3M Canada Company
Post Office Box 5757
London, Ontario N6A 4T1
Medical Emergency Telephone: (519) 451-2500, Ext. 2222
Transportation Emergency Telephone (CANUTEC): (613) 996-6666
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Material Safety Data Sheet
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Document id : 16-4935-9 Issue date : 02/16/2004
Version : 9.00 Supersedes date : 01/21/2004
Copyright, 1997, 3M Canada Company. All rights reserved. Copying
and/or downloading of this information for the purpose of properly
utilizing 3M products is allowed provided that: (1) the information
is copied in full with no changes unless prior written agreement is
obtained from 3M, and (2) neither the copy nor the original is resold
or otherwise distributed with the intention of earning a profit
thereon.
Prepared by: Environmental Health and Safety Services
Department, 3M Canada Company
Telephone: (519) 452-2161, Fax: (519) 452-6015, Web Site: www.3M.ca
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1 Product Identification
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Tradename:
3M(TM) HI-STRENGTH SPRAY ADHESIVE 90 (AEROSOL)
Product ID:
62-4942-0926-5 62-4942-4925-3 62-4942-4928-7 62-4942-4930-3
62-4942-4935-2 62-4942-4938-6 CS-0406-7096-3 CS-0406-7111-0
CS-0406-7139-1
Intended Use of Product:
Aerosol Adhesive
Division:
Industrial Adhesives and Tapes
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2 Composition/Information on Ingredients
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Ingredient Name CAS Number Percentage
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DIMETHYL ETHER 115-10-6 35 - 45
METHYL ACETATE 79-20-9 25 - 35
NONVOLATILE COMPONENTS Trade Secret 10 - 20
CYCLOHEXANE 110-82-7 7 - 13
PENTANE 109-66-0 1 - 5
1,1-DIFLUOROETHANE 75-37-6 1 - 5
METHYL ALCOHOL 67-56-1 0.1 - 0.4
NOTE:
3M(TM) HI-STRENGTH SPRAY ADHESIVE 90 (AEROSOL) Page 2 of 11
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NON-VOLATILE COMPONENTS is a non-hazardous Trade Secret material
according to WHMIS criteria.
Each percentage is expressed as the
ratio of the weight of the ingredient to the weight of the
controlled product.
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3 Hazards Identification
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Critical Hazards:
Flammable liquified gas.
Moderate Eye Irritation: Signs/symptoms may include redness,
swelling, pain, tearing, and blurred or hazy vision.
May be absorbed through skin and cause target organ effects.
May be absorbed following inhalation and cause target organ effects.
May be absorbed following ingestion and cause target organ effects.
WARNING: Contains a chemical which can cause birth defects.
See Sections 7 and 11 for further information.
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4 First Aid Measures
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Instructions for Eye Contact:
Flush eyes with large amounts of water. If signs/symptoms persist,
get medical attention.
Instructions for Skin Contact:
Wash affected area with soap and water. If signs/symptoms develop,
get medical attention.
Instructions for Inhalation:
Remove person to fresh air. If signs/symptoms develop, get medical
attention.
Instructions for Ingestion:
Do not induce vomiting. Give victim two glasses of water. Never
give anything by mouth to an unconscious person. Get immediate
medical attention.
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5 Fire Fighting Measures
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Flash point: -41.11 C TCC
Lower Explosive Limit (%): Not Available
Upper Explosive Limit (%): Not Available
Autoignition temperature: Not Available
Suitable Extinguishing Media:
Use fire extinguishers with class B extinguishing agents (e.g., dry
chemical, carbon dioxide).
Exposure Hazards during Fire:
No data available.
3M(TM) HI-STRENGTH SPRAY ADHESIVE 90 (AEROSOL) Page 3 of 11
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Combustion Products from Fire:
Carbon monoxide - During Combustion;
Carbon dioxide - During Combustion;
Irritant Vapours or Gases - During Combustion;
Fire Fighting Procedures:
Wear full protective clothing, including helmet, self-contained,
positive pressure or pressure demand breathing apparatus, bunker
coat and pants, bands around arms, waist and legs, face mask, and
protective covering for exposed areas of the head.
NFPA: Health 2
NFPA: Fire 4
NFPA: Reactivity 0
NFPA: Unusual Reaction Hazard none
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6 Accidental Release Measures
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Personal Precautions:
No data available.
Spill Response:
Evacuate unprotected and untrained personnel from hazard area. The
spill should be cleaned up by qualified personnel. Remove all
ignition sources such as flames, smoking materials, and electrical
spark sources. Use only non-sparking tools. Ventilate the area
with fresh air. If possible, seal leaking container. Place leaking
containers in a well-ventilated area, preferably an operating
exhaust hood, or if necessary outdoors on an impermeable surface
until appropriate packaging for the leaking container or its
contents is available. Close cylinder. If the cylinder can't be
closed, place in a well-ventilated area, preferably an operating
exhaust hood, or if necessary outdoors. Dispose of collected
material as soon as possible. Discharge the resulting residue
containing solution to a municipal or industrial wastewater
treatment facility.
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7 Handling and Storage
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Storage Requirements:
No data available.
Incompatible Materials:
Store away from heat.
Store out of direct sunlight.
Store away from acids;
Ventilation:
No data available.
Fire Prevention:
Flammable liquified gas.
3M(TM) HI-STRENGTH SPRAY ADHESIVE 90 (AEROSOL) Page 4 of 11
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Explosion Prevention:
Keep away from heat, sparks, open flame, pilot lights and other
sources of ignition.
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8 Exposure Controls/Personal Protection
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Personal Protection
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Eye Protection:
Avoid eye contact with vapours, mists, or spray. The following
should be worn alone or in combination, as appropriate, to prevent
eye contact: Safety glasses with side shields
Hand Protection:
Select and use gloves and/or protective clothing to prevent skin
contact based on the results of an exposure assessment. Consult
with your glove and/or protective clothing manufacturer for
selection of appropriate compatible materials.
Skin Protection:
Avoid prolonged or repeated skin contact. Gloves not normally
required. Avoid skin contact.
Respiratory Protection:
Consult the current 3M Respirator Selection Guide for additional
information or call 1-800-243-4630 for 3M technical assistance.
Avoid breathing of vapours, mists or spray. Select one of the
following approved respirators based on airborne concentration of
contaminants and in accordance with regulations: Half facepiece or
fullface air-purifying respirator with organic vapor cartridges.
Ingestion (Prevention):
Do not eat, drink or smoke when using this product. Wash exposed
areas thoroughly with soap and water. Keep out of the reach of
children.
Recommended Ventilation:
Use with appropriate local exhaust ventilation. Do not use in a
confined area or areas with little or no air movement. Use general
dilution ventilation and/or local exhaust ventilation to control
airborne exposures to below Occupational Exposure Limits and/or
control mist, vapor, or spray. If ventilation is not adequate, use
respiratory protection equipment.
Ingredient Exposure Data
------------------------
DIMETHYL ETHER (115-10-6)
LD50 (rat, oral)
: No data available.
LC50 (rat, inhalation/4 hours): 164000 ppm
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PIN (Product Identification Number): UN 1033
Inventory Certifications: AICS - Australian Inventory of Chemical
Substances
DSL - Domestic Substances List (Canada)
CICS - Chinese Inventory of Chemical Substances
2040658 EINECS - European Inventory of Existing
Commercial Chemical Substances
KE-27704 KECI - Korean Existing Chemicals Inventory
2-360 MITI - Ministry of International Trade and Industry (JAPAN)
PICCS - Philippines Inventory of Commercial Chemical Substances
TSCA - Toxic Substances Control Act (USA)
Exposure Limits: AIHA: TWA 1000 ppm
CMRG: TWA 1000 ppm
EU Hazard Symbols and Risk Phrases: EU - Adaptation 21 (F+; R:12)
METHYL ACETATE (79-20-9)
LD50 (rat, oral): >5 g/kg
LD50 (dermal, rabbit): >5 g/kg
LC50 (rat, inhalation/4 hours)
: No data available.
PIN (Product Identification Number): 1231
Inventory Certifications: AICS - Australian Inventory of Chemical
Substances
DSL - Domestic Substances List (Canada)
CICS - Chinese Inventory of Chemical Substances
2011852 EINECS - European Inventory of Existing
Commercial Chemical Substances
KE-23405 KECI - Korean Existing Chemicals Inventory
2-725 MITI - Ministry of International Trade and Industry (JAPAN)
PICCS - Philippines Inventory of Commercial Chemical Substances
TSCA - Toxic Substances Control Act (USA)
Exposure Limits: ACGIH: TWA 200 ppm
ACGIH: TWA 606 mg/m3
ACGIH: STEL 250 ppm
ACGIH: STEL 760 mg/m3
EU Hazard Symbols and Risk Phrases: EU - Adaptation 25 (F,Xi;
R:11-36-66-67)
EU Nota: 6
NONVOLATILE COMPONENTS (Trade Secret)
Specific Ingredient Data: No data available. No data available.
LD50 (rat, oral)
: No data available.
LC50 (rat, inhalation/4 hours)
: No data available.
Exposure Limits
: No data available.
CYCLOHEXANE (110-82-7)
3M(TM) HI-STRENGTH SPRAY ADHESIVE 90 (AEROSOL) Page 6 of 11
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LD50 (rat, oral): 12,705 mg/kg
LC50 (rat, inhalation/4 hours)
: No data available.
PIN (Product Identification Number): 1145
Inventory Certifications: AICS - Australian Inventory of Chemical
Substances
DSL - Domestic Substances List (Canada)
CICS - Chinese Inventory of Chemical Substances
2038062 EINECS - European Inventory of Existing
Commercial Chemical Substances
KE-18562 KECI - Korean Existing Chemicals Inventory
3-2233 MITI - Ministry of International Trade and Industry (JAPAN)
PICCS - Philippines Inventory of Commercial Chemical Substances
TSCA - Toxic Substances Control Act (USA)
Exposure Limits: ACGIH: TWA 100 ppm
EU Nota: 4,6
PENTANE (109-66-0)
LD50 (rat, oral): 400 mg/kg
LC50 (rat, inhalation/4 hours): 364 g/m3
PIN (Product Identification Number): 1265
Inventory Certifications: AICS - Australian Inventory of Chemical
Substances
DSL - Domestic Substances List (Canada)
CICS - Chinese Inventory of Chemical Substances
2036924 EINECS - European Inventory of Existing
Commercial Chemical Substances
KE-27968 KECI - Korean Existing Chemicals Inventory
2-5 MITI - Ministry of International Trade and Industry (JAPAN)
PICCS - Philippines Inventory of Commercial Chemical Substances
TSCA - Toxic Substances Control Act (USA)
Exposure Limits: ACGIH: TWA 600 ppm
ACGIH: TWA 1770 mg/m3
EU Hazard Symbols and Risk Phrases: EU - Adaptation 25 (F+,N,Xn;
R:12-51-53-65-66-67)
EU Nota: 4,6,C
1,1-DIFLUOROETHANE (75-37-6)
LD50 (rat, oral)
: No data available.
LC50 (rat, inhalation/4 hours): 64,000 ppm
PIN (Product Identification Number): 1030
Inventory Certifications: AICS - Australian Inventory of Chemical
Substances
DSL - Domestic Substances List (Canada)
CICS - Chinese Inventory of Chemical Substances
2008661 EINECS - European Inventory of Existing
Commercial Chemical Substances
3M(TM) HI-STRENGTH SPRAY ADHESIVE 90 (AEROSOL) Page 7 of 11
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KE-10545 KECI - Korean Existing Chemicals Inventory
2-86 MITI - Ministry of International Trade and Industry (JAPAN)
PICCS - Philippines Inventory of Commercial Chemical Substances
TSCA - Toxic Substances Control Act (USA)
Exposure Limits: AIHA: TWA 1000 ppm
AIHA: TWA 2700 mg/m3
CMRG: TWA 1000 ppm
METHYL ALCOHOL (67-56-1)
LD50 (rat, oral): 5628 mg/kg
LD50 (dermal, rabbit): 15800 mg/kg
LC50 (rat, inhalation/4 hours): 64000 ppm
PIN (Product Identification Number): UN1230
Inventory Certifications: AICS - Australian Inventory of Chemical
Substances
CICS - Chinese Inventory of Chemical Substances
DSL - Domestic Substances List (Canada)
2006596 EINECS - European Inventory of Existing
Commercial Chemical Substances
KE-23193 KECI - Korean Existing Chemicals Inventory
2-201 MITI - Ministry of International Trade and Industry (JAPAN)
PICCS - Philippines Inventory of Commercial Chemical Substances
TSCA - Toxic Substances Control Act (USA)
Exposure Limits: ACGIH: TWA 200 ppm (skin contact contributes to
exposure)
ACGIH: TWA 262 mg/m3 (skin contact contributes to exposure)
ACGIH: STEL 250 ppm (skin contact contributes to exposure)
ACGIH: STEL 328 mg/m3 (skin contact contributes to exposure)
EU Hazard Symbols and Risk Phrases: EU - Adaptation 28 (F,T;
R:11-23-24-25-39/23-39/24-39/25)
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9 Physical and Chemical Properties
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Physical form,Color,Odour: Aerosol; Gas; clear; sweet,
fruity odour.
Odour Threshold: No data available.
pH: Not Available
Boiling point/boiling range: Not applicable
Melting point/melting range: Not applicable
Vapour pressure: Compressed Gas;
Water Solubility: Nil
Partition coefficient (K o/w): No data available.
Specific gravity: 0.726 Water=1
Vapour density: 2.97 Air=1
Volatile organic compounds: Approximately54 % SCAQ443
3M(TM) HI-STRENGTH SPRAY ADHESIVE 90 (AEROSOL) Page 8 of 11
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Evaporation rate: 1.90 Ether=1
Viscosity: Not applicable
Percent Volatile: <75 % by weight
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10 Stability and Reactivity
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Conditions to Avoid:
Store away from heat.
Store out of direct sunlight.
Materials to Avoid:
Store away from acids;
Hazardous Decomposition:
Carbon monoxide - During Combustion;
Carbon dioxide - During Combustion;
Irritant Vapours or Gases - During Combustion;
Stability and Reactivity:
Stable. Hazardous polymerization will not occur.
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11 Toxicological Information
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Effects from Eye Contact:
Moderate Eye Irritation: Signs/symptoms may include redness,
swelling, pain, tearing, and blurred or hazy vision.
Effects from Skin Contact:
May be absorbed through skin and cause target organ effects.
Prolonged or repeated exposure may cause: Mild Skin Irritation:
Signs/symptoms can include localized redness, swelling, and
itching.
Effects from Inhalation:
Upper Respiratory Tract Irritation: Signs/symptoms may include
cough, sneezing, nasal discharge, headache, hoarseness, and nose
and throat pain.
May be absorbed following inhalation and cause target organ effects.
Intentional concentration and inhalation may be harmful or fatal.
Effects from Ingestion:
Gastrointestinal Irritation: Signs/symptoms may include abdominal
pain, nausea, diarrhea and vomiting.
May be absorbed following ingestion and cause target organ effects.
Sensitization Information:
No data available.
Carcinogenicity:
No data available.
Mutagenicity:
No data available.
Reproductive Effects:
WARNING: Contains a chemical which can cause birth defects.
3M(TM) HI-STRENGTH SPRAY ADHESIVE 90 (AEROSOL) Page 9 of 11
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Component Based Information:
No data available.
Product Based Information:
No data available.
Other Effects & Information:
Central Nervous System (CNS) Depression: Signs/symptoms may include
headache, dizziness, drowsiness, incoordination, nausea, slowed
reaction time, slurred speech, giddiness, and unconsciousness.
Prolonged or repeated exposure, above recommended guidelines, may
cause:
Liver Effects: Signs/symptoms may include loss of appetite,
weight loss, fatigue, weakness, abdominal tenderness and jaundice.
Kidney Effects: Signs/symptoms may include reduced or absent urine
production, increased serum creatinine, lower back pain, increased
protein in urine, and increased blood urea nitrogen (BUN).
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12 Ecological Information
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Environmental Data:
Ecotoxicity Data:
Not determined.
Ecofate Data:
Not determined.
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13 Disposal Considerations
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Product as Sold:
Incinerate in a permitted hazardous waste incinerator. The facility
should be equipped to handle gaseous waste. Recycle empty aerosol
containers where available.
Product Packaging:
No data available.
Special Instructions:
Since regulations vary, consult applicable regulations or
authorities before disposal.
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14 Transportation Information
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Transportation of Dangerous Goods
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TDG Classification: Consumer Commodity
Class/Division: 2.1
Special Information:
Contact 3M for more information.
International Dangerous Goods Classification
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15 Regulatory Information
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WHMIS Classification: A, B5, D2A, D2B
CS-0406-7111-0: Exempt For
Export Only.
NOTE:
This product has been classified in accordance with the hazard
criteria of the Controlled Products Regulations (CPR) and the MSDS
contains all the information required by the CPR.
Product Certifications:
The product on this MSDS, or all its components, is included on the
following countries' chemical inventories, as noted:
PICCS - Philippines Inventory of Commercial Chemical Substances
TSCA - Toxic Substances Control Act (USA)
AICS - Australian Inventory of Chemical Substances
DSL - Domestic Substances List (Canada)
CICS - Chinese Inventory of Chemical Substances
EINECS -
European Inventory of Existing Commercial Chemical Substances
KECI - Korean Existing Chemicals Inventory
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16 Other Information
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Reason for Reissue:
The following Sections and topics have been updated or revised:
Added product ids to the MSDS;
The information in this Material Safety Data Sheet (MSDS) is believed
to be correct as of the date issued. 3M MAKES NO WARRANTIES,
EXPRESSED OR IMPLIED, STATUTORY OR OTHERWISE, INCLUDING, BUT NOT
3M(TM) HI-STRENGTH SPRAY ADHESIVE 90 (AEROSOL) Page 11 of 11
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LIMITED TO, ANY IMPLIED WARRANTY OR CONDITION OF MERCHANTABILITY OR
FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. User is responsible for determining whether the 3M product is
fit for a particular purpose and suitable for user's method of use or
application. Given the variety of factors that can affect the use
and application of a 3M product, some of which are uniquely within
the user's knowledge and control, it is essential that the user
evaluate the 3M product to determine whether it is fit for a
particular purpose and suitable for user's method of use or
application.
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