MATERIAL SAFETY DATA SHEETS
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SECTION I: SUBSTANCE IDENTIFICATION AND COMPANY INFORMATION
USA/CANADA EMERGENCY TELEPHONE: 1.800.535.5053
MANUFACTURER'S NAME: ENTITY BEAUTY, INC.
INTERNATIONAL EMERGENCY TELEPHONE: 1.352.323.3500
INFORMATION CONTACT: INFOTRAC
ADDRESS: 440 W. ONTARIO STREET
ENTITY'S FORMULA NUMBER: CONFIDENTIAL
CHICAGO, IL 60654 USA
PRODUCT CODE: KMS-2124A, KMS-2146A, KMS- 2146B,
KMS-2146C, KMS-2146D, KMS-2146E
FAMILY: ACRYLIC POLYMER
PRODUCT TYPE: COLORED ACRYLIC POLYMER
TRADE NAME: NUDITE SCULPTING POWDERS (6)
PRODUCT USE: NAIL POLYMER ISSUED: DECEMBER 20, 2005 (REVISION 1)
SECTION II: COMPOSITION AND INGREDIENT INFORMATION
Hazard Symbols: Xi Safety Phrases: S18, S22, S24/25, S38 Risk Phrases: R36/37/38
CAS Number EINECS# U. S. INCI EU INCI
9003-42-3 N/E Poly (ethyl methacrylate) Polyethyl Methacrylate
9011-14-7 N/E Poly (methyl methacrylate) Polymethyl Methacrylate
13463-67-7 236-675-5 Titanium dioxide Titanium dioxide/CI77891
94-36-0 202-327-6 Dibenzoyl peroxide Benzoyl peroxide
Please see Section 16 for
May contain the
additional compounds
following:
Chemical Identity Exposure Limits Carcinogen %
OSHA ACGIH
TWA/STEL TWA/STEL IARC/NTP/OSHA
Polyethyl methacrylate N/E N/E Not Listed 65-99
Polymethyl methacrylate N/E N/E Group 3/no/no 0-35
15 mg/m3 10 mg/m3
Titanium dioxide Group 3/no/no 0-1
5 mg/m3 5 mg/m3
Dibenzoyl peroxide Group 3/no/no 0-1
SECTION III: HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
This information is based on findings from related or similar materials.
May cause allergic skin reaction
?br>
May cause eye irritation.
?br>
Dust may cause irritation of the nose, throat and lungs.
?br>
This product may contain particulate, not otherwise classified (Nuisance Dust)
?br>
Please read entire MSDS for additional information.
?br>
Potential Health Effects, Signs and Symptoms of Exposure:
Primary Route of Entry: Eyes or skin (No Absorption); inhalation of dust
Eye: Higher concentration can irritate eyes. May cause eye irritation or damage.
Skin: Repeated or prolonged exposure may cause allergic skin rashes.
Ingestion: Higher concentration can irritate gastrointestinal system.
Inhalation: Possible temporary discomfort due to inhalation of dust concentration above the permissible exposure
limit. Dust may cause irritation of the nose, throat and lungs.
MATERIAL SAFETY DATA SHEETS
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Sub-Chronic Effects: For polymer: Avoid inhalation of dust. Keep dust out of eyes to prevent possible irritation.
For decomposition product ?methyl methacrylate monomer: liquid or high vapor concentration can
irritate eyes, respiratory system and cause skin rashes. Prolonged exposure can lead to headaches,
nausea, staggering gait, confusion, drowsiness and unconsciousness. Repeated and prolonged exposure
may cause permanent brain and nervous system damage, allergic skin rashes, eye corrosion and
permanent injury, as well as changes in liver and kidney function or damage.
For benzoyl peroxide: repeated or prolonged contact may cause skin sensitization.
NOTE: Refer to Section 11, Toxicological Information for Details
SECTION IV: FIRST AID MEASURES
First Aid for Eye: Flush with water for 15 minutes, including under eyelids. Seek medical help if discomfort persists.
First Aid for Skin: Wash thoroughly with soap and water. Remove contaminated clothing and wash before reuse. Seek
medical attention if discomfort persists.
First Aid for Inhalation: Remove to fresh air. If having breathing difficulty, give oxygen. If breathing has stopped, give
artificial respiration. Get medical help if discomfort persists.
First Aid for Ingestion: Rinse mouth out with water. Only induce vomiting if directed by a physician. Never give anything
by mouth to an unconscious person. Seek prompt medical attention.
SECTION V: FIRE FIGHTING METHODS
Flash Point Flammable Limit Auto-ignition Temperature
(癋/癈) (vol%) (vol%)
N/A N/E
Tag Closed Cup: 580癋/304篊
Method:
Extinguishing Media: Water, carbon dioxide, dry chemical.
Fire Fighting Instructions: Avoid extinguishing methods that generate dust clouds. Water streams can disperse dust into air,
producing a fire hazard and possible explosion hazard. Fire-fighters should wear self-contained
breathing apparatus.
Unusual Hazards: Polymer dust is combustible, explosive limits of the polymer particles suspended in air are
approximately those of coal dust.
SECTION VI: ACCIDENTAL RELEASE MEASURES
Spill or Release Sweep up to avoid slipping hazard. Keep airborne particulates at a minimum when cleaning up spills.
Procedures:
SECTION VII: HANDLING AND STORAGE
Handling: Observe precautions found on the label. Wash face and hands thoroughly with soap and water after handling
and before eating, drinking or smoking. Avoid prolonged or repeated contact with skin. Avoid
contamination. Use only with adequate ventilation.
Storage: Store in a cool, dry place away from heat, sparks, flame and direct sunlight. Close container after each use.
Ground all metal containers when transferring. Use explosion-proof equipment.
MATERIAL SAFETY DATA SHEETS
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Explosion Hazard: Polymer dust is combustible, explosive limits of the polymer particles suspended I air are approximately
those of coal dust.
SECTION VIII: EXPOSURE CONTROLS / PERSONAL PROTECTIVE EQUIPMENT
Engineering Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne
Controls: levels below recommended exposure limits. Use explosion-proof ventilation equipment.
Personal Protective Equipment
General: Dust collectors are recommended for handling powder in bulk.
Eye/ Face Protection: Use safety glasses and have eye flushing equipment immediately available.
Skin Protection: Minimize contamination by following good industrial practice. Wearing nitrile, neoprene, pvc, latex or other
impermeable gloves is recommended.
Respiratory Avoid breathing dust. Use dust mask.
Protection:
SECTION IX: PHYSICAL AND CHEMICAL PROPERTIES
Appearance Odor & Odor Threshold PH Specific Gravity Viscosity % Volatile -
Fine, white powder Faint odor in bulk N/A N/A N/A N/A
Ignition
Boiling Point/ Decomposition Octanol/Water Vapor Vapor Evaporation Solubility In
Freezing Point Temperature Partitioning Coefficient Pressure: Density Rate Water (20癈)
Log Po/w
N/A N/A N/A N/A N/A N/A N/A insoluble
Flash Point (癋/癈) Flammable Limit (vol%) Auto-ignition Temperature (vol%)
N/A N/A
Tag Closed Cup: 580癋/304篊
SECTION X: STABILITY AND REACTIVITY
Stability: Incompatibility (Materials to Avoid):
Stable Strong oxidizing agents
Hazardous Decomposition Products: Hazardous Polymerization:
Methacrylate monomers Will not occur
Conditions to Avoid:
Heating above 240篊, 464篎
SECTION XI: TOXICOLOGICAL INFORMATION
Acute Oral Toxicity Acute Dermal Toxicity Acute Inhalation Toxicity Irritation - skin Irritation - Eye
LD50 (rat) : 7990 mg/kg LD50 (rabbit): 35,500 mg/kg LC50 (rat): >12,500 to 16,500 ppm mild mild
for 0.5 hours
Sensitization Mutagenicity Sub-chronic Toxicity
N/DA N/DA N/DA
RTECS #: 9011-14-7: TR0400000
SECTION XII: ECOLOGICAL INFORMATION
MATERIAL SAFETY DATA SHEETS
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Ecotoxicological Information
Acute Toxicity to Fish Acute Toxicity to Invertebrates Acute Toxicity to Algae Bioconcentration Toxicity to Sewage Bacteria
Flathead minnows and N/DA N/DA N/DA N/DA
goldfish TLm24: 420
ppm;
bluegills TLm: 368 ppm
Chemical Fate Information
N/DA
Biodegradability
N/DA
Chemical Oxygen Demand
SECTION XIII: DISPOSABLE CONSIDERATION
May be disposed of in a landfill or incinerated. Follow Federal, State and Local regulations for disposal. For EU Member States,
please refer to any relevant Community provisions relating to waste. In their absence, it is useful to remind the user that national or
regional provisions may be in force.
SECTION XIV: TRANSPORTATION INFORMATION
DOT (49 CFR 172)
Proper Shipping Name: Non-regulated material
Identification Number: N/A
Marine Pollutant: No
Special Provisions: N/A
Emergency Response Guidebook (ERG) #: N/A
IATA (DGR):
Proper Shipping Name: Non-regulated material
Class or Division: N/A
UN or ID Number: N/A
Packaging Instructions:
Emergency Response Guidance (ICAO)#:
IMO (IMDG):
Proper Shipping Name: Non-regulated material
Class or Division: N/A
UN or ID Number: N/A
Special Provisions & Stowage/Segregation: None
Emergency Schedule (EmS)#:
Other Information: Flash point > 100篊
SECTION XV: REGULATORY INFORMATION
US Federal Regulations
Clean Air Act: HAP/ODS This product contains the following hazardous air pollutants (HAP's) as defined by the
U. S. Clean Air Act:
?None
This product does not contain any Class1 or Class 2 ODS.
Clean Water Act: This product contains the following Hazardous Substances as defined by the CWA:
?NONE
This product does not contain any substances that are a Priority Pollutant or Toxic
Pollutant under the CWA.
FDA: Food Packaging Status This product has not been cleared by the FDA for use in food packaging and/or
other applications as an indirect food additive.
MATERIAL SAFETY DATA SHEETS
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Occupational Safety and Health Act This product is not considered to be hazardous under the OSHA Hazard
?br>
Communication Standard.
RCRA This product contains no chemicals considered to be hazardous waste under RCRA (40
CFR 261).
SARA Title III: Section 302 (TPQ) This product contains no chemicals regulated under Sec. 302 as extremely hazardous
substances that carry a TPQ.
SARA Title III: Section 302 (RQ) This product contains no chemicals regulated under Sec. 304 as extremely hazardous
chemicals for emergency release notification ("CERCLA" List)
SARA Title III: Section 311-312: This product does not contain hazardous substances under the OSHA Hazard
Communication standard, and is not regulated under Section 311-312 (40 CFR 370).
SARA Title III: Section 313: This product contains the following substances subject to the reporting requirements of
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986
and 40 CFR Part 372:
?NONE
TSCA Section 8(b): Inventory: This product contains chemicals listed on the TSCA inventory or otherwise complies
with TSCA premanufacture notification requirements.
State Regulations
CA Right-to-Know Law: Benzoyl peroxide CAS #94-36-0
California No Significant Risk Rule: NONE
MA Right-to-Know Law: Titanium dioxide CAS #13463-67-7; Benzoyl peroxide CAS #94-36-0
NJ Right-to-Know Law: Titanium dioxide CAS #13463-67-7; Benzoyl peroxide CAS #94-36-0
PA Right-to-Know Law: Titanium dioxide CAS #13463-67-7; Benzoyl peroxide CAS #94-36-0
FL Right-to-Know Law: Benzoyl peroxide CAS #94-36-0
MN Right-to-Know Law: Titanium dioxide CAS #13463-67-7; Benzoyl peroxide CAS #94-36-0
International Regulations
CDSL: Canadian Inventory Polyethyl methacrylate DSL regulatory status: Included, WHMIS: N/DA
(on Canadian Transitional Polymethyl methacrylate DSL regulatory status: Included, WHMIS: N/DA
List) Titanium dioxide DSL regulatory status: Included, WHMIS: not controlled
Benzoyl peroxide DSL regulatory status: included, WHMIS = C, D2B, B4
: Nudite Sculpting Powders (6):
?HAZARD SYMBOLS: Xi: Irritant
?RISK PHRASES: R36/37/38: Irritating to eyes, respiratory system and skin
?SAFETY PHRASES: S18: handle and open container with care, S22: do not breathe dust,
S24/25: avoid contact with skin and eyes, S38: in case of insufficient ventilation, wear
suitable respiratory equipment
MATERIAL SAFETY DATA SHEETS
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SECTION XVI: OTHER INFORMATION
Hazard Rating System (Pictograms)
NFPA: HMIS:
1
Flammability
1
1
1 1
Reactivity
Health
1
Respiratory protection may be necessary depending on conditions of use. Refer to Section 8 of this MSDS
for respiratory protection guidelines.
MAY CONTAIN THE FOLLOWING CHEMICALS:
Chemical CAS EINECS# INCI Name Exposure Limits Carcinogen %
Identity Numbers OSHA ACGIH IARC/NTP/OSHA
TWA/STEL TWA/STEL
FD&C Blue 3844-45-9 223-339-8 Blue N/E N/E Not listed 0-1
#1 1/CI42090
Yellow No. 4 1934-21-0 217-699-5 Yellow N/E N/E Not listed 0-1
5/CI19140
D&C Red#7 5281-04-9 226-109-5 Red 7/CI15850 N/E N/E Not listed 0-1
D&C Red 2379-74-0 219-163-6 Red N/E N/E Not listed 0-1
#30 30/CI73360
D&C Orange 596-03-2 209-876-0 Orange N/E N/E Not listed 0-1
#5 5/CI45370
D&C Violet 81-48-1 201-353-5 Violet N/E N/E Not listed 0-1
#2 2/CI60725
Iron oxide 1317-61-9 215-277-5 Iron N/E N/E Not listed 0-1
black oxide/CI77489
10 mg/m3 5 mg/m3
Red iron 1309-37-1 215-168-2 Iron Group3/no/no 0-1
oxide oxide/CI77491
Yellow iron 51274-00-1 257-098-5 Iron N/E N/E Not listed 0-1
oxide oxides/CI77492
3 mg/m3
Mica 12001-26-2 N/E Mica N/E Not listed 0-1
N/E = None N/R = Not N/DA = No N/A = Not
established reviewed data available applicable
The information presented herein was obtained from sources considered to be reliable. However, this information is provided without
any warranty, expressed or implied, regarding its correctness or suitability for consumers intended use and/or application. For this and
other reasons, we assume no responsibility and expressly disclaim liability for loss, damage or expense arising out of any way connected
with the handling, storage, use or disposal of the product. This MSDS was prepared expressly for this product. Use the materials only
as directed. If the product is used as a component of another product, the information contained within the MSDS may not be
applicable. If one could have any concerns with or problems understanding this MSDS form, please direct all questions to INFOTRAC,
Chemical Emergency Resources System at 1(800) 535-5053.
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