Ciba Specialty Chemicals Corporation
Material Safety Data Sheet
MSDS date: 18-Feb-2005
OSHA / ANSI 2003 Compliant
NFPA Rating: Health: 2 Flammability: 1 Instability: 0
HMIS Rating: Health: 2 Flammability: 1 Physical Hazard: 0 Personal Protection: X
1. PRODUCT AND COMPANY IDENTIFICATION
Product Name: LANASET RED 2GA
Product Number: 0871617
Chemical Family: Mixture of Azo Metal Complex Dyes
Intended Use: For dyeing wool fibers
Manufacturer/Supplier: Ciba Specialty Chemicals Corporation
4050 Premier Drive
HighPoint, NC 27265
8:30am - 5pm Phone Number: 1-336-801-2500
MSDS Request Line (voicemail): 1-800-431-2360
Customer Service/Product Information 1-800-334-8124
Emergency 24-Hour Health/Environmental Phone: 1-800-873-1138
2. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Signal Word: WARNING!
Physical Form: Powder
Color: Red
Odor: Odorless
Health: May cause irritation to eyes.
Physical Hazards: Refer to MSDS Section 7 for Dust Explosion information.
OSHA Hazardous Substance: This material is classified as hazardous under OSHA regulations.
Potential Health Effects: May cause eye irritation.
Primary Route(s) of Entry: Ingestion, Skin, Inhalation, Eyes.
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MSDS date: 18-Feb-2005 Product Name: LANASET RED 2GA
3. COMPOSITION/INFORMATION ON INGREDIENTS
HAZARDOUS COMPONENTS
Components CAS Number Weight %
Metal complex dye 00893 70209-87-9 20 - 30%
4. FIRST AID MEASURES
Eyes: Immediately flush the eye(s) with lukewarm, gently flowing water for 15 minutes or
until the chemical is removed. Lift or retract eyelids often while flushing with water.
Get immediate medical attention if irritation persists.
Skin: If clothing is contaminated, remove and launder before reuse. Wash off immediately
with soap and plenty of water. Get medical attention if irritation occurs.
Inhalation: Remove to fresh air, if not breathing give artificial respiration. If breathing is difficult,
give oxygen and get immediate medical attention.
Ingestion: Do not induce vomiting. If vomiting occurs naturally, have casualty lean forward to
reduce the risk of aspiration. Seek medical attention immediately.
5. FIRE FIGHTING MEASURES
Fire Fighting Measures: Standard procedure for chemical fires.
Suitable Extinguishing Media: Carbon dioxide, dry chemical, foam or water mist.
Fire Fighting Equipment: Wear self-contained breathing apparatus and protective suit.
Unusual hazards: The product can form an explosive dust/air mixture. For further information, see
Section 7 Explosion Hazards.
Hazardous Combustion Burning may produce toxic combustion products.
Products:
6. ACCIDENTAL RELEASE MEASURES
Cleanup Instructions: Sweep up and shovel into suitable containers for disposal. Avoid dust formation.
Wear suitable protective equipment. Should not be released into the environment.
7. HANDLING AND STORAGE
Handling: As with all industrial chemicals, use good industrial practices when handling. Avoid
eye, skin, and clothing contact. Do not inhale. Do not taste or swallow. Use only
with adequate ventilation.
Storage: Keep containers tightly closed in a cool, well-ventilated place.
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MSDS date: 18-Feb-2005 Product Name: LANASET RED 2GA
Explosion Hazards: - Combustible powder.
- Avoid creating dusty conditions.
- Grounding is required when emptying into a conductive container.
- When flammable solvents are present, the container must be inerted or the system
otherwise designed to prevent or contain an explosion. Seek expert advice.
In addition, for products packaged in fused-lined (coated) fiber drums, fiber drums
with conductive liners, steel drums, steel pails, and Type "C" FIBC (bulk bags), or
other conductive the following instructions also apply:
- Always ground this package before emptying.
The user is responsible for designing the system to handle solid and ensuring proper
training of employees in the system's use.
For Industrial Use Only
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Exposure Guidelines:
There are no OSHA or ACGIH exposure guidelines available for component(s) in this product.
Personal Protective Equipment
Eye/Face Protection: Wear safety glasses or goggles to protect against dust particles.
Skin Protection: Wear chemical resistant gloves and protective clothing.
Respiratory Protection: Use NIOSH approved respirator as needed to mitigate exposure.
Engineering Controls: Work in well ventilated areas. Do not breathe dust.
Other Protective Equipment: Eye wash station and safety shower should be available in immediate work area.
Select additional protective equipment based upon potential for exposure.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical Form: Powder
Color: Red
Odor: Odorless.
Freezing/Melting Point: Not determined
Solubility in water: 30 g/L @ 30 篊 (86 篎)
60 g/L @ 90 篊 (194篎)
Vapor Density: Not applicable
Vapor Pressure: Not applicable
Density: Not determined
Specific Gravity: Not applicable
pH: 6.0 - 7.0 @ 1 g/l H20
Percent Volatile: Not determined
VOC: Not determined
Partition Coefficient (Octanol/Water): Not determined
Decomposition Temperature: Not determined
Flammability Limits in Air:
Flash point: Not applicable
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MSDS date: 18-Feb-2005 Product Name: LANASET RED 2GA
Test Method (for Flash Point): Not applicable
10. STABILITY AND REACTIVITY
Stability: Stable.
Conditions to Avoid: Avoid static discharge.
Incompatibility: Strong oxidizing agents, strong acids, strong bases.
Hazardous Decomposition No decomposition expected under normal storage conditions.
Products:
Possibility of Hazardous None expected.
Reactions:
11. TOXICOLOGICAL INFORMATION
Acute Oral Toxicity: (Rats) LD50 > 5,000 mg/kg
Acute Dermal Toxicity: Not determined
Acute Inhalation Toxicity: Not determined
Eye Irritation: (Rabbits) Irritant
Skin Irritation: (Rabbits) Not an irritant.
Skin Sensitization: Not evaluated
Carcinogenicity (IARC; NTP; None of the components in this product at concentrations greater than 0.1% are
OSHA; ACGIH): listed by IARC; NTP, OSHA or ACGIH as a carcinogen.
Mutagenicity: Not evaluated.
Reproductive Toxicity: Not determined
Teratogenicity: Not evaluated
Neurotoxicity: Not determined
Subacute Toxicity: Not evaluated.
Subchronic Toxicity: Not determined
Chronic toxicity: Not determined
Absorption / Distribution / Not determined
Excretion / Metabolism:
Toxicologically Synergistic Not evaluated
Products:
Additional Information: Not determined
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MSDS date: 18-Feb-2005 Product Name: LANASET RED 2GA
12. ECOLOGICAL INFORMATION
Toxicity to Fish: (Zebra fish) LC50 = 50 mg/L 96 hour
Toxicity to Invertebrates: Not determined
Toxicity to Algae: Not determined
Toxicity to Sewage Bacteria: Not determined
Activated Sludge Respiration IC50 > 400 mg/l (3 Hrs.)
Inhibition Test:
Biochemical Oxygen Demand 25.0 mg/g
(BOD):
Chemical Oxygen Demand (COD):720.0 mg/g
Total Oxygen Demand (TOD): Not determined
Biodegradability: Not determined
Bioaccumulation: Not determined
Additional Environmental Data: Not determined
13. DISPOSAL CONSIDERATIONS
Waste Disposal: Dispose in accordance with local, state, provincial and federal regulations.
14. TRANSPORT INFORMATION
U.S. Department of Transportation (DOT):
Not regulated for this mode of transport.
International Maritime Dangerous Goods (IMDG):
Not regulated for this mode of transport.
International Air Transportation Authority (IATA):
Not regulated for this mode of transport.
15. REGULATORY INFORMATION
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MSDS date: 18-Feb-2005 Product Name: LANASET RED 2GA
Federal Regulations
OSHA Hazardous Substance: This material is classified as hazardous under OSHA regulations
Clean Air Act - Hazardous Air Pollutants (HAP): This product does not contain any Hazardous Air Pollutants (HAP),
as defined by the U.S. Clean Air Act Section 112 (40 CFR 61).
Clean Air Act - Volatile Organic Compounds (VOC): This product does not contain any SOCMI Intermediate or Final
Volatile Organic Compounds (VOC), as defined by the U.S. Clean Air Act Section 111 (40 CFR 60.489).
Clean Air Act - Ozone Depleting Substances (ODS): This product neither contains, nor was manufactured with, a
Class I or Class II ozone depleting substance (ODS), as defined by the U.S. Clean Air Act Section 602 (40 CFR 82,
Subpt. A, App. A+B).
Clean Water Act - Priority Pollutants (PP): This product does not contain any priority pollutants listed under the U.S.
Clean Water Act Section 307 (2)(1) Priority Pollutant List (40 CFR 401.15).
Resource Conservation and Recovery Act (RCRA): Not a hazardous waste under RCRA (40 CFR 261.21).
SARA Section 302 Extremely Hazardous Substances (EHS): This product does not contain any components
regulated under Section 302 (40 CFR 355) as Extremely Hazardous Substances.
SARA Section 304 CERCLA Hazardous Substances: This product does not contain any components regulated under
Section 304 (40 CFR 302) as hazardous chemicals for emergency release notification ("CERCLA" List).
SARA Section 311/312 Hazard Communication Standard (HCS): This product is regulated under Section 311/312
HCS (40 CFR 370), Acute (immediate) health hazard.
SARA Section 313 Toxic Chemical List (TCL): This product does not contain any component(s) listed on the Section
313 Toxic Chemical List.
TSCA Section 8(b) Inventory Status: All component(s) comprising this product are either exempt or listed on the TSCA
inventory.
TSCA Section 5(e) Consent Orders: This product is not subject to a Section 5(e) Consent Order.
TSCA Significant New Use Rule (SNUR): This product is not subject to a Significant New Use Rule (SNUR).
TSCA Section 5(f): This product is not subject to a Section 5(f)/6(a) rule.
TSCA Section 12(b) Export Notification: This product does not contain any component(s) that are subject to a Section
12(b) Export Notification
State Regulations
California Proposition 65: This product does not contain any components currently on the California list of
Known Carcinogens and Reproductive Toxins.
Pennsylvania Right-To-Know: This product contains the following component(s) which are subject to Pennsylvania
Right-to-Know disclosure requirement.
Pennsylvania Right-to-Know
Components CAS Number
Listed.
Sulfuric acid disodium salt 7757-82-6
Environmental hazard.
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MSDS date: 18-Feb-2005 Product Name: LANASET RED 2GA
International Regulations
Chemical Weapons Convention (CWC): This product does not contain any component(s) listed under the Chemical
Weapons Convention Schedule of Chemicals.
16. OTHER INFORMATION
Reason for revision: New MSDS format.
Disclaimer: The information contained herein is based upon data believed to be correct. However, no guarantee or
warranty of any kind, expressed or implied, is made with respect to such data or information. The user is responsible for
determining whether the product is suitable for its intended conditions of use.
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