in repeat
dose studies. Repeated oral exposure produced liver changes in animal models.
Target organs affected liver, body weight
Repeat dose toxicity: dog, diet, chronic,
Produced effects on body weight, serum enzymes and/or organ weights in repeat
dose studies. No adverse effects reported in repeat dose studies.
Target organs affected body weight, liver
Developmental toxicity: rat, diet, , No effects on offspring observed in laboratory animals in the presence of
maternal toxicity.
rat, intraperitoneal, , Minor variations and/or reduced fetal weight, but no birth
defects were observed in rat pups following treatment during pregnancy., No birth
defects were noted in rats given the active ingredient orally during pregnancy.
Reproductive toxicity: rat, diet, , Signs of generalized toxicity (reduced body weight and/or reduced
weight gain) were observed in parental animals and offspring with no effect on
fertility or reproduction.
Carcinogenicity: rat, diet, 24 months, No treatment-related effects were observed.
mouse, diet, 24 months, No clear evidence of treatment related tumours.
Mutagenicity: No genetic effects were observed in standard tests using bacterial and animal cells.
The weight of the evidence indicates that this material is not mutagenic in in vivo
assays.
12. ECOLOGICAL INFORMATION
Environmental Toxicity:
Invertebrates 48 h, EC50 Water flea (Daphnia magna)
EC50/LC50 greater than water solubility.
Fish: 96 h, LC50 Rainbow trout (Oncorhynchus mykiss)
EC50/LC50 greater than water solubility.
96 h, LC50 Fathead minnow (Pimephales promelas)
EC50/LC50 greater than water solubility.
Algae: 96 h, EC50 Algae
EC50/LC50 greater than water solubility.
Environmental fate
Biodegradation
Readily biodegradable.
13. DISPOSAL CONSIDERATIONS
US EPA RCRA Status: This material when discarded is not a hazardous waste as that term is defined by the
Resource, Conservation and Recovery Act (RCRA), 40 CFR 261.
Disposal considerations: Incineration
Recycle
Product name: DIOCTYL ADIPATE (DOA) Page 6 / 7
Solutia Inc. Material Safety Data Sheet Date: 12/03/2004
Reference Number: 000000000366 Version 5./E
Miscellaneous advice: Local, state, provincial, and national disposal regulations may be more or less stringent.
Consult your attorney or appropriate regulatory officials for information on such
disposal.
This product should not be dumped, spilled, rinsed or washed into sewers or public
waterways.
14. TRANSPORT INFORMATION
The data provided in this section is for information only. Please apply the appropriate regulations to properly
classify your shipment for transportation.
US DOT
Other: Not regulated for transport.
Canadian TDG
Other: Not regulated for transport.
15. REGULATORY INFORMATION
All components are in compliance with U.S. TSCA, Canadian DSL, EU EINECS, Australian AICS, Korean,
the following inventories: Japanese ENCS, Phillipine PICCS, Chinese
Canadian WHMIS classification: Not Controlled
SARA Hazard Notification:
Hazard Categories Under Title III Not applicable
Rules (40 CFR 370):
Section 302 Extremely Hazardous Not applicable
Substances:
Section 313 Toxic Chemical(s): Not applicable
CERCLA Reportable Quantity:
Not applicable
FDA 21 CFR 175.105
21 CFR 175.300
21 CFR 177.1200
21 CFR 177.1210
21 CFR 177.2600
21 CFR 178.3740
Subject to provisions of these regulations, the final formulator is responsible for complying with any
limitations listed in specific sections.
This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products
Regulation and the MSDS contains all the information required by the Canadian Controlled Products Regulation.
Product name: DIOCTYL ADIPATE (DOA) Page 7 / 7
Solutia Inc. Material Safety Data Sheet Date: 12/03/2004
Reference Number: 000000000366 Version 5./E
Refer to Section 11 for OSHA/HPA Hazardous Chemical(s) and Section 13 for RCRA classification.
Safety data sheet also created in accordance with Brazilian law NBR 14725
16. OTHER INFORMATION
Product use: Plasticizer
Reason for revision: New ANSI Standard
Health Fire Reactivity Additional Information
Suggested NFPA Rating 0 1 0
Suggested HMIS Rating: 0 1 0 B
Prepared by the Solutia Hazard Communication Group. Please consult Solutia @ 314-674-6661 if further
information is needed.
TM, ?is a registered trademark of Solutia Inc.
SOLUTIA is a trademark of Solutia Inc.
Responsible Care?is a registered trademark of the American Chemistry Council.
Although the information and recommendations set forth herein (hereinafter "Information") are presented
in good faith and believed to be correct as of the date hereof, Solutia Inc. makes no representations as to
the completeness or accuracy thereof. Information is supplied upon the condition that the persons
receiving same will make their own determination as to its suitability for their purposes prior to use. In no
event will Solutia Inc. be responsible for damages of any nature whatsoever resulting from the use of or
reliance upon Information. NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS OR
IMPLIED, OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE OR OF ANY
OTHER NATURE ARE MADE HEREUNDER WITH RESPECT TO INFORMATION OR THE
PRODUCT TO WHICH INFORMATION REFERS.
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