MATERIAL SAFETY DATA SHEETS
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SECTION I: SUBSTANCE IDENTIFICATION AND COMPANY INFORMATION
USA/CANADA EMERGENCY TELEPHONE: 1.800.535.5053
MANUFACTURER'S NAME: ENTITY BEAUTY, INC.
INTERNATIONAL EMERGENCY TELEPHONE: 1.352.323.3500
INFORMATION CONTACT: INFOTRAC
ADDRESS: 440 W. ONTARIO STREET
ENTITY'S FORMULA NUMBER: CONFIDENTIAL
CHICAGO, IL 60654 USA
PRODUCT CODE: 4022228 / 4022232
FAMILY: ACRYLIC POLYMER
PRODUCT TYPE: POLYMER PINK TRANSPARENT
TRADE NAME: PINK NAIL SCULPTING POWDER
PRODUCT USE: NAIL POLYMER ISSUED: JULY 28, 2005 REVISION 1
SECTION II: COMPOSITION AND INGREDIENT INFORMATION
Hazard Symbols: Xi Risk Phrases: R36/37/38 Safety Phrases: S18, S22, S24/25, S38
CAS Numbers EINECS # U.S. INCI EU INCI
9003-42-3 N/E Polyethylmethacrylate Polyethylmethacrylate
9011-14-7 N/E Polymethyl Methacrylate Polymethyl Methacrylate
5281-04-9 29092-56-6 Red 7 CI 15850
94-36-0 202-327-6 Benzoyl Peroxide Benzoyl Peroxide
N/E - None Established
This product is not considered hazardous by OSHA Hazard Communication Standard.
Carcinogen %
Limits
Chemical Identity Exposure
IARC/NTP/OSHA
OSHA ACGIH
TWA/STEL TWA/STEL
Poly (ethyl methacrylate) N/E N/E Not Listed 65-99
Poly (methyl methacrylate) N/E N/E Group 3/no/no 0-35
Red 7 N/E N/E Not listed 0-1
Dibenzoyl Peroxide 5 mg/m3 5 mg/m3 3/no/no 0-1
N/E - None Established
SECTION III: HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
This information is based on findings from related or similar materials.
May cause allergic skin reaction.
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May cause eye irritation.
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Dust may cause irritation of the nose, throat, and lungs.
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This product may contain particulate, not otherwise classified (Nuisance Dust)
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Potential Health Effects, Signs and Symptoms of Exposure:
Primary Route of Entry: Eyes or skin (No absorption); inhalation of dust.
Eye: Higher concentration can irritate eyes. May cause eye irritation or damage.
Skin: Repeated or prolonged exposure may cause allergic skin rashes.
Ingestion: Higher concentration can irritate respiratory system.
Inhalation: Possible temporary discomfort due to inhalation of dust concentration above the permissible exposure
limit. Dust may cause irritation of the nose, throat, and lungs.
MATERIAL SAFETY DATA SHEETS
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Sub-Chronic Effects: For Polymer: OSHA classifies this material as Particulates, Not Otherwise Classified. Eyes, skin and
Respiratory tract may be irritated by gross overexposure to Particulates, Not Otherwise Classified, no
matter how they are generated. Avoid inhalation of dust. Keep dust out of eyes to prevent possible
irritation.
For decomposition product: Methyl Methacrylate Monomer; Liquid or high vapor concentration can
irritate eyes, respiratory system and cause skin rashes. Prolonged exposure can lead to headaches,
nausea, staggering gait, confusion, drowsiness and unconsciousness. Repeated and prolonged over
exposure may cause permanent brain and nervous system damage, allergic skin rashes, eye corrosion
and permanent injury, as well as changes in liver and kidney function or damage.
For Benzoyl Peroxide: repeated or prolonged contact may cause skin sensitization.
NOTE: Refer to Section 11, Toxicological Information for Details
SECTION IV: FIRST AID MEASURES
First Aid for Eye: Flush with water for 15 minutes, including under eyelids. Get medical help if discomfort persists.
First Aid for Skin: Wash with soap and water. Get medical help if discomfort persists.
First Aid for Inhalation: Remove to fresh air. Get medical help if discomfort persists.
First Aid for Ingestion: Rinse mouth out with water. Call doctor if amount was large.
SECTION V: FIRE FIGHTING METHODS
Flash Point (癋/癈) - TAG Closed: 580篎/304篊 Auto-ignition Temperature (vol. %) - N/E
Flammable Limit (vol. %) ?N/A
Method:
Extinguishing Media: Water, carbon dioxide, dry chemical.
Fire Fighting Avoid extinguishing methods that generate dust clouds. Water streams can disperse dust into
Instructions: air, producing a fire hazard and possible explosion hazard. Fire-fighters should wear self -
contained breathing apparatus.
Unusual Hazards: Polymer dust is combustible, explosive limits of the polymer particles suspended in air are
approximately those of coal dust.
SECTION VI: ACCIDENTAL RELEASE MEASURES
Spill/Release Procedures: Sweep up to avoid slipping hazard. Keep airborne particulates at a minimum when cleaning up spills.
SECTION VII: HANDLING AND STORAGE
Handling: Observe precautions found on the label. Wash face and hands thoroughly with soap and water
after handling and before eating, drinking or smoking.Avoid prolonged or repeated contact
with skin. Avoid contamination. Use only with adequate ventilation.
Storage: Store in cool, dry place away from heat, sparks, flame and direct sunlight. Close container
after each use. Ground all metal conrainers when transferring. Use explosion-proof equipment
Store away from combustibles and incompatible materials.
Explosion Hazard: Polymer dust is combustible, explosive limits of the polymer particles suspended in air are
approximately those of coal dust.
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MATERIAL SAFETY DATA SHEETS
SECTION VIII: EXPOSURE CONTROLS / PERSONAL PROTECTIVE EQUIPMENT
Engineering Controls: Use good local exhaust at processing equipment, including buffers, sanders, grinders and
polishers . High temperature processing equipment should be well ventilated. Use explosion-
proof equipment.Provide ventilation if necessary to control exposure levels below airborne
exposure limits.
Personal Protective Equipment
General Dust collectors are recommended for handling powder in bulk.
Eye/ Face Protection Use safety glasses and have eye flushing equipment immediately available.
Skin Protection Minimize contamination by following good industrial practice. Wearing nitrile, neoprene, pvc,
latex ot other impermeable gloves is recommended.
Respiratory Protection Avoid breathing dust and mist. Use dust mask.
SECTION IX: PHYSICAL AND CHEMICAL PROPERTIES
Appearance Odor & Odor Threshold PH Specific Gravity Viscosity % Volatile
Fine, white powder Faint odor in bulk. N/A N/A N/A N/A
Boiling Point/ Decomposition Octanol/Water Partitioning Vapor Vapor Evapora Ignition Solubility
tion
Coefficient (Log Po/w)
Freezing Point Pressure Density Rate In Water
(20癈)
N/A N/A N/A N/A N/A N/A N/A insoluble
Flash Point (癋/癈) Flammable Limit (vol%) Auto-ignition Temperature (vol%) N/E
TAG Closed: 580篎/304篊 N/A
SECTION X: STABILITY AND REACTIVITY
Stability: Stable Incompatibility (Materials to Avoid): Strong oxidizing
Hazardous Decomposition Products: methacrylate monomers agents
Conditions to Avoid: Heating above 240 deg C , 464 deg F Hazardous Polymerization: will not occur
SECTION XI: TOXICOLOGICAL INFORMATION
Acute Oral Toxicity Acute Dermal Toxicity Acute Inhalation Toxicity Irritation ?skin Irritation - Eye
LD50 Oral (Rat) : LD50 Dermal (Rabbit): LC50 Inhalation (Rat) : >12,500 mild mild
7990mg/kg 35,500 mg/kg to 16,500 ppm for 0.5 hours
Since this product contains a very low concentration of active components, the primary toxicological information is derived from the
copolymers. Further hazardous properties cannot be excluded. The product should be handled with care when dealing with chemicals.
Sensitization Mutagenicity Sub-chronic Toxicity
No information available No information available No information available
RTECS#: 9011-14-7: TR040000
SECTION XII: ECOLOGICAL INFORMATION
Ecotoxicological Information
Acute Toxicity to Fish Acute Toxicity to Acute Toxicity to Bioconcentration Toxicity to Sewage
Invertebrates Algae Bacteria
Flathead Minnows/GoldfishTLm24: N/DA N/DA N/DA N/DA
420 ppm /Blue Gills TLm24:368ppm
Chemical Fate Information
N/DA
Biodegradability
N/DA
Chemical Oxygen Demand
To the best of our knowledge, the ecotoxicological and chemical fate properties have not been thoroughly investigated.
Do not allow to enter drinking water supplies, wastewater, or soil.
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MATERIAL SAFETY DATA SHEETS
SECTION XIII: DISPOSABLE CONSIDERATION
May be disposed of in a landfill or incinerated. Follow Federal, State and Local regulations for disposal. For EU Member States,
please refer to any relevant Community provisions relating to waste. In their absence, it is useful to remind the user that national or regional
provisions may be in force.
SECTION XIV: TRANSPORTATION INFORMATION
DOT (49 CFR 172)
Proper Shipping Name: Non-Regulated Material
Identification Number: N/A
Marine Pollutant: No
Special Provisions: N/A
Emergency Response Guidebook (ERG) #: N/A
IATA (DGR):
Proper Shipping Name: Non-Regulated Material
Class or Division: N/A
UN or ID Number: N/A
Packaging Instructions:
Emergency Response Guidance (ICAO)#:
IMO (IMDG):
Proper Shipping Name: Non-Regulated Material
Class or Division: N/A
UN or ID Number: N/A
Special Provisions & Stowage/Segregation: None
Emergency Schedule (EmS)#:
Other Information: Flash point > 100篊
SECTION XV: REGULATORY INFORMATION
US Federal Regulations
Clean Air Act: HAP/ODS This product contains the following hazardous air pollutants (HAP's) or ozone dipleting
substances (ODS's), as defined by the U. S. Clean Air Act:
NONE
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Clean Water Act: Priority Pollutant This product contains the following chemicals listed under the U.S. Clean Water Act Priority
Pollutant List:
NONE
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FDA: Food Packaging Status This product has not been cleared by the FDA for use in food packaging and/ or other
applications as an indirect food additive.
Occupational Safety and Health Act This product is not considered a hazardous chemical under the OSHA Hazard Communication
Standard.
RCRA This product contains no chemicals considered to be hazardous waste under RCRA ( 40
CFR 261).
SARA Title III: Section 302 (TPQ) This product contains no chemicals regulated under Sec. 302 as extremely hazardous
substances.
SARA Title III: Section 302 (RQ) This product contains no chemicals regulated under Sec. 304 as extremely hazardous
chemicals for emergency release notification ( "CERCLA " List).
SARA Title III: Section 311-312: This product does not contain hazardous substances under the OSHA Hazard Communication
Standard, and is not regulated under Section 311-312 (40 CFR 370).
SARA Title III: Section 313: This product contains the following chemicals outlined in SARA Title III: Section 313:
Benzoyl Peroxide CAS #94-36-0.
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TSCA Section 8(b): Inventory: This product contains chemicals listed on the TSCA inventory or otherwise complies with
TSCA premanufacture notification requirements.
TSCA Significant New Use Rule: None of the chemicals listed have a SNUR under TSCA.
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MATERIAL SAFETY DATA SHEETS
State Regulations
CA Right-to-Know Law: Benzoyl Peroxide CAS #94-36-0
California No Significant Risk Rule: NONE
MA Right-to-Know Law: Benzoyl Peroxide CAS #94-36-0
NJ Right-to-Know Law: Benzoyl Peroxide CAS #94-36-0
PA Right-to-Know Law: Benzoyl Peroxide CAS #94-36-0
FL Right-to-Know Law: Benzoyl Peroxide CAS #94-36-0
MN Right-to-Know Law: Benzoyl Peroxide CAS #94-36-0
International Regulations
CDSL: Canadian Inventory Polymethyl methacrylate CAS# 9011-14-7 is on the DSL List. WHMIS = n/da
(on Canadian Transitional List) Polyethylmethacrylate CAS# 9003-42-3 is on the DSL List. WHMIS = n/da
Benzoyl Peroxide CAS #94-36-0 is on the DSL list. WHMIS = C, D2B, B4
EINECS: European Inventory: Polymer Pink:
?HAZARD SYMBOLS: Xi: Irritant
?RISK PHRASES: R36/37/38: Irritating to eyes, respiratory system and skin
?SAFETY PHRASES: S18: Handle and open container with care, S22: do not
breath dust, S24/25: avoid contact with skin and eyes, S38: in case of
insufficient ventilation, wear suitable respiratory equipment.
SECTION XVI: OTHER INFORMATION
Hazard Rating System (Pictograms)
NFPA: HMIS:
1
Flammability
1
1
1 1
Health Reactivity
1
D
*D
* - Respiratory protection may be necessary depending on conditions of use. Refer to Section 8 of this MSDS for respiratory protection guidelines.
15 mg/m3 (total dust) 5 mg/m3 (respire able dust) 10 mg/m3
OSHA PEL for nuisance dust: ACGIH PEL for nuisance dust:
The information presented herein was obtained from sources considered to be reliable. However, this information is provided without any
warranty, expressed or implied, regarding its correctness or suitability for consumers intended use and/or application. For this and other
reasons, we assume no responsibility and expressly disclaim liability for loss, damage or expense arising out of any way connected with the
handling, storage, use or disposal of the product. This MSDS was prepared expressly for this product. Use the materials only as directed. If
the product is used as a component of another product, the information contained within the MSDS may not be applicable. If one could have
any concerns with or problems understanding this MSDS form, please direct all questions to INFOTRAC, Chemical Emergency Resources
System at 1(800) 535-5053.
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