Page 1/4
Material Safety Data Sheet
According to 91/155 EC
Printing date 13.10.2003 Reviewed on 24.01.2003
1 Identification of substance:
?Product details:
?Trade name: IRM Liquid
?Application of the substance / the preparation Zinc eugenol cement
?Manufacturer/Supplier:
DENTSPLY DeTrey GmbH
De-Trey-Str. 1
D-78467 Konstanz
GERMANY
Tel.: +49-7531-583-0
Fax: +49-7531-583-104
?Further information obtainable from:
- Departement Analytical Research / Research & Development for technical information
- Departement Marketing & Sales for distribution of the safety data sheets
2 Composition/Data on components:
?Chemical characterization
?Description: Mixture of substances listed below with nonhazardous additions.
?Dangerous components:
CAS: 97-53-0 eugenol Xn; R 22 50-100%
EINECS: 202-589-1
?Additional information For the wording of the listed risk phrases refer to section 16.
3 Hazard identification
?Hazard description:
Xn Harmful
?Information concerning to particular hazards to man and environment
The product has to be labelled due to the calculation procedure of the "General Classification guideline for
preparations of the EU" in the latest valid version.
R 22 Harmful if swallowed.
?Classification system
The classification is according to the latest editions of the EU-lists, and extended by company and literature
data.
4 First aid measures
?After inhalation Supply fresh air; consult doctor in case of complaints.
?After skin contact Immediately wash with water and soap and rinse thoroughly.
?After eye contact
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
?After swallowing
Rinse out mouth and then drink plenty of water.
Induce vomiting and call for medical help.
5 Fire fighting measures
?Suitable extinguishing agents CO2, powder or water spray. Fight larger fire with alcohol resistant foam.
?Protective equipment: Wear self-contained respiratory protective device
6 Accidental release measures
?Person-related safety precautions:
Not required.
(Contd. on page 2)
GB
DR
Page 2/4
Material Safety Data Sheet
According to 91/155 EC
Printing date 13.10.2003 Reviewed on 24.01.2003
Trade name: IRM Liquid
(Contd. of page 1)
Wear protective clothing.
Ensure adequate ventilation
?Measures for environmental protection: Do not allow to enter sewers/ surface or ground water.
?Measures for cleaning/collecting:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose contaminated material as waste according to item 13.
7 Handling and storage
?Handling Product is intended for dental use only.
?Information for safe handling: Observe normal care for working with chemicals.
?Information about fire - and explosion protection: No special measures required.
?Storage
?Requirements to be met by storerooms and receptacles: Store only in the original receptacle.
?Information about storage in one common storage facility: Not required.
?Further information about storage conditions:
Keep receptacle tightly sealed.
Protect from heat and direct sunlight.
8 Exposure controls and personal protection gear
?Additional information about design of technical facilities: No further data; see item 7.
?Ingredients with limit values that require monitoring at the workplace:
The product does not contain any relevant quantities of materials with critical values that have to be
monitored at the workplace.
?Additional information: The lists valid during the making were used as basis.
?Personal protective equipment
?General protective and hygienic measures
The usual precautionary measures are to be adhered to when handling chemicals.
?Respiratory protection: Not necessary if room is well-ventilated.
?Protection of hands:
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/
the chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the
degradation
?Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality
and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the
resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the
application.
?Penetration time of glove material
The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be
observed.
?Eye protection: Safety glasses
?Body protection: Protective work clothing.
9 Physical and chemical properties:
?General Information
Liquid
Form:
Yellowish
Colour:
Characteristic
Odour:
?Change in condition
Melting point/Melting range: -10癈
(Contd. on page 3)
GB
DR
Page 3/4
Material Safety Data Sheet
According to 91/155 EC
Printing date 13.10.2003 Reviewed on 24.01.2003
Trade name: IRM Liquid
(Contd. of page 2)
Boiling point/Boiling range: 254癈
110癈
?Flash point:
Product is not selfigniting.
?Self-igniting:
Product does not present an explosion hazard.
?Danger of explosion:
1.06 g/cm?br>
?Density at 20癈:
?Solubility in / Miscibility with
Insoluble
Water:
10 Stability and reactivity
?Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.
?Dangerous reactions No dangerous reactions known
?Dangerous decomposition products: No dangerous decomposition products known
11 Toxicological information
?Acute toxicity:
?LD/LC50 values relevant for classification:
97-53-0 eugenol
Oral LD50 1930 mg/kg (rat)
?Primary irritant effect:
?on the skin: may cause skin irritation
?on the eye: Irritating effect.
?Sensitization: Sensitization possible through skin contact.
?Additional toxicological information:
Harmful
The product shows the following dangers according to the calculation method of the General EU
Classification Guidelines for Preparations as issued in the latest version.
12 Ecological information:
?General notes:
Water hazard class 1 (German Regulation) (Self-assessment): slightly hazardous for water.
Do not allow product to reach ground water, water course or sewage system.
13 Disposal considerations
?Product:
?Recommendation
Must not be disposed together with household garbage. Do not allow product to reach sewage
system.
?Uncleaned packaging:
?Recommendation: Disposal must be made according to official regulations.
GB
(Contd. on page 4)
DR
Page 4/4
Material Safety Data Sheet
According to 91/155 EC
Printing date 13.10.2003 Reviewed on 24.01.2003
Trade name: IRM Liquid
(Contd. of page 3)
14 Transport information
?Land transport ADR/RID (cross-border)
?ADR/RID class: -
?Maritime transport IMDG:
-
?IMDG Class:
?Marine pollutant: No
?Air transport ICAO-TI and IATA-DGR:
?ICAO/IATA Class: -
15 Regulations
?Labelling according to EU guidelines:
The product has been classified and marked in accordance with EU Directives / Ordinance on Hazardous
Materials
?Code letter and hazard designation of product:
Xn Harmful
?Hazard-determining components of labelling:
eugenol
?Risk phrases:
22 Harmful if swallowed.
?Safety phrases:
24/25 Avoid contact with skin and eyes.
36 Wear suitable protective clothing.
?National regulations
?Waterhazard class: Water hazard class 1 (Self-assessment): slightly hazardous for water.
16 Other information:
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
?Relevant R-phrases
22 Harmful if swallowed.
?Department issuing MSDS: Analytical Research
?Contact: HotLine for urgent technical support: +49-7531-583-333
GB
DR
Page 1/4
Material Safety Data Sheet
According to 91/155 EC
Printing date 13.10.2003 Reviewed on 13.12.2001
1 Identification of substance:
?Product details:
?Trade name: IRM Powder
?Application of the substance / the preparation Zinc eugenol cement
?Manufacturer/Supplier:
DENTSPLY DeTrey GmbH
De-Trey-Str. 1
D-78467 Konstanz
GERMANY
Tel.: +49-7531-583-0
Fax: +49-7531-583-104
?Further information obtainable from:
- Departement Analytical Research / Research & Development for technical information
- Departement Marketing & Sales for distribution of the safety data sheets
2 Composition/Data on components:
?Chemical characterization
?Description: Mixture of substances listed below with nonhazardous additions.
?Dangerous components:
CAS: 1314-13-2 zinc oxide N; R 50/53 50-100%
EINECS: 215-222-5
?Additional information For the wording of the listed risk phrases refer to section 16.
3 Hazard identification
?Hazard description:
N Dangerous for the environment
?Information concerning to particular hazards to man and environment
The product has to be labelled due to the calculation procedure of the "General Classification guideline for
preparations of the EU" in the latest valid version.
R 50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
?Classification system
The classification is according to the latest editions of the EU-lists, and extended by company and literature
data.
4 First aid measures
?After inhalation Supply fresh air; consult doctor in case of complaints.
?After skin contact Generally the product does not irritate the skin.
?After eye contact Rinse opened eye for several minutes under running water.
?After swallowing Void
5 Fire fighting measures
?Suitable extinguishing agents
CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
?Protective equipment: No special measures required.
6 Accidental release measures
?Person-related safety precautions:
Avoid formation of dust.
Wear protective clothing.
(Contd. on page 2)
GB
DR
Page 2/4
Material Safety Data Sheet
According to 91/155 EC
Printing date 13.10.2003 Reviewed on 13.12.2001
Trade name: IRM Powder
(Contd. of page 1)
?Measures for environmental protection:
Inform respective authorities in case of seepage into water course or sewage system.
?Measures for cleaning/collecting: Pick up mechanically.
7 Handling and storage
?Handling Product is intended for dental use only.
?Information for safe handling: Observe normal care for working with chemicals.
?Information about fire - and explosion protection: No special measures required.
?Storage
?Requirements to be met by storerooms and receptacles: Store only in the original receptacle.
?Information about storage in one common storage facility: Not required.
?Further information about storage conditions: None.
8 Exposure controls and personal protection gear
?Additional information about design of technical facilities: No further data; see item 7.
?Ingredients with limit values that require monitoring at the workplace:
1314-13-2 zinc oxide
OEL Short-term value: 10 mg/m3
Long-term value: 5 mg/m3
?Additional information: The lists valid during the making were used as basis.
?Personal protective equipment
?General protective and hygienic measures
The usual precautionary measures are to be adhered to when handling chemicals.
?Respiratory protection: Not necessary if room is well-ventilated.
?Protection of hands:
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/
the chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the
degradation
?Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality
and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the
resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the
application.
?Penetration time of glove material
The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be
observed.
?Eye protection: Not required.
?Body protection: Protective work clothing.
9 Physical and chemical properties:
?General Information
Powder
Form:
White
Colour:
Odourless
Odour:
?Change in condition
Melting point/Melting range: undetermined
Boiling point/Boiling range: undetermined
Not applicable
?Flash point:
(Contd. on page 3)
GB
DR
Page 3/4
Material Safety Data Sheet
According to 91/155 EC
Printing date 13.10.2003 Reviewed on 13.12.2001
Trade name: IRM Powder
(Contd. of page 2)
Product is not selfigniting.
?Self-igniting:
Product does not present an explosion hazard.
?Danger of explosion:
Not determined
?Density:
?Solubility in / Miscibility with
Insoluble
Water:
10 Stability and reactivity
?Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.
?Dangerous reactions No dangerous reactions known
?Dangerous decomposition products: No dangerous decomposition products known
11 Toxicological information
?Acute toxicity:
?Primary irritant effect:
?on the skin: No irritant effect.
?on the eye: No irritating effect.
?Sensitization: No sensitizing effects known.
12 Ecological information:
?Ecotoxical effects:
?Remark: Very toxic for fish
?General notes:
Water hazard class 2 (German Regulation) (Self-assessment): hazardous for water.
Also poisonous for fish and plankton in water bodies.
Very toxic for aquatic organisms
13 Disposal considerations
?Product:
?Recommendation
Must not be disposed together with household garbage. Do not allow product to reach sewage
system.
?Uncleaned packaging:
?Recommendation: Disposal must be made according to official regulations.
14 Transport information
?Land transport ADR/RID (cross-border)
9 (M7) Miscellaneous dangerous substances and articles.
?ADR/RID class:
?Danger code (Kemler): 90
3077
?UN-Number:
III
?Packaging group:
(Contd. on page 4)
GB
DR
Page 4/4
Material Safety Data Sheet
According to 91/155 EC
Printing date 13.10.2003 Reviewed on 13.12.2001
Trade name: IRM Powder
(Contd. of page 3)
9
?Hazard label
?Maritime transport IMDG:
9
?IMDG Class:
3077
?UN Number:
9
?Label
III
?Packaging group:
F-A,S-F
?EMS Number:
Yes
?Marine pollutant:
?Proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (zinc oxide)
?Air transport ICAO-TI and IATA-DGR:
9
?ICAO/IATA Class:
3077
?UN/ID Number:
9
?Label
III
?Packaging group:
?Proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (zinc oxide)
15 Regulations
?Labelling according to EU guidelines:
The product has been classified and marked in accordance with EU Directives / Ordinance on Hazardous
Materials
?Code letter and hazard designation of product:
N Dangerous for the environment
?Risk phrases:
50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
?Safety phrases:
57 Use appropriate container to avoid environmental contamination.
60 This material and its container must be disposed of as hazardous waste.
?National regulations
?Waterhazard class: Water hazard class 2 (Self-assessment): hazardous for water.
16 Other information:
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
?Relevant R-phrases
50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
?Department issuing MSDS: Analytical Research
?Contact: HotLine for urgent technical support: +49-7531-583-333
GB
DR
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