Material Safety Data Sheet
1. Product and company identification
Product name : 4856601 14-3-3 ProTurf FF II Turf Fertilizer with 15.4% Quintozene
Synonym : Fertilizer plus fungicide
Trade name : Not available.
Code :
Material uses : Agricultural industry: Fertilizer. Soil additive, pesticides, feed additive, etc.
Manufacturer : Agrium Advanced Technologies, Inc.
10 Craig St.
Brantford, ON N3R 7J1
Supplier : Agrium Advanced Technologies, Inc.
10 Craig St.
Brantford, ON N3R 7J1
For general Inquiries call 519-757-0077
Validation date : Validated by Company on 4/30/2009.
In case of emergency : Transportation: 1-800-792-8311
Medical: 1-888-670-8123
2. Hazards identification
Physical state : Solid.
Odor : Not available.
Emergency overview : CAUTION!
MAY BE HARMFUL IF SWALLOWED. CONTAINS MATERIAL THAT MAY CAUSE
TARGET ORGAN DAMAGE, BASED ON ANIMAL DATA.
May be harmful if swallowed. Avoid exposure - obtain special instructions before use.
Do not ingest. Avoid contact with eyes, skin and clothing. Contains material that may
cause target organ damage, based on animal data. Wash thoroughly after handling.
Routes of entry : Not available.
Potential acute health effects
Inhalation : Exposure to decomposition products may cause a health hazard. Serious effects may
be delayed following exposure.
Ingestion : Harmful if swallowed.
Skin : No known significant effects or critical hazards.
Eyes : No known significant effects or critical hazards.
Potential chronic health effects
Chronic effects : Contains material that may cause target organ damage, based on animal data.
Carcinogenicity : No known significant effects or critical hazards.
Mutagenicity : No known significant effects or critical hazards.
Teratogenicity : No known significant effects or critical hazards.
Developmental effects : No known significant effects or critical hazards.
Fertility effects : No known significant effects or critical hazards.
Target organs : Contains material which may cause damage to the following organs: gastrointestinal
tract, eyes.
Over-exposure signs/symptoms
Inhalation : No specific data.
Ingestion : No specific data.
Skin : No specific data.
Eyes : No specific data.
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4856601 14-3-3 ProTurf FF II Turf Fertilizer with 15.4% Quintozene
2. Hazards identification
Medical conditions : Pre-existing disorders involving any target organs mentioned in this MSDS as being at
risk may be aggravated by over-exposure to this product.
aggravated by over-
exposure
See toxicological information (section 11)
3. Composition/information on ingredients
Name CAS number %
quintozene (ISO) 82-68-8 15.4
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in
this section.
4. First aid measures
Eye contact : Check for and remove any contact lenses. Immediately flush eyes with plenty of water
for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical
attention immediately.
Skin contact : In case of contact, immediately flush skin with plenty of water for at least 15 minutes
while removing contaminated clothing and shoes. Wash clothing before reuse. Clean
shoes thoroughly before reuse. Get medical attention if irritation develops.
Inhalation : Move exposed person to fresh air. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel.
Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention
immediately.
Ingestion : Wash out mouth with water. Do not induce vomiting unless directed to do so by medical
personnel. Never give anything by mouth to an unconscious person. Get medical
attention immediately.
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. It may
be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Notes to physician : In case of inhalation of decomposition products in a fire, symptoms may be delayed.
The exposed person may need to be kept under medical surveillance for 48 hours.
5. Fire-fighting measures
Flammability of the product : No specific fire or explosion hazard.
Extinguishing media
Suitable : Use an extinguishing agent suitable for the surrounding fire.
Not suitable : None known.
Special exposure hazards : Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training.
Hazardous thermal : Decomposition products may include the following materials:
carbon dioxide
decomposition products
carbon monoxide
nitrogen oxides
phosphorus oxides
halogenated compounds
metal oxide/oxides
Special protective : Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
equipment for fire-fighters
Special remarks on fire : Not available.
hazards
Special remarks on : Not available.
explosion hazards
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4856601 14-3-3 ProTurf FF II Turf Fertilizer with 15.4% Quintozene
6. Accidental release measures
Personal precautions : No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Provide adequate ventilation.
Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal
protective equipment (see section 8).
Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
Methods for cleaning up
Small spill : Move containers from spill area. Vacuum or sweep up material and place in a
designated, labeled waste container. Dispose of via a licensed waste disposal
contractor.
Large spill : Move containers from spill area. Approach release from upwind. Prevent entry into
sewers, water courses, basements or confined areas. Vacuum or sweep up material
and place in a designated, labeled waste container. Dispose of via a licensed waste
disposal contractor. Note: see section 1 for emergency contact information and section
13 for waste disposal.
7. Handling and storage
Handling : Put on appropriate personal protective equipment (see section 8). Eating, drinking and
smoking should be prohibited in areas where this material is handled, stored and
processed. Workers should wash hands and face before eating, drinking and smoking.
Do not get in eyes or on skin or clothing. Do not ingest. If during normal use the
material presents a respiratory hazard, use only with adequate ventilation or wear
appropriate respirator. Keep in the original container or an approved alternative made
from a compatible material, kept tightly closed when not in use. Empty containers retain
product residue and can be hazardous. Do not reuse container.
Storage : Store in accordance with local regulations. Store in original container protected from
direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials
(see section 10) and food and drink. Keep container tightly closed and sealed until ready
for use. Containers that have been opened must be carefully resealed and kept upright
to prevent leakage. Do not store in unlabeled containers. Use appropriate containment
to avoid environmental contamination.
8. Exposure controls/personal protection
Canada
Occupational exposure limits TWA (8 hours) STEL (15 mins) Ceiling
Ingredient List name ppm mg/m?Other ppm mg/m?Other ppm mg/m?Other Notations
quintozene (ISO) US ACGIH 1/2008 - 0.5 - - - - - - -
AB 6/2008 - 0.5 - - - - - - -
BC 6/2008 - 0.5 - - - - - - -
ON 6/2008 - 0.5 - - - - - - -
QC 6/2008 - 0.5 - - - - - - -
Consult local authorities for acceptable exposure limits.
Recommended monitoring : If this product contains ingredients with exposure limits, personal, workplace atmosphere
or biological monitoring may be required to determine the effectiveness of the ventilation
procedures
or other control measures and/or the necessity to use respiratory protective equipment.
Engineering measures : If user operations generate dust, fumes, gas, vapor or mist, use process enclosures,
local exhaust ventilation or other engineering controls to keep worker exposure to
airborne contaminants below any recommended or statutory limits.
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4856601 14-3-3 ProTurf FF II Turf Fertilizer with 15.4% Quintozene
8. Exposure controls/personal protection
Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period. Appropriate
techniques should be used to remove potentially contaminated clothing. Wash
contaminated clothing before reusing. Ensure that eyewash stations and safety showers
are close to the workstation location.
Personal protection
Respiratory : Use a properly fitted, air-purifying or air-fed respirator complying with an approved
standard if a risk assessment indicates this is necessary. Respirator selection must be
based on known or anticipated exposure levels, the hazards of the product and the safe
working limits of the selected respirator.
Hands : Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary.
Eyes : Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists or
dusts.
Skin : Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before handling
this product.
Environmental exposure : Emissions from ventilation or work process equipment should be checked to ensure they
comply with the requirements of environmental protection legislation. In some cases,
controls
fume scrubbers, filters or engineering modifications to the process equipment will be
necessary to reduce emissions to acceptable levels.
Other protection : Not available.
Personal protective : Not available.
equipment (Pictograms)
9. Physical and chemical properties
Physical state : Solid.
Flash point : Not available.
Auto-ignition temperature : Not available.
Flammable limits : Not available.
Color : Not available.
Odor : Not available.
Taste : Not available.
Molecular weight : Not applicable.
Molecular formula : Not applicable.
pH : Not available.
Boiling/condensation point : Not available.
Melting/freezing point : Not available.
Critical temperature : Not available.
Relative density : Not available.
Vapor pressure : Not available.
Vapor density : Not available.
Volatility : Not available.
Odor threshold : Not available.
Evaporation rate : Not available.
VOC : Not available.
Viscosity : Not available.
Ionicity (in water) : Not available.
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4856601 14-3-3 ProTurf FF II Turf Fertilizer with 15.4% Quintozene
9. Physical and chemical properties
Dispersibility properties : Not available.
Solubility : Not available.
Physical/chemical : Not available.
properties comments
Bulk density : Not available.
10 . Stability and reactivity
Chemical stability : The product is stable.
Possibility of hazardous : Under normal conditions of storage and use, hazardous reactions will not occur.
reactions
Hazardous polymerization : Under normal conditions of storage and use, hazardous polymerization will not occur.
Conditions to avoid : No specific data.
Materials to avoid : No specific data.
Hazardous decomposition : Under normal conditions of storage and use, hazardous decomposition products should
not be produced.
products
Conditions of reactivity : Not available.
Not available.
11 . Toxicological information
Acute toxicity
Product/ingredient name Result Species Dose Exposure
quintozene (ISO) LD Dermal Rabbit >4 g/kg -
LD50 Oral Rat 1100 mg/kg -
LD50 Rat 5 g/kg -
Intraperitoneal
Conclusion/Summary : Not available.
Chronic toxicity
Product/ingredient name Result Species Dose Exposure
Not available.
Conclusion/Summary : Not available.
Irritation/Corrosion
Product/ingredient name Result Species Score Exposure Observation
Not available.
Conclusion/Summary : Not available.
Sensitizer
Product/ingredient name Route of Species Result
exposure
Not available.
Conclusion/Summary : Not available.
Carcinogenicity
Product/ingredient name Result Species Dose Exposure
Not available.
Conclusion/Summary : Not available.
Classification
Product/ingredient name ACGIH IARC EPA NIOSH NTP OSHA
quintozene (ISO) A4 3 - - - -
Mutagenicity
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4856601 14-3-3 ProTurf FF II Turf Fertilizer with 15.4% Quintozene
11 . Toxicological information
Product/ingredient name Test Experiment Result
Not available.
Conclusion/Summary : Not available.
Teratogenicity
Product/ingredient name Species Dose Exposure
Result
Not available.
Conclusion/Summary : Not available.
Reproductive toxicity
Product/ingredient name Maternal Fertility Development Species Dose Exposure
toxicity toxin
Not available.
Conclusion/Summary : Not available.
Synergistic products : Not available.
12 . Ecological information
Environmental effects : No known significant effects or critical hazards.
Aquatic ecotoxicity
Product/ingredient name Test Result Species Exposure
quintozene (ISO) - Acute EC50 0.77 Daphnia - Water 48 hours
to 1.1 ppm Fresh flea - Daphnia
water magna - LARVAE
- Acute LC50 1.6 to Fish - Rainbow 96 hours
2.3 ppm Fresh trout,donaldson
water trout -
Oncorhynchus
mykiss
- Acute LC50 1.5 to Fish - 96 hours
1.8 ppm Marine Sheepshead
water minnow -
Cyprinodon
variegatus -
Juvenile
(Fledgling,
Hatchling,
Weanling)
- Acute LC50 0.88 Fish - Bluegill - 96 hours
to 1.3 ppm Fresh Lepomis
water macrochirus
- Acute LC50 7.9 to Fish - 96 hours
18 ppm Marine Sheepshead
water minnow -
Cyprinodon
variegatus
- Acute LC50 0.75 Fish - Bluegill - 96 hours
to 0.97 ppm Lepomis
Fresh water macrochirus
- Acute LC50 0.55 Fish - Rainbow 96 hours
to 0.65 ppm trout,donaldson
Fresh water trout -
Oncorhynchus
mykiss
- Acute LC50 0.32 Fish - Rainbow 96 hours
to 0.37 ppm trout,donaldson
Fresh water trout -
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4856601 14-3-3 ProTurf FF II Turf Fertilizer with 15.4% Quintozene
12 . Ecological information
Oncorhynchus
mykiss
- Acute LC50 0.31 Fish - Rainbow 96 hours
to 0.44 ppm trout,donaldson
Fresh water trout -
Oncorhynchus
mykiss
- Acute LC50 0.24 Fish - Bluegill - 96 hours
to 0.58 ppm Lepomis
Fresh water macrochirus
- Acute LC50 0.1 to Fish - Bluegill - 96 hours
0.14 ppm Fresh Lepomis
water macrochirus
Conclusion/Summary : Not available.
Biodegradability
Product/ingredient name Test Result Dose Inoculum
Not available.
Conclusion/Summary : Not available.
Octanol/water partition : Not available.
coefficient
Bioconcentration factor : Not available.
Mobility : Not available.
Toxicity of the products of : Not available.
biodegradation
Other adverse effects : No known significant effects or critical hazards.
13 . Disposal considerations
Waste disposal : The generation of waste should be avoided or minimized wherever possible. Empty
containers or liners may retain some product residues. This material and its container
must be disposed of in a safe way. Dispose of surplus and non-recyclable products via
a licensed waste disposal contractor. Disposal of this product, solutions and any by-
products should at all times comply with the requirements of environmental protection
and waste disposal legislation and any regional local authority requirements. Avoid
dispersal of spilled material and runoff and contact with soil, waterways, drains and
sewers.
Waste stream : Not available.
RCRA classification : Not available.
Disposal should be in accordance with applicable regional, national and local laws and regulations.
Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
for additional handling information and protection of employees.
14 . Transport information
Regulatory UN number Proper shipping Classes PG* Label Additional
information name information
DOT Classification Not available. Not available. Not available. - -
TDG Classification Not available. Not available. Not available. - -
Mexico Not available. Not available. Not available. - -
Classification
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4856601 14-3-3 ProTurf FF II Turf Fertilizer with 15.4% Quintozene
14 . Transport information
PG* : Packing group
15 . Regulatory information
United States inventory : All components are listed or exempted.
(TSCA 8b)
WHMIS (Canada) : Not controlled under WHMIS (Canada).
Canadian lists : CEPA Toxic substances: None of the components are listed.
Canadian ARET: None of the components are listed.
Canadian NPRI: The following components are listed: Ammonia (total)
Alberta Designated Substances: None of the components are listed.
Ontario Designated Substances: None of the components are listed.
Quebec Designated Substances: None of the components are listed.
Canada inventory : At least one component is not listed in DSL but all such components are listed in NDSL.
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations
and the MSDS contains all the information required by the Controlled Products Regulations.
EU regulations
Hazard symbol or symbols :
Risk phrases : R43- May cause sensitization by skin contact.
R51/53- Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
Safety phrases : S2- Keep out of the reach of children.
S24- Avoid contact with skin.
S29- Do not empty into drains.
S37- Wear suitable gloves.
S46- If swallowed, seek medical advice immediately and show this container or label.
S61- Avoid release to the environment. Refer to special instructions/safety data sheet.
International regulations
International lists : Australia inventory (AICS): All components are listed or exempted.
China inventory (IECSC): All components are listed or exempted.
Japan inventory (ENCS): All components are listed or exempted.
Japan inventory (ISHL): Not determined.
Korea inventory (KECI): Not determined.
New Zealand Inventory of Chemicals (NZIoC): All components are listed or exempted.
Philippines inventory (PICCS): All components are listed or exempted.
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4856601 14-3-3 ProTurf FF II Turf Fertilizer with 15.4% Quintozene
15 . Regulatory information
Chemical Weapons : Not listed
Convention List Schedule I
Chemicals
Chemical Weapons : Not listed
Convention List Schedule
II Chemicals
Chemical Weapons : Not listed
Convention List Schedule
III Chemicals
16 . Other information
Label requirements : MAY BE HARMFUL IF SWALLOWED. CONTAINS MATERIAL THAT MAY CAUSE
TARGET ORGAN DAMAGE, BASED ON ANIMAL DATA.
Hazardous Material :
Information System (U.S.A.)
2
Health
0
Flammability
0
Physical hazards
Caution: HMIS?ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks Although HMIS?ratings are not required on MSDSs under 29 CFR
1910.1200, the preparer may choose to provide them. HMIS?ratings are to be used with a fully implemented
HMIS?program. HMIS?is a registered mark of the National Paint & Coatings Association (NPCA). HMIS?br>
materials may be purchased exclusively from J. J. Keller (800) 327-6868.
The customer is responsible for determining the PPE code for this material. Suggested protective clothing might
not be adequate. Consult a specialist before handling this product.
Other special : Not available.
considerations
References : Not available.
Date of issue : 4/30/2009.
Version :1
Indicates information that has changed from previously issued version.
Notice to reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above-named
supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the
information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present
unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot
guarantee that these are the only hazards that exist.
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