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Section 1 - Chemical Product and Company Identification |
MSDS Name: Palladium (II) Chloride
Catalog Numbers:
P6 5, P6-5, P65
Synonyms:
Palladium Chloride; Palladous Chloride; Palladium Dichloride;
Dichloropalladium; Paladium(ous) Chloride.
Company Identification:
Fisher Scientific
1 Reagent Lane
Fair Lawn, NJ 07410
For information, call: 201-796-7100
Emergency Number: 201-796-7100
For CHEMTREC assistance, call: 800-424-9300
For International CHEMTREC assistance, call: 703-527-3887
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Section 2 - Composition, Information on Ingredients
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| CAS# |
Chemical Name |
Percent |
EINECS/ELINCS |
| 7647-10-1 | Palladium(II) chloride |
ca.100 | 231-596-2 |
Hazard Symbols: XI
Risk Phrases: 36/37/38
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Section 3 - Hazards Identification
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EMERGENCY OVERVIEW
Appearance: dark brown powder and chunks.
Warning! Causes eye and skin irritation. May cause
digestive tract irritation. Causes respiratory tract irritation.
Hygroscopic (absorbs moisture from the air). Reproductively active.
Target Organs: No data found.
Potential Health Effects
Eye:
Causes eye irritation. May cause chemical conjunctivitis.
Skin:
Causes skin irritation.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea.
Inhalation:
Causes irritation of mucous membrane. Can produce delayed pulmonary
edema.
Chronic:
Effects may be delayed. Laboratory experiments have resulted in
mutagenic effects. Animal studies have reported the development of
tumors. May cause adverse reproductive effects.
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Section 4 - First Aid Measures
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Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Immediately flush skin with plenty of water for at
least 15 minutes while removing contaminated clothing and shoes.
Wash clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid. Do NOT use mouth-to-mouth
resuscitation.
Notes to Physician:
Treat symptomatically and supportively.
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Section 5 - Fire Fighting Measures
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General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. This
material in sufficient quantity and reduced particle size is capable
of creating a dust explosion.
Extinguishing Media:
Use extinguishing media most appropriate for the surrounding fire.
Use water spray, dry chemical, carbon dioxide, or appropriate foam.
Flash Point: Not applicable.
Autoignition Temperature: Not applicable.
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating:
(estimated) Health: 1; Flammability: 0; Instability: 0
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Section 6 - Accidental Release Measures
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General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Clean up spills immediately, observing precautions in the
Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.
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Section 7 - Handling and Storage
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Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Avoid contact with eyes, skin, and clothing. Avoid
contact with skin and eyes. Keep container tightly closed. Avoid
ingestion and inhalation. Use with adequate ventilation.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances. Store
protected from moisture.
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Section 8 - Exposure Controls, Personal Protection
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Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
| Chemical Name |
ACGIH |
NIOSH |
OSHA - Final PELs |
| Palladium(II) chloride | none listed |
none listed | none listed |
OSHA Vacated PELs:
Palladium(II) chloride:
No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant a respirator's use.
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Section 9 - Physical and Chemical Properties
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Physical State: Powder and chunks
Appearance: dark brown
Odor: odorless
pH: Not available.
Vapor Pressure: Not available.
Vapor Density: Not available.
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: Not applicable.
Freezing/Melting Point:678-680 deg C (dec)
Decomposition Temperature:500 deg C
Solubility: Completely soluble in water.
Specific Gravity/Density:4.0 @ 18癈
Molecular Formula:PdCl2
Molecular Weight:177.306
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Section 10 - Stability and Reactivity
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Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Incompatible materials, dust generation, excess heat, exposure to
moist air or water.
Incompatibilities with Other Materials:
Strong oxidizing agents, acids, aluminum, ammonia, magnesium,
nitrates, zinc, heat, moisture, thiocyanates, organic solvents.
Hazardous Decomposition Products:
Hydrogen chloride, irritating and toxic fumes and gases, oxides of
palladium.
Hazardous Polymerization: Will not occur.
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Section 11 - Toxicological Information
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RTECS#:
CAS# 7647-10-1: RT3500000
LD50/LC50:
CAS# 7647-10-1:
Draize test, rabbit, skin: 100 mg/24H Mild;
Oral, mouse: LD50 = >1 gm/kg;
Oral, rat: LD50 = 2704
mg/kg;
Carcinogenicity:
CAS# 7647-10-1:
Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Epidemiology:
Oral, mouse: TDLo = 880 mg/kg/75W-C (Tumorigenic - Carcinoge
nic by RTECS criteria - Lungs, Thorax, or Respiration -
tumors and Blood - leukemia).
Teratogenicity:
No information available.
Reproductive Effects:
Intratesticular, rat: TDLo = 3546 ug/kg (male 1 day(s) pre-mating)
Paternal Effects - spermatogenesis (incl. genetic material, sperm
morphology, motility, and count) and Paternal Effects - testes,
epididymis, sperm duct.; Subcutaneous, mouse: TDLo = 3546 ug/kg
(male 30 day(s) pre-mating) Paternal Effects - testes, epididymis,
sperm duct.
Neurotoxicity:
No information available.
Mutagenicity:
DNA Inhibition: Human, Lymphocyte = 600 umol/L.
Other Studies:
Standard Draize Test: Administration onto the skin (rabbit)
= 100 mg/24H (Mild).
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Section 12 - Ecological Information
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No information available.
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Section 13 - Disposal Considerations
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Chemical waste generators must determine whether a discarded chemical is classified
as a hazardous waste.
US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3.
Additionally, waste generators must consult state and local hazardous waste regulations to
ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
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Section 14 - Transport Information
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US DOT |
IATA |
RID/ADR |
IMO |
Canada TDG |
| Shipping Name: |
No information available. |
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No information available. |
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Section 15 - Regulatory Information
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US FEDERAL
TSCA
CAS# 7647-10-1 is listed on the TSCA inventory.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
SARA
CERCLA Hazardous Substances and corresponding RQs
None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
None of the chemicals in this product have a TPQ.
SARA Codes
CAS # 7647-10-1: acute.
Section 313
No chemicals are reportable under Section 313.
Clean Air Act:
This material does not contain any hazardous air pollutants.
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals in this product are listed as Hazardous
Substances under the CWA.
None of the chemicals in this product are listed as Priority
Pollutants under the CWA.
None of the chemicals in this product are listed as Toxic Pollutants
under the CWA.
OSHA:
None of the chemicals in this product are considered highly hazardous
by OSHA.
STATE
CAS# 7647-10-1 is not present on state lists from CA, PA, MN, MA,
FL, or NJ.
California No Significant Risk Level:
None of the chemicals in this product are listed.
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
XI
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 7647-10-1: 1
Canada - DSL/NDSL
CAS# 7647-10-1 is listed on Canada's DSL List.
Canada - WHMIS
This product has a WHMIS classification of D2A.
Canadian Ingredient Disclosure List
CAS# 7647-10-1 is listed on the Canadian Ingredient Disclosure List.
Exposure Limits
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Section 16 - Additional Information
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MSDS Creation Date: 7/02/1999
Revision #3 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no event shall Fisher be liable
for any claims, losses, or damages of any third party or for lost profits
or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if Fisher has been advised of
the possibility of such damages.
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