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MSDS Material Safety Data Sheet
CAS

25068-39-6 120547-52-6 111-40-0 80-05-7

File Name: 25068-39-6_120547-52-6_111-40-0_80-05.asp

AB Slurry Broadcast Resin Part A                                                                  Page 1 of 4




MATERIAL SAFETY DATA SHEET
Distributed by:
INDUSTRIAL PROTECTIVE COATINGS, INC.
1855 ENTERPRISE DRIVE, DEPERE, WI 54115 (920) 336-0801
24 HOUR EMERGENCY ASSISTANCE: CHEMTREC 1-800-424-9300

Acute Health Fire Reactivity Hazard Rating: Least-0, Slight-1, Moderate-2, High-3,
2 1 0 Extreme-4.
For acute chronic health effects, refer to the discussion in Section III.

SECTION I
Product: ANCHOR BOND SLURRY BROADCAST RESIN PART A
Chemical Name: Modified Bisphenol A/Epichlorohydrin Resin
Chemical Family: Epoxy Resin

SECTION IIA PRODUCT/INGREDIENT

No. Composition CAS Number Percent
P Anchor Bond Resin Mixture 100
1 Bisphenol A/Epichlorohydrin Resin 25068-39-6 70-90
2 Aliphatic Polyglycidyl Ether 120547-52-6 1-20

SECTION IIB ACUTE TOXICITY DATA

No. Acute Oral LD50 Acute Dermal LD50 Acute Inhalation LC50
P Not available
1 11.4 g/kg (Rat) >20 ml/kg (Rabbit) No deaths sat'd air 4 Hr
2 >10 g/kg (Rat) >2.0 g/kg (Rat)

SECTION III HEALTH INFORMATION

The health effects noted below are consistent with requirements under the OSHA hazard communication
standard (29 CFR 1910.1200).

EYE CONTACT: Based on presence of component #2, product is presumed to be irritating to the eyes.

SKIN CONTACT: Based on presence of components #1 and #2, product is presumed to be moderately
irritating to the skin. Based on presence of components #1 and #2, product is presumed to cause skin
sensitization. Prolonged or repeated liquid contact can result in defatting and drying of the skin which may
result in skin and dermatitis.

INHALATION: Based on presence of component #2, product is presumed to cause irritation to the nose,
throat, and respiratory tract.

INGESTION: Product is moderately toxic and maybe harmful is swallowed.

SIGNS AND SYMPTOMS: Irritation as noted above. Skin sensitization (allergy) may be evidenced by
rashes especially hives.
AB Slurry Broadcast Resin Part A Page 2 of 4



AGGRAVATED MEDICAL CONDITIONS: Preexisting eye, skin, and respiratory disorders may be
aggravated by exposure to this product. Preexisting skin or lung allergies may increase the chance of
developing increased allergy symptoms from exposure to this product.

OTHER HEALTH EFFECTS: None identified.

SECTION IV OCCUPATIONAL EXPOSURE LIMITS

OSHA ACGIH OTHER
No. PEL/TWA PEL Ceiling TLV/TWA TLV/STEL
P None established
1 None established
2 None established

SECTION V EMERGENCY AND FIRST AID PROCEDURES

EYE CONTACT: Flush eyes with plenty of water for 15 minutes while holding eyelids open. Get medical
attention.

SKIN CONTACT: Remove contaminated clothing/shoes and wipe excess from skin. Flush skin with water.
Follow by washing with soap and water. If irritation occurs, get medical attention. Do not reuse clothing
until cleaned. Contaminated leather articles; including shoes, cannot be decontaminated and should be
destroyed.

INHALATION: Remove victim to fresh air and provide oxygen if breathing is difficult. Give artificial
respiration if not breathing. Get medical attention.

INGESTION: Do not give liquids if victim is unconscious or very drowsy. Otherwise, give no more than 2
glasses of water and induce vomiting by giving 30cc (2 tablespoons) syrup of ipecac. If ipecac is
unavailable, give 2 glasses of water and induce vomiting by touching finger to back of victim's throat.
Keep victim's head below hips while vomiting. Get medical attention.

NOTE TO PHYSICIAN: If symptoms such as loss of gag reflex, convulsions, or unconsciousness occur
before emesis, gastric lavage should be considered following intubation with a cuffed endotracheal tube.

SECTION VI SUPPLEMENTAL HEALTH INFORMATION

NOTE: This product contains trace (<62 ppm, typical) residual quantities of epichlorohydrin (ECH), CAS
No. 104-???. It is very unlikely that normal work practice with this product could result in atmospheric
ECH concentrations approaching the OSHA limit. Nevertheless, you should be aware that ECH has been
reported to produce cancer in laboratory animals and to produce mutagenic changes in bacteria and cultured
human cells. The International Agency for Research on Cancer (IARC) states that the evidence that ECH
causes cancer in humans is inadequate.
Component #1: Although the significance is unknown, component # 1 has been shown to be mutagenic in some microbial tests, but
has failed to show mutagenicity in others. Chromosome aberrations were observed in cultured rat liver cells.

SECTION VII PHYSICAL DATA

Boiling Point: Not available Specific Gravity: 1.125 Vapor Pressure: <3
(Deg. F) (H20 =1) (n=hg))
Melting Point: Not available Solubility: Slight Vapor Density: >1
(Deg. F) (in water) (air=1)
Evaporation Rate: Not available
(n-Butyl Acetate=1)
AB Slurry Broadcast Resin Part A Page 3 of 4



APPEARANCE AND ODOR: Light yellow liquid.

SECTION VIII FIRE AND EXPLOSION HAZARDS

Flash point and method: Flammable Limits % volume in air
>310癋 (setaflash) lowest component Lower: N/AV Upper: N/AV

EXTINGUISHING MEDIA: Use water fog, foam, dry chemical, or C02.

SPECIAL FIRE FIGHTING PROCEDURES AND PRECAUTIONS: Material will not burn unless
preheated. Do not enter confined fire space without full bunker (helmet with face shield, bunker coats,
gloves, and rubber boots), including a positive pressure NIOSH-approved self-contained breathing
apparatus. Cool fire-exposed contains with water.

UNUSUAL FIRE AND EXPLOSION HAZARDS: No unusual hazards.

SECTION IX REACTIVITY

Stability: Stable Hazardous Polymerization: Will not occur

CONDITIONS AND MATERIAL TO AVOID: Can react vigorously with strong oxidizing agents and
strong levels of mineral acids. Reaction many curing agents give considerable heat release.

HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide, aldehydes, and acids may be formed
during combustion. Reacting curing agents give considerable heat release.

SECTION X EMPLOYEE PROTECTION

RESPIRATORY PROTECTION: Avoid breathing vapor or mists. If exposure may or does exceed
occupational exposure limits (see IV), use a NIOSH-approved respirator to prevent overexposure. In
accord with 29 CFR 1910.134 use either an atmosphere-supplying respirator or an air-purifying respirator
for organic vapors.

PROTECTIVE CLOTHING: Avoid contact with eyes. Wear chemical goggles if there is likelihood of
contact with eyes. Avoid prolonged or repeated contact with skin. Wear chemical-resistant gloves and other
clothing as required to minimize contact.

ADDITIONAL PROTECTIVE MEASURES: Use ventilation as required to control vapor concentrations.
Eye wash fountains and safety showers should be available for emergency use.

SECTION XI ENVIRONMENTAL PROTECTION

SPILL OR LEAK PROCEDURES: May burn although not readily ignitable. Use cautious judgment when
cleaning up large spills. Large spills -Wear respirator and protective clothing as appropriate. Shut off
source of leak if safe to do so. Dike and contain. Remove with vacuum trucks or pump to storage/salvage
vessels. Soak up residue with an absorbent such as clay, sand, or other suitable material. Dispose of
property. Flush area with water to remove trace residue. Small spills ?Take up with an absorbent material
and dispose of properly.

WASTE DISPOSAL: Place in an appropriate disposal facility in compliance with local regulations.

ENVIRONMENTAL HAZARDS: Keep out of surface waters, sewers, and waterways entering or leading
to surface waters. Notify authorities if any exposure to the general public or environment occurs or is likely
to occur.
AB Slurry Broadcast Resin Part A Page 4 of 4




SECTION XII SPECIAL PRECAUTIONS

Store in a cool dry place with adequate ventilation. Keep away from open flames and high temperatures.
Handle in accordance with the potential hazard of the curing agent used. Containers, even those that have
been emptied, can contain hazardous product residues.

Warning, Potential sensitizer. Minimize all contact with material. Wash with soap and water before eating,
drinking, smoking or using toilet facilities. Launder contaminated clothing before reuse. Contaminated
leather articles, including shoes cannot be decontaminated and should be destroyed.

SECTION XIII TRANSPORTATION REQUIREMENTS

DEPARTMENT OF TRANSPORTATION CLASSIFICATION: Not hazardous by D.O.T. Regulations.
D.O.T. PROPER SHIPPING NAME: Not Regulated.

SECTION XIV OTHER REGULATORY CONTROLS

The components of this product are listed on the EPA/TSCA inventory of chemical substances.

The information contained herein is based on the data available to us and is believed to be correct.
However, Industrial Protective Coatings, Inc. makes no warranty, expressed or implied regarding the
accuracy of these data or results to be obtained from the use thereof. Industrial Protective Coatings, Inc.
assumes no responsibility for injury from use of the product described herein.

Date prepared: 3/18/98
Revised date: 01/01/08
AB Slurry Broadcast Hardener Part B Page 1 of 5




MATERIAL SAFETY DATA SHEET
Distributed by:
INDUSTRIAL PROTECTIVE COATINGS, INC.
1855 ENTERPRISE DRIVE, DEPERE, WI 54115 (920) 336-0801
24 HOUR EMERGENCY ASSISTANCE: CHEMTREC 1-800-424-9300

Acute Health Fire Reactivity Hazard Rating: Least-0, Slight-1, Moderate-2, High-3,
3 1 0 Extreme-4.
For acute chronic health effects, refer to the discussion in Section III.

SECTION I
Product: ANCHOR BOND SLURRY BROADCAST HARDENER PART B
Chemical Name: Mixture
Chemical Family: Aliphatic Amine

SECTION IIA PRODUCT/INGREDIENT

No. Composition CAS Number Percent
P Anchor Bond Flooring Hardener Mixture 100
1 Diethylenetriamine (DETA) 111-40-0 >50
2 Bisphenol A 80-05-7 <50

SECTION IIB ACUTE TOXICITY DATA

No. Acute Oral LD50 Acute Dermal LD50 Acute Inhalation LC50
P Not available
1 2.33 g/kg (Rat) 1.09 ml/kg (Rabbit) >300 ppm/8H (Rat)
2 4.2 g/kg (Rat) 3.0 g/kg (Rabbit) Data Not Available

SECTION III HEALTH INFORMATION

The health effects noted below are consistent with requirements under the OSHA hazard communication
standard (29 CFR 1910.1200).

EYE CONTACT: Corrosive to the eyes and may cause severe damage including blindness. Vapors may be
irritating.

SKIN CONTACT: Corrosive to the skin. May cause skin sensitization. May be toxic if absorbed.

INHALATION: Vapors/Mists may be corrosive to upper respiratory tract. Repeated exposure can result in
lung damage. May be moderately toxic if inhaled. May cause central nervous system (CNS) depression.

INGESTION: Not expected to be a relevant route of exposure. However, corrosive and may cause severe
and permanent damage to mouth, throat and stomach. May be moderately toxic if swallowed.

SIGNS AND SYMPTOMS: Irritation as noted above. Lung damage (Scarring, Bronchitis, Emphysema)
may be evidenced by shortness of breath, especially on exertion, and may be accompanied by chronic
cough. Skin sensitization (Allergy) may be evidenced by rashes, especially hives.

AGGRAVATED MEDICAL CONDITIONS: Preexisting eye, skin, and respiratory disorders may be
aggravated by exposure to this product.
AB Slurry Broadcast Hardener Part B Page 2 of 5



OTHER HEALTH EFFECTS: See Section VI for supplemental health information.

SECTION IV OCCUPATIONAL EXPOSURE LIMITS

OSHA ACGIH OTHER
No. PEL/TWA PEL Ceiling TLV/TWA TLV/STEL
P None established
1 1 ppm 1 ppm (Skin)*
*The skin notation indicates the substance may be absorbed through the skin. Mucous membranes, or eyes, by direct or airborne
exposure and suggests that appropriate measures be taken to prevent such absorption so that the exposure limit is not invalidated.

SECTION V EMERGENCY AND FIRST AID PROCEDURES

EYE CONTACT: Immediately flush eyes with plenty of water for at least 15 minutes while holding eyelids
open. Rinse continuously with water while on way to get medical attention.

SKIN CONTACT: Immediately remove contaminated clothing or shoes, wipe excess from skin and flush
with plenty of water for at least 15 minutes. Use soap and water. Do not reuse clothing until thoroughly
decontaminated. Get medical attention immediately.

INHALATION: Remove victim to fresh air and provide oxygen if breathing is difficult. Give artificial
respiration if not breathing. Get medical attention.

INGESTION: Do not induce vomiting. Give one glass of water unless victim is drowsy, convulsing, or
unconscious. Seek medical attention immediately.

SECTION VI SUPPLEMENTAL HEALTH INFORMATION

Component 1: Although the significance is unknown, Diethylenetriamine (DETA) has been found to
increase the frequency of sister chromatid exchange. It was also found to be positive in the unscheduled
DNA mutagenicity assay. Microbial tests and in vitro gene mutation assays were negative. A lifetime skin
painting study in mice did not result in carcinogenicity.

Histopathological effects of the kidney, liver, spleen and adrenals were observed in two rat lifetime feeding
studies.

Component 2: In a reproductive study on rats, Bisphenol A (BPA) caused paternal toxicity reproductive
kidney and liver effects and fetotoxicity at doses of 0.5% and 1.0% of the diet. No significant treatment
related effects were seen at 0.25% of the diet. In other reproductive studies, BPA produced fetotoxicity in
mice at maternally toxic doses, but not in rats.

A dust inhalation study in rats at doses up to 150 MG/M3 BPA for 6H/D for 9 exposures did not result in
any significant treatment related systemic toxicity.

Bisphenol A at high oral doses and by intraperitoneal injection produced slight estrogenic effects (ovarian
enlargement) in laboratory animals. The significance of this information in humans in unknown.

SECTION VII PHYSICAL DATA

Boiling Point: >404癋 (207癈) Specific Gravity: 1.02 Vapor Pressure: <0.1 @ 20癈
(Deg. F) (H20 =1) (MMHG))
Melting Point: Not available Solubility: Partially Vapor Density: >1
(Deg. F) (in water) (air=1)
Evaporation Rate: <1 of available
(n-Butyl Acetate=1)
AB Slurry Broadcast Hardener Part B Page 3 of 5




APPEARANCE AND ODOR: Clear, Amber mobile liquid with amine odor.

SECTION VIII FIRE AND EXPLOSION HAZARDS

Flash point and method: Flammable Limits % volume in air
>200癋 (>93癈) (SETAFLASH) Lower: 1.4 Upper: N/AV

EXTINGUISHING MEDIA: Use water fog, "alcohol" foam, dry chemical, or C02. Water or fog may cause
frothing which can be violent, especially if sprayed into containers of hot, burning liquid.

SPECIAL FIRE FIGHTING PROCEDURES AND PRECAUTIONS: Material will not burn unless
preheated. Do not enter confined fire space without full bunker (helmet with face shield, bunker coats,
gloves, and rubber boots), including a positive pressure NIOSH-approved self-contained breathing
apparatus. Cool fire-exposed contains with water.

UNUSUAL FIRE AND EXPLOSION HAZARDS: Delayed lung damage (pulmonary edema) can be
experienced after exposure to combustion products, sometimes hours after the exposure. Nitrogen oxides
and nitrogen containing organic compounds may be released upon combustion. See Section XII.

SECTION IX REACTIVITY

Stability: Stable Hazardous Polymerization: Will not occur

CONDITIONS AND MATERIAL TO AVOID: Avoid heat, flame and contact with strong oxidizing
agents.

HAZARDOUS DECOMPOSITION PRODUCTS: Nitrogen oxides, carbon monoxide and unidentified
organic compounds may be formed during combustion..

SECTION X EMPLOYEE PROTECTION

RESPIRATORY PROTECTION: Do not breath vapor or mists. If exposure may or does exceed
occupational exposure limits (see IV), use a NIOSH-approved respirator to prevent overexposure. In accord
with 29 CFR 1910.124 use either a full-face, atmosphere-supplying respirator or an air-purifying respirator
for organic vapors.

Avoid breathing vapors which may be produced under some conditions such as heating or applications of
uncured material in large surface areas (e.g. Flooring and Painting). Avoid breathing aerosols and mists
which may be formed by various methods of application.

PROTECTIVE CLOTHING: Do not get in eyes. Wear chemical goggles if there is potential contact with
eyes. Do not get on skin, on clothing. Wear chemical-resistant protective clothing such as gloves. Outer
clothing or apron, overshoes and a face-shield suitable to potential exposure.

ADDITIONAL PROTECTIVE MEASURES: Use ventilation as required to control vapor concentrations.
Eye wash fountains and safety showers should be available for emergency use.

SECTION XI ENVIRONMENTAL PROTECTION

SPILL OR LEAK PROCEDURES:
Danger. Corrosive. Prevent all bodily contact with spilled material. Wear appropriate respirator and full-
body protective clothing.
AB Slurry Broadcast Hardener Part B Page 4 of 5



***Large Spills***Shut off leak only if safe to do so. Eliminate potential fire hazards. Dike and contain.
Remove with vacuum truck or pump to storage/salvage vessels. Soak up residue with an absorbent such as
clay, sand or other suitable material. Place in non-leaking containers for proper disposal. Flush area with
water to remove last traces of residue; dispose of flush solutions by absorption as above.
***Small Spills***Take up with an absorbent material and place in non-leaking containers; seal tightly for
proper disposal.

SECTION XII SPECIAL PRECAUTIONS

Store in a cool dry place with adequate ventilation. Keep away from open flames and high temperatures.
Do not pressurize drum containers to empty them.

Heating this curing agent in the presence of air may cause thermal and oxidative decomposition with some
epoxy resins. It may produce exothermic reactions which in large masses can cause runaway
polymerization and charring of the reactants. Fumes and vapors from these thermal and chemical
decompositions vary widely in composition and toxicity. Do not breathe fumes. Use a NIOSH-Approved
respirator as required to prevent over exposure. In accord with 29 CFR 1910.134. Use either an
atmosphere-supplying respirator or an air-purifying respirator for organic vapors.

Danger!! Corrosive. Causes burns to eye, skin and respiratory tract. May be toxic if absorbed through skin.
May cause skin sensitization. May cause CNS depression. Do not get in eyes, on skin or on clothing. Do
not breathe vapors or mists.

Containers, even those that have been emptied, can contain hazardous product residues. Wash with soap
and water before eating, drinking, smoking, applying cosmetics, or using toilet facilities. Launder
contaminated clothing before reuse. Contaminated leather articles including shoes cannot be
decontaminated and should be destroyed to prevent reuse.

SECTION XIII TRANSPORTATION REQUIREMENTS

DEPARTMENT OF TRANSPORTATION CLASSIFICATION: Class 8 (Corrosive Material), III

D.O.T. PROPER SHIPPING NAME: Polyamines, Liquid, Corrosive, N.O.S. (Contains
Diethylenetriamine)

Other requirements: UN2735, Guide 153

SECTION XIV OTHER REGULATORY CONTROLS

The components of this product are listed on the EPA/TSCA inventory of chemical substances.

Protection of stratospheric ozone (pursuant to section 611 of the Clean Air Act Amendments of 1990) per
40 CFR part 82. This product does not contain nor was it directly manufactured with any Class I or Class II
ozone depleting substances.

In accordance with Sara Title III, Section 313, the attached environmental data sheet (EDS should always
be copied and sent with MSDS).

SECTION XV STATE REGULATORY INFORMATION

The following chemicals are specifically listed by individual states: other product specific health and safety
data in other sections of the MSDS may also be applicable for state requirements. For details on your
regulatory requirements you should contact the appropriate agency in your state.
AB Slurry Broadcast Hardener Part B Page 5 of 5




STATE LISTED COMPONENT PERCENT STATE CODE

Diethylenetriamine
>50
(CAS NO. 111-40-0) CA, FL, IL, LA, MA, ME,
MN, MO, PA, RI

Bisphenol A
<50
(CAS NO. 80-05-7) CA, MA, NJ, PA

Phenol
<0.01
(CAS NO. 108-95-2) MA, RI

CA = California, Haz. Subst. List; CA65C/R = California safe drinking water and toxics Enforcement Act
of 1986 or proposition 65 List; FL = Florida subst. List; IL = Illinois Tox. Subst. List; LA = Louisiana Tox.
Subst. List: MA = Massachusetts Tox. Subst. List; PA = Pennsylvania Tox. Subst. List; RI = Rhode Island
Tox. Subst. List

SECTION XVI SPECIAL NOTES

The information contained herein is based on the data available to us and is believed to be correct.
However, Industrial Protective Coatings, Inc. makes no warranty, expressed or implied regarding the
accuracy of these data or results to be obtained from the use thereof. Industrial Protective Coatings, Inc.
assumes no responsibility for injury from use of the product described herein.

Date prepared: 3/18/98
Revised date: 11-18-08

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68953-36-6_112-57-2_111-40-0_80-05-7.asp 68953-36-6 112-57-2 111-40-0 80-05-7
25068-38-6_28064-14-4_71617-64.asp 25068-38-6 28064-14-4 71617-64-6
25068-39-6_120547-52-6_111-40-0_80-05.asp 25068-39-6 120547-52-6 111-40-0 80-05-7
111-40-0_80-05.asp 111-40-0 80-05-7
25068-38-6_13463-67-7_68609-97-2_074-00.asp 25068-38-6 13463-67-7 68609-97-2 074-00-8
25068-38-6_107-98-2_108-32-7_13463-67-7_1317-61-9_1332-37.asp 25068-38-6 107-98-2 108-32-7 13463-67-7 1317-61-9 1332-37-2 51274-00-1 68953-36-6 112-57-2 111-40-0 80-05-7
15520-10-2_100-51-6_100-52-7_103-50-4_150-76-5_80-05-7_108-95-2.asp 15520-10-2 100-51-6 100-52-7 103-50-4 150-76-5 80-05-7 108-95-2 25085-99-8
111-40-0_80-05-7.asp 111-40-0 80-05-7


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