Section 1 - Chemical Product and Company Identification |
MSDS Name: Trichloroisocyanuric Acid, 99% (Titr.)
Catalog Numbers:
AC421540000, AC421540010, AC421542500
Synonyms:
Symclosene; 1,3,5-Trichloro-1-Triazine-2,4,6(1H,3H,5H)-Trione.
Company Identification:
Acros Organics N.V.
One Reagent Lane
Fair Lawn, NJ 07410
For information in North America, call: 800-ACROS-01
For emergencies in the US, call CHEMTREC: 800-424-9300
Section 2 - Composition, Information on Ingredients
|
CAS# |
Chemical Name |
Percent |
EINECS/ELINCS |
87-90-1 |
Trichloroisocyanuric Acid |
99 | 201-782-8 |
Section 3 - Hazards Identification
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EMERGENCY OVERVIEW
Appearance: white solid.
Danger! Strong oxidizer. Contact with other
material may cause a fire. May cause severe eye, skin and
respiratory tract irritation with possible burns. Harmful if
swallowed. May cause liver and kidney damage. Hygroscopic (absorbs
moisture from the air).
Target Organs: Kidneys, liver.
Potential Health Effects
Eye:
May cause conjunctivitis. May cause permanent corneal
opacification.
Skin:
May cause severe irritation and possible burns.
Ingestion:
Harmful if swallowed. May cause liver and kidney damage. May cause
nausea, vomiting, and diarrhea, possibly with blood.
Inhalation:
Causes respiratory tract irritation. May cause acute pulmonary
edema, asphyxia, chemical pneumonitis, and upper airway obstruction
caused by edema.
Chronic:
May cause liver and kidney damage. Effects may be delayed.
Section 4 - First Aid Measures
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Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid imme
diately.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Remove
contaminated clothing and shoes.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid immediately. Do NOT induce vomiting. If conscious and alert,
rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen. Do NOT use mouth-to-mouth
resuscitation.
Notes to Physician:
Treat symptomatically and supportively.
Section 5 - Fire Fighting Measures
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General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Strong oxidizer. Contact with other material may
cause fire. During a fire, irritating and highly toxic gases may be
generated by thermal decomposition or combustion. Use water with
caution and in flooding amounts. Contact with acid or acid fumes
evolves heat and flammable vapors. Some oxidizers may react
explosively with hydrocarbons(fuel). May accelerate burning if
involved in a fire. Containers may explode when heated.
Extinguishing Media:
Contact professional fire-fighters immediately. For small fires, do
NOT use dry chemicals, carbon dioxide, halon or foams. USE WATER
ONLY. For large fires flood fire with water from a distance.
Flash Point: 225 deg C ( 437.00 deg F)
Autoignition Temperature: Not available.
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating:
(estimated) Health: 3; Flammability: 0; Instability: 1; Special Hazard: OX
Section 6 - Accidental Release Measures
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General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Avoid runoff into storm sewers and ditches which lead to waterways.
Clean up spills immediately, observing precautions in the Protective
Equipment section. Sweep up, then place into a suitable container for
disposal. Avoid generating dusty conditions. Remove all sources of
ignition. Do not use combustible materials such as paper towels to
clean up spill.
Section 7 - Handling and Storage
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Handling:
Wash thoroughly after handling. Use with adequate ventilation.
Minimize dust generation and accumulation. Keep container tightly
closed. Avoid contact with clothing and other combustible materials.
Do not get on skin or in eyes. Avoid ingestion and inhalation.
Storage:
Keep away from heat, sparks, and flame. Do not store near
combustible materials. Corrosives area. Keep away from acids. Store
protected from moisture.
Section 8 - Exposure Controls, Personal Protection
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Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
Chemical Name |
ACGIH |
NIOSH |
OSHA - Final PELs |
Trichloroisocyanuric Acid
|
none listed
|
none listed
|
none listed
|
OSHA Vacated PELs:
Trichloroisocyanuric Acid:
No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear appropriate clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
Section 9 - Physical and Chemical Properties
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Physical State: Solid
Appearance: white
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Vapor Density: Not available.
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point:249.00 - 251.00 deg C
Decomposition Temperature:225 deg C
Solubility: 1.2 G/100ML (25°C)
Specific Gravity/Density:Not available.
Molecular Formula:C3Cl3N3O3
Molecular Weight:232.41
Section 10 - Stability and Reactivity
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Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, dust generation, acids,
excess heat, combustible materials, reducing agents, strong oxidants,
exposure to moist air or water.
Incompatibilities with Other Materials:
Moisture, reducing agents, acids (mineral, non-oxidizing, e.g.
hydrochloric acid, hydrofluoric acid, muriatic acid, phosphoric
acid), acids (mineral, oxidizing, e.g. chromic acid, hypochlorous
acid, nitric acid, sulfuric acid), acids (organic, e.g. acetic acid,
benzoic acid, formic acid, methanoic acid, oxalic acid).
Hazardous Decomposition Products:
Hydrogen chloride, nitrogen oxides, carbon monoxide, irritating and
toxic fumes and gases, carbon dioxide, nitrogen.
Hazardous Polymerization: Has not been reported.
Section 11 - Toxicological Information
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RTECS#:
CAS# 87-90-1:
XZ1925000
LD50/LC50:
CAS# 87-90-1: Draize test, rabbit,
eye: 500 mg Severe; Draize test,
rabbit, skin: 500 mg/24H Moderate;
Oral, rat: LD50 = 406 mg/kg; .
Carcinogenicity:
CAS# 87-90-1:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
Epidemiology:
No information found
Teratogenicity:
No information found
Reproductive Effects:
No information found
Mutagenicity:
No information found
Neurotoxicity:
No information found
Other Studies:
Section 12 - Ecological Information
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No information available.
Section 13 - Disposal Considerations
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Chemical waste generators must determine whether a discarded chemical is classified
as a hazardous waste.
US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3.
Additionally, waste generators must consult state and local hazardous waste regulations to
ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
Section 14 - Transport Information
|
|
US DOT |
Canada TDG |
Shipping Name: |
TRICHLOROISOCYANURIC ACID, DRY |
TRICHLOROISOCYANURIC ACID,DRY |
Hazard Class: |
5.1 |
5.1 |
UN Number: |
UN2468 |
UN2468 |
Packing Group: |
II |
II |
Section 15 - Regulatory Information
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US FEDERAL
TSCA
CAS# 87-90-1 is listed on the TSCA inventory.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
None of the chemicals in this product have a TPQ.
SARA Codes
CAS # 87-90-1: immediate, fire, reactive.
Section 313
No chemicals are reportable under Section 313.
Clean Air Act:
This material does not contain any hazardous air pollutants.
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals in this product
are listed as Hazardous Substances under the CWA.
None of the chemicals in this
product are listed as Priority Pollutants under the CWA.
None of the chemicals in this
product are listed as Toxic Pollutants under the CWA.
OSHA:
None of the chemicals in this product
are considered highly hazardous by OSHA.
STATE
CAS# 87-90-1 can be found on the
following state right to know lists: New Jersey, Pennsylvania,
Massachusetts.
California Prop 65
California No Significant Risk Level:
None of the chemicals in this product are listed.
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN O
Risk Phrases:
R 22 Harmful if swallowed.
R 31 Contact with acids liberates toxic gas.
R 36/37 Irritating to eyes and respiratory system.
R 8 Contact with combustible material may cause fire.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately with plenty of
water and seek medical advice.
S 41 In case of fire and/or explosion do not breathe fumes.
S 8 Keep container dry.
WGK (Water Danger/Protection)
CAS# 87-90-1: No information available.
Canada - DSL/NDSL
CAS# 87-90-1 is listed on Canada's DSL List.
Canada - WHMIS
not available.
This product has been classified in accordance with the hazard
criteria of the Controlled Products Regulations and the MSDS
contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
CAS# 87-90-1 is listed on the Canadian Ingredient Disclosure List.
Section 16 - Additional Information
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MSDS Creation Date: 8/24/1997 Revision #5 Date: 10/03/2005
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no event shall Fisher be liable
for any claims, losses, or damages of any third party or for lost profits
or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if Fisher has been advised of
the possibility of such damages.
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