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27177-77-1 77-92-9 112-34-5 50-21-5 7732-18-5 68002-97-1 866-84-2

File Name: 27177-77-1_77-92-9_112-34-5_50-21-5_7732-18-5_68002-97-1_866-84-2.asp

                                                                                                MATERIAL SAFETY DATA SHEET



Crew Bathroom & Scale Remover
HMIS NFPA Personal protective equipment
Health 2 2
Fire Hazard 0 0
Reactivity 0 0
Version Number: 3 Preparation date: 2007-10-04
1. PRODUCT AND COMPANY IDENTIFICATION
Product name: Crew Bathroom & Scale Remover

MSDS #: MS0200012
Product Code: 3145310, 3172650
Recommended use: Cleaning product. This product is intended to be diluted prior to use.

Manufacturer, importer, supplier:
US Headquarters Canadian Headquarters
JohnsonDiversey, Inc. JohnsonDiversey - Canada, Inc.
8310 16th St. 2401 Bristol Circle
Sturtevant, Wisconsin 53177-0902 Oakville, Ontario L6H 6P1
Phone: 1-888-352-2249 Phone: 1-800-668-3131
MSDS Internet Address:
www.johnsondiversey.com

Emergency telephone number: 1-800-851-7145 (Prosar); 1-651-917-6133 (Int'l Prosar); 01-800-710-3400 (M閤ico)

2. HAZARDS IDENTIFICATION

EMERGENCY OVERVIEW
WARNING. CAUSES EYE AND SKIN IRRITATION. MAY BE HARMFUL IF SWALLOWED .

Principle routes of exposure: Eye contact. Skin contact. Inhalation. Ingestion.
Eye contact: Severe eye irritation.
Skin contact: Moderately irritating to the skin.
Inhalation: May be irritating to nose, throat, and respiratory tract.
Ingestion: May be irritating to mouth, throat and stomach .

3. COMPOSITION/INFORMATION ON INGREDIENTS
HAZARDOUS COMPONENTS
Ingredient(s) CAS # Weight % LD50 Oral - Rat LD50 Dermal - LC50 Inhalation - Rat
(mg/kg) Rabbit
Potassium dodecylbenzene sulfonate 27177-77-1 20 - 30% Not available Not available
Citric acid 77-92-9 1 - 5% Not available Not available
Diethylene glycol butyl ether 112-34-5 10 - 20% 3384 =2700 mg/kg Not available
Lactic acid 50-21-5 1 - 5% Not available Not available

4. FIRST AID MEASURES
Eye contact: Immediately flush eyes with running water for at least 15 minutes, keeping eyelids open. Get medical
attention.
Skin contact: Flush immediately with plenty of water. If irritation persists, get medical attention.
Inhalation: If breathing is affected, remove to fresh air. Get medical attention.
Ingestion: If swallowed, give a cupful of water or milk. THEN IMMEDIATELY CONTACT A PHYSICIAN OR POISON
CENTER. DO NOT induce vomiting unless directed to do so by medical personnel. Never give anything by
mouth to an unconscious person.
Aggravated Medical Conditions: Persons with pre-existing skin disorders may be more susceptable to irritating effects.

5. FIRE-FIGHTING MEASURES
Suitable extinguishing media: The product is not flammable. Extinguish fire using agent suitable for surrounding fire.
Specific hazards: None known.
Unusual hazards: None known
Specific methods: No special methods required




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5. FIRE-FIGHTING MEASURES
Special protective equipment for firefighters: As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or
equivalent) and full protective gear
Extinguishing media which must not be used for safety reasons: No information available


6. ACCIDENTAL RELEASE MEASURES
Personal precautions: Use personal protective equipment
Environmental precautions Absorb spill with inert material (e.g. dry sand or earth), then place in a chemical waste container.
and clean-up methods:

7. HANDLING AND STORAGE
Handling:
Avoid contact with skin, eyes and clothing. Do not taste or swallow. Remove and wash contaminated clothing and footwear before re-use. Wash
thoroughly after handling. Product residue may remain on/in empty containers. All precautions for handling the product must be used in handling the
empty container and residue. FOR COMMERCIAL AND INDUSTRIAL USE ONLY.
Storage:
Protect from freezing. Keep tightly closed in a dry, cool and well-ventilated place. KEEP OUT OF REACH OF CHILDREN.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Engineering measures to reduce exposure:
No special ventilation requirements. General room ventilation is adequate.

Personal Protective Equipment
Eye protection: Chemical-splash goggles.
Hand protection: Chemical-resistant gloves
Skin and body protection: No special protective clothing is required.
Respiratory protection: No special protective clothing is required.
Hygiene measures: Handle in accordance with good industrial hygiene and safety practice



9. PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Liquid Bulk density: No information available
pH: 4.09 Dilution pH: No information available.
Appearance: Aqueous solution Vapor density: No information available
Color: Purple Evaporation Rate No information available
Odor: Characteristic Boiling point/range: Not determined
Specific gravity: 1.064 Melting point/range: Not determined
Density: 8.88 Decomposition temperature: Not determined
VOC: 0.42% * Autoignition temperature: No information available
Flash point: >200癋 >93.3癈 Partition coefficient (n-octanol/water): No information available
Solubility: completely soluble Solubility in other solvents: No information available
Viscosity: No information available Elemental Phosphorus: 0.0 %P


* - Title 17, California Code of Regulations, Division 3, Chapter 1, Subchapter 8.5, Article 2, Consumer Products, Sections 94508

10. STABILITY AND REACTIVITY
Stability: The product is stable
Polymerization: Hazardous polymerization does not occur
Hazardous decomposition products: None reasonably foreseeable.
Conditions to avoid: Do not freeze.

11. TOXICOLOGICAL INFORMATION
Acute toxicity: Oral LD50 estimated to be between 2000 - 3000 mg/kg. Dermal LD50 estimated to be > 2000 mg/kg
Component Information: See Section 3

Chronic toxicity: None known

Specific effects
Carcinogenic effects: None known
Mutagenic effects: None known
Reproductive toxicity: None known
Target organ effects: None known




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12. ECOLOGICAL INFORMATION
Environmental Information: No data available


13. DISPOSAL CONSIDERATIONS


14. TRANSPORT INFORMATION
DOT/TDG: Please refer to the Bill of Lading/receiving documents for up to date shipping information

15. REGULATORY INFORMATION
International Inventories
All components of this product are listed on the following inventories: U.S.A. (TSCA), Canada (DSL/NDSL), Europe (EINECS/ELINCS/NLP), Australia
(AICS), Korea (ECL), Philippines (PICCS), New Zealand (NZIoC), China (IECSC).

U.S. Regulations
California Proposition 65: This product is not subject to the reporting requirements under California's Proposition 65

STATE RIGHT TO KNOW
Ingredient(s) CAS # MARTK: NJRTK: PARTK: RIRTK:
Water 7732-18-5 - - - -
Diethylene glycol butyl ether 112-34-5 - X X -
Alcohol ethoxylate 68002-97-1 - - - -
Lactic acid 50-21-5 - X - -
Potassium dodecylbenzene sulfonate 27177-77-1 - - - -
Potassium Citrate 866-84-2 - - - -


CERCLA/ SARA
Ingredient(s) CAS # Weight % CERCLA/SARA RQ (lbs) Section 302 TPQ (lbs) Section 313
Diethylene glycol butyl ether 112-34-5 10 - 20% X


Ingredient(s) CAA HAP CAA ODS CWA Priority Pollutants
Diethylene glycol butyl ether X


SARA 311/312 Hazard Categories

Canada
WHMIS hazard class: D2B Toxic materials.




Ingredient(s) CAS # NPRI
Diethylene glycol butyl ether 112-34-5 X




16. OTHER INFORMATION
Reason for revision: Not applicable
Prepared by: NAPRAC
Additional advice: None

Notice to Reader: This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty, express
or implied, as to the accuracy of the information contained within. Actual conditions of use and handling are beyond seller's control. User is responsible
to evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and Local laws and
regulations.




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