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Section 1 - Chemical Product and Company Identification |
MSDS Name: 1,2-Diaminopropane
Catalog Numbers:
AC152400000, AC152400010, AC152402500, AC219480000, AC219485000, AC418330000
AC418330000, AC418330010, AC418332500
Synonyms:
1,2-Propanediamine; Propylenediamine.
Company Identification:
Acros Organics N.V.
One Reagent Lane
Fair Lawn, NJ 07410
For information in North America, call: 800-ACROS-01
For emergencies in the US, call CHEMTREC: 800-424-9300
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Section 2 - Composition, Information on Ingredients
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| CAS# |
Chemical Name |
Percent |
EINECS/ELINCS |
| 78-90-0 |
1,2-Diaminopropane |
99+ | 201-155-9 |
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Section 3 - Hazards Identification
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EMERGENCY OVERVIEW
Appearance: APHA: 20 max liquid. Flash Point: 33 deg C.
Danger! Harmful in contact with skin and if
swallowed. Causes burns by all exposure routes.
Flammable liquid and vapor. Hygroscopic (absorbs
moisture from the air).
Target Organs: Respiratory system,
gastrointestinal system, eyes, skin.
Potential Health Effects
Eye:
Causes eye burns. Causes redness and pain.
Skin:
Harmful if absorbed through the skin. Causes skin burns.
Ingestion:
Harmful if swallowed. Causes gastrointestinal tract burns.
Inhalation:
May cause severe irritation of the respiratory tract with sore
throat, coughing, shortness of breath and delayed lung edema. Causes
chemical burns to the respiratory tract.
Chronic:
No information found.
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Section 4 - First Aid Measures
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Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid imme
diately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes.
Ingestion:
Do not induce vomiting. Get medical aid immediately. Call a poison
control center.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do not use
mouth-to-mouth resuscitation if victim ingested or inhaled the
substance; induce artificial respiration with the aid of a pocket
mask equipped with a one-way valve or other proper respiratory
medical device.
Notes to Physician:
Treat symptomatically and supportively.
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Section 5 - Fire Fighting Measures
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General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. Combustion
generates toxic fumes. Will burn if involved in a fire. Containers
may explode in the heat of a fire. Flammable liquid and vapor.
Extinguishing Media:
Use water spray to cool fire-exposed containers. Use foam, dry
chemical, or carbon dioxide. Water may be ineffective. If water is
the only media available, use in flooding amounts.
Flash Point: 33 deg C ( 91.40 deg F)
Autoignition Temperature: 360 deg C ( 680.00 deg F)
Explosion Limits, Lower:2.2 vol %
Upper: 11.1 vol %
NFPA Rating:
(estimated) Health: 3; Flammability: 3; Instability: 1
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Section 6 - Accidental Release Measures
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General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Wear a self contained breathing
apparatus and appropriate personal protection. (See Exposure
Controls, Personal Protection section). Remove all sources of
ignition. Use a spark-proof tool. Do not let this chemical enter the
environment.
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Section 7 - Handling and Storage
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Handling:
Use spark-proof tools and explosion proof equipment. Do not get in
eyes, on skin, or on clothing. Keep away from heat, sparks and flame.
Do not ingest or inhale. Use and store under nitrogen. Use only in a
chemical fume hood.
Storage:
Keep away from sources of ignition. Store in a cool, dry place.
Store in a tightly closed container. Flammables-area. Store under
nitrogen.
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Section 8 - Exposure Controls, Personal Protection
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Engineering Controls:
Use explosion-proof ventilation equipment. Facilities storing or
utilizing this material should be equipped with an eyewash facility
and a safety shower. Use only under a chemical fume hood.
Exposure Limits
| Chemical Name |
ACGIH |
NIOSH |
OSHA - Final PELs |
| 1,2-Diaminopropane
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none listed
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none listed
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none listed
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OSHA Vacated PELs:
1,2-Diaminopropane:
No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
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Section 9 - Physical and Chemical Properties
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Physical State: Liquid
Appearance: clear, colorless - APHA: 20 max
Odor: none reported
pH: Not available.
Vapor Pressure: 10 mbar @ 20 deg C
Vapor Density: 2.6
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: 119 - 120 deg C @ 760 mmHg
Freezing/Melting Point:-37 deg C
Decomposition Temperature:Not available.
Solubility: Soluble.
Specific Gravity/Density:0.870
Molecular Formula:C3H10N2
Molecular Weight:74.13
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Section 10 - Stability and Reactivity
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Chemical Stability:
Absorbs carbon dioxide from the air. Hygroscopic: absorbs moisture
or water from the air.
Conditions to Avoid:
High temperatures, incompatible materials, ignition sources, exposure
to air, excess heat, exposure to moist air or water.
Incompatibilities with Other Materials:
Acids, acid chlorides, acid anhydrides, mercury.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.
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Section 11 - Toxicological Information
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RTECS#:
CAS# 78-90-0:
TX6650000
LD50/LC50:
CAS# 78-90-0:
Draize test, rabbit,
eye: 87 mg Severe;
Draize test,
rabbit, eye: 750 ug/24H Severe;
Draize test, rabbit, skin: 5 mg/24H
Severe;
Oral, rat: LD50 = 2230
mg/kg;
Skin, rabbit: LD50 = 500
uL/kg;
.
Carcinogenicity:
CAS# 78-90-0:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
Epidemiology:
No information available.
Teratogenicity:
No information available.
Reproductive Effects:
No information available.
Mutagenicity:
No information available.
Neurotoxicity:
No information available.
Other Studies:
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Section 12 - Ecological Information
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Ecotoxicity:
No data available.
No information available.
Environmental:
This chemical is expected to rapidly volatilize into the atmosphere.
Physical:
No information available.
Other:
Do not empty into drains.
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Section 13 - Disposal Considerations
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Chemical waste generators must determine whether a discarded chemical is classified
as a hazardous waste.
US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3.
Additionally, waste generators must consult state and local hazardous waste regulations to
ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
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Section 14 - Transport Information
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US DOT |
Canada TDG |
| Shipping Name: |
1,2-PROPYLENEDIAMINE |
1,2-PROPYLENEDIAMINE |
| Hazard Class: |
8 |
8(3) |
| UN Number: |
UN2258 |
UN2258 |
| Packing Group: |
II |
II |
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Section 15 - Regulatory Information
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US FEDERAL
TSCA
CAS# 78-90-0 is listed on the TSCA inventory.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
None of the chemicals in this product have a TPQ.
SARA Codes
CAS # 78-90-0: immediate, fire.
Section 313
No chemicals are reportable under Section 313.
Clean Air Act:
This material does not contain any hazardous air pollutants.
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals in this product
are listed as Hazardous Substances under the CWA.
None of the chemicals in this
product are listed as Priority Pollutants under the CWA.
None of the chemicals in this
product are listed as Toxic Pollutants under the CWA.
OSHA:
None of the chemicals in this product
are considered highly hazardous by OSHA.
STATE
CAS# 78-90-0 can be found on the
following state right to know lists: New Jersey, Pennsylvania,
Massachusetts.
California Prop 65
California No Significant Risk Level:
None of the chemicals in this product are listed.
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
C
Risk Phrases:
R 10 Flammable.
R 21/22 Harmful in contact with skin and if swallowed.
R 35 Causes severe burns.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately with plenty of
water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face protection.
S 45 In case of accident or if you feel unwell, seek medical advice
immediately (show the label where possible).
WGK (Water Danger/Protection)
CAS# 78-90-0: 1
Canada - DSL/NDSL
CAS# 78-90-0 is listed on Canada's DSL List.
Canada - WHMIS
This product has a WHMIS classification of B2, D1B, E.
This product has been classified in accordance with the hazard
criteria of the Controlled Products Regulations and the MSDS
contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
CAS# 78-90-0 is listed on the Canadian Ingredient Disclosure List.
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Section 16 - Additional Information
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MSDS Creation Date: 2/10/1999
Revision #4 Date: 4/04/2008
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no event shall Fisher be liable
for any claims, losses, or damages of any third party or for lost profits
or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if Fisher has been advised of
the possibility of such damages.
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