Ethylene Acrylic Rubber 'Final' 30-june-2006
MATERIAL SAFETY DATA SHEET
1 PRODUCT AND COMPANY IDENTIFICATION
Product Name: Ethylene Acrylic Rubber 'Final'
Product No.: L-068, L-069, L-085, L-090, K-007, R10600, R10601
Manufacturer Name: Emergency Telephone:
Federal Mogul Corporation, Indiana Medical Emergency (24HR): 1-800-56 SPILL
2845 West State Road 28 (800-567-7455)
Frankfort, Indiana 46041 Transport ER Ph. (outside NA): 703-527-3887
Telephone Number: (765) 654-8761 (Accepts collect calls)
Non-emergency Telephone:
General Information: 248-354-9844
Intended Use: Rubber
2 HAZARDS IDENTIFICATION
Emergency Overview
Physical State: Solid rubber
Color: Black
Odor: Acrylic
WARNING!
May cause allergic skin reaction. May cause adverse reproductive effects - such as birth defects,
miscarriages, or infertility. Cancer hazard - can cause cancer. Rubber compounds generally do not pose a
health hazard unless heated. Under normal conditions of processing and use, exposure to the chemical
constituents in this product is unlikely. All ingredients are tightly bound in a polymeric matrix that has a
negligible vapor pressure so there is a low potential for inhalation or ingestion of ingredients. Skin (dermal)
contact is possible.
Potential Health Effects
Inhalation: Grinding and sanding this product may generate dust. Dust may irritate throat and respiratory
system and cause coughing. Lower concentrations of fumes from burning this material may cause
respiratory irritation with coughing, difficulty in breathing, or shortness of breath. High concentrations
may cause severe irritation, pulmonary edema (body fluid in the lungs) with coughing, wheezing, and
abnormal lung sounds. Symptoms may progress to severe shortness of breath, central nervous system
effects, and collapse. Symptoms may be delayed and progressively worsen.
Eye Contact: Grinding and sanding this product may generate dust. Dust may irritate the eyes.
Decomposition products may cause eye irritation. Contact with hot material can cause thermal burns which
may result in permanent damage.
Skin Contact: May cause sensitization by skin contact. Prolonged or repeated skin contact may cause
irritation. Individuals sensitive to small amounts of curing agents present may develop a rash (dermatitis).
NA ENGLISH MSDS 1 /8
Ethylene Acrylic Rubber 'Final' 30-june-2006
Contact with hot material can cause thermal burns which may result in permanent damage.
Ingestion: No adverse effects due to ingestion are expected.
Chronic Health Effects: Danger of adverse health effects by prolonged exposure. May impair fertility.
Cancer hazard - can cause cancer. Carbon black has caused cancer in experimental animals. Crystalline
silica has been classified by IARC as a known human carcinogen. These ingredients are bound within the
rubber and release is not expected.
Target Organ(s): | Reproductive system | Skin |
Potential Physical / Chemical Effects: This product is not flammable.
OSHA Regulatory Status: Under some use conditions, this material may be considered to be hazardous in
accordance with OSHA 29 CFR 1910.1200. When used for its intended purpose, this material is classified
as hazardous in accordance with OSHA 29CFR 1910.1200.
Environment: The environmental hazard of the product is considered to be limited.
3 COMPOSITION / INFORMATION ON INGREDIENTS
Concentration*
Chemical Name CAS-No.
Ethylene/methyl acrylate copolymer None < 55%
Carbon black 1333-86-4 < 41%
Graphite 7782-42-5 < 12%
Ester/Ester plasticizer Mixture < 9%
Di-ortho-tolylguanidine 97-39-2 < 2%
4,4'-Di(a,a-dimethylbenzyl) diphenylamine 10081-67-1 < 1%
Polyethylene glycol 25322-68-3 < 1%
Sorbitan monostearate None < 1%
1,3-Diphenylguanidine 102-06-7 < 1%
Crystalline silica, quartz 14808-60-7 < 1%
* All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume. This
chemical is hazardous according to OSHA/WHMIS criteria.
4 FIRST AID MEASURES
General: For contact with hot polymer: Flush eyes with lukewarm water for at least 15 minutes.
Immerse skin in cool water. DO NOT attempt to remove polymer from skin as this can cause further
damage. Get immediate medical attention. Prompt medical attention is required if decomposition products
are inhaled.
Inhalation: If fumes from heated product are inhaled: Move into fresh air and keep at rest. Move the
exposed person to fresh air at once. For breathing difficulties oxygen may be necessary. If breathing stops,
provide artificial respiration. Consult a physician for specific advice.
Eye Contact: Dust in the eyes: Flush eyes thoroughly with water, taking care to rinse under eyelids. If
irritation persists, continue flushing for 15 minutes, rinsing from time to time under eyelids. If discomfort
continues, consult a physician.
NA ENGLISH MSDS 2 /8
Ethylene Acrylic Rubber 'Final' 30-june-2006
Skin Contact: Remove contaminated clothing immediately and wash skin with soap and water. If skin
irritation or an allergic skin reaction develops, get medical attention.
Ingestion: Rinse mouth thoroughly. Drink plenty of water. Get medical attention if symptoms occur.
5 FIRE-FIGHTING MEASURES
Extinguishing Media: This product is not flammable. Use fire-extinguishing media appropriate for
surrounding materials.
Unsuitable Extinguishing Media: Not applicable.
Special Fire Fighting Procedures: Use standard firefighting procedures and consider the hazards of other
involved materials.
Unusual Fire & Explosion Hazards: The product is non-combustible. If heated, toxic vapors may be
formed. Burning this material, or exposing it to temperatures above 300 癈 may result in the release of
irritating fumes.
Hazardous Combustion Products: Ammonia, Carbon Dioxide, Carbon Monoxide, Hydrogen Chloride,
Nitrogen Oxides
Protective Measures: Self contained breathing apparatus and full protective clothing must be worn in case
of fire.
6 ACCIDENTAL RELEASE MEASURES
Personal Precautions: Avoid contact with skin. Wear necessary protective equipment. See Section 8 of
the MSDS for Personal Protective Equipment.
Spill Cleanup Methods: Shovel up and place in a container for salvage or disposal. For waste disposal,
see section 13 of the MSDS.
Environmental Precautions: No specific precautions.
7 HANDLING AND STORAGE
Handling: All handling to take place in well-ventilated area. Avoid inhalation of dust and contact with
skin and eyes. Wear protective gloves and appropriate clothing to prevent skin contact. Do not breathe
fumes produced at elevated temperatures. Periodically clean work and storage areas to prevent dust
accumulation. Observe good industrial hygiene practices.
Storage: Store in a cool, dry place out of direct sunlight. Keep containers tightly closed to prevent
moisture absorption and contamination.
8 EXPOSURE CONTROLS / PERSONAL PROTECTION
Exposure Limits:
Chemical Name Source Type Exposure Limits Notes
Carbon black ACGIH TWA 3.5 mg/m?br>
NA ENGLISH MSDS 3 /8
Ethylene Acrylic Rubber 'Final' 30-june-2006
Carbon black NIOSH Guide Concentration 1750 mg/m?br>
Carbon black US. OSHA Table TWA 3.5 mg/m?br>
Z-1
Crystalline silica, quartz ACGIH TWA 0.05 mg/m?br>
(Respirable fraction.)
Crystalline silica, quartz NIOSH Guide Concentration 50 mg/m?br>
Crystalline silica, quartz (Total OSHA Z3 OSHA Z3 0.3 mg/m?br>
dust.) (TWA)
Crystalline silica, quartz OSHA Z3 TWA 15 Mppcf 5 mg/m?br>
(Respirable fraction.)
Crystalline silica, quartz (Total OSHA Z3 TWA 50 Mppcf 15 mg/m?br>
dust.)
Crystalline silica, quartz OSHA Z3 TWAC 0.1 mg/m?2.4 Mppcf
(Respirable.)
Crystalline silica, quartz US. OSHA Table TWA 5 mg/m?br>
(Respirable fraction.) Z-1
Crystalline silica, quartz (Total US. OSHA Table TWA 15 mg/m?br>
dust.) Z-1
Graphite (Respirable fraction.) ACGIH TWA 2 mg/m?br>
Graphite NIOSH Guide Concentration 1250 mg/m?br>
Graphite OSHA Z3 TWA 15 Mppcf
Graphite (Respirable fraction.) US. OSHA Table TWA 5 mg/m?br>
Z-1
Engineering Controls: Provide adequate ventilation. If dust or fumes are generated during use, use local
exhaust in combination with general ventilation as necessary to remove fumes/dust from the workers'
breathing zone and to ensure exposures do not exceed applicable limits.
Respiratory Protection: No protection is ordinarily required under normal conditions of use and with
adequate ventilation. During dust-raising work or inhalation of hot/molten material: Use a
NIOSH-approved respirator (See 29 CRF 1910.134, respiratory protection standard).
Eye Protection: If contact with hot material may occur, safety glasses and face shield are recommended.
Hand Protection: Wear suitable gloves. When material is heated, wear gloves to protect against thermal
burns.
Skin Protection: It is a good industrial hygiene practice to minimize skin contact. Thermally protective,
chemical resistant apron and long sleeves are recommended when volume of hot material is significant.
Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the
material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective
equipment to remove contaminants.
9 PHYSICAL AND CHEMICAL PROPERTIES
Color: Black
Odor: Acrylic
Odor Threshold: No data available.
Physical State: Solid rubber
pH: Not applicable
Melting Point: No data available.
NA ENGLISH MSDS 4 /8
Ethylene Acrylic Rubber 'Final' 30-june-2006
Freezing Point: No data available.
Boiling Point: Not applicable.
Flash Point: Not applicable.
Evaporation Rate: Not applicable.
Flammability (Solid): No data available.
Flammability Limit - Upper (%): Not applicable.
Flammability Limit - Lower (%): Not applicable.
Vapor Pressure: Not applicable.
Vapor Density (Air=1): Not applicable.
Specific Gravity: 1.1 - 1.2
Solubility in Water: Insoluble
Solubility (Other): Not applicable.
Partition Coefficient (n-Octanol/water): Not applicable.
Autoignition Temperature: Not applicable.
Decomposition Temperature: No data available.
Explosive Properties: No data available
10 STABILITY AND REACTIVITY
Stability: Stable under normal temperature conditions and recommended use.
Conditions to Avoid: Oxidizing agents
Incompatible Materials: In general, elastomers are incompatible with: Strong oxidizing agents.
Reducing agents.
Hazardous Decomposition Products:
At Elevated Temperatures: Alcohols, Aldehydes, Aliphatic Hydrocarbons,
Ammonia, Aromatic Hydrocarbons, Carbon Dioxide,
Carbon Monoxide, Carboxylic acids, Ethyl acrylate,
Hydrogen Chloride, Ketones, Methyl acrylate, Nitric
oxide, Nitrogen Oxides
Possibility of Hazardous Reactions: Will not occur. The product is fully polymerized.
11 TOXICOLOGICAL INFORMATION
Specified Substance(s)
Acute Toxicity:
Component Chemical Name Test Results
1,3-Diphenylguanidine Dermal LD50 (Rabbit): 794 mg/kg
1,3-Diphenylguanidine Oral LD50 (Rat): 323 mg/kg
Carbon black Dermal LD50 (Rabbit): > 3000 mg/kg
Carbon black Oral LD50 (Rat): > 15400 mg/kg
Di-ortho-tolylguanidine Oral LD50 (Rat): 500 mg/kg
Listed Carcinogens: The rubber industry is listed as an exposure circumstance that is known to be
carcinogenic to humans (Group 1). IARC, NTP, or OSHA list some of the thermal decomposition products
that may be produced at elevated temperatures as confirmed human carcinogens. Carbon black: Certain
carbon blacks have proved carcinogenic in animal studies. Inhalation animal studies of high concentrations
NA ENGLISH MSDS 5 /8
Ethylene Acrylic Rubber 'Final' 30-june-2006
resulted in chronic inflammation, lung fibrosis and lung tumors. Epidemiology studies of workers include
findings of bronchitis, pneumonia, emphysema and excess cancer. Crystalline silica, as respirable dust
particles, has caused pulmonary fibrosis in laboratory animals and humans. Crystalline silica has been
classified by IARC as a known human carcinogen. Substances bound in a polymer or other matrix should
present little or no hazard.
Chemical Name IARC NTP OSHA ACGIH
Carbon black 2B Not Listed Not Listed Not Listed
Crystalline silica, quartz 1 Listed Not Listed A2
IARC: 1 = Carcinogenic to Humans; 2A = Probably Carcinogenic to Humans; 2B = Possibly Carcinogenic to Humans. Not listed
= Either Group 3 (Not classifiable as to carcinogenicity to humans), Group 4 (Probably not carcinogenic to humans), or not
evaluated by IARC.
ACGIH: A1 = Confirmed Human Carcinogen; A2 = Suspected Human Carcinogen; A3 = Confirmed Animal Carcinogen. Not
listed = Either A4 (Not classifiable as a human carcinogen), A5 (Not suspected to be a human carcinogen), or not evaluated by
ACGIH.
Product Information
Other Acute: The principal components used in this product have been reacted and are no longer present
in their original form. The finished polymerized product is an inert polyacrylic rubber, and exposure to the
original constituents would not be expected under normal conditions. Like most high-molecular weight
polymers, this product is not known to exhibit any adverse acute or chronic health effects. Burning this
material or exposing it to temperatures in excess of 300 癈 can generate irritating and toxic fumes. The type
of compounds generated depends upon temperature and conditions. Health effects from these fumes can
range from transient to severe eye, skin and respiratory rritation, pulmonary edema, headache, nausea,
drowsiness as well as a variety of other effects. Some decomposition products are toxic if absorbed through
the skin in sufficient quantities. Grinding and sanding this product may generate dust. Dusts may irritate
the respiratory tract, skin and eyes. Repeated exposure to high concentrations of dust may adversely affect
the lungs. Dust inhalation can also inhibit the clearance of toxic particles from the lung by decreasing the
mobility of alveolar macrophages.
Chronic Toxicity: May cause allergic skin reaction. May impair fertility. Cancer hazard. Can cause
cancer.
12 ECOLOGICAL INFORMATION
Ecotoxicity: Acute aquatic toxicity information.
Specified Substance(s)
Chemical Name Test
1,3-Diphenylguanidine LC50 (96 hour(s), Oncorhynchus mykiss): 11 mg/l
1,3-Diphenylguanidine LC50 (96 hour(s), Fathead Minnow): 4.2 mg/l
1,3-Diphenylguanidine LC50 (96 hour(s), Bluegill Sunfish): 9.6 mg/l
Carbon black EC50 (24 hour(s), Daphnia magna): >5600 mg/l
Carbon black EC50 (72 hour(s), Green Alga): >10000 mg/l
Carbon black LC50 (96 hour(s), Zebra Fish): >1000 mg/l
Mobility: The product is non-volatile. The product is insoluble in water.
Persistence and Degradability: No data available
Bioaccumulation Potential: No data available on bioaccumulation.
NA ENGLISH MSDS 6 /8
Ethylene Acrylic Rubber 'Final' 30-june-2006
13 DISPOSAL CONSIDERATIONS
General Information: Dispose of waste and residues in accordance with local authority requirements.
Disposal Methods: No specific disposal method required.
Container: Since emptied containers retain product residue, follow label warnings even after container is
emptied.
14 TRANSPORT INFORMATION
DOT Not Regulated
TDG Not Regulated
IATA Not Regulated
IMDG Not Regulated
15 REGULATORY INFORMATION
Canadian Controlled Products Regulations: This product has been classified according to the hazard
criteria of the Canadian Controlled Products Regulations, Section 33, and the MSDS contains all required
information.
WHMIS Classification: D2A, D2B
Mexican Dangerous Statement: This is a Mexican "dangerous" product.
Inventory Status: All ingredients are either listed or exempt from listing on EINECS, DSL or TSCA.
US Regulations
CERCLA Hazardous Substance List (40 CFR 302.4): None
SARA Title III
Section 302 Extremely Hazardous Substances (40 CFR 355, Appendix A): None
Section 311/312 (40 CFR 370):
X Acute (Immediate) X Chronic (Delayed) Fire Reactive Pressure Generating
Section 313 Toxic Release Inventory (40 CFR 372):
Chemical Name CAS-No. Concentration
Ester/Ester plasticizer Mixture < 9%
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130): None
Clean Water Act Section 311 Hazardous Substances (40 CFR 117.3): None
Drug Enforcement Act: None
NA ENGLISH MSDS 7 /8
Ethylene Acrylic Rubber 'Final' 30-june-2006
TSCA: No component is listed on TSCA Sections 4(a), 5(a)(2), 5(e) or 12(b).
State Regulations
California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): Carbon black;
Crystalline silica, quartz
Massachusetts Right-To-Know List: Carbon black; Crystalline silica, quartz; Graphite
Michigan Critical Materials List (Michigan Natural Resources and Environmental Protection Act
(Act. 451 of 1994)): None
Minnesota Hazardous Substances List: Carbon black; Graphite
New Jersey Right-To-Know List: Carbon black; Ester/Ester plasticizer
Pennsylvania Right-To-Know List: Carbon black; Ester/Ester plasticizer; Graphite
Rhode Island Right-To-Know List: Carbon black; Graphite
16 OTHER INFORMATION
HAZARD RATINGS
Health Hazard Fire Hazard Reactivity Hazard Special Hazard
1 1 0 --
NFPA
Health Hazard Fire Hazard Reactivity Hazard Personal Protection
1* 1 0 B
HMIS
0 - Minimal; 1- Slight; 2 - Moderate; 3 - Serious; 4 - Severe *- Chronic Health Effect
B - Safety Glasses & Gloves
Issue Date: 30-June-2006
Supercedes Date: 30-June-2006
SDS No.: 1003424
Disclaimer: The information provided on this data sheet was abstracted from supplier material safety data
sheets and standard references in occupational health and toxicology. Federal-Mogul makes no
representation or warranty with respect to the information obtained from such references. The information
is however, as of the date provided, true and accurate to the best of Federal-Mogul's knowledge, and should
be used to make an independent determination of the methods to safeguard workers and the environment.
NA ENGLISH MSDS 8 /8
|