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Section 1 - Chemical Product and Company Identification |
MSDS Name: Ethyl(ethoxymethylene)cyanoacetate, 98%
Catalog Numbers:
AC118480000, AC118481000, AC118485000, NC9116106, NC9116164, NC9136838,
NC9224968, NC9454000, XXAC11848-1GR, XXAC11848-1GRS, XXAC11848-30KG
Synonyms:
Ethyl 2-cyano-3-ethoxyacrylate
Company Identification:
Fisher Scientific
1 Reagent Lane
Fair Lawn, NJ 07410
For information, call: 201-796-7100
Emergency Number: 201-796-7100
For CHEMTREC assistance, call: 800-424-9300
For International CHEMTREC assistance, call: 703-527-3887
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Section 2 - Composition, Information on Ingredients
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| CAS# |
Chemical Name |
Percent |
EINECS/ELINCS |
| 94-05-3 |
Ethyl(ethoxymethylene)cyanoacetate, 98% |
98% | 202-299-5 |
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Section 3 - Hazards Identification
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EMERGENCY OVERVIEW
Appearance: off-white solid.
Warning! Irritant. Harmful. May cause severe eye
irritation and possible injury. Causes skin irritation. Causes
digestive and respiratory tract irritation.
Target Organs: None.
Potential Health Effects
Eye:
May cause irreversible eye injury.
Skin:
May cause irritation with burning pain, itching and redness.
Ingestion:
Harmful if swallowed. May cause gastrointestinal irritation with
nausea, vomiting and diarrhea.
Inhalation:
Causes respiratory tract irritation.
Chronic:
Not available.
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Section 4 - First Aid Measures
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Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid imme
diately.
Skin:
Get medical aid. Immediately flush skin with plenty of water for at
least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid immediately. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. Get medical
aid.
Notes to Physician:
Treat symptomatically.
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Section 5 - Fire Fighting Measures
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General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.
Flash Point: 130 deg C ( 266.00 deg F)
Autoignition Temperature: Not available.
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating:
Not published.
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Section 6 - Accidental Release Measures
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General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container.
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Section 7 - Handling and Storage
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Handling:
Avoid contact with skin and eyes. Do not breathe dust, mist, or
vapor.
Storage:
Store in a cool, dry place. Store in a tightly closed container.
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Section 8 - Exposure Controls, Personal Protection
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Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower.
Exposure Limits
| Chemical Name |
ACGIH |
NIOSH |
OSHA - Final PELs |
| Ethyl(ethoxymethylene)cyanoacetate, 98%
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none listed
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none listed
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none listed
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OSHA Vacated PELs:
Ethyl(ethoxymethylene)cyanoacetate, 98%:
No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes:
Wear chemical splash goggles.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear a chemical apron.
Respirators:
A NIOSH/MSHA approved air purifying dust or mist
respirator or European Standard EN 149.
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Section 9 - Physical and Chemical Properties
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Physical State: Solid
Appearance: off-white
Odor: odorless
pH: Not available.
Vapor Pressure: .1 hPa @ 20 deg C
Vapor Density: Not available.
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: 190 - 191 deg C @ 30.00mm Hg
Freezing/Melting Point:51 - 53 deg C
Decomposition Temperature:Not available.
Solubility: <0.01 g/l (20 c)
Specific Gravity/Density:Not available.
Molecular Formula:C8H11NO3
Molecular Weight:169.18
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Section 10 - Stability and Reactivity
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Chemical Stability:
Not available.
Conditions to Avoid:
Not available.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong acids, strong bases, strong reducing
agents.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.
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Section 11 - Toxicological Information
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RTECS#:
CAS# 94-05-3
unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
CAS# 94-05-3:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
Epidemiology:
No data available.
Teratogenicity:
No data available.
Reproductive Effects:
No data available.
Mutagenicity:
No data available.
Neurotoxicity:
No data available.
Other Studies:
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Section 12 - Ecological Information
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Ecotoxicity:
No data available.
Daphniatoxicity: EC50 (Daphnia magna): 211.4 mg/l/40h
Environmental:
No information available.
Physical:
No information available.
Other:
No information available.
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Section 13 - Disposal Considerations
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Chemical waste generators must determine whether a discarded chemical is classified
as a hazardous waste.
US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3.
Additionally, waste generators must consult state and local hazardous waste regulations to
ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
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Section 14 - Transport Information
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US DOT |
Canada TDG |
| Shipping Name: |
TOXIC SOLIDS, ORGANIC, N.O.S. |
No information available. |
| Hazard Class: |
6.1 |
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| UN Number: |
UN2811 |
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| Packing Group: |
III |
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Section 15 - Regulatory Information
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US FEDERAL
TSCA
CAS# 94-05-3 is listed on the TSCA inventory.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
None of the chemicals in this product have a TPQ.
Section 313
No chemicals are reportable under Section 313.
Clean Air Act:
This material does not contain any hazardous air pollutants.
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals in this product
are listed as Hazardous Substances under the CWA.
None of the chemicals in this
product are listed as Priority Pollutants under the CWA.
None of the chemicals in this
product are listed as Toxic Pollutants under the CWA.
OSHA:
None of the chemicals in this product
are considered highly hazardous by OSHA.
STATE
CAS# 94-05-3 is not present on
state lists from CA, PA, MN, MA, FL, or NJ.
California Prop 65
California No Significant Risk Level:
None of the chemicals in this product are listed.
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
XN
Risk Phrases:
R 22 Harmful if swallowed.
R 37/38 Irritating to respiratory system and skin.
R 41 Risk of serious damage to eyes.
R 42/43 May cause sensitization by inhalation and skin contact.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately with plenty of
water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face protection.
WGK (Water Danger/Protection)
CAS# 94-05-3: 1
Canada - DSL/NDSL
CAS# 94-05-3 is listed on Canada's NDSL List.
Canada - WHMIS
not available.
This product has been classified in accordance with the hazard
criteria of the Controlled Products Regulations and the MSDS
contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
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Section 16 - Additional Information
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MSDS Creation Date: 9/02/1997
Revision #4 Date: 3/15/2007
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no event shall Fisher be liable
for any claims, losses, or damages of any third party or for lost profits
or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if Fisher has been advised of
the possibility of such damages.
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