Material Safety Data Sheet
service enigineer for washing machines and
dishwashers
Section 1. Chemical product and company identification
2480100
: HG International b.v.
Manufacturer Code :
1.02
: Damsluisweg 70 1332 EJ Almere MSDS# :
Address
5/19/2010.
: Netherlands Validation date :
Country
5/19/2010.
: +31 (0)36 54 94 700 Print date :
Telephone No.:
P. Stienstra
: +31 (0)36 54 94 744 Responsible name :
Fax
: www.hg.eu +1.705.726.5445
:
Internet: Telephone No.:
: Solstrand Trading +1.705.734.0857
Supplier Fax :
: 60 Lockhart road Barrie, Ontario L4N 9G8 Canada
Address Country :
: Cleaning solutions.
Material uses
In Case of Emergency : Chem. Tel Inc. (813) 248 0585 or Toll free (800) 255 3924
Section 2. Composition, Information on Ingredients
CAS # % by weight Exposure limits
Name
sodium chloride 7647-14-5 30 - 100 Not available.
Sodium hydroxide 1310-73-2 15 - 30 Not available.
Sodium carbonate 497-19-8 5 - 15 Not available.
sodium sulfate 7757-82-6 15 - 30 Not available.
Alifatic alcohols, C12-18 1-5 Not available.
Perfume 0-1 Not available.
Section 3. Hazards identification
: Solid. [Powder.]
Physical State and
Appearance
: DANGER
Emergency overview
CORROSIVE.
Causes severe eye and skin burns.
Avoid contact with eyes. Store in tightly closed container. Wash thoroughly after handling.
: Dermal contact. Eye contact. Ingestion.
Routes of entry
Potential acute health effects
Corrosive to eyes on contact.
Eyes :
Corrosive to skin on contact.
Skin :
Corrosive to the respiratory system.
Inhalation :
Corrosive to the digestive tract.
Ingestion :
: CARCINOGENIC EFFECTS: Not available.
Potential chronic health
MUTAGENIC EFFECTS: Not available.
effects
TERATOGENIC EFFECTS: Not available.
: Repeated exposure of the eyes to a low level of dust can produce eye irritation. Repeated skin exposure
Medical conditions
can produce local skin destruction, or dermatitis. Repeated inhalation of dust can produce varying degree
aggravated by
of respiratory irritation or lung damage.
overexposure:
: Not available.
Over-exposure
signs/symptoms
See toxicological Information (section 11)
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service enigineer for washing machines
and dishwashers
Section 4. First aid measures
: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical
Eye Contact
attention if irritation occurs.
: In case of contact, immediately flush skin with plenty of water. Remove contaminated clothing and shoes.
Skin Contact
Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention.
: If inhaled, remove to fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial
Inhalation
respiration. Get medical attention.
: Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to
Ingestion
an unconscious person. Get medical attention if symptoms appear.
: Not available.
Notes to Physician
Section 5. Fire fighting measures
May be combustible at high temperature.
Flammability of the product :
Not available.
Auto-ignition Temperature :
Not available.
Flash Points :
Not available.
Flammable limits :
Decomposition products may include the following materials: carbon oxides (CO, CO2), sulfur oxides (SO
Products of combustion :
2, SO3...), halogenated compounds, hydrogen chloride. Some metallic oxides.
: Not available.
Fire hazards in presence of
various substances
: Not available.
Explosion hazards in
presence of various
substances
: Use an extinguishing agent suitable for surrounding fires.
Fire fighting media and
instructions No specific hazard.
: Fire fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA)
Special protective equipment
with a full facepiece operated in positive pressure mode.
for fire-fighters
: Not available.
Special remarks on fire
hazards
Special remarks on explosion : Not available.
hazards
Section 6. Accidental release measures
: Immediately contact emergency personnel. Keep unnecessary personnel away. Use suitable protective
Personal precautions
equipment (Section 8).
: Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.
Environmental precautions
: If emergency personnel are unavailable vacuum or carefully scoop up spilled materials and place in an
Methods for cleaning up
appropriate container for disposal. Avoid creating dusty conditions and prevent wind dispersal.
Section 7. Handling and storage
: Wash thoroughly after handling. Avoid breathing dust. Avoid contact with eyes, skin and clothing. Keep out
Handling
of the reach of children.
: Keep container tightly closed. Keep container in a cool, well-ventilated area.
Storage
Section 8. Exposure Controls, Personal Protection
: Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure
Engineering controls
to airborne contaminants below any recommended or statutory limits. If user operations generate dust,
fume or mist, use ventilation to keep exposure to airborne contaminants below the exposure limit.
Personal protection
Eyes : Safety eyewear complying with an approved standard should be used when a risk assessment indicates
this is necessary to avoid exposure to liquid splashes, mists or dusts.
Recommended:safety glasses with side shields
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service enigineer for washing machines
and dishwashers
Skin : Personal protective equipment for the body should be selected based on the task being performed and the
risks involved and should be approved by a specialist before handling this product.
Body: Recommended:Work uniform or laboratory coat.
Respiratory : Use a properly fitted, particulate filter respirator complying with an approved standard if a risk assessment
indicates this is necessary.Respirator selection must be based on known or anticipated exposure levels,
the hazards of the product and the safe working limits of the selected respirator.
Recommended:Dust respirator.
Hands : Chemical-resistant, impervious gloves or gauntlets complying with an approved standard should be worn at
all times when handling chemical products if a risk assessment indicates this is necessary.
>8 hour(s) (breakthrough time): Butyl rubber gloves.
Other protection : Not available.
:
Personal protective
equipment (Pictograms)
: Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self-contained breathing apparatus should
Personal protection in case
be used to avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult
of a large spill
a specialist BEFORE handling this product.
Product Name Exposure limits
Sodium hydroxide Not available.
Consult local authorities for acceptable exposure limits.
Section 9. Physical and chemical properties
: Solid. [Powder.]
Physical State and
Appearance
White to yellowish.
Color :
Fragrance like.
Odor :
13,09 [Conc. (% w/w): 1%]
pH :
1.21 to 1.26 g/cm3 (20癈 / 68癋)
:
Relative density
Not available.
Viscosity :
Easily soluble in the following materials: hot water.
Solubility :
Soluble in the following materials: cold water.
Not available.
:
Flash point
Not available.
Explosive properties :
Not available.
Oxidizing properties :
Not available.
Physical chemical comments :
Section 10. Stability and reactivity
: Stable under recommended storage and handling conditions (see section 7).
Stability and Reactivity
: Keep from any possible contact with water.
Conditions of instability
: Extremely reactive or incompatible with acids, moisture.
Incompatibility with various
Reactive with metals.
substances
: Decomposition products may include the following materials: halogenated compounds, hydrogen
Hazardous Decomposition
chloride.
Products
: Will not occur.
Hazardous polymerization
Section 11. Toxicological information
Sodium hydroxide LDLo 500 mg/kg Oral Rabbit
Sodium carbonate LD50 4090 mg/kg Oral Rat
LD50 6600 mg/kg Oral Mouse
LDLo 714 mg/kg Oral man
sodium sulfate LD50 5989 mg/kg Oral Mouse
LD50 5989 mg/kg Dermal Mouse
sodium chloride LD50 3000 mg/kg Oral Rat
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service enigineer for washing machines
and dishwashers
:
: Contains material which causes damage to the following organs: lungs, upper respiratory tract, skin, eye,
Chronic effects on humans
lens or cornea, stomach.
: Extremely hazardous by the following route of exposure: of skin contact (corrosive, irritant), of eye
Other toxic effects on
contact (irritant, corrosive), of inhalation (lung irritant, lung corrosive).
humans
: Not available.
Special remarks on toxicity
to animals
: Not available.
Special remarks on chronic
effects on humans
: Not available.
Special remarks on other
toxic effects on humans
Specific effects
: No known significant effects or critical hazards.
Carcinogenic effects
: No known significant effects or critical hazards.
Mutagenic effects
: No known significant effects or critical hazards.
Reproduction toxicity
Section 12. Ecological information
Sodium carbonate LEPOMIS MACROCHIRUS 96 hour(s) 300 mg/l
(LC50)
DAPHNIA MAGNA (LC50) 96 hour(s) 500 mg/l
DAPHNIA MAGNA (LC50) 24 hour(s) 265 mg/l
sodium sulfate Pimephales promelas (LC50) 96 hour(s) 7960 mg/l
Lepomis macrochirus (LC50) 96 hour(s) 12500 mg/l
Lepomis macrochirus (LC50) 96 hour(s) 12750 mg/l
Lepomis macrochirus (LC50) 96 hour(s) 13000 mg/l
Lepomis macrochirus (LC50) 96 hour(s) 13500 mg/l
sodium chloride Daphnia magna (EC50) 48 hour(s) 402.6 mg/l
Oncorhynchus mykiss (LC50) 96 hour(s) 6094 mg/l
Pimephales promelas (LC50) 96 hour(s) 6390 mg/l
Pimephales promelas (LC50) 96 hour(s) 7050 mg/l
Pimephales promelas (LC50) 96 hour(s) 7100 mg/l
Pimephales promelas (LC50) 96 hour(s) 7200 mg/l
Not available.
BOD and COD :
Biodegradable
Biodegradable/OECD :
Not available.
Mobility :
Decomposition products may include the following materials: carbon oxides (CO, CO2) and water, sulfur
Products of degradation :
oxides (SO2, SO3...), halogenated compounds. Some metallic oxides.
: non-toxic.
Toxicity of the products of
biodegradation
: Not available.
Special remarks on the
products of biodegradation
Section 13. Disposal considerations
: The generation of waste should be avoided or minimised wherever possible. Avoid dispersal of spilled
Waste information
material and runoff and contact with soil, waterways, drains and sewers. Disposal of this product, solutions
and any by-products should at all times comply with the requirements of environmental protection and
waste disposal legislation and any regional local authority requirements. Use a shovel to put the material
into a convenient waste disposal container.
: Not available.
Waste stream
Consult your local or regional authorities.
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service enigineer for washing machines
and dishwashers
Section 14. Transport information
Regulatory UN Proper shipping name Class Packing group Label Additional information
Information number
3262 CORROSIVE SOLIDS, 8 II Remarks
DOT
N.O.S. (Sodium ORM-D
Classification CORROSIVE
hydroxide) 8
3262 CORROSIVE SOLIDS, 8 II -
TDG
N.O.S. (Sodium
Classification
hydroxide) 8
UN 3262, LMT QTY, 8 II
3262 Hazard identification
ADR/RID
BASIC, INORGANIC,
Class number
N.O.S. , CLASS 8, II 80
8
(Sodium hydroxide)
Reportable quantity
12
Limited quantity
LQ23
UN 3262, LMT QTY, 8 II
3262 Emergency schedules
IMDG Class
BASIC, INORGANIC, (EmS)
N.O.S. , CLASS 8, II F-A S-B
8
mixture (Sodium
hydroxide)
3262 UN 3262, LMT QTY, 8 II -
IATA-DGR
BASIC, INORGANIC,
Class
N.O.S. , CLASS 8, II 8
mixture (Sodium
hydroxide)
Section 15. Regulatory information
: Class D-2A: Material causing other toxic effects (VERY TOXIC).
WHMIS (Canada)
Class D-2B: Material causing other toxic effects (TOXIC).
Class E: Corrosive solid.
CEPA DSL: sodium sulfate; Sodium carbonate; Sodium hydroxide; sodium chloride; terpinolene;
Terpeneoil; camphene; bicyclo[2.2.1]heptan-2-ol, 1,7,7-trimethyl-, acetate, exo-; 1,6-octadien-3-ol, 3,7-
dimethyl-; (R)-p-Mentha-1,8-diene; 2,6-octadien-1-ol, 3,7-dimethyl-, (e)-; Citral; 6-octen-1-ol, 3,7-
dimethyl-; phenol, 4-allyl-2-methoxy-
International regulations
EINECS : Not available.
DSCL (EEC) : R35- Causes severe burns.
International lists : Not available.
Section 16. Other information
: CORROSIVE.
Label Requirements
Causes severe eye and skin burns.
Hazardous Material *3 National Fire
Health Flammability
0
Information System Protection
0
Fire hazard
Health Instability
3 0
(U.S.A.) Association
3
Reactivity
(U.S.A.) Special
C
Personal protection
: Not available.
References
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service enigineer for washing machines
and dishwashers
Other special considerations : Not available.
5/19/2010.
Date of printing :
5/19/2010.
:
Date of issue
No previous validation.
Date of previous issue :
1.02
Version :
Notice to reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its
subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should
be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.
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