LOCTITE CORPORATION 07/02/97
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 01 of 05
1L 3021 MEDICAL DEVICE ADHESIVE UV CURING
18008
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Product Name: 1L 3021 MEDICAL DEVICE ADHESIVE UV CURING
Item No.: 18008
Product Type: UV Curing Adhesive
2. COMPOSITION, INFORMATION ON INGREDIENTS
Ingredients CAS No. %
High boiling methacrylate 68586-19-6 30-35
Urethane Methacrylate Resin Proprietary 25-30
Polyurethane methacrylate
resin Proprietary 20-25
High boiling methacrylate 7534-94-3 5-10
ACRYLIC ACID* 79-10-7 3-5
Hydroxyalkyl methacrylate 868-77-9 3-5
Photoinitiator 947-19-3 3-5
Hydroxyalkyl methacrylate 27813-02-1 1-3
Substituted silane 2530-83-8 1-3
* This component is listed as a SARA Section 313 Toxic Chemical.
Ingredients which have exposure limits
Exposure Limits (TWA) ACGIH OSHA OTHER
Ingredients (TLV) (PEL)
ACRYLIC ACID 2 ppm TWA skin 10 ppm TWA skin 1 ppm TWA skin
5.9 mg/m3 skin 30 mg/m3 skin 3 ppm STEL skin
Hydroxyalkyl methacrylate None None 3 ppm ceiling
Hydroxyalkyl methacrylate None None 3 ppm ceiling
Exposure Limits (STEL) ACGIH OSHA
Ingredients (TLV) (PEL)
3. HAZARDS IDENTIFICATION
Toxicity: Liquid is an eye and skin irritant.
Vapors may irritate eye, nose and throat.
Estimated oral LD50 more than 5000 mg/kg.
Estimated dermal LD50 more than 2000 mg/kg.
Primary Routes of Entry: Eyes, skin
Signs and symptoms
of Exposure: Irritation of eyes, skin , nose or throat. May
cause dermatitis on prolonged contact in sensitive
individuals.
LOCTITE CORPORATION 07/02/97
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 02 of 05
Product Name: 1L 3021 MEDICAL DEVICE ADHESIVE UV CURING
Item No.: 18008
3. HAZARDS IDENTIFICATION (continued)
Existing Conditions
Aggravated by Exposure: Acrylic acid: Upper respiratory and lung diseases,
dermatitis
Literature Referenced Carcinogen
Ingredients Target Organ and Other Health Effects NTP IARC OSHA
High boiling methacrylate ALG IRR NO NO NO
Urethane Methacrylate Resin No Data NO NO NO
Polyurethane methacrylate
resin No Data NO NO NO
High boiling methacrylate ALG IRR NO NO NO
ACRYLIC ACID AC4 ALG COR IRR NO N/A NO
Hydroxyalkyl methacrylate ALG IRR NO NO NO
Photoinitiator No Data NO NO NO
Hydroxyalkyl methacrylate ALG IRR NO NO NO
Substituted silane IRR NO NO NO
-------------------------------------------------------------------------------
Abbreviations
N/A Not Applicable AC4 ACGIH-Unclassifiable as human carc.
ALG Allergen COR Corrosive
IRR Irritant
4. FIRST AID MEASURES
Ingestion: Do not induce vomiting. Keep individual calm.
Obtain medical attention.
Inhalation: Remove to fresh air. If symptoms persist, obtain
medical attention.
Skin Contact: Wash with soap and water.
Eye Contact: Flush at least 15 minutes with water. Obtain
medical attention.
5. FIRE FIGHTING MEASURES
Flash Point: 193癋 Method: Tag Closed Cup
Recommended
Extinguishing Agents: Carbon dioxide, foam, dry chemical
Hazardous Products formed
by Fire or Thermal Decomp Irritating organic vapors
Unusual Fire or
Explosion Hazards: None
Explosive Limits:
(% by volume in air)Lower Acrylic acid: 2%
LOCTITE CORPORATION 07/02/97
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 03 of 05
Product Name: 1L 3021 MEDICAL DEVICE ADHESIVE UV CURING
Item No.: 18008
5. FIRE FIGHTING MEASURES (continued)
(% by volume in air)Upper Acrylic acid: 8%
6. ACCIDENTAL RELEASE MEASURES
Steps to be taken in case
of spill or leak: Maintain adequate ventilation.
Soak up with an inert absorbent.
Store in a partly filled, closed container
until disposal.
7. HANDLING AND STORAGE
Safe Storage: Store below 100 deg. F
(Contact Loctite Customer Service 1-800-243-4874 for shelf Life information)
Handling: Avoid prolonged skin contact. Keep away from eyes
Avoid prolonged breathing of vapors.
8. EXPOSURE CONTROLS, PERSONAL PROTECTION
Eyes: Safety glasses or goggles.
Skin: Rubber or plastic gloves.
Ventilation: Sufficient to maintain vapor concentration below
TLV.
See Section 2 for Exposure Limits.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance: Clear, straw colored viscous liquid
Odor: Sharp
Boiling Point: More than 300癋
pH: Does not apply
Solubility in Water: Low
Specific Gravity 1.09
Volatile Organic Compound
(EPA Method 24) Not available
Vapor Pressure: Less than 5 mm.
Vapor Density: Not available
Evaporation Rate
(Ether = 1) Not available
10. STABILITY AND REACTIVITY
Stability: Stable
Hazardous Polymerization: Will not occur
Incompatibility: None
Conditions to Avoid: Not available
LOCTITE CORPORATION 07/02/97
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 04 of 05
Product Name: 1L 3021 MEDICAL DEVICE ADHESIVE UV CURING
Item No.: 18008
10. STABILITY AND REACTIVITY (continued)
Hazardous Decomposition
Products (non-thermal): None
11. TOXICOLOGICAL INFORMATION
See Section 3.
12. ECOLOGICAL INFORMATION
No data available
13. DISPOSAL CONSIDERATIONS
Recommended methods of
disposal: Incinerate following EPA and local regulations.
EPA Hazardous Waste
Number NH - Not a RCRA Hazardous Waste Material
14. TRANSPORTATION INFORMATION
DOT (49 CFR 172)
Domestic Ground Transport
Proper Shipping Name: Unrestricted (Not more than 450 liters);
Combustible liquids, n.o.s.(Contains acrylic acid)
(More than 450 liters)
Hazard Class or
Division: Unrestricted (Not more than 450 liters)
Combustible liquid (More than 450 liters)
Identification Number: None (Not more than 450 liters);
NA 1993 (More than 450 liters)
Marine Pollutant: None
IATA
Proper Shipping Name: Unrestricted
Class or Division: Unrestricted
UN or ID Number: None
15. REGULATORY INFORMATION
CA Proposition 65: WARNING: This product contains chemicals known to
the State of California to cause cancer
and birth defects or other reproductive
harm.
Toluene Diisocyanate, Ethylene Oxide,
Toluene
LOCTITE CORPORATION 07/02/97
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 05 of 05
Product Name: 1L 3021 MEDICAL DEVICE ADHESIVE UV CURING
Item No.: 18008
16. OTHER INFORMATION
Estimated NFPA(R) Code:
Health Hazard: 2
Fire Hazard: 2
Reactivity Hazard: 1
Specific Hazard: Does not apply
Estimated HMIS(R) Code:
Health Hazard: 2
Flammability Hazard: 2
Reactivity Hazards: 1
Personal Protection: See Section 8.
NFPA is a registered trademark of the National Fire Protection Assn.
HMIS is a registered trademark of the National Paint and Coatings Assn.
Prepared By: Stephen Repetto
Title: Research Chemist, Health and Safety
Company: Loctite Corp., 1001 Tr Br Cr, Rocky Hill CT 06067
(24hr.) Phone: (860) 571-5100
Revision Date: April 15, 1997 Revision: 0023
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