Lilly Miller Brands
Health Hazard 0
0
MATERIAL SAFETY DATA SHEET
Fire Hazard 0
0
0
Reactivity 0
Personal Protection A
HMIS RATING NFPA RATING
SECTION I - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Trade Name: Worry Free by Lilly Miller Moss & Algae Control MSDS Number: LM-053
Generic Name: Herbicide for moss and algae. Revision Number: 2
Manufacturer: Lilly Miller Brands Date Revised: 2/18/2004
Address: P.O. Box 2289 Manufacturer's Phone Number: 503-451-4451
Clackamas, OR 97015
COMPOSITION/INFORMATION ON INGREDIENTS
SECTION II -
Chemical Name CAS Number % TLV PEL
Citric acid 77-92-9 6 N/A N/A
Acetic acid 64-19-7 <8 N/A N/A
Sodium Lauryl Sulfate 151-21-3 15 N/A N/A
Water 7732-18-5 >50 N/A N/A
Key: TLV = ACGIH, 8 hr. time weighted average (TWA); PEL = OSHA permissible exposure limit.
SECTION III - HAZARDS IDENTIFICATION
Emergency Overview: This product is a water soluble herbicide for moss and algae which is generally non-
hazardous. Ingestion of large quantities may cause gastro-intestinal distress. In such cases consultation with a
physician is recommended
Wash hands and exposed skin with soap and water after using this product.
HMIS Rating: Health: 0 Fire: 0 Reactivity: 0 Personal Protection: A
Potential Health Effects:
Routes of Entry: Skin contact, eye contact, ingestion
Inhalation: There is minimal risk of inhalation hazards with this product.
Skin Contact: Essentially non-irritating to the skin.
Eye Contact: May cause irritation or corneal injury.
Ingestion: Ingestion of large quantities may be irritating to the G.I. system.
Medical Conditions Aggravated by Exposure: Dermatitis.
Carcinogenicity: Not listed by NTP or IARC. Not regulated as a carcinogen by OSHA.
Revised:2/18/2004 Page 1 of 4
Trade Name: Worry Free by Lilly Miller Moss & Algae Control MSDS Number: LM-053
SECTION IV - FIRST AID MEASURES
Inhalation: Move to an area free from risk of further exposure. Treat symptomatically if required. No adverse
effects anticipated by this route of exposure incidental to proper handling.
Eye Contact: Flush with clean, lukewarm water at low pressure. Seek medical attention if irritation persists.
Skin Contact: Wash affected areas thoroughly with soap and warm water immediately after use of this product.
Ingestion: Ingestion of large quantities may be irritating to the GI tract, requiring symptomatic treatment.
Consultation with a physician is recommended.
SECTION V - FIREFIGHTING MEASURES
NFPA Rating: Health: 0 Fire: 0 Reactivity: 0 Other: 0
Flash point and Method: N/D
Extinguishing Method: Water based, non-flammable product.
Fire or Explosion Hazards: None.
Special Firefighting Procedures: None.
SECTION VI - ACCIDENTAL RELEASE MEASURES
Clean-up Procedures: Wipe up excess, rinse area with clear water
Personal Precautions: Not normally required.
Environmental Precautions: Keep major spills from entering lakes and waterways.
SECTION VII - HANDLING AND STORAGE
Storage Temperature: Not affected by extremes of temperature.
Shelf Life: Indefinite.
Special Sensitivity: None.
Handling and Storage Precautions: Avoid eye contact, keep from freezing.
SECTION VIII - EXPOSURE CONTROLS/PERSONAL PROTECTION
Respiratory Protection: Not normally required.
Eye Protection: Use safety glasses if there is potential for exposure to splashes which could cause irritation to the
eyes.
Skin Protection: None needed under normal conditions of use.
Engineering Controls: Good general ventilation should be sufficient for most conditions.
Revised: 2/18/2004 Page 2 of 4
Trade Name: Worry Free by Lilly Miller Moss & Algae Control MSDS Number: LM-053
SECTION IX - PHYSICAL AND CHEMICAL PROPERTIES
Physical Form: Tan to brownish liquid
Odor: Negligible Specific Gravity: N/D
Bulk Density: N/D pH: N/D
Solubility in Water: 100 % % Volatile by Weight (VOC): Nil
SECTION X - REACTIVITY
Stability : This is stable material.
Hazardous Polymerization: Will not occur.
Incompatibilities: None in designed use.
Decomposition Products: CO, CO2, irritating hydrocarbon particulate.
SECTION XI - TOXICOLOGICAL/ECOLOGICAL INFORMATION
Ecological Concerns: Worry Free by Lilly Miller Moss & Algae Control is non-hazardous herbicide. No
ecological concerns are anticipated.
SECTION XII - DISPOSAL CONSIDERATIONS
Waste Disposal Method: This material is non-hazardous moss and algae herbicide and may be disposed of by
applying to soil in accordance with manufacturer's recommendations.
SECTION XIII - TRANSPORTATION INFORMATION
DOT Shipping Name: Not regulated DOT Label: None
Technical Shipping Name: None DOT Placard: None
DOT Hazard Class: None UN/NA Number: None
SECTION XIV - REGULATORY INFORMATION
OSHA Status: Chemicals contained in this product are regulated as non-hazardous substances under OSHA
criteria.
TSCA Status: All applicable chemicals are registered under TSCA.
CERCLA Reportable Quantity: Not regulated under CERCLA.
SARA Title III: Not regulated under SARA Title III.
Section 302, Extremely Hazardous: N/A
Section 311/312 Hazard Categories: N/A.
Section 313 Toxic Chemicals: N/A
RCRA Status: Not regulated under RCRA
Revised: 2/18/2004 Page 3 of 4
Trade Name: Worry Free by Lilly Miller Moss & Algae Control MSDS Number: LM-053
SECTION XV - APPROVALS
Reason for issue: Updated inert ingredient declaration by MEH Approval Date: 2/18/2004
Prepared by: Compliance Consulting Group, Inc. Supersedes Date: April 14, 2003
303-795-2060
SECTION XVI - DISCLAIMER
As of the date of this document, the foregoing information is believed to be accurate and is provided in good faith to
comply with applicable federal and state laws. However, no warranty or representation of law or fact, with respect
to such information, is intended or given.
Revised: 2/18/2004 Page 4 of 4
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