3M MATERIAL SAFETY DATA SHEET 3M(TM) Hi-Strength Spray Adhesive 90 (aerosol) 06/09/2005
Material Safety Data Sheet
Copyright, 2005, 3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly
utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is
obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit
thereon.
SECTION 1: PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: 3M(TM) Hi-Strength Spray Adhesive 90 (aerosol)
MANUFACTURER: 3M
DIVISION: Industrial Adhesives and Tapes
ADDRESS: 3M Center
St. Paul, MN 55144-1000
EMERGENCY PHONE: 1-800-364-3577 or (651) 737-6501 (24 hours)
Issue Date: 06/09/2005
Supercedes Date: 03/25/2005
Document Group: 16-4935-9
Product Use:
Intended Use: aerosol adhesive
Specific Use: hi-strength aerosol adhesive
SECTION 2: INGREDIENTS
Ingredient C.A.S. No. % by Wt
DIMETHYL ETHER 115-10-6 35 -45
METHYL ACETATE 79-20-9 25 -35
NONVOLATILE COMPONENTS - N.J. TRADE SECRET REGISTRY NO. Trade Secret 10 -2004499600-6448P
CYCLOHEXANE 110-82-7 7 -13
1,1-DIFLUOROETHANE 75-37-6 1 -5
PENTANE 109-66-0 1 -5
SECTION 3: HAZARDS IDENTIFICATION
3.1 EMERGENCY OVERVIEW
Specific Physical Form: Aerosol
Odor, Color, Grade: clear, sweet fruity odor
General Physical Form: Gas
Immediate health, physical, and environmental hazards: Closed containers exposed to heat from fire may build pressure and
explode. Extremely flammable liquid and vapor. Vapors may travel long distances along the ground or floor to an ignition source and
flash back. Aerosol container contains flammable material under pressure. May cause target organ effects.
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3M MATERIAL SAFETY DATA SHEET 3M(TM) Hi-Strength Spray Adhesive 90 (aerosol) 06/09/2005
3.2 POTENTIAL HEALTH EFFECTS
Eye Contact:
Moderate Eye Irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision.
Skin Contact:
May be absorbed through skin and cause target organ effects.
Prolonged or repeated exposure may cause:
Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, and itching.
Inhalation:
Upper Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose
and throat pain.
May be absorbed following inhalation and cause target organ effects.
Intentional concentration and inhalation may be harmful or fatal.
Ingestion:
Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, nausea, diarrhea and vomiting.
May be absorbed following ingestion and cause target organ effects.
Target Organ Effects:
Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea,
slowed reaction time, slurred speech, giddiness, and unconsciousness.
Prolonged or repeated exposure, above recommended guidelines, may cause:
Liver Effects: Signs/symptoms may include loss of appetite, weight loss, fatigue, weakness, abdominal tenderness and
jaundice.
Kidney Effects: Signs/symptoms may include reduced or absent urine production, increased serum creatinine, lower back
pain, increased protein in urine, and increased blood urea nitrogen (BUN).
SECTION 4: FIRST AID MEASURES
4.1 FIRST AID PROCEDURES
The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are
followed.
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3M MATERIAL SAFETY DATA SHEET 3M(TM) Hi-Strength Spray Adhesive 90 (aerosol) 06/09/2005
Eye Contact: Flush eyes with large amounts of water. If signs/symptoms persist, get medical attention.
Skin Contact: Wash affected area with soap and water. If signs/symptoms develop, get medical attention.
Inhalation: Remove person to fresh air. If signs/symptoms develop, get medical attention.
If Swallowed: Do not induce vomiting. Give victim two glasses of water. Never give anything by mouth to an unconscious
person. Get immediate medical attention.
SECTION 5: FIRE FIGHTING MEASURES
5.1 FLAMMABLE PROPERTIES
Autoignition temperature No Data Available
Flash Point -42.00 咶 [Test Method: Tagliabue Closed Cup]
Flammable Limits - LEL No Data Available
Flammable Limits - UEL No Data Available
OSHA Flammability Classification: Class IA Flammable Liquid
5.2 EXTINGUISHING MEDIA
Use fire extinguishers with class B extinguishing agents (e.g., dry chemical, carbon dioxide).
5.3 PROTECTION OF FIRE FIGHTERS
Special Fire Fighting Procedures: Wear full protective equipment (Bunker Gear) and a self-contained breathing apparatus
(SCBA).
Unusual Fire and Explosion Hazards: Closed containers exposed to heat from fire may build pressure and explode. Extremely
flammable liquid and vapor. Vapors may travel long distances along the ground or floor to an ignition source and flash back. Aerosol
container contains flammable material under pressure.
Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decomposition
information.
SECTION 6: ACCIDENTAL RELEASE MEASURES
Accidental Release Measures: Evacuate unprotected and untrained personnel from hazard area. The spill should be cleaned up by
qualified personnel. Remove all ignition sources such as flames, smoking materials, and electrical spark sources. Use only non-
sparking tools. Ventilate the area with fresh air. If possible, seal leaking container. Place leaking containers in a well-ventilated area,
preferably an operating exhaust hood, or if necessary outdoors on an impermeable surface until appropriate packaging for the leaking
container or its contents is available. Close cylinder. If the cylinder can't be closed, place in a well-ventilated area, preferably an
operating exhaust hood, or if necessary outdoors. Dispose of collected material as soon as possible. Discharge the resulting residue
containing solution to a municipal or industrial wastewater treatment facility.
In the event of a release of this material, the user should determine if the release qualifies as reportable according to
local, state, and federal regulations.
SECTION 7: HANDLING AND STORAGE
7.1 HANDLING
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3M MATERIAL SAFETY DATA SHEET 3M(TM) Hi-Strength Spray Adhesive 90 (aerosol) 06/09/2005
Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Keep away from heat,
sparks, open flame, pilot lights and other sources of ignition. Avoid prolonged or repeated skin contact. Avoid eye contact with
vapors, mists, or spray. Keep out of the reach of children. Vapors may ignite explosively. May cause flash fire. Prevent build-up of
vapors - open all windows and doors. Maintain vapor concentrations below recommended exposure limits. Use only with cross-
ventilation. Without adequate ventilation, vapors may settle in low-lying areas. Keep away from heat, sparks, and open flame. Do not
smoke or ignite matches, lighters, etc.
7.2 STORAGE
Store away from acids. Store away from heat. Store out of direct sunlight.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1 ENGINEERING CONTROLS
Use with appropriate local exhaust ventilation. Do not use in a confined area or areas with little or no air movement. Use general
dilution ventilation and/or local exhaust ventilation to control airborne exposures to below Occupational Exposure Limits and/or
control mist, vapor, or spray. If ventilation is not adequate, use respiratory protection equipment.
8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE)
8.2.1 Eye/Face Protection
Avoid eye contact. Avoid eye contact with vapors, mists, or spray.
The following eye protection(s) are recommended: Safety Glasses with side shields.
8.2.2 Skin Protection
Gloves not normally required. Avoid skin contact. Avoid prolonged or repeated skin contact.
8.2.3 Respiratory Protection
Avoid breathing of vapors, mists or spray. Consult the current 3M Respirator Selection Guide for additional information or call 1800-
243-4630 for 3M technical assistance.
Select one of the following NIOSH approved respirators based on airborne concentration of contaminants and in accordance with
OSHA regulations: Half facepiece or fullface air-purifying respirator with organic vapor cartridges. Consult the current 3M
Respiratory Selection Guide for additional information or call 1-800-243-4630 for 3M technical assistance.
8.2.4 Prevention of Swallowing
Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water.
8.3 EXPOSURE GUIDELINES
Ingredient Authority Type Limit Additional Information
1,1-DIFLUOROETHANE AIHA TWA 1000 ppm
1,1-DIFLUOROETHANE CMRG TWA 1000 ppm
CYCLOHEXANE ACGIH TWA 100 ppm
CYCLOHEXANE OSHA TWA 300 ppm Table Z-
1
DIMETHYL ETHER AIHA TWA 1000 ppm
DIMETHYL ETHER CMRG TWA 1000 ppm
METHYL ACETATE ACGIH TWA 200 ppm
METHYL ACETATE ACGIH STEL 250 ppm
METHYL ACETATE OSHA TWA 200 ppm Table Z-1A
METHYL ACETATE OSHA STEL 250 ppm Table Z-1A
PENTANE ACGIH TWA 600 ppm
PENTANE OSHA TWA, Vacated 600 ppm
PENTANE OSHA STEL, Vacated 750 ppm
PENTANE OSHA TWA 1000 ppm Table Z-
1
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3M MATERIAL SAFETY DATA SHEET 3M(TM) Hi-Strength Spray Adhesive 90 (aerosol) 06/09/2005
VAC Vacated PEL:Vacated Permissible Exposure Limits [PEL] are enforced as the OSHA PEL in some states. Check with your local
regulatory agency.
SOURCE OF EXPOSURE LIMIT DATA:
ACGIH: American Conference of Governmental Industrial Hygienists
CMRG: Chemical Manufacturer Recommended Guideline
OSHA: Occupational Safety and Health Administration
AIHA: American Industrial Hygiene Association Workplace Environmental Exposure Level (WEEL)
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
Specific Physical Form: Aerosol
Odor, Color, Grade: clear, sweet fruity odor
General Physical Form: Gas
Autoignition temperature No Data Available
Flash Point -42.00 咶 [Test Method: Tagliabue Closed Cup]
Flammable Limits - LEL No Data Available
Flammable Limits - UEL No Data Available
Boiling point Not Applicable
Vapor Density 2.97 [Ref Std: AIR=1]
Specific Gravity 0.726 [Ref Std: WATER=1]
pH No Data Available
Melting point Not Applicable
Solubility in Water Nil
Evaporation rate 1.90 [Ref Std: ETHER=1]
Hazardous Air Pollutants <=.4 % weight [Test Method: Calculated]
Volatile Organic Compounds 54 %
Percent volatile <=75 % weight
VOC Less H2O & Exempt Solvents 533 g/l
Viscosity Not Applicable
SECTION 10: STABILITY AND REACTIVITY
Stability: Stable.
Materials and Conditions to Avoid: Heat
Hazardous Polymerization: Hazardous polymerization will not occur.
Hazardous Decomposition or By-Products
Substance Condition
Carbon monoxide During Combustion
Carbon dioxide During Combustion
Irritant Vapors or Gases During Combustion
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3M MATERIAL SAFETY DATA SHEET 3M(TM) Hi-Strength Spray Adhesive 90 (aerosol) 06/09/2005
SECTION 11: TOXICOLOGICAL INFORMATION
Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its
components.
SECTION 12: ECOLOGICAL INFORMATION
ECOTOXICOLOGICAL INFORMATION
Not determined.
CHEMICAL FATE INFORMATION
Not determined.
SECTION 13: DISPOSAL CONSIDERATIONS
Waste Disposal Method: Incinerate in a permitted hazardous waste incinerator. The facility should be equipped to handle gaseous
waste.
RECYCLE EMPTY AEROSOL CONTAINERS WHERE AVAILABLE.
EPA Hazardous Waste Number (RCRA): D001 (Ignitable)
Since regulations vary, consult applicable regulations or authorities before disposal.
SECTION 14:TRANSPORT INFORMATION
ID Number(s):
62-4942-0926-5, 62-4942-4925-3, 62-4942-4928-7, 62-4942-4930-3, 62-4942-4935-2, 62-4942-4938-6, CS-0406-7111-0
Please contact the emergency numbers listed on the first page of the MSDS for Transportation Information for this
material.
SECTION 15: REGULATORY INFORMATION
US FEDERAL REGULATIONS
Contact 3M for more information.
311/312 Hazard Categories:
Fire Hazard - Yes Pressure Hazard - Yes Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - Yes
Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA):
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3M MATERIAL SAFETY DATA SHEET 3M(TM) Hi-Strength Spray Adhesive 90 (aerosol) 06/09/2005
Ingredient C.A.S. No % by Wt
CYCLOHEXANE 110-82-7 7 -13
This material contains a chemical which requires export notification under TSCA Section 12[b]:
Ingredient (Category if applicable) C.A.S. No Regulation Status
PENTANE 109-66-0 Toxic Substances Control Act (TSCA) 4 Test ApplicableRule Chemicals
CYCLOHEXANE 110-82-7 Toxic Substances Control Act (TSCA) 4 Test ApplicableRule Chemicals
METHYL ACETATE 79-20-9 Toxic Substances Control Act (TSCA) 4 Test Applicable
Rule Chemicals
STATE REGULATIONS
Contact 3M for more information.
CHEMICAL INVENTORIES
The components of this product are in compliance with the chemical notification requirements of TSCA.
All applicable chemical ingredients in this material are listed on the European Inventory of Existing Chemical Substances (EINECS),
or are exempt polymers whose monomers are listed on EINECS.
Contact 3M for more information.
INTERNATIONAL REGULATIONS
Contact 3M for more information.
This MSDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.
SECTION 16: OTHER INFORMATION
NFPA Hazard Classification
Health: 2 Flammability: 4 Reactivity: 0 Special Hazards: None
Aerosol Storage Code: 3
National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are
presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the
inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to
be generated in significant quantities.
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3M MATERIAL SAFETY DATA SHEET 3M(TM) Hi-Strength Spray Adhesive 90 (aerosol) 06/09/2005
Revision Changes:
Section 9: Property description for optional properties was modified.
DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M
MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY
OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of
use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely
within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for
a
particular purpose and suitable for user's method of use or application.
3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may
have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy.
In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M.
3M MSDSs are available at www.3M.com
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