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60676-86-0 94-36-0 868-77-9 72869-86-4

File Name: 60676-86-0_94-36-0_868-77-9_72869-86-4.asp

5266080604                                                                                                                                                              Reviewed on April 01, 2006


TOKUYAMA DENTAL CORPORATION
MATERIAL SAFETY DATA SHEET

1. Identification of substance 10. Stability and reactivity
TOKUYAMA IONOTITE F Powder
Product name Conditions to avoid Heat, direct sunlight, sparks and open flames.
Description of Product Dental Cement, For dental professionals only. Strong acid, strong alkalis, strong oxidizers,
Materials to avoid
accelerators and reducing agents.
Tokuyama Dental Corporation
Manufacturer 38-9, Taitou 1-chome, Taitou-ku, Tokyo, Japan Incomplete thermal decomposition may cause toxic
Hazardous reactions
TEL: +81-3-3835-7201 gases.
Tokuyama Europe GmbH
EC Representative 11. Toxicological information
Oststrasse 10, 40211 D黶seldorf, Germany
(Emergency Contact in EU)
TEL: +49 211 1754480 FAX: +49 211 357379
Inhalation Irritation of respiratory organs.
Ingestion Slight irritation of digestive organs.
2. Composition / Data on components
Slight irritation, repeated prolonged contact may cause
Skin contact
Ingredients % Cas.No. Symbols R-phrases OSHA PEL skin inflammation.
Fluoroaluminosilicate glass
Eye contact Irritation, redness, pain.
60-90 N/E N/E N/E N/E
filler
Carcinogenicity N/R
3
Silica filler, amorphous-fused 10-40 60676-86-0 N/E N/E 80 mg/m
Others
5mg/m3
Benzoyl peroxide (BPO) <3 94-36-0 E, Xi 2-36-43
12. Ecological information
3. Hazard identification
Biodegradability N/A
Hazard description Irritant
Bioaccumulative N/A
R36: Irritating to eyes.
R-phrases Aquatic toxicity N/A
R43: May cause sensitization by skin contact.
Others
4. First aid measures
13. Disposal consideration
After skin contact Wash immediately with soap and plenty of water.
Disposal must be made according to federal, state and local regulations.
Wash immediately with plenty of water. Get medical
After eye contact
attention.
14. Transport information
After swallowing Induce vomiting immediately. Get medical attention.
Proper shipping name Not subject to this section.
5. Fire fighting measures This product contains an organic peroxide (see section
UN number
2, BPO, less than 3%); however, this product does not
Suitable extinguishing media Chemical foam, carbon dioxide or dry chemical. Classification meet the definition of Organic Peroxide which is
Media not to be used None. described to 173.128 of 49CFR or 3.5.2 of IATA
Packing group
Dangerous Goods Regulations because this material
Combustion products and Irritant gas may be released during heating or in case Air transport meets the following exception,
resulting gases of fire.
173.128, (a)(4)(ii) of 49CFR, and
Sea transport
Special precaution for Use protective clothing and a self-contained breathing 3.5.2.2, (b) of IATA Dangerous Goods
firefighters apparatus. Inland transport Regulations.

6. Accidental release measures 15. Regulatory information
Personal protection Wear suitable protective groves. Marking according to EU
67/548/EEC, 92/32/EEC
regulations
Environmental protection Not required.
Contains Benzoyl Peroxide
Clean up with a water-soaked inert absorbent and
Methods for cleaning up
dispose of it at special waste collection point. Symbols Xi: Irritant
R36: Irritating to eyes.
R-phrases
7. Handling and storage R43: May cause sensitization by skin contact
Handling Use in a well ventilated place. S2: Keep out of the reach of children.
S-phrases S36/37/39: Wear suitable protective clothing, gloves
Store in a cool, dark place (0-25 , 32-77 ).
and eye/face protection.
Storage Keep away from heat, direct sunlight, sparks and open
flames. R and S-phrases are not marked according to contents
Others not more than 125 ml and the case not related to the
general public (Article 23 Labeling -3).
8. Exposure controls / personal protection
In general Not required. 16. Other information
Respiration protection Not required.
The information which is contained in this document is based on available data.
Hand protection Wear suitable protective gloves. However, as such has been obtained from various sources, including independent
laboratories, it is given without warranty or representation that is complete, accurate and
Eye protection Wear suitable protective glasses.
can be replied upon. Tokuyama Dental Corp. has not attempted to conceal in any way the
Skin protection Wear suitable protective clothing. deleterious aspects of the product listed herein, but makes no warranty as to such.
* N/E: Not Established, N/A: Not Available, N/R: Not Regulated by IARC
9. Physical and chemical properties
Explosive
Appearance Powder, white N/A
properties
Oxidizing
Odor None N/A
properties
pH N/A Vapor pressure N/A
Boiling point None Relative density N/A
Melting point N/A Solubility (water) N/A
Flash point N/A Solubility (solvent) N/A
Flammability None Partition coefficient N/A
Autoflammability N/A Others
Reviewed on April 01, 2006


TOKUYAMA DENTAL CORPORATION
MATERIAL SAFETY DATA SHEET

1. Identification of substance 10. Stability and reactivity
TOKUYAMA IONOTITE F Liquid
Product name Conditions to avoid Heat, direct sunlight, sparks and open flames.
Description of Product Dental Cement, For dental professionals only. Strong acid, strong alkalis, strong oxidizers,
Materials to avoid
accelerators and reducing agents.
Tokuyama Dental Corporation
Manufacturer 38-9, Taitou 1-chome, Taitou-ku, Tokyo, Japan Hazardous reactions No hazardous reactions known.
TEL: +81-3-3835-7201
11. Toxicological information
Tokuyama Europe GmbH
EC Representative
Oststrasse 10, 40211 D黶seldorf, Germany
(Emergency Contact in EU) No irritating effect (This material contains no volatile
TEL: +49 211 1754480 FAX: +49 211 357379 Inhalation
ingredient.)
Ingestion Slight irritation of digestive organs.
2. Composition / Data on components
Slight irritation, defatting action, repeated prolonged
Skin contact
Ingredients % Cas.No. Symbols R-phrases OSHA PEL contact may cause skin inflammation.
2-Hydroxyethyl methacrylate 30-70 868-77-9 Xi 36/38-43 N/E
Eye contact Irritation, redness, pain.
1,6-bis(methacrylethyloxycarbo
Carcinogenicity N/R
10-30 72869-86-4 N/E N/E N/E
-nylamino) trimethyl hexane
Others
Methacryloxyalkyl acid
phosphate (Phosphoric acid 10-30 N/E Xi 36/37/38 N/E
12. Ecological information
monomer)
6-Methacryloyloxyhexyl Biodegradability N/A
<1 N/E Xi 36/37/38 N/E
2-thiouracil-5-carboxylate
Bioaccumulative N/A
Aquatic toxicity N/A
3. Hazard identification
Others
Hazard description Irritant
R36/38: Irritating to eyes and skin. 13. Disposal consideration
R-phrases
R43: May cause sensitization by skin contact.
Disposal must be made according to federal, state and local regulations.
4. First aid measures
14. Transport information
After skin contact Wash immediately with soap and plenty of water.
Proper shipping name
Wash immediately with plenty of water. Get medical
After eye contact UN number
attention.
Not subject to this section.
Classification
Induce drinking plenty of water and get medical
This product does not meet the definition of
After swallowing
attention. Packing group Flammable liquid which is described to 173.120
of 49CFR or 3.3 of IATA Dangerous Goods
Air transport
5. Fire fighting measures Regulations (see Flash point of section 9).
Sea transport
Suitable extinguishing media Chemical foam, carbon dioxide or dry chemical.
Inland transport
Media not to be used None.
Combustion products and Irritant gas may be released during heating or in case 15. Regulatory information
resulting gases of fire.
Marking according to EU
67/548/EEC, 92/32/EEC
Special precaution for Use protective clothing and a self-contained breathing regulations
firefighters apparatus.
2-Hydroxyethyl methacrylate, Methacryloxyalkyl acid
Contains phosphate (Phosphoric acid monomer) and
6. Accidental release measures
6-Methacryloyloxyhexyl 2-thiouracil-5-carboxylate.
Personal protection Wear suitable protective groves. Symbols Xi: Irritant
Environmental protection Do not empty into drains. R36/38: Irritating to eyes and skin.
R-phrases
R43: May cause sensitization by skin contact.
Clean up with an inert absorbent and dispose of it at
Methods for cleaning up
special waste collection point. S2 : Keep out of the reach of children.
S26 : In case of contact with eyes, rinse immediately
S-phrases with plenty of water and seek medical advice.
7. Handling and storage
S28 : After contact with skin, wash immediately with
Handling Use in a well ventilated place. soap and plenty of water.
Store in a cool, dark place (0-25 , 32-77 ). R and S-phrases are not marked according to contents
Storage Keep away from heat, direct sunlight, sparks and open Others not more than 125 ml and the case not related to the
flames. general public (Article 23 Labeling -3).

8. Exposure controls / personal protection 16. Other information
In general Not required. The information which is contained in this document is based on available data.
However, as such has been obtained from various sources, including independent
Respiration protection Not required.
laboratories, it is given without warranty or representation that is complete, accurate and
Hand protection Wear suitable protective gloves. can be replied upon. Tokuyama Dental Corp. has not attempted to conceal in any way the
deleterious aspects of the product listed herein, but makes no warranty as to such.
Eye protection Wear suitable protective glasses.
* N/E: Not Established, N/A: Not Available, N/R: Not Regulated by IARC
Skin protection Wear suitable protective clothing.

9. Physical and chemical properties
Explosive
Appearance Transparent liquid N/A
properties
Characteristic Oxidizing
Odor N/A
Odour properties
pH Acidic Vapor pressure N/A
1.09g/cm3
Boiling point N/A Relative density
Melting point N/A Solubility (water) N/A
Flash point 123 C Solubility (solvent) N/A
Flammability None Partition coefficient N/A
Autoflammability N/A Others

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